{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T07:18:47Z","timestamp":1785914327564,"version":"3.56.0"},"reference-count":99,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T00:00:00Z","timestamp":1667260800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T00:00:00Z","timestamp":1667260800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T00:00:00Z","timestamp":1667260800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T00:00:00Z","timestamp":1667260800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T00:00:00Z","timestamp":1667260800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T00:00:00Z","timestamp":1667260800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2022,11,1]],"date-time":"2022-11-01T00:00:00Z","timestamp":1667260800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Chemosphere"],"published-print":{"date-parts":[[2022,11]]},"DOI":"10.1016\/j.chemosphere.2022.135520","type":"journal-article","created":{"date-parts":[[2022,6,30]],"date-time":"2022-06-30T12:39:20Z","timestamp":1656592760000},"page":"135520","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":59,"special_numbering":"C","title":["Remediation of pharmaceutical pollutants using graphene-based materials - A review on operating conditions, mechanism and toxicology"],"prefix":"10.1016","volume":"306","author":[{"given":"S.","family":"Akash","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baskaran","family":"Sivaprakash","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5015-0694","authenticated-orcid":false,"given":"Natarajan","family":"Rajamohan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Muthusamy","family":"Govarthanan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"B.Tamil","family":"Elakiya","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.chemosphere.2022.135520_bib2","doi-asserted-by":"crossref","first-page":"733","DOI":"10.1016\/j.molliq.2017.06.068","article-title":"Removal of non-steroidal anti-inflammatory drugs from water using high surface area nanographene: kinetic and thermodynamic studies","volume":"241","author":"Al-Khateeb","year":"2017","journal-title":"J. Mol. Liq."},{"issue":"10","key":"10.1016\/j.chemosphere.2022.135520_bib3","doi-asserted-by":"crossref","first-page":"1620","DOI":"10.3390\/polym13101620","article-title":"Predicting the adsorption of amoxicillin and ibuprofen on chitosan and graphene oxide materials: a density functional theory study","volume":"13","author":"Anchique","year":"2021","journal-title":"Polymers"},{"key":"10.1016\/j.chemosphere.2022.135520_bib4","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/j.polymer.2018.03.005","article-title":"Comparison of mechanical, electrical and thermal properties in graphene oxide and reduced graphene oxide filled epoxy nanocomposite adhesives","volume":"141","author":"Aradhana","year":"2018","journal-title":"Polymer"},{"issue":"23\u201324","key":"10.1016\/j.chemosphere.2022.135520_bib5","doi-asserted-by":"crossref","first-page":"3703","DOI":"10.1080\/00268976.2019.1662129","article-title":"Molecular simulations of phenol and ibuprofen removal from water using multilayered graphene oxide membranes","volume":"117","author":"Bahamon","year":"2019","journal-title":"Mol. Phys."},{"key":"10.1016\/j.chemosphere.2022.135520_bib6","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1016\/j.psep.2016.01.021","article-title":"Application of graphene oxide nanoplatelets for adsorption of ibuprofen from aqueous solutions: evaluation of process kinetics and thermodynamics","volume":"101","author":"Banerjee","year":"2016","journal-title":"Process Saf. Environ. Protect."},{"key":"10.1016\/j.chemosphere.2022.135520_bib8","article-title":"Remediation of emerging metal pollutants using environment friendly biochar-Review on applications and mechanism","volume":"133384","author":"Berslin","year":"2021","journal-title":"Chemosphere"},{"issue":"6217","key":"10.1016\/j.chemosphere.2022.135520_bib10","doi-asserted-by":"crossref","DOI":"10.1126\/science.1246501","article-title":"Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage","volume":"347","author":"Bonaccorso","year":"2015","journal-title":"Science"},{"key":"10.1016\/j.chemosphere.2022.135520_bib11","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2020.148400","article-title":"Magnetic core-shell MnFe2O4@ TiO2 nanoparticles decorated on reduced graphene oxide as a novel adsorbent for the removal of ciprofloxacin and Cu (II) from water","volume":"541","author":"Chang","year":"2021","journal-title":"Appl. Surf. Sci."