{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,2]],"date-time":"2026-11-02T01:09:56Z","timestamp":1793581796543,"version":"4.5.0"},"reference-count":49,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2023,2,1]],"date-time":"2023-02-01T00:00:00Z","timestamp":1675209600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2023,2,1]],"date-time":"2023-02-01T00:00:00Z","timestamp":1675209600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2023,2,1]],"date-time":"2023-02-01T00:00:00Z","timestamp":1675209600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2023,2,1]],"date-time":"2023-02-01T00:00:00Z","timestamp":1675209600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2023,2,1]],"date-time":"2023-02-01T00:00:00Z","timestamp":1675209600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2023,2,1]],"date-time":"2023-02-01T00:00:00Z","timestamp":1675209600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2023,2,1]],"date-time":"2023-02-01T00:00:00Z","timestamp":1675209600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100001809","name":"NSFC","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Chemosphere"],"published-print":{"date-parts":[[2023,2]]},"DOI":"10.1016\/j.chemosphere.2022.137670","type":"journal-article","created":{"date-parts":[[2022,12,26]],"date-time":"2022-12-26T20:25:10Z","timestamp":1672086310000},"page":"137670","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":64,"special_numbering":"C","title":["Metal-organic frameworks-derived In2O3\/ZnO porous hollow nanocages for highly sensitive H2S gas sensor"],"prefix":"10.1016","volume":"314","author":[{"given":"Jesse Nii","family":"Okai Amu-Darko","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shahid","family":"Hussain","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangzhao","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Asma A.","family":"Alothman","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohamed","family":"Ouladsmane","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M. Tariq","family":"Nazir","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guanjun","family":"Qiao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guiwu","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.chemosphere.2022.137670_bib1","doi-asserted-by":"crossref","DOI":"10.1016\/j.carbpol.2020.116064","article-title":"Low power consumption and fast response H2S gas sensor based on a chitosan-CuO hybrid nanocomposite thin film","volume":"236","author":"Ali","year":"2020","journal-title":"Carbohydr. Polym."},{"key":"10.1016\/j.chemosphere.2022.137670_bib2","doi-asserted-by":"crossref","first-page":"3096","DOI":"10.3390\/s20113096","article-title":"Nanostructured metal oxide-based acetone gas sensors: a review","volume":"20","author":"Amiri","year":"2020","journal-title":"Sensors"},{"key":"10.1016\/j.chemosphere.2022.137670_bib3","doi-asserted-by":"crossref","first-page":"900","DOI":"10.3390\/nano9060900","article-title":"Heterostructured NiO\/ZnO nanorod arrays with significantly enhanced H2S sensing performance","volume":"9","author":"Ao","year":"2019","journal-title":"Nanomaterials"},{"key":"10.1016\/j.chemosphere.2022.137670_bib4","doi-asserted-by":"crossref","DOI":"10.1016\/j.snb.2020.129053","article-title":"Temperature modulated Cu-MOF based gas sensor with dual selectivity to acetone and NO2 at low operating temperatures","volume":"329","author":"Arul","year":"2021","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib5","doi-asserted-by":"crossref","first-page":"8776","DOI":"10.1039\/D1TC01857D","article-title":"Gas sensing performance of 2D nanomaterials\/metal oxide nanocomposites: a review","volume":"9","author":"Bhati","year":"2021","journal-title":"J. Mater. Chem. C"},{"key":"10.1016\/j.chemosphere.2022.137670_bib6","doi-asserted-by":"crossref","first-page":"29950","DOI":"10.3390\/s151229775","article-title":"A single Eu-doped In2O3 nanobelt device for selective H2S detection","volume":"15","author":"Chen","year":"2015","journal-title":"Sensors"},{"key":"10.1016\/j.chemosphere.2022.137670_bib7","doi-asserted-by":"crossref","first-page":"14592","DOI":"10.1021\/acsomega.8b01635","article-title":"Fabrication and H2-sensing properties of SnO2 nanosheet gas sensors","volume":"3","author":"Choi","year":"2018","journal-title":"ACS Omega"},{"key":"10.1016\/j.chemosphere.2022.137670_bib8","doi-asserted-by":"crossref","first-page":"475","DOI":"10.3390\/met10040475","article-title":"WO3 and ionic liquids: a synergic pair for pollutant gas sensing and desulfurization","volume":"10","author":"D'Anna","year":"2020","journal-title":"Metals"},{"key":"10.1016\/j.chemosphere.2022.137670_bib9","series-title":"Semiconducting