{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T04:08:27Z","timestamp":1785730107631,"version":"3.56.0"},"reference-count":40,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2021,10,1]],"date-time":"2021-10-01T00:00:00Z","timestamp":1633046400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2021,10,1]],"date-time":"2021-10-01T00:00:00Z","timestamp":1633046400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2022,5,21]],"date-time":"2022-05-21T00:00:00Z","timestamp":1653091200000},"content-version":"am","delay-in-days":232,"URL":"http:\/\/www.elsevier.com\/open-access\/userlicense\/1.0\/"},{"start":{"date-parts":[[2021,10,1]],"date-time":"2021-10-01T00:00:00Z","timestamp":1633046400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2021,10,1]],"date-time":"2021-10-01T00:00:00Z","timestamp":1633046400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2021,10,1]],"date-time":"2021-10-01T00:00:00Z","timestamp":1633046400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2021,10,1]],"date-time":"2021-10-01T00:00:00Z","timestamp":1633046400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2021,10,1]],"date-time":"2021-10-01T00:00:00Z","timestamp":1633046400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/100014103","name":"Key Technology Research and Development Program of Shandong","doi-asserted-by":"publisher","award":["2020C03085"],"award-info":[{"award-number":["2020C03085"]}],"id":[{"id":"10.13039\/100014103","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21576241"],"award-info":[{"award-number":["21576241"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Chemosphere"],"published-print":{"date-parts":[[2021,10]]},"DOI":"10.1016\/j.chemosphere.2021.130913","type":"journal-article","created":{"date-parts":[[2021,5,17]],"date-time":"2021-05-17T05:29:07Z","timestamp":1621229347000},"page":"130913","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":12,"special_numbering":"C","title":["Enhanced dechlorination of an enzyme-catalyzed electrolysis system by ionic liquids: Electron transfer, enzyme activity and dichloromethane diffusion"],"prefix":"10.1016","volume":"281","author":[{"given":"Meng","family":"Wu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Hu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuexin","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuwei","family":"Tang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanhong","family":"Guan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zimo","family":"Lou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiliang","family":"Yu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianming","family":"Yu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.chemosphere.2021.130913_bib1","doi-asserted-by":"crossref","first-page":"484","DOI":"10.1016\/j.tsf.2018.06.055","article-title":"Fabrication and characterization of cytochrome c-immobilized polyaniline\/multi-walled carbon nanotube composite thin film layers for biosensor applications","volume":"660","author":"Aghamiria","year":"2018","journal-title":"Thin Solid Films"},{"key":"10.1016\/j.chemosphere.2021.130913_bib2","doi-asserted-by":"crossref","first-page":"552","DOI":"10.1038\/s41563-019-0598-7","article-title":"Molecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes","volume":"19","author":"Bi","year":"2020","journal-title":"Nat. Mater."},{"key":"10.1016\/j.chemosphere.2021.130913_bib3","doi-asserted-by":"crossref","first-page":"1602","DOI":"10.1016\/j.jhazmat.2009.08.033","article-title":"Effects of electrokinetic treatment of a heavy metal contaminated soil on soil enzyme activities","volume":"172","author":"Cang","year":"2009","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.chemosphere.2021.130913_bib4","first-page":"8887","article-title":"Protein denaturation by ionic liquids and the Hofmeister series: a case study of aqueous solutions of ribonuclease A","volume":"46","author":"Constantinescu","year":"2007"},{"key":"10.1016\/j.chemosphere.2021.130913_bib5","doi-asserted-by":"crossref","DOI":"10.1371\/journal.pone.0143647","article-title":"Structural analysis and aggregation propensity of pyroglutamate A\u03b2(3-40) in aqueous trifluoroethanol","author":"Dammers","year":"2015","journal-title":"PLoS One 10"},{"key":"10.1016\/j.chemosphere.2021.130913_bib6","doi-asserted-by":"crossref","first-page":"341","DOI":"10.1590\/S0103-50532004000300002","article-title":"On the solid, liquid and solution structural organization of imidazolium ionic liquids","volume":"15","author":"Dupont","year":"2004","journal-title":"J. Braz. Chem. Soc."