{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T04:17:17Z","timestamp":1791346637765,"version":"4.3.1"},"reference-count":32,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2025,3,1]],"date-time":"2025-03-01T00:00:00Z","timestamp":1740787200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2025,3,1]],"date-time":"2025-03-01T00:00:00Z","timestamp":1740787200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2025,2,17]],"date-time":"2025-02-17T00:00:00Z","timestamp":1739750400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100002809","name":"Generalitat de Catalunya","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100014440","name":"Spain Ministry of Science and Innovation","doi-asserted-by":"publisher","award":["PID2023-147405OR-I00"],"award-info":[{"award-number":["PID2023-147405OR-I00"]}],"id":[{"id":"10.13039\/100014440","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Chromatography A"],"published-print":{"date-parts":[[2025,3]]},"DOI":"10.1016\/j.chroma.2025.465750","type":"journal-article","created":{"date-parts":[[2025,2,3]],"date-time":"2025-02-03T11:11:01Z","timestamp":1738581061000},"page":"465750","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":12,"special_numbering":"C","title":["Determination of carbon dioxide by gas chromatography using an electron capture detector for the analysis of greenhouse gases: A comparison and validation with the standard method"],"prefix":"10.1016","volume":"1745","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2945-7835","authenticated-orcid":false,"given":"Joan Noguerol","family":"Arias","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1848-6438","authenticated-orcid":false,"given":"August","family":"Bonmat\u00ed","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9514-7029","authenticated-orcid":false,"given":"Francesc X.","family":"Prenafeta-Bold\u00fa","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2189-1127","authenticated-orcid":false,"given":"M\u00edriam","family":"Cerrillo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.chroma.2025.465750_bib0001","series-title":"Climate Change 2023: Synthesis Report. Contribution of Working Groups I, II and III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change [Core Writing Team","first-page":"35","year":"2023"},{"key":"10.1016\/j.chroma.2025.465750_bib0002","series-title":"Agricultural Ecosystem Effects on Trace Gases and Global Climate Change","first-page":"1","article-title":"Contribution of agroecosystems to global climate change","author":"Duxbury","year":"1993"},{"key":"10.1016\/j.chroma.2025.465750_bib0003","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1016\/0269-7491(94)90027-2","article-title":"Agriculture's share in the emission of trace gases affecting the climate and some cause-oriented proposals for sufficiently reducing this share","volume":"83","author":"Isermann","year":"1994","journal-title":"Environ. Pollut."},{"issue":"8","key":"10.1016\/j.chroma.2025.465750_bib0004","doi-asserted-by":"crossref","first-page":"3139","DOI":"10.2527\/jas.2015-0017","article-title":"Analytical methods for quantifying greenhouse gas flux in animal production systems","volume":"94","author":"Powers","year":"2016","journal-title":"J. Anim. Sci."},{"issue":"4","key":"10.1016\/j.chroma.2025.465750_bib0005","doi-asserted-by":"crossref","first-page":"451","DOI":"10.2298\/HEMIND150315051Z","article-title":"Estimating precision and accuracy of GC-TCD method for carbon dioxide, propane and carbon monoxide determination at different flow rate of carrier gas","volume":"70","author":"Zuas","year":"2016","journal-title":"Hemijska Industrija"},{"key":"10.1016\/j.chroma.2025.465750_bib0006","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1016\/j.biortech.2003.01.003","article-title":"Greenhouse gas emission during storage of pig manure on a pilot scale","volume":"95","author":"Schuchardt","year":"2004","journal-title":"Bioresour. Technol."},{"issue":"5","key":"10.1016\/j.chroma.2025.465750_bib0007","doi-asserted-by":"crossref","first-page":"842","DOI":"10.1007\/BF02915410","article-title":"Quick measurement of CH4, CO2 and N2O emissions from a short-plant ecosystem","volume":"20","author":"Wang","year":"2003","journal-title":"Adv. Atmos. Sci."