Metal Oxides for Gas Sensing","first-page":"23","article-title":"Sensing mechanism and evaluation criteria of semiconducting metal oxides gas sensors","author":"Deng","year":"2019"},{"key":"10.1016\/j.chemosphere.2022.137670_bib10","doi-asserted-by":"crossref","DOI":"10.1016\/j.snb.2021.130741","article-title":"Facile synthesis of metal-organic framework-derived ZnO\/CuO nanocomposites for highly sensitive and selective H2S gas sensing","volume":"349","author":"Doan","year":"2021","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib11","doi-asserted-by":"crossref","first-page":"853","DOI":"10.1016\/j.apsusc.2019.03.329","article-title":"Engineering the surface structure of porous indium oxide hexagonal nanotubes with antimony trioxide for highly-efficient nitrogen dioxide detection at low temperature","volume":"484","author":"Du","year":"2019","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.chemosphere.2022.137670_bib12","doi-asserted-by":"crossref","first-page":"828","DOI":"10.1016\/j.snb.2016.10.129","article-title":"Development of highly sensitive ZnO\/In2O3 composite gas sensor activated by UV-LED","volume":"241","author":"Espid","year":"2017","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib13","doi-asserted-by":"crossref","first-page":"22534","DOI":"10.1007\/s10854-020-04764-y","article-title":"One-pot synthesis of core\u2013shell ZIF-8@ ZnO porous nanospheres with improved ethanol gas sensing","volume":"31","author":"Feng","year":"2020","journal-title":"J. Mater. Sci. Mater. Electron."},{"key":"10.1016\/j.chemosphere.2022.137670_bib14","doi-asserted-by":"crossref","first-page":"9046","DOI":"10.1021\/acsanm.0c01731","article-title":"Needle-shaped WO3 nanorods for triethylamine gas sensing","volume":"3","author":"Hu","year":"2020","journal-title":"ACS Appl. Nano Mater."},{"key":"10.1016\/j.chemosphere.2022.137670_bib15","doi-asserted-by":"crossref","DOI":"10.1016\/j.molliq.2022.119765","article-title":"Polyhedral Co3O4@ZnO nanostructures as proficient photocatalysts for vitiation of organic dyes from waste water","volume":"362","author":"Hussain","year":"2022","journal-title":"J. Mol. Liq."},{"key":"10.1016\/j.chemosphere.2022.137670_bib16","doi-asserted-by":"crossref","first-page":"22664","DOI":"10.1039\/C9NR07699A","article-title":"Gas sensing mechanisms of metal oxide semiconductors: a focus review","volume":"11","author":"Ji","year":"2019","journal-title":"Nanoscale"},{"key":"10.1016\/j.chemosphere.2022.137670_bib17","doi-asserted-by":"crossref","DOI":"10.1016\/j.snb.2022.131995","article-title":"Metal-organic framework-derived ZnO decorated with CuO for ultra-high response and selectivity H2S gas sensor","volume":"366","author":"Li","year":"2022","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib18","doi-asserted-by":"crossref","first-page":"470","DOI":"10.1039\/C8MH01365A","article-title":"Advances in designs and mechanisms of semiconducting metal oxide nanostructures for high-precision gas sensors operated at room temperature","volume":"6","author":"Li","year":"2019","journal-title":"Mater. Horiz."},{"key":"10.1016\/j.chemosphere.2022.137670_bib19","doi-asserted-by":"crossref","DOI":"10.1016\/j.snb.2020.129425","article-title":"Triethylamine gas sensor based on Pt-functionalized hierarchical ZnO microspheres","volume":"331","author":"Liu","year":"2021","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib20","doi-asserted-by":"crossref","first-page":"4186","DOI":"10.1021\/am405858v","article-title":"MOF-templated synthesis of porous Co3O4 concave nanocubes with high specific surface area and their gas sensing properties","volume":"6","author":"L\u00fc","year":"2014","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"10.1016\/j.chemosphere.2022.137670_bib21","article-title":"Pt nanoparticles sensitized ordered mesoporous WO3 semiconductor: gas sensing performance and mechanism study","volume":"28","author":"Ma","year":"2018","journal-title":"Adv. Funct. Mater."},{"key":"10.1016\/j.chemosphere.2022.137670_bib22","doi-asserted-by":"crossref","first-page":"170","DOI":"10.3390\/electronics8020170","article-title":"A cost-effective air quality supervision solution for enhanced living environments through the internet of things","volume":"8","author":"Marques","year":"2019","journal-title":"Electronics"},{"key":"10.1016\/j.chemosphere.2022.137670_bib23","doi-asserted-by":"crossref","first-page":"4024","DOI":"10.3390\/su12104024","article-title":"Indoor air quality monitoring systems for enhanced living environments: a review toward sustainable smart cities","volume":"12","author":"Marques","year":"2020","journal-title":"Sustainability"},{"key":"10.1016\/j.chemosphere.2022.137670_bib24","doi-asserted-by":"crossref","first-page":"9575","DOI":"10.1007\/s10853-021-05884-4","article-title":"A review on mechanisms and recent developments in pn heterojunctions of 2D materials for gas sensing applications","volume":"56","author":"Mathew","year":"2021","journal-title":"J. Mater. Sci."