},{"issue":"10","key":"10.1016\/j.chemosphere.2022.135520_bib12","doi-asserted-by":"crossref","first-page":"2898","DOI":"10.1002\/slct.201803512","article-title":"Green synthesis of graphene quantum dots from cotton cellulose","volume":"4","author":"Chen","year":"2019","journal-title":"ChemistrySelect"},{"issue":"14","key":"10.1016\/j.chemosphere.2022.135520_bib13","doi-asserted-by":"crossref","first-page":"6065","DOI":"10.1007\/s10853-020-04413-z","article-title":"CdS\u2013Bi2MoO6\/RGO nanocomposites for efficient degradation of ciprofloxacin under visible light","volume":"55","author":"Chen","year":"2020","journal-title":"J. Mater. Sci."},{"key":"10.1016\/j.chemosphere.2022.135520_bib14","doi-asserted-by":"crossref","first-page":"94","DOI":"10.1016\/j.colsurfb.2019.03.043","article-title":"Green synthesis of Pluronic stabilized reduced graphene oxide: chemical and biological characterization","volume":"179","author":"Cherian","year":"2019","journal-title":"Colloids Surf. B Biointerfaces"},{"key":"10.1016\/j.chemosphere.2022.135520_bib15","doi-asserted-by":"crossref","first-page":"549","DOI":"10.1016\/j.chemosphere.2018.03.117","article-title":"Ciprofloxacin-metal complexes\u2013stability and toxicity tests in the presence of humic substances","volume":"202","author":"Cuprys","year":"2018","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2022.135520_bib16","doi-asserted-by":"crossref","DOI":"10.1016\/j.scitotenv.2020.138288","article-title":"Multi-omics analyses reveal molecular mechanisms for the antagonistic toxicity of carbon nanotubes and ciprofloxacin to Escherichia coli","volume":"726","author":"Deng","year":"2020","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.chemosphere.2022.135520_bib17","doi-asserted-by":"crossref","first-page":"690","DOI":"10.1016\/j.carbon.2019.11.041","article-title":"Green synthesis of chemical converted graphene sheets derived from pulping black liquor","volume":"158","author":"Ding","year":"2020","journal-title":"Carbon"},{"key":"10.1016\/j.chemosphere.2022.135520_bib18","doi-asserted-by":"crossref","first-page":"113","DOI":"10.1016\/j.chemosphere.2018.05.148","article-title":"Ferrocene functionalized graphene based electrode for the electro\u2212 Fenton oxidation of ciprofloxacin","volume":"209","author":"Divyapriya","year":"2018","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2022.135520_bib19","doi-asserted-by":"crossref","first-page":"858","DOI":"10.1016\/j.electacta.2018.06.186","article-title":"Highly active and stable ferrocene functionalized graphene encapsulated carbon felt array-A novel rotating disc electrode for electro-Fenton oxidation of pharmaceutical compounds","volume":"283","author":"Divyapriya","year":"2018","journal-title":"Electrochim. Acta"},{"issue":"3","key":"10.1016\/j.chemosphere.2022.135520_bib20","doi-asserted-by":"crossref","first-page":"3453","DOI":"10.1021\/acssuschemeng.7b03687","article-title":"Green approach to produce a graphene thin film on a conductive LCD matrix for the oxidative transformation of ciprofloxacin","volume":"6","author":"Divyapriya","year":"2018","journal-title":"ACS Sustain. Chem. Eng."},{"key":"10.1016\/j.chemosphere.2022.135520_bib21","doi-asserted-by":"crossref","first-page":"577","DOI":"10.1016\/j.ultsonch.2015.10.010","article-title":"Use of hydrodynamic cavitation in (waste) water treatment","volume":"29","author":"Dular","year":"2016","journal-title":"Ultrason. Sonochem."},{"key":"10.1016\/j.chemosphere.2022.135520_bib22","doi-asserted-by":"crossref","DOI":"10.1016\/j.ecoenv.2019.109892","article-title":"A toxicological study on photo-degradation products of environmental ibuprofen: ecological and human health implications","volume":"188","author":"Ellepola","year":"2020","journal-title":"Ecotoxicol. Environ. Saf."},{"issue":"4","key":"10.1016\/j.chemosphere.2022.135520_bib24","doi-asserted-by":"crossref","DOI":"10.1371\/journal.pone.0231045","article-title":"Valorization of biomass into amine-functionalized bio graphene for efficient ciprofloxacin adsorption in water-modeling and optimization study","volume":"15","author":"Ghadiri","year":"2020","journal-title":"PLoS One"},{"key":"10.1016\/j.chemosphere.2022.135520_bib25","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1016\/j.carbpol.2018.02.021","article-title":"Continuous flow adsorption of ciprofloxacin by using a nanostructured chitin\/graphene oxide hybrid material","volume":"188","author":"Gonz\u00e1lez","year":"2018","journal-title":"Carbohydr. Polym."},{"key":"10.1016\/j.chemosphere.2022.135520_bib26","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2021.119605","article-title":"Graphene-boron nitride composite aerogel: a high efficiency adsorbent for ciprofloxacin removal from water","volume":"278","author":"Han","year":"2021","journal-title":"Separ. Purif. Technol."