{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,28]],"date-time":"2026-10-28T03:57:52Z","timestamp":1793159872932,"version":"4.5.0"},"reference-count":29,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52273072"],"award-info":[{"award-number":["52273072"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003787","name":"Natural Science Foundation of Hebei Province","doi-asserted-by":"publisher","award":["E2021201003"],"award-info":[{"award-number":["E2021201003"]}],"id":[{"id":"10.13039\/501100003787","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008047","name":"Hebei University","doi-asserted-by":"publisher","award":["DXK202003"],"award-info":[{"award-number":["DXK202003"]}],"id":[{"id":"10.13039\/501100008047","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Chemosphere"],"published-print":{"date-parts":[[2024,1]]},"DOI":"10.1016\/j.chemosphere.2023.140521","type":"journal-article","created":{"date-parts":[[2023,11,2]],"date-time":"2023-11-02T00:31:41Z","timestamp":1698885101000},"page":"140521","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":51,"special_numbering":"C","title":["A graphene@Cu-MOF hybrid synthesized by mechanical ball milling method and its flame retardancy and smoke suppression effect on EP"],"prefix":"10.1016","volume":"346","author":[{"given":"Ge","family":"Zhang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weihong","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Yao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yumeng","family":"Cui","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunhong","family":"Jiao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongqiang","family":"Qu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianzhong","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.chemosphere.2023.140521_bib1","doi-asserted-by":"crossref","DOI":"10.1063\/1.4809794","article-title":"An effective route to produce few-layer graphene using combinatorial ball milling and strong aqueous exfoliants","volume":"5","author":"Aparna","year":"2013","journal-title":"J. Renew. Sustain. Energy"},{"key":"10.1016\/j.chemosphere.2023.140521_bib2","doi-asserted-by":"crossref","first-page":"6406","DOI":"10.1166\/jnn.2020.18120","article-title":"Improving flame retardancy of epoxy resin nanocomposites by carbon nanotubes grafted CuAI-layered double hydroxide hybrid","volume":"20","author":"Cai","year":"2020","journal-title":"J. Nanosci. Nanotechnol."},{"key":"10.1016\/j.chemosphere.2023.140521_bib3","doi-asserted-by":"crossref","first-page":"3519","DOI":"10.1021\/nl201699j","article-title":"Synthesis and characterization of large-area graphene and graphite films on commercial Cu-Ni alloy foils","volume":"11","author":"Chen","year":"2011","journal-title":"Nano Lett."},{"key":"10.1016\/j.chemosphere.2023.140521_bib4","doi-asserted-by":"crossref","DOI":"10.1016\/j.colsurfa.2021.128093","article-title":"Phosphor nitrile functionalized UiO-66-NH2\/graphene hybrid flame retardants for fire safety of epoxy","volume":"635","author":"Duan","year":"2022","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"10.1016\/j.chemosphere.2023.140521_bib5","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1021\/es202828k","article-title":"Volatilization behavior of fluorine in fluoroborate residue during pyrolysis","volume":"46","author":"Feng","year":"2012","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2023.140521_bib6","doi-asserted-by":"crossref","first-page":"3930","DOI":"10.1021\/am405130w","article-title":"Efficient oxygen reduction electrocatalyst based on edge-nitrogen-rich graphene nanoplatelets: toward a large-scale synthesis","volume":"6","author":"Fu","year":"2014","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"10.1016\/j.chemosphere.2023.140521_bib7","doi-asserted-by":"crossref","first-page":"3267","DOI":"10.1007\/s11581-020-03497-6","article-title":"Investigation of wet-milled graphene nanosheets with sulfur doping for lithium-ion battery","volume":"26","author":"Guo","year":"2020","journal-title":"Ionics"},{"key":"10.1016\/j.chemosphere.2023.140521_bib8","doi-asserted-by":"crossref","first-page":"7772","DOI":"10.1021\/ie200152x","article-title":"In situ polymerization of graphene, graphite oxide, and functionalized graphite oxide into epoxy resin and comparison study of on-the-flame behavior","volume":"50","author":"Guo","year":"2011","journal-title":"Ind. Eng. Chem. Res."