},{"key":"10.1016\/j.chemosphere.2022.137670_bib25","doi-asserted-by":"crossref","first-page":"250","DOI":"10.1016\/j.snb.2014.07.074","article-title":"Nanoscale metal oxide-based heterojunctions for gas sensing: a review","volume":"204","author":"Miller","year":"2014","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib26","doi-asserted-by":"crossref","first-page":"10186","DOI":"10.1073\/pnas.0602439103","article-title":"Exceptional chemical and thermal stability of zeolitic imidazolate frameworks","volume":"103","author":"Park","year":"2006","journal-title":"Proc. Natl. Acad. Sci. USA"},{"key":"10.1016\/j.chemosphere.2022.137670_bib27","doi-asserted-by":"crossref","first-page":"3427","DOI":"10.1166\/jnn.2013.7231","article-title":"Enhanced gas sensing properties of multiple networked In2O3-core\/ZnO-shell nanorod sensors","volume":"13","author":"Park","year":"2013","journal-title":"J. Nanosci. Nanotechnol."},{"key":"10.1016\/j.chemosphere.2022.137670_bib28","doi-asserted-by":"crossref","DOI":"10.1016\/j.snb.2021.129606","article-title":"Comparative study on the gas-sensing performance of ZnO\/SnO2 external and ZnO\u2013SnO2 internal heterojunctions for ppb H2S and NO2 gases detection","volume":"334","author":"Phuoc","year":"2021","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib29","doi-asserted-by":"crossref","DOI":"10.1016\/j.matchemphys.2020.124038","article-title":"Selective detection of hydrogen sulphide from the background of low concentration reducing gases","volume":"260","author":"Priya","year":"2021","journal-title":"Mater. Chem. Phys."},{"key":"10.1016\/j.chemosphere.2022.137670_bib30","doi-asserted-by":"crossref","DOI":"10.1016\/j.chemosphere.2021.132178","article-title":"Efficient detection of hazardous H2S gas using multifaceted Co3O4\/ZnO hollow nanostructures","volume":"287","author":"Shi","year":"2022","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2022.137670_bib31","doi-asserted-by":"crossref","first-page":"2913","DOI":"10.1021\/acsaelm.0c00547","article-title":"Selective detection of toluene using pulse-driven SnO2 micro gas sensors","volume":"2","author":"Suematsu","year":"2020","journal-title":"ACS Appl. Electron. Mater."},{"key":"10.1016\/j.chemosphere.2022.137670_bib32","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1016\/j.snb.2018.12.080","article-title":"Pyrolyzing Co\/Zn bimetallic organic framework to form pn heterojunction of Co3O4\/ZnO for detection of formaldehyde","volume":"285","author":"Sun","year":"2019","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib33","doi-asserted-by":"crossref","first-page":"48","DOI":"10.1016\/j.snb.2019.02.107","article-title":"Microfluidically synthesized Au, Pd and AuPd nanoparticles supported on SnO2 for gas sensing applications","volume":"292","author":"Tofighi","year":"2019","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib34","doi-asserted-by":"crossref","DOI":"10.1088\/1361-648X\/abf477","article-title":"Gas sensing materials roadmap","volume":"33","author":"Wang","year":"2021","journal-title":"J. Phys. Condens. Matter"},{"key":"10.1016\/j.chemosphere.2022.137670_bib35","doi-asserted-by":"crossref","first-page":"5209","DOI":"10.1021\/acsomega.9b04243","article-title":"Fabrication of ZnO nanoparticles modified by uniformly dispersed Ag nanoparticles: enhancement of gas sensing performance","volume":"5","author":"Wang","year":"2020","journal-title":"ACS Omega"},{"key":"10.1016\/j.chemosphere.2022.137670_bib36","doi-asserted-by":"crossref","first-page":"15858","DOI":"10.1016\/j.ceramint.2020.03.133","article-title":"Low-temperature and highly sensitivity H2S gas sensor based on ZnO\/CuO composite derived from bimetal metal-organic frameworks","volume":"46","author":"Wang","year":"2020","journal-title":"Ceram. Int."