},{"key":"10.1016\/j.chemosphere.2022.135520_bib28","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1016\/j.catcom.2018.12.006","article-title":"A novel 3D-structured flower-like bismuth tungstate\/mag-graphene nanoplates composite with excellent visible-light photocatalytic activity for ciprofloxacin degradation","volume":"121","author":"Hou","year":"2019","journal-title":"Catal. Commun."},{"key":"10.1016\/j.chemosphere.2022.135520_bib29","doi-asserted-by":"crossref","DOI":"10.1016\/j.envpol.2021.117310","article-title":"A novel modified Fe\u2013Mn binary oxide graphite felt (FMBO-GF) cathode in a neutral electro-Fenton system for ciprofloxacin degradation","volume":"286","author":"Huang","year":"2021","journal-title":"Environ. Pollut."},{"key":"10.1016\/j.chemosphere.2022.135520_bib30","doi-asserted-by":"crossref","DOI":"10.1016\/j.scitotenv.2020.137560","article-title":"Effect of Fe2+, Mn2+ catalysts on the performance of electro-Fenton degradation of antibiotic ciprofloxacin, and expanding the utilizing of acid mine drainage","volume":"720","author":"Huang","year":"2020","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.chemosphere.2022.135520_bib31","doi-asserted-by":"crossref","DOI":"10.1016\/j.colsurfa.2020.124758","article-title":"Fabrication of a ternary BiOCl\/CQDs\/rGO photocatalyst: the roles of CQDs and rGO in adsorption-photocatalytic removal of ciprofloxacin","volume":"597","author":"Huang","year":"2020","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"10.1016\/j.chemosphere.2022.135520_bib32","doi-asserted-by":"crossref","DOI":"10.1021\/acs.langmuir.0c00654","article-title":"Preparation of 3D porous graphene oxide-kaolinite-poly (vinyl alcohol) composite for efficient adsorption and removal of ciprofloxacin","author":"Huang","year":"2020","journal-title":"Langmuir: ACS J. Surf. Colloids"},{"issue":"11","key":"10.1016\/j.chemosphere.2022.135520_bib33","doi-asserted-by":"crossref","DOI":"10.1371\/journal.pone.0260032","article-title":"Response of Rhodococcus cerastii IEGM 1278 to toxic effects of ibuprofen","volume":"16","author":"Ivshina","year":"2021","journal-title":"PLoS One"},{"issue":"15","key":"10.1016\/j.chemosphere.2022.135520_bib34","doi-asserted-by":"crossref","first-page":"3667","DOI":"10.1007\/s00216-014-7614-1","article-title":"Elucidation of transformation pathway of ketoprofen, ibuprofen, and furosemide in surface water and their occurrence in the aqueous environment using UHPLC-QTOF-MS","volume":"406","author":"Jakimska","year":"2014","journal-title":"Anal. Bioanal. Chem."},{"key":"10.1016\/j.chemosphere.2022.135520_bib35","doi-asserted-by":"crossref","DOI":"10.1016\/j.envint.2020.106265","article-title":"Influence of ibuprofen and its biotransformation products on different biological sludge systems and ecosystem","volume":"146","author":"Jia","year":"2021","journal-title":"Environ. Int."},{"key":"10.1016\/j.chemosphere.2022.135520_bib36","series-title":"Pharma-ecology: the Occurrence and Fate of Pharmaceuticals and Personal Care Products in the Environment","author":"Jjemba","year":"2018"},{"key":"10.1016\/j.chemosphere.2022.135520_bib37","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2020.125440","article-title":"Nanostructured porous graphene for efficient removal of emerging contaminants (pharmaceuticals) from water","volume":"398","author":"Khalil","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.chemosphere.2022.135520_bib38","doi-asserted-by":"crossref","DOI":"10.1016\/j.compositesb.2019.107120","article-title":"Synthesis of TiO2\/Graphene oxide nanocomposites for their enhanced photocatalytic activity against methylene blue dye and ciprofloxacin","volume":"175","author":"Khan","year":"2019","journal-title":"Compos. B Eng."},{"issue":"6","key":"10.1016\/j.chemosphere.2022.135520_bib39","doi-asserted-by":"crossref","first-page":"1531","DOI":"10.1007\/s10653-019-00392-6","article-title":"Ecological impact of the antibiotic ciprofloxacin on microbial community of aerobic activated sludge","volume":"42","author":"Kim","year":"2020","journal-title":"Environ. Geochem. Health"},{"key":"10.1016\/j.chemosphere.2022.135520_bib40","doi-asserted-by":"crossref","DOI":"10.1016\/j.msec.2020.110777","article-title":"Photocatalytic, fluorescent BiPO4@ Graphene oxide based magnetic molecularly imprinted polymer for detection, removal and degradation of ciprofloxacin","volume":"111","author":"Kumar","year":"2020","journal-title":"Mater. Sci. Eng. C"},{"key":"10.1016\/j.chemosphere.2022.135520_bib41","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2020.124621","article-title":"BiVO4 prepared by the sol\u2013gel doped on graphite felt cathode for ciprofloxacin degradation and mechanism in solar-photo-electro-Fenton","volume":"408","author":"Lai","year":"2021","journal-title":"J. Hazard Mater."