},{"key":"10.1016\/j.chemosphere.2021.130913_bib7","doi-asserted-by":"crossref","first-page":"150","DOI":"10.1016\/j.molliq.2017.12.050","article-title":"Ionic liquids as a potential solvent for lipase-catalysed reactions: a review","volume":"251","author":"Elgharbawy","year":"2018","journal-title":"J. Mol. Liq."},{"key":"10.1016\/j.chemosphere.2021.130913_bib8","first-page":"128","article-title":"Spectroscopic studies on the inhibitory effects of ionic liquids on lipase activity","volume":"159","author":"Fan","year":"2016","journal-title":"Acta: Mol. Biomol. Spectrosc"},{"key":"10.1016\/j.chemosphere.2021.130913_bib9","doi-asserted-by":"crossref","first-page":"592","DOI":"10.1007\/s12010-012-9801-x","article-title":"Fluorescence spectroscopic analysis of the interaction of papain with ionic liquids","volume":"168","author":"Fan","year":"2012","journal-title":"Appl. Biochem. Biotechnol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib10","first-page":"2541","volume":"18","author":"Gonzalo","year":"2007","journal-title":"Asymmetric biocatalytic reduction of ketones using hydroxy-functionalised water-miscible ionic liquids as solvents. Tetrahedron: Asymmetr"},{"key":"10.1016\/j.chemosphere.2021.130913_bib11","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1016\/j.elecom.2016.03.013","article-title":"Mutation of heme c axial ligands in d-fructose dehydrogenase for investigation of electron transfer pathways and reduction of overpotential in direct electron transfer-type bioelectrocatalysis","volume":"67","author":"Hibino","year":"2016","journal-title":"Electrochem. Commun."},{"key":"10.1016\/j.chemosphere.2021.130913_bib12","doi-asserted-by":"crossref","first-page":"21353","DOI":"10.3390\/ijms141121353","article-title":"Homogeneous liquid-liquid extraction of rare earths with the betaine-betainium bis(trifluoromethylsulfonyl) imide ionic liquid system","volume":"14","author":"Hoogerstraete","year":"2013","journal-title":"Int. J. Mol. Sci."},{"key":"10.1016\/j.chemosphere.2021.130913_bib13","doi-asserted-by":"crossref","first-page":"19","DOI":"10.1016\/j.molcatb.2008.01.006","article-title":"Enzymatic ketone reductions with co-factor recycling: improved reactions with ionic liquid co-solvents","volume":"55","author":"Hussain","year":"2008","journal-title":"J. Mol. Catal. B Enzym."},{"key":"10.1016\/j.chemosphere.2021.130913_bib14","doi-asserted-by":"crossref","first-page":"7522","DOI":"10.1021\/acs.jpcb.8b04661","article-title":"Effect of imidazolium-based ionic liquids on the structure and stability of stem bromelain: concentration and alkyl chain length effect","volume":"122","author":"Jha","year":"2018","journal-title":"J. Phys. Chem. B"},{"key":"10.1016\/j.chemosphere.2021.130913_bib15","first-page":"28","article-title":"The electron transfer pathway in direct electrochemical communication of fructose dehydrogenase with electrodes. Electrochem","volume":"38","author":"Kawai","year":"2014","journal-title":"Commun. Now."},{"key":"10.1016\/j.chemosphere.2021.130913_bib16","doi-asserted-by":"crossref","first-page":"1649","DOI":"10.1039\/C0CP01509A","article-title":"On the different roles of anions and cations in the solvation of enzymes in ionic liquids","volume":"13","author":"Klahn","year":"2011","journal-title":"Phys. Chem. Chem. Phys."