},{"key":"10.1016\/j.chemosphere.2023.140521_bib9","doi-asserted-by":"crossref","first-page":"4214","DOI":"10.1007\/s10853-013-7234-8","article-title":"Preparation and properties of polystyrene nanocomposites with graphite oxide and graphene as flame retardants","volume":"48","author":"Han","year":"2013","journal-title":"J. Mater. Sci."},{"key":"10.1016\/j.chemosphere.2023.140521_bib10","article-title":"Core\u2013shell structure flame retardant Salen-PZN-Cu@Ni-MOF microspheres enhancing fire safety of epoxy resin through the synergistic effect","volume":"29","author":"He","year":"2021","journal-title":"J. Polym. Res."},{"key":"10.1016\/j.chemosphere.2023.140521_bib11","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1016\/j.compscitech.2017.08.032","article-title":"A novel Co(\u2161)\u2013based metal-organic framework with phosphorus-containing structure: build for enhancing fire safety of epoxy","volume":"152","author":"Hou","year":"2017","journal-title":"Compos. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2023.140521_bib12","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1016\/j.matlet.2011.08.063","article-title":"How can graphene reduce the flammability of polymer nanocomposites?","volume":"66","author":"Huang","year":"2012","journal-title":"Mater. Lett."},{"key":"10.1016\/j.chemosphere.2023.140521_bib13","doi-asserted-by":"crossref","first-page":"4313","DOI":"10.1021\/cg2006502","article-title":"1. Solvent, linker, and anion effects on the formation, connectivity, and topology of Cu(I)\/PPh3\/N-donor ligand coordination polymers","volume":"11","author":"Janssen","year":"2011","journal-title":"Cryst. Growth Des."},{"key":"10.1016\/j.chemosphere.2023.140521_bib14","doi-asserted-by":"crossref","first-page":"100","DOI":"10.1016\/j.mser.2008.09.002","article-title":"New prospects in flame retardant polymer materials: from fundamentals to nanocomposites","volume":"63","author":"Laoutid","year":"2009","journal-title":"Mater. Sci. Eng. R Rep."},{"key":"10.1016\/j.chemosphere.2023.140521_bib15","doi-asserted-by":"crossref","first-page":"563","DOI":"10.1021\/nn405148t","article-title":"Exfoliation of graphite with triazine derivatives under ball-milling conditions: preparation of few-layer graphene via selective noncovalent interactions","volume":"8","author":"Leon","year":"2014","journal-title":"ACS Nano"},{"key":"10.1016\/j.chemosphere.2023.140521_bib16","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2022.155736","article-title":"Boron-containing ionic liquid functionalized Mo-MOF\/graphene oxide hybrid for improving fire safety and maintaining mechanical properties for epoxy resin","volume":"611","author":"Li","year":"2023","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.chemosphere.2023.140521_bib17","doi-asserted-by":"crossref","first-page":"18652","DOI":"10.1039\/C4RA01267D","article-title":"Effect of graphene nanosheets and layered double hydroxides on the flame retardancy and thermal degradation of epoxy resin","volume":"4","author":"Liu","year":"2014","journal-title":"RSC Adv."},{"key":"10.1016\/j.chemosphere.2023.140521_bib18","article-title":"Growth of copper organophosphate nanosheets on graphene oxide to improve fire safety and mechanical strength of epoxy resins","volume":"311","author":"Rao","year":"2022","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2023.140521_bib19","doi-asserted-by":"crossref","first-page":"76","DOI":"10.1016\/j.compscitech.2016.10.002","article-title":"Influence of functionalized graphene by grafted phosphorus containing flame retardant on the flammability of carbon fiber\/epoxy resin (CF\/ER) composite","volume":"136","author":"Sun","year":"2016","journal-title":"Compos. Sci. Technol."