},{"issue":"11","key":"10.1016\/j.chemosphere.2022.135520_bib42","doi-asserted-by":"crossref","first-page":"934","DOI":"10.3390\/nano8110934","article-title":"Synthesis of reduced graphene oxide\/titanium dioxide nanotubes (rGO\/TNT) composites as an electrical double layer capacitor","volume":"8","author":"Lazarte","year":"2018","journal-title":"Nanomaterials"},{"key":"10.1016\/j.chemosphere.2022.135520_bib43","doi-asserted-by":"crossref","DOI":"10.1016\/j.matchemphys.2020.123650","article-title":"Bi2Ti2O7\/TiO2\/RGO composite for the simulated sunlight-driven photocatalytic degradation of ciprofloxacin","volume":"256","author":"Li","year":"2020","journal-title":"Mater. Chem. Phys."},{"key":"10.1016\/j.chemosphere.2022.135520_bib44","doi-asserted-by":"crossref","first-page":"6","DOI":"10.1016\/j.jelechem.2016.11.057","article-title":"Synergistic degradation of antimicrobial agent ciprofloxacin in water by using 3D CeO2\/RGO composite as cathode in electro-Fenton system","volume":"784","author":"Li","year":"2017","journal-title":"J. Electroanal. Chem."},{"issue":"2","key":"10.1016\/j.chemosphere.2022.135520_bib45","first-page":"425","article-title":"Efficient mineralization of ciprofloxacin using a 3D Ce x Zr 1\u2212 x O 2\/RGO composite cathode","volume":"4","author":"Li","year":"2017","journal-title":"Environ. Sci.: Nano"},{"issue":"1","key":"10.1016\/j.chemosphere.2022.135520_bib46","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1016\/j.colsurfb.2011.07.011","article-title":"A mechanistic study of ciprofloxacin removal by kaolinite","volume":"88","author":"Li","year":"2011","journal-title":"Colloids Surf. B Biointerfaces"},{"key":"10.1016\/j.chemosphere.2022.135520_bib47","doi-asserted-by":"crossref","first-page":"237","DOI":"10.1016\/j.jcis.2019.01.011","article-title":"Constructing high-efficiency photocatalyst for degrading ciprofloxacin: three-dimensional visible light driven graphene based NiAlFe LDH","volume":"540","author":"Liang","year":"2019","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2022.135520_bib48","article-title":"Biocompatible synthesis of reduced graphene oxide from Euphorbia heterophylla (L.) and their in-vitro cytotoxicity against human cancer cell lines","volume":"24","author":"Lingaraju","year":"2019","journal-title":"Biotechnol. Rep."},{"key":"10.1016\/j.chemosphere.2022.135520_bib49","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1016\/j.carbpol.2019.05.060","article-title":"Removal of pharmaceuticals by novel magnetic genipin-crosslinked chitosan\/graphene oxide-SO3H composite","volume":"220","author":"Liu","year":"2019","journal-title":"Carbohydr. Polym."},{"issue":"17","key":"10.1016\/j.chemosphere.2022.135520_bib50","doi-asserted-by":"crossref","first-page":"6475","DOI":"10.1016\/j.watres.2013.08.024","article-title":"EU-wide monitoring survey on emerging polar organic contaminants in wastewater treatment plant effluents","volume":"47","author":"Loos","year":"2013","journal-title":"Water Res."},{"issue":"9","key":"10.1016\/j.chemosphere.2022.135520_bib51","doi-asserted-by":"crossref","first-page":"1921","DOI":"10.3390\/polym12091921","article-title":"Preparation of cross-linked graphene oxide on polyethersulfone membrane for pharmaceuticals and personal care products removal","volume":"12","author":"Lou","year":"2020","journal-title":"Polymers"},{"issue":"11","key":"10.1016\/j.chemosphere.2022.135520_bib52","doi-asserted-by":"crossref","first-page":"1409","DOI":"10.3390\/mi12111409","article-title":"Recent progress in nanomaterials modified electrochemical biosensors for the detection of MicroRNA","volume":"12","author":"Low","year":"2021","journal-title":"Micromachines"},{"key":"10.1016\/j.chemosphere.2022.135520_bib53","doi-asserted-by":"crossref","first-page":"444","DOI":"10.1016\/j.chemosphere.2018.10.065","article-title":"Construction of Z-Scheme g-C3N4\/RGO\/WO3 with in situ photoreduced graphene oxide as electron mediator for efficient photocatalytic degradation of ciprofloxacin","volume":"215","author":"Lu","year":"2019","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2022.135520_bib54","doi-asserted-by":"crossref","DOI":"10.1016\/j.chemosphere.2019.125188","article-title":"Enhanced adsorption for the removal of antibiotics by carbon nanotubes\/graphene oxide\/sodium alginate triple-network nanocomposite hydrogels in aqueous solutions","volume":"242","author":"Ma","year":"2020","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2022.135520_bib55","doi-asserted-by":"crossref","first-page":"230","DOI":"10.1016\/j.carbpol.2016.02.057","article-title":"Graphene oxide\/chitin nanofibril composite foams as column adsorbents for aqueous pollutants","volume":"144","author":"Ma","year":"2016","journal-title":"Carbohydr. Polym."