},{"key":"10.1016\/j.chemosphere.2022.137670_bib37","doi-asserted-by":"crossref","first-page":"413","DOI":"10.1016\/j.snb.2018.08.130","article-title":"Facile synthesis of La-doped In2O3 hollow microspheres and enhanced hydrogen sulfide sensing characteristics","volume":"276","author":"Wei","year":"2018","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib38","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1016\/j.jcis.2017.03.072","article-title":"Hierarchical assembly of In2O3 nanoparticles on ZnO hollow nanotubes using carbon fibers as templates: enhanced photocatalytic and gas-sensing properties","volume":"498","author":"Wei","year":"2017","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.chemosphere.2022.137670_bib39","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1016\/j.snb.2016.09.193","article-title":"The crystal facet-dependent gas sensing properties of ZnO nanosheets: experimental and computational study","volume":"242","author":"Xu","year":"2017","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib40","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2020.147697","article-title":"Ultrasensitive ethanol sensor based on segregated ZnO-In2O3 porous nanosheets","volume":"535","author":"Yan","year":"2021","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.chemosphere.2022.137670_bib41","doi-asserted-by":"crossref","first-page":"1135","DOI":"10.1039\/C1CE06143G","article-title":"Zn-doped In2O3 nanostructures: preparation, structure and gas-sensing properties","volume":"14","author":"Yang","year":"2012","journal-title":"CrystEngComm"},{"key":"10.1016\/j.chemosphere.2022.137670_bib42","doi-asserted-by":"crossref","DOI":"10.1016\/j.snb.2019.127617","article-title":"Facile synthesis of \u03b1-Fe2O3\/ZnO core-shell nanowires for enhanced H2S sensing","volume":"307","author":"Yang","year":"2020","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib43","doi-asserted-by":"crossref","first-page":"1026","DOI":"10.3390\/nano11041026","article-title":"Metal oxide based heterojunctions for gas sensors: a review","volume":"11","author":"Yang","year":"2021","journal-title":"Nanomaterials"},{"key":"10.1016\/j.chemosphere.2022.137670_bib44","doi-asserted-by":"crossref","DOI":"10.1016\/j.chemosphere.2021.132842","article-title":"Enhanced NO2 gas-sensing performance by core-shell SnO2\/ZIF-8 nanospheres","volume":"291","author":"Zhan","year":"2022","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2022.137670_bib45","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2020.122191","article-title":"Ultra-sensitive ethanol gas sensors based on nanosheet-assembled hierarchical ZnO-In2O3 heterostructures","volume":"391","author":"Zhang","year":"2020","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.chemosphere.2022.137670_bib46","doi-asserted-by":"crossref","DOI":"10.1016\/j.snb.2019.126887","article-title":"Metal\u2013organic framework-derived Co3O4\/CoFe2O4 double-shelled nanocubes for selective detection of sub-ppm-level formaldehyde","volume":"298","author":"Zhang","year":"2019","journal-title":"Sensor. Actuator. B Chem."},{"key":"10.1016\/j.chemosphere.2022.137670_bib47","doi-asserted-by":"crossref","first-page":"2071","DOI":"10.1016\/j.cclet.2019.12.014","article-title":"Metal-organic frameworks-derived hierarchical ZnO structures as efficient sensing materials for formaldehyde detection","volume":"31","author":"Zhang","year":"2020","journal-title":"Chin. Chem. Lett."},{"key":"10.1016\/j.chemosphere.2022.137670_bib48","doi-asserted-by":"crossref","first-page":"9765","DOI":"10.1021\/acsami.7b17669","article-title":"Metal\u2013organic frameworks-derived hierarchical Co3O4 structures as efficient sensing materials for acetone detection","volume":"10","author":"Zhang","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"10.1016\/j.chemosphere.2022.137670_bib49","doi-asserted-by":"crossref","first-page":"991","DOI":"10.1016\/j.snb.2018.05.167","article-title":"The role of Ce doping in enhancing sensing performance of ZnO-based gas sensor by adjusting the proportion of oxygen species","volume":"273","author":"Zhang","year":"2018","journal-title":"Sensor. Actuator. B Chem."}],"container-title":["Chemosphere"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653522041637?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653522041637?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,9,23]],"date-time":"2025-09-23T12:32:05Z","timestamp":1758630725000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0045653522041637"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,2]]},"references-count":49,"alternative-id":["S0045653522041637"],"URL":"https:\/\/doi.org\/10.1016\/j.chemosphere.2022.137670","relation":{},"ISSN":["0045-6535"],"issn-type":[{"value":"0045-6535","type":"print"}],"subject":[],"published":{"date-parts":[[2023,2]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Metal-organic frameworks-derived In2O3\/ZnO porous hollow nanocages for highly sensitive H2S gas sensor","name":"articletitle","label":"Article Title"},{"value":"Chemosphere","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.chemosphere.2022.137670","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2022 Elsevier Ltd. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"137670"}}