},{"key":"10.1016\/j.chroma.2025.465750_bib0008","first-page":"1321","article-title":"A single gas chromatograph for accurate atmospheric mixing ratio measurements of CO2, CH4, N2O, SF6 and CO","volume":"2","author":"Meijer","year":"2009","journal-title":"Atmos. Meas. Discuss."},{"key":"10.1016\/j.chroma.2025.465750_bib0009","unstructured":"Zafonte, L. Rieger, P.L., Fuentes, M., Ling, R. A precise gas chromatographic method using ECD detection for the measurement of nitrous oxide in vehicle exhaust. EPA\/AWMA Symposium on Air Quality Measurement Methods and Technology, Los Angeles, California November 2, 2010."},{"key":"10.1016\/j.chroma.2025.465750_bib0010","series-title":"Simultaneous Analysis of Greenhouse Gases by Gas Chromatography","author":"Wang","year":"2010"},{"key":"10.1016\/j.chroma.2025.465750_bib0011","series-title":"Analysis of Permanent Gases and Light Hydrocarbons Using Agilent 7820A GC with 3-Valve System Application","first-page":"5990","author":"Li","year":"2009"},{"key":"10.1016\/j.chroma.2025.465750_bib0012","series-title":"Analysis of Permanent Gases and Methane with the Agilent 6820 Gas Chromatograph","author":"Zhou","year":"2003"},{"key":"10.1016\/j.chroma.2025.465750_bib0013","doi-asserted-by":"crossref","first-page":"2001","DOI":"10.1016\/0004-6981(78)90136-1","article-title":"Gas chromatographic measurement of nitrous oxide and carbon dioxide in air using electron capture detection","volume":"12","author":"Thijsse","year":"1978","journal-title":"Atmos. Environ."},{"key":"10.1016\/j.chroma.2025.465750_bib0014","doi-asserted-by":"crossref","first-page":"593","DOI":"10.1016\/S0021-9673(00)95644-9","article-title":"Direct determination of ambient carbon dioxide and nitrous oxide with a high-temperature 63Ni electron-capture detector","volume":"166","author":"Simmonds","year":"1978","journal-title":"J. Chromatogr."},{"key":"10.1016\/j.chroma.2025.465750_bib0015","doi-asserted-by":"crossref","first-page":"142","DOI":"10.1016\/S0021-9673(00)81455-7","article-title":"Response of electron-capture detector to hydrogen, oxygen, nitrogen, carbon dioxide, nitric oxide and nitrous oxide","volume":"193","author":"Kaspar","year":"1980","journal-title":"J. Chrornatogr."},{"key":"10.1016\/j.chroma.2025.465750_bib0016","series-title":"Validation and Qualification in Analytical Laboratories","author":"Huber","year":"1998"},{"key":"10.1016\/j.chroma.2025.465750_bib0017","series-title":"General Requirements for the Competence of Testing and Calibration Laboratories","year":"2017"},{"key":"10.1016\/j.chroma.2025.465750_bib0018","doi-asserted-by":"crossref","first-page":"94","DOI":"10.1016\/j.chroma.2015.08.008","article-title":"Harmonization of the quantitative determination of volatile fatty acids profile in aqueous matrix samples by direct injection using gas chromatography and high-performance liquid chromatography techniques: multi-laboratory validation study","volume":"1413","author":"Raposo","year":"2015","journal-title":"J. Chromatogr. A"},{"issue":"5","key":"10.1016\/j.chroma.2025.465750_bib0019","doi-asserted-by":"crossref","first-page":"835","DOI":"10.1351\/pac200274050835","article-title":"Harmonized guidelines for single-laboratory validation of methods of analysis (IUPAC Technical Report)","volume":"74","author":"Thomson","year":"2002","journal-title":"Pure Appl. Chem."},{"key":"10.1016\/j.chroma.2025.465750_bib0020","unstructured":"B. Magnusson, U. \u00d6rnemark (Eds.), Eurachem Guide: The Fitness for Purpose of Analytical Methods a Laboratory Guide to Method Validation and Related Topics, 2nd ed., ISBN 978-91-87461-59-0, 2014. Available from https:\/\/www.eurachem.org."},{"key":"10.1016\/j.chroma.2025.465750_bib0021","series-title":"Statistics and Chemometrics for Analytical Chemistry","author":"Miller","year":"2010"},{"key":"10.1016\/j.chroma.2025.465750_bib0022","doi-asserted-by":"crossref","first-page":"993","DOI":"10.1351\/pac199870040993","article-title":"Guidelines for calibration in analytical chemistry. Part 1. Fundamentals and single component calibration","volume":"70","author":"Danzer","year":"1998","journal-title":"Pure Appl. Chem."