},{"key":"10.1016\/j.chemosphere.2022.135520_bib56","doi-asserted-by":"crossref","DOI":"10.1155\/2021\/6681710","article-title":"A novel and simplest green synthesis method of reduced graphene oxide using methanol extracted Vernonia Amygdalina: large-scale production","volume":"2021","author":"Meka Chufa","year":"2021","journal-title":"Adv. Condens. Matter Phys."},{"key":"10.1016\/j.chemosphere.2022.135520_bib57","doi-asserted-by":"crossref","first-page":"365","DOI":"10.1016\/j.jhazmat.2018.12.074","article-title":"Enhanced catalytic degradation by using RGO-Ce\/WO3 nanosheets modified CF as electro-Fenton cathode: influence factors, reaction mechanism and pathways","volume":"367","author":"Mi","year":"2019","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.chemosphere.2022.135520_bib58","doi-asserted-by":"crossref","first-page":"371","DOI":"10.1016\/j.cattod.2019.03.013","article-title":"RGO\/MoS2\/Ce0. 75Zr0. 25O2 electro-Fenton cathode with higher matching and complementarity for efficient degradation of ciprofloxacin","volume":"339","author":"Mi","year":"2020","journal-title":"Catal. Today"},{"issue":"3","key":"10.1016\/j.chemosphere.2022.135520_bib59","doi-asserted-by":"crossref","first-page":"1226","DOI":"10.1007\/s10904-018-0782-2","article-title":"Equilibrium, kinetic and thermodynamic study of magnetic polyaniline\/graphene oxide based nanocomposites for ciprofloxacin removal from water","volume":"28","author":"Mohammadi Nodeh","year":"2018","journal-title":"J. Inorg. Organomet. Polym. Mater."},{"key":"10.1016\/j.chemosphere.2022.135520_bib60","first-page":"1","article-title":"Green remediation of pharmaceutical wastes using biochar: a review","author":"Monisha","year":"2021","journal-title":"Environ. Chem. Lett."},{"key":"10.1016\/j.chemosphere.2022.135520_bib61","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2019.143655","article-title":"Ultrathin BiOCl\/nitrogen-doped graphene quantum dots composites with strong adsorption and effective photocatalytic activity for the degradation of antibiotic ciprofloxacin","volume":"496","author":"Mou","year":"2019","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.chemosphere.2022.135520_bib62","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1016\/j.colsurfa.2018.01.054","article-title":"Environmental benign synthesis of reduced graphene oxide (rGO) from spent lithium-ion batteries (LIBs) graphite and its application in supercapacitor","volume":"543","author":"Natarajan","year":"2018","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"10.1016\/j.chemosphere.2022.135520_bib63","doi-asserted-by":"crossref","DOI":"10.1016\/j.chemosphere.2020.127702","article-title":"Reduced graphene oxide\u2212 TiO2\/sodium alginate 3-dimensional structure aerogel for enhanced photocatalytic degradation of ibuprofen and sulfamethoxazole","volume":"261","author":"Nawaz","year":"2020","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2022.135520_bib64","doi-asserted-by":"crossref","first-page":"102","DOI":"10.1016\/j.jhazmat.2015.05.025","article-title":"Optimized removal of antibiotic drugs from aqueous solutions using single, double and multi-walled carbon nanotubes","volume":"298","author":"Ncibi","year":"2015","journal-title":"J. Hazard Mater."},{"issue":"11","key":"10.1016\/j.chemosphere.2022.135520_bib65","doi-asserted-by":"crossref","first-page":"1177","DOI":"10.1002\/tox.22819","article-title":"Embryonic development, locomotor behavior, biochemical, and epigenetic effects of the pharmaceutical drugs paracetamol and ciprofloxacin in larvae and embryos of Danio rerio when exposed to environmental realistic levels of both drugs","volume":"34","author":"Nogueira","year":"2019","journal-title":"Environ. Toxicol."},{"key":"10.1016\/j.chemosphere.2022.135520_bib66","doi-asserted-by":"crossref","DOI":"10.1016\/j.etap.2019.103242","article-title":"Evaluation of physiological changes induced by the fluoroquinolone antibiotic ciprofloxacin in the freshwater macrophyte species Lemna minor and Lemna gibba","volume":"72","author":"Nunes","year":"2019","journal-title":"Environ. Toxicol. Pharmacol."},{"issue":"3","key":"10.1016\/j.chemosphere.2022.135520_bib67","doi-asserted-by":"crossref","first-page":"293","DOI":"10.2989\/16085914.2018.1465393","article-title":"Acute toxicity effects of ibuprofen on behaviour and haematological parameters of African catfish Clarias gariepinus (Burchell, 1822)","volume":"43","author":"Ogueji","year":"2018","journal-title":"Afr. J. Aquat. Sci."