},{"key":"10.1016\/j.chemosphere.2023.140521_bib20","doi-asserted-by":"crossref","DOI":"10.1016\/j.compositesa.2022.107187","article-title":"Interface assembly of flower-like Ni-MOF functional MXene towards the fire safety of thermoplastic polyurethanes","volume":"163","author":"Wan","year":"2022","journal-title":"Compos. Appl. Sci. Manuf."},{"key":"10.1016\/j.chemosphere.2023.140521_bib21","article-title":"Improving the flame retardancy of epoxy resin with ZIF\u201067@GO\u2010PA nanohybrid as filler","volume":"139","author":"Wang","year":"2022","journal-title":"J. Appl. Polym. Sci."},{"key":"10.1016\/j.chemosphere.2023.140521_bib22","doi-asserted-by":"crossref","first-page":"542","DOI":"10.1080\/00222348.2020.1753339","article-title":"Kinetic evaluation of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide as a flame retardant for epoxy resins","volume":"59","author":"Wang","year":"2020","journal-title":"J. Macromol. Sci., Part B"},{"key":"10.1016\/j.chemosphere.2023.140521_bib23","first-page":"359","article-title":"Investigation of nickel ammonia phosphate with different morphologies as a new high-efficiency flame retardant for epoxy resin","volume":"32","author":"Weiwei","year":"2019","journal-title":"High Perform. Polym."},{"key":"10.1016\/j.chemosphere.2023.140521_bib24","doi-asserted-by":"crossref","first-page":"30252","DOI":"10.1021\/acsomega.0c04722","article-title":"Corn flour nano-graphene prepared by the hummers redox method","volume":"5","author":"Wu","year":"2020","journal-title":"ACS Omega"},{"key":"10.1016\/j.chemosphere.2023.140521_bib25","doi-asserted-by":"crossref","DOI":"10.1016\/j.chemosphere.2022.137058","article-title":"Biomass-derived polyphosphazene toward simultaneously enhancing the flame retardancy and mechanical properties of epoxy resins","volume":"311","author":"Xiao","year":"2023","journal-title":"Chemosphere"},{"key":"10.1016\/j.chemosphere.2023.140521_bib26","doi-asserted-by":"crossref","first-page":"613","DOI":"10.1080\/14686996.2018.1494493","article-title":"Structure of graphene and its disorders: a review","volume":"19","author":"Yang","year":"2018","journal-title":"Sci. Technol. Adv. Mater."},{"key":"10.1016\/j.chemosphere.2023.140521_bib27","doi-asserted-by":"crossref","first-page":"5950","DOI":"10.1039\/C7CS00318H","article-title":"Preparation of two dimensional layered double hydroxide nanosheets and their applications","volume":"46","author":"Yu","year":"2017","journal-title":"Chem. Soc. Rev."},{"key":"10.1016\/j.chemosphere.2023.140521_bib28","doi-asserted-by":"crossref","DOI":"10.1016\/j.jclepro.2019.119150","article-title":"A sustainable approach to scalable production of a graphene based flame retardant using waste fish deoxyribonucleic acid","volume":"247","author":"Zabihi","year":"2020","journal-title":"J. Clean. Prod."},{"key":"10.1016\/j.chemosphere.2023.140521_bib29","doi-asserted-by":"crossref","first-page":"1709","DOI":"10.1002\/pat.4898","article-title":"Preparation of graphene oxide modified glass fibers and their application in flame retardant polyamide 6","volume":"31","author":"Zhu","year":"2020","journal-title":"Polym. Adv. Technol."}],"container-title":["Chemosphere"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653523027911?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0045653523027911?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,11,4]],"date-time":"2025-11-04T02:45:52Z","timestamp":1762224352000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0045653523027911"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,1]]},"references-count":29,"alternative-id":["S0045653523027911"],"URL":"https:\/\/doi.org\/10.1016\/j.chemosphere.2023.140521","relation":{},"ISSN":["0045-6535"],"issn-type":[{"value":"0045-6535","type":"print"}],"subject":[],"published":{"date-parts":[[2024,1]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"A graphene@Cu-MOF hybrid synthesized by mechanical ball milling method and its flame retardancy and smoke suppression effect on EP","name":"articletitle","label":"Article Title"},{"value":"Chemosphere","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.chemosphere.2023.140521","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2023 Elsevier Ltd. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"140521"}}