},{"key":"10.1016\/j.chroma.2025.465750_bib0023","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/j.aca.2015.01.017","article-title":"Practical guidelines for reporting results in single- and multi-component analytical calibration: a tutorial","volume":"868","author":"Oliveri","year":"2015","journal-title":"Anal. Chim. Acta"},{"key":"10.1016\/j.chroma.2025.465750_bib0024","doi-asserted-by":"crossref","first-page":"1699","DOI":"10.1351\/pac199567101699","article-title":"Recommendations in evaluation of analytical methods including detection and quantification capabilities","volume":"67","author":"Currie","year":"1995","journal-title":"Pure Appl. Chem."},{"key":"10.1016\/j.chroma.2025.465750_bib0025","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.aca.2014.04.057","article-title":"Statistical comparison of the slopes of two regression lines: a tutorial","volume":"838","author":"Andrade","year":"2014","journal-title":"Anal. Chim. Acta"},{"key":"10.1016\/j.chroma.2025.465750_bib0026","doi-asserted-by":"crossref","first-page":"203","DOI":"10.1016\/j.atmosenv.2018.01.023","article-title":"Different approaches to assess the environmental performance of a cow manure biogas plant","volume":"177","author":"Torrellas","year":"2018","journal-title":"Atmos. Environ."},{"key":"10.1016\/j.chroma.2025.465750_bib0027","doi-asserted-by":"crossref","first-page":"15987","DOI":"10.3390\/su152215987","article-title":"Assessing ammonia and greenhouse gas emissions from livestock manure storage: comparison of measurements with dynamic and static chambers","volume":"25","author":"Cattaneo","year":"2023","journal-title":"Sustainability"},{"key":"10.1016\/j.chroma.2025.465750_bib0028","doi-asserted-by":"crossref","first-page":"222","DOI":"10.3390\/agronomy11020222","article-title":"Combined acidification and solar drying of pig slurries for nutrient recovery and controlled atmospheric emissions","volume":"11","author":"Prenafeta-Bold\u00fa","year":"2021","journal-title":"Agronomy"},{"issue":"1","key":"10.1016\/j.chroma.2025.465750_bib0029","first-page":"27","article-title":"Solar drying in the vineyard: a sustainable technology for the recovery of nutrients from winery organic waste","volume":"82","author":"Prenafeta-Bold\u00fa","year":"2020","journal-title":"Water Sci. Technol."},{"key":"10.1016\/j.chroma.2025.465750_bib0030","first-page":"5","article-title":"Neglecting the fallow season can significantly underestimate annual methane emissions in Mediterranean rice fields","volume":"13","author":"Mart\u0131nez-Eixarch","year":"2018","journal-title":"PLoS One"},{"issue":"1\u20132","key":"10.1016\/j.chroma.2025.465750_bib0031","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1007\/s11104-020-04809-5","article-title":"The main drivers of methane emissions differ in the growing and fallow seasons in Mediterranean rice fields","volume":"460","author":"Mart\u0131nez-Eixarch","year":"2021","journal-title":"Plant Soil"},{"key":"10.1016\/j.chroma.2025.465750_bib0032","doi-asserted-by":"crossref","first-page":"119","DOI":"10.3390\/agronomy14010119","article-title":"Effect of fertigation with struvite and ammonium nitrate on substrate microbiota and N20 emissions in a tomato crop on soilless culture system","volume":"14","author":"Carreras-Sempere","year":"2024","journal-title":"Agronomy"}],"container-title":["Journal of Chromatography A"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0021967325000998?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0021967325000998?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T22:59:35Z","timestamp":1778626775000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0021967325000998"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,3]]},"references-count":32,"alternative-id":["S0021967325000998"],"URL":"https:\/\/doi.org\/10.1016\/j.chroma.2025.465750","relation":{},"ISSN":["0021-9673"],"issn-type":[{"value":"0021-9673","type":"print"}],"subject":[],"published":{"date-parts":[[2025,3]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Determination of carbon dioxide by gas chromatography using an electron capture detector for the analysis of greenhouse gases: A comparison and validation with the standard method","name":"articletitle","label":"Article Title"},{"value":"Journal of Chromatography A","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.chroma.2025.465750","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 The Authors. Published by Elsevier B.V.","name":"copyright","label":"Copyright"}],"article-number":"465750"}}