},{"key":"10.1016\/j.chemosphere.2022.135520_bib68","series-title":"Potential Risks and Approaches to Reduce the Toxicity of Disinfection By-Product\u2013A Review","author":"Pandian","year":"2022"},{"issue":"1","key":"10.1016\/j.chemosphere.2022.135520_bib69","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1038\/s41467-017-02479-z","article-title":"Green synthesis of graphene oxide by seconds timescale water electrolytic oxidation","volume":"9","author":"Pei","year":"2018","journal-title":"Nat. Commun."},{"key":"10.1016\/j.chemosphere.2022.135520_bib70","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1016\/j.watres.2014.08.053","article-title":"A review on emerging contaminants in wastewaters and the environment: current knowledge, understudied areas and recommendations for future monitoring","volume":"72","author":"Petrie","year":"2015","journal-title":"Water Res."},{"key":"10.1016\/j.chemosphere.2022.135520_bib71","doi-asserted-by":"crossref","first-page":"274","DOI":"10.1016\/j.envpol.2017.09.046","article-title":"Environmental risk assessment of triclosan and ibuprofen in marine sediments using individual and sub-individual endpoints","volume":"232","author":"Pusceddu","year":"2018","journal-title":"Environ. Pollut."},{"key":"10.1016\/j.chemosphere.2022.135520_bib72","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2020.145803","article-title":"Rational fabrication of needle with spherical shape ternary reduced Graphene Oxide-HoVO4-TiO2 photocatalyst for degradation of ibuprofen under visible light","volume":"513","author":"Raja","year":"2020","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.chemosphere.2022.135520_bib73","doi-asserted-by":"crossref","DOI":"10.1016\/j.electacta.2019.135062","article-title":"Wool roving textured reduced graphene oxide-HoVO4-ZnO nanocomposite for photocatalytic and supercapacitor performance","volume":"328","author":"Raja","year":"2019","journal-title":"Electrochim. Acta"},{"key":"10.1016\/j.chemosphere.2022.135520_bib74","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2019.115996","article-title":"Visible active reduced graphene oxide-BiVO4-ZnO ternary photocatalyst for efficient removal of ciprofloxacin","volume":"233","author":"Raja","year":"2020","journal-title":"Separ. Purif. Technol."},{"issue":"2\u20134","key":"10.1016\/j.chemosphere.2022.135520_bib75","doi-asserted-by":"crossref","first-page":"229","DOI":"10.1504\/IJETM.2010.031530","article-title":"Biosorption of inorganic mercury onto marine alga Sargassum tenerrimum: batch and column studies","volume":"12","author":"Rajamohan","year":"2010","journal-title":"Int. J. Environ. Technol. Manag."},{"key":"10.1016\/j.chemosphere.2022.135520_bib76","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1016\/j.surfin.2017.03.003","article-title":"Fabrication of reduced graphene oxide-graphite paste electrode for H2O2 formation and its implication for ciprofloxacin degradation","volume":"7","author":"Rani","year":"2017","journal-title":"Surface. Interfac."},{"key":"10.1016\/j.chemosphere.2022.135520_bib77","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1016\/j.cej.2017.04.106","article-title":"Treatment technologies for emerging contaminants in water: a review","volume":"323","author":"Rodriguez-Narvaez","year":"2017","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.chemosphere.2022.135520_bib78","doi-asserted-by":"crossref","first-page":"22","DOI":"10.1016\/j.watres.2017.12.016","article-title":"Abiotic degradation and environmental toxicity of ibuprofen: roles of mineral particles and solar radiation","volume":"131","author":"Rubasinghege","year":"2018","journal-title":"Water Res."},{"key":"10.1016\/j.chemosphere.2022.135520_bib79","doi-asserted-by":"crossref","first-page":"396","DOI":"10.5004\/dwt.2020.25027","article-title":"Adsorption of ibuprofen from wastewater using activated carbon and graphene oxide embedded chitosan\u2013pva: equilibrium, kinetics, and thermodynamics and optimization with central composite design","volume":"179","author":"Sahin","year":"2020","journal-title":"Desalination Water Treat."},{"issue":"4","key":"10.1016\/j.chemosphere.2022.135520_bib81","doi-asserted-by":"crossref","first-page":"229","DOI":"10.1205\/095758203322299743","article-title":"Consumption and environmental hazards of pharmaceutical substances in the UK","volume":"81","author":"Sebastine","year":"2003","journal-title":"Process Saf. Environ. Protect."