},{"key":"10.1016\/j.chemosphere.2021.130913_bib17","doi-asserted-by":"crossref","first-page":"676","DOI":"10.1128\/jb.162.2.676-681.1985","article-title":"Dichloromethane dehalogenase of Hyphomicrobium sp. strain DM2","volume":"162","author":"Kohler-Staub","year":"1985","journal-title":"J. Bacteriol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib18","doi-asserted-by":"crossref","first-page":"995","DOI":"10.1002\/cssc.201100835","article-title":"Enzymatic versus microbial bio-catalyzed electrodes in bio-electrochemical systems","volume":"5","author":"Lapinsonniere","year":"2012","journal-title":"ChemSusChem"},{"key":"10.1016\/j.chemosphere.2021.130913_bib19","doi-asserted-by":"crossref","first-page":"19","DOI":"10.1016\/S0022-0728(79)80075-3","article-title":"General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems","volume":"101","author":"Laviron","year":"1979","journal-title":"J. Electroanal. Chem."},{"key":"10.1016\/j.chemosphere.2021.130913_bib20","first-page":"769","article-title":"Effect of imidazolium ionic liquids on the hydrolytic activity of lipase. Chinese J","volume":"34","author":"Li","year":"2013","journal-title":"Catal"},{"key":"10.1016\/j.chemosphere.2021.130913_bib21","doi-asserted-by":"crossref","first-page":"630","DOI":"10.1021\/es00064a001","article-title":"Groundwater contamination: pump-and-treat remediation","volume":"23","author":"Mackay","year":"1989","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib22","doi-asserted-by":"crossref","first-page":"122","DOI":"10.1016\/j.cej.2014.03.035","article-title":"Tandem Knoevenagel\u2013Michael cyclocondensation reaction of malononitrile, various aldehydes and 2-naphthol over acetic acid functionalized ionic liquid","volume":"248","author":"Moosavi-Zare","year":"2014","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.chemosphere.2021.130913_bib23","doi-asserted-by":"crossref","first-page":"555","DOI":"10.1016\/j.ijbiomac.2012.06.020","article-title":"Effect of ionic liquid on activity, stability, and structure of enzymes: a review","volume":"51","author":"Naushad","year":"2012","journal-title":"Int. J. Biol. Macromol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib24","doi-asserted-by":"crossref","first-page":"3087","DOI":"10.1016\/j.bios.2011.01.004","article-title":"Recent progress and continuing challenges in bio-fuel cells. Part I: enzymatic cells","volume":"26","author":"Osman","year":"2011","journal-title":"Biosens. Bioelectron."},{"key":"10.1016\/j.chemosphere.2021.130913_bib25","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1021\/bi00504a006","article-title":"Estimation of globular protein secondary structure from circular dichroism","volume":"20","author":"Provencher","year":"1981","journal-title":"Biochemistry"},{"key":"10.1016\/j.chemosphere.2021.130913_bib26","doi-asserted-by":"crossref","first-page":"9699","DOI":"10.1021\/acs.est.5b02542","article-title":"Characterization of resistances of a capacitive deionization system","volume":"49","author":"Qu","year":"2015","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib27","doi-asserted-by":"crossref","first-page":"8923","DOI":"10.1016\/j.biortech.2010.06.161","article-title":"Ionic liquids: applications and future trends in bioreactor technology","volume":"101","author":"Quijano","year":"2010","journal-title":"Bioresour. Technol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib28","doi-asserted-by":"crossref","first-page":"2145","DOI":"10.1021\/je0602824","article-title":"Temperature and composition dependence of the density and viscosity of binary mixtures of water + ionic liquid","volume":"51","author":"Rodr\u00edguez","year":"2006","journal-title":"J. Chem. Eng. Data"},{"key":"10.1016\/j.chemosphere.2021.130913_bib29","doi-asserted-by":"crossref","first-page":"607","DOI":"10.1007\/s00253-008-1730-9","article-title":"Ionic liquids in biotechnology: applications and perspectives for biotransformations","volume":"81","author":"Roosen","year":"2008","journal-title":"Appl. Microbiol. Biotechnol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib30","first-page":"625","volume":"191","author":"Saadatia","year":"2014","journal-title":"Direct electron transfer and electrocatalytic properties of immobilized hemoglobin onto glassy carbon electrode modified with ionic-liquid\/titanium-nitride nanoparticles: application to nitrite detection. Sensor. Actuat. B: Chem."