},{"key":"10.1016\/j.chemosphere.2022.135520_bib82","doi-asserted-by":"crossref","first-page":"444","DOI":"10.1016\/j.matlet.2018.10.145","article-title":"Gas sensing behaviour of green synthesized reduced graphene oxide (rGO) for H2 and NO","volume":"236","author":"Sharma","year":"2019","journal-title":"Mater. Lett."},{"key":"10.1016\/j.chemosphere.2022.135520_bib83","doi-asserted-by":"crossref","first-page":"702","DOI":"10.1016\/j.chemosphere.2015.12.084","article-title":"A review of the influence of treatment strategies on antibiotic resistant bacteria and antibiotic resistance genes","volume":"150","author":"Sharma","year":"2016","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2022.135520_bib84","doi-asserted-by":"crossref","DOI":"10.1016\/j.envpol.2019.07.029","article-title":"The cardiovascular toxicity induced by high doses of gatifloxacin and ciprofloxacin in zebrafish","volume":"254","author":"Shen","year":"2019","journal-title":"Environ. Pollut."},{"key":"10.1016\/j.chemosphere.2022.135520_bib85","doi-asserted-by":"crossref","first-page":"1219","DOI":"10.1016\/j.scitotenv.2018.08.218","article-title":"Plant toxicity and accumulation of biosolids-borne ciprofloxacin and azithromycin","volume":"648","author":"Sidhu","year":"2019","journal-title":"Sci. Total Environ."},{"issue":"1","key":"10.1016\/j.chemosphere.2022.135520_bib86","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1002\/tqem.21701","article-title":"Kinetic studies on the removal of cadmium using Acacia tortilis","volume":"30","author":"Sivaprakash","year":"2020","journal-title":"Environ. Qual. Manag."},{"issue":"1","key":"10.1016\/j.chemosphere.2022.135520_bib87","first-page":"155","article-title":"Batch and column sorption of heavy metal from aqueous solution using a marine alga Sargassum tenerrimum","volume":"2","author":"Sivaprakash","year":"2010","journal-title":"Int. J. ChemTech Res."},{"key":"10.1016\/j.chemosphere.2022.135520_bib88","series-title":"Characterization of the Biosorption Process","first-page":"102","author":"Sivashankar","year":"2022"},{"key":"10.1016\/j.chemosphere.2022.135520_bib89","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1016\/j.cej.2016.12.022","article-title":"Graphene-family nanomaterials in wastewater treatment plants","volume":"313","author":"Su\u00e1rez-Iglesias","year":"2017","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.chemosphere.2022.135520_bib90","doi-asserted-by":"crossref","first-page":"124","DOI":"10.1016\/j.molliq.2019.03.118","article-title":"Response surface methodological evaluation and optimization for adsorption removal of ciprofloxacin onto graphene hydrogel","volume":"284","author":"Sun","year":"2019","journal-title":"J. Mol. Liq."},{"key":"10.1016\/j.chemosphere.2022.135520_bib91","doi-asserted-by":"crossref","first-page":"1294","DOI":"10.1016\/j.matpr.2021.06.381","article-title":"Synthesis and characterization of acid treated reduced graphene oxide","volume":"49","author":"Tambe","year":"2022","journal-title":"Mater. Today Proc."},{"issue":"1","key":"10.1016\/j.chemosphere.2022.135520_bib105","doi-asserted-by":"crossref","DOI":"10.1088\/2043-6262\/abe933","article-title":"Preparation of magnetic manganese ferrite\/graphene oxide nanocomposites as efficient adsorbents towards ibuprofen","volume":"12","author":"Thy","year":"2021","journal-title":"Adv. Nat. Sci. Nanosci. Nanotechnol."},{"key":"10.1016\/j.chemosphere.2022.135520_bib92","doi-asserted-by":"crossref","first-page":"356","DOI":"10.1016\/j.jcis.2018.05.010","article-title":"Self-assembled three-dimensional reduced graphene oxide-based hydrogel for highly efficient and facile removal of pharmaceutical compounds from aqueous solution","volume":"527","author":"Umbreen","year":"2018","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2022.135520_bib93","doi-asserted-by":"crossref","first-page":"442","DOI":"10.1016\/j.scitotenv.2017.08.120","article-title":"Detoxification mechanisms, defense responses, and toxicity threshold in the earthworm Eisenia foetida exposed to ciprofloxacin-polluted soils","volume":"612","author":"Wang","year":"2018","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.chemosphere.2022.135520_bib94","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2021.118884","article-title":"Selective electrochemical H2O2 generation on the graphene aerogel for efficient electro-Fenton degradation of ciprofloxacin","volume":"272","author":"Wang","year":"2021","journal-title":"Separ. Purif. Technol."},{"key":"10.1016\/j.chemosphere.2022.135520_bib95","doi-asserted-by":"crossref","first-page":"88","DOI":"10.1016\/j.jpba.2018.04.023","article-title":"Magnetic solid-phase extraction based on Fe3O4\/graphene nanocomposites for enantioselective determination of representative profens in the environmental water samples and molecular docking study on adsorption mechanism of graphene","volume":"156","author":"Wang","year":"2018","journal-title":"J. Pharmaceut. Biomed. Anal."