},{"key":"10.1016\/j.chemosphere.2021.130913_bib31","doi-asserted-by":"crossref","first-page":"14528","DOI":"10.1021\/acs.est.9b04148","article-title":"Degradation of perfluorooctanesulfonate by reactive electrochemical membrane composed of magn\u00e9li phase titanium suboxide SI","volume":"53","author":"Shi","year":"2019","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib32","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.molcatb.2009.03.008","article-title":"Biocatalytic reactions in hydrophobic ionic liquids","volume":"60","author":"Sureshkumar","year":"2009","journal-title":"J. Mol. Catal. B Enzym."},{"key":"10.1016\/j.chemosphere.2021.130913_bib33","doi-asserted-by":"crossref","first-page":"233","DOI":"10.1134\/S0003683809030016","article-title":"The aerobic degradation of dichloromethane: structural-functional aspects (a review)","volume":"45","author":"Trotsenko","year":"2009","journal-title":"Appl. Biochem. Microbiol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib34","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1038\/373580a0","article-title":"Crystal structure of the nickel-iron hydrogenase from Desulfovibrio gigas","volume":"373","author":"Volbeda","year":"1995","journal-title":"Nature"},{"key":"10.1016\/j.chemosphere.2021.130913_bib35","doi-asserted-by":"crossref","first-page":"1281","DOI":"10.1007\/s11434-016-1151-6","article-title":"Recent advances in ionic liquid-based electrochemical biosensors","volume":"61","author":"Wang","year":"2016","journal-title":"Sci. Bull."},{"key":"10.1016\/j.chemosphere.2021.130913_bib36","doi-asserted-by":"crossref","first-page":"9509","DOI":"10.1021\/acs.chemrev.9b00115","article-title":"Tackling the challenges of enzymatic (bio)fuel cells","volume":"119","author":"Xiao","year":"2019","journal-title":"Chem. Rev."},{"key":"10.1016\/j.chemosphere.2021.130913_bib37","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1016\/j.jbiotec.2009.04.011","article-title":"Hofmeister effects: an explanation for the impact of ionic liquids on biocatalysis","volume":"144","author":"Yang","year":"2009","journal-title":"J. Biotechnol."},{"key":"10.1016\/j.chemosphere.2021.130913_bib38","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1016\/j.molcatb.2013.02.009","article-title":"A comparative study: immobilization of yeast cells and invertase in poly(ethyleneoxide) electrodes","volume":"91","author":"Yildiz","year":"2013","journal-title":"J. Mol. Catal. B Enzym."},{"key":"10.1016\/j.chemosphere.2021.130913_bib39","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1016\/j.jes.2019.05.029","article-title":"Enzyme-electrolytic degradation of dichloromethane: efficiency, kinetics and mechanism","volume":"86","author":"Yu","year":"2019","journal-title":"J. Environ. Sci."},{"key":"10.1016\/j.chemosphere.2021.130913_bib40","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.molcatb.2005.10.003","article-title":"Enhancement of enantioselectivity in lipase-catalyzed resolution of N-(2-ethyl-6-methylphenyl)alanine by additives","volume":"38","author":"Zheng","year":"2006","journal-title":"J. Mol. Catal. B Enzym."}],"container-title":["Chemosphere"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653521013849?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653521013849?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T20:45:38Z","timestamp":1753908338000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0045653521013849"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,10]]},"references-count":40,"alternative-id":["S0045653521013849"],"URL":"https:\/\/doi.org\/10.1016\/j.chemosphere.2021.130913","relation":{},"ISSN":["0045-6535"],"issn-type":[{"value":"0045-6535","type":"print"}],"subject":[],"published":{"date-parts":[[2021,10]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Enhanced dechlorination of an enzyme-catalyzed electrolysis system by ionic liquids: Electron transfer, enzyme activity and dichloromethane diffusion","name":"articletitle","label":"Article Title"},{"value":"Chemosphere","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.chemosphere.2021.130913","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2021 Elsevier Ltd. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"130913"}}