},{"key":"10.1016\/j.chemosphere.2022.135520_bib96","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1016\/j.jcat.2017.11.029","article-title":"Photocatalytic degradation of ciprofloxacin by a novel Z-scheme CeO2\u2013Ag\/AgBr photocatalyst: influencing factors, possible degradation pathways, and mechanism insight","volume":"358","author":"Wen","year":"2018","journal-title":"J. Catal."},{"key":"10.1016\/j.chemosphere.2022.135520_bib97","doi-asserted-by":"crossref","first-page":"61","DOI":"10.1016\/j.seppur.2011.11.022","article-title":"Removal of ibuprofen and 4-isobutylacetophenone by non-dispersive solvent extraction using a hollow fibre membrane contactor","volume":"88","author":"Williams","year":"2012","journal-title":"Separ. Purif. Technol."},{"key":"10.1016\/j.chemosphere.2022.135520_bib98","doi-asserted-by":"crossref","first-page":"621","DOI":"10.1016\/j.jcis.2021.03.034","article-title":"One-step synthesis of reduced graphene oxide based ceric dioxide modified with cadmium sulfide (CeO2\/CdS\/RGO) heterojunction with enhanced sunlight-driven photocatalytic activity","volume":"594","author":"Yao","year":"2021","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2022.135520_bib99","doi-asserted-by":"crossref","first-page":"195","DOI":"10.1016\/j.jhazmat.2019.04.021","article-title":"Adsorption mechanism and effect of moisture contents on ciprofloxacin removal by three-dimensional porous graphene hydrogel","volume":"374","author":"Yu","year":"2019","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.chemosphere.2022.135520_bib100","doi-asserted-by":"crossref","DOI":"10.1016\/j.scitotenv.2021.148628","article-title":"Stress symptoms and plant hormone-modulated defense response induced by the uptake of carbamazepine and ibuprofen in Malabar spinach (Basella alba L.)","volume":"793","author":"Zhang","year":"2021","journal-title":"Sci. Total Environ."},{"issue":"2","key":"10.1016\/j.chemosphere.2022.135520_bib101","doi-asserted-by":"crossref","first-page":"189","DOI":"10.3390\/catal10020189","article-title":"A novel reduced graphene oxide-attapulgite (RGO-ATP) supported Fe2O3 catalyst for heterogeneous Fenton-like oxidation of ciprofloxacin: degradation mechanism and pathway","volume":"10","author":"Zhang","year":"2020","journal-title":"Catalysts"},{"key":"10.1016\/j.chemosphere.2022.135520_bib102","doi-asserted-by":"crossref","DOI":"10.1155\/2020\/6094984","article-title":"Synergistic removal of bromate and ibuprofen by graphene oxide and TiO2 heterostructure doped with F: performance and mechanism","volume":"2020","author":"Zhang","year":"2020","journal-title":"J. Nanomater."},{"key":"10.1016\/j.chemosphere.2022.135520_bib103","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1016\/j.watres.2018.04.056","article-title":"Typical pharmaceuticals in major WWTPs in Beijing, China: occurrence, load pattern and calculation reliability","volume":"140","author":"Zhang","year":"2018","journal-title":"Water Res."},{"key":"10.1016\/j.chemosphere.2022.135520_bib104","doi-asserted-by":"crossref","DOI":"10.1016\/j.jallcom.2021.159305","article-title":"Synthesis of graphene-based CdS@ CuS core-shell nanorods by cation-exchange for efficient degradation of ciprofloxacin","volume":"869","author":"Zhao","year":"2021","journal-title":"J. Alloys Compd."}],"container-title":["Chemosphere"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653522020136?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653522020136?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,1,8]],"date-time":"2025-01-08T15:43:02Z","timestamp":1736350982000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0045653522020136"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11]]},"references-count":99,"alternative-id":["S0045653522020136"],"URL":"https:\/\/doi.org\/10.1016\/j.chemosphere.2022.135520","relation":{},"ISSN":["0045-6535"],"issn-type":[{"value":"0045-6535","type":"print"}],"subject":[],"published":{"date-parts":[[2022,11]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Remediation of pharmaceutical pollutants using graphene-based materials - A review on operating conditions, mechanism and toxicology","name":"articletitle","label":"Article Title"},{"value":"Chemosphere","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.chemosphere.2022.135520","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2022 Elsevier Ltd. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"135520"}}