{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T10:16:03Z","timestamp":1787998563481,"version":"build-2784847793"},"reference-count":49,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2021,6,1]],"date-time":"2021-06-01T00:00:00Z","timestamp":1622505600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2021,6,1]],"date-time":"2021-06-01T00:00:00Z","timestamp":1622505600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2021,3,24]],"date-time":"2021-03-24T00:00:00Z","timestamp":1616544000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Ecotoxicology and Environmental Safety"],"published-print":{"date-parts":[[2021,6]]},"DOI":"10.1016\/j.ecoenv.2021.112189","type":"journal-article","created":{"date-parts":[[2021,4,2]],"date-time":"2021-04-02T17:46:23Z","timestamp":1617385583000},"page":"112189","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":40,"special_numbering":"C","title":["Enhanced peroxymonosulfate activation over heterogeneous catalyst Cu0.76Co2.24O4\/SBA-15 for efficient degradation of sulfapyridine antibiotic"],"prefix":"10.1016","volume":"216","author":[{"given":"Jiahong","family":"He","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taiping","family":"Xie","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianhong","family":"Luo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Ye","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jibin","family":"An","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiankang","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.ecoenv.2021.112189_bib1","doi-asserted-by":"crossref","first-page":"234","DOI":"10.1016\/j.cej.2019.01.129","article-title":"Metal-organic framework-derived hollow Co3O4\/carbon as efficient catalyst for peroxymonosulfate activation","volume":"363","author":"Abdul Nasir Khan","year":"2019","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib2","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1016\/j.watres.2018.12.007","article-title":"Elucidation of stoichiometric efficiency, radical generation and transformation pathway during catalytic oxidation of sulfamethoxazole via peroxymonosulfate activation","volume":"151","author":"Bao","year":"2019","journal-title":"Water Res."},{"key":"10.1016\/j.ecoenv.2021.112189_bib3","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1016\/j.jhazmat.2014.04.054","article-title":"Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes","volume":"275","author":"Bokare","year":"2014","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.ecoenv.2021.112189_bib4","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2020.125279","article-title":"Magnetic iron phosphide particles mediated peroxymonosulfate activation for highly efficient elimination of sulfonamide antibiotics","volume":"397","author":"Cai","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib5","doi-asserted-by":"crossref","first-page":"1304","DOI":"10.1016\/j.cej.2018.12.156","article-title":"Sulfur-doped copper-cobalt bimetallic oxides with abundant Cu(I), a novel peroxymonosulfate activator for chloramphenicol degradation","volume":"361","author":"Chen","year":"2019","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib6","doi-asserted-by":"crossref","DOI":"10.1016\/j.watres.2020.115559","article-title":"Catalytic degradation of ciprofloxacin by a visible-light-assisted peroxymonosulfate activation system: performance and mechanism","volume":"173","author":"Chen","year":"2020","journal-title":"Water Res."},{"key":"10.1016\/j.ecoenv.2021.112189_bib7","doi-asserted-by":"crossref","first-page":"456","DOI":"10.1016\/j.seppur.2018.12.049","article-title":"Novel magnetic MnO2\/MnFe2O4 nanocomposite as a heterogeneous catalyst for activation of peroxymonosulfate (PMS) toward oxidation of organic pollutants","volume":"213","author":"Chen","year":"2019","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.ecoenv.2021.112189_bib8","doi-asserted-by":"crossref","first-page":"941","DOI":"10.1016\/j.cej.2018.08.049","article-title":"Graphene- and CNTs-based carbocatalysts in persulfates activation, material design and catalytic mechanisms","volume":"354","author":"Chen","year":"2018","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib9","doi-asserted-by":"crossref","first-page":"2054","DOI":"10.1021\/acs.est.8b05901","article-title":"Overlooked role of peroxides as free radical precursors in advanced oxidation processes","volume":"53","author":"Chen","year":"2019","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.ecoenv.2021.112189_bib10","doi-asserted-by":"crossref","first-page":"505","DOI":"10.1016\/j.cej.2016.09.075","article-title":"Heterogeneous activation of peroxymonosulfate using ordered mesoporous Co3O4 for the degradation of chloramphenicol at neutral pH","volume":"308","author":"Deng","year":"2017","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib11","doi-asserted-by":"crossref","first-page":"505","DOI":"10.1016\/j.cej.2017.07.149","article-title":"Mesoporous manganese cobaltite nanocages as effective and reusable heterogeneous peroxymonosulfate activators for carbamazepine degradation","volume":"330","author":"Deng","year":"2017","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib12","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2018.05.177","article-title":"Facile preparation of porous Mn\/Fe3O4 cubes as peroxymonosulfate activating catalyst for effective bisphenol A degradation","volume":"376","author":"Du","year":"2019","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib13","doi-asserted-by":"crossref","first-page":"4169","DOI":"10.1021\/am508416n","article-title":"Nitrogen-doped graphene for generation and evolution of reactive radicals by metal-free catalysis","volume":"7","author":"Duan","year":"2015","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"10.1016\/j.ecoenv.2021.112189_bib14","doi-asserted-by":"crossref","first-page":"176","DOI":"10.1016\/j.apcatb.2017.10.007","article-title":"Nanodiamonds in sp2\/sp3 configuration for radical to nonradical oxidation, core-shell layer dependence","volume":"222","author":"Duan","year":"2018","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.ecoenv.2021.112189_bib15","doi-asserted-by":"crossref","first-page":"514","DOI":"10.1016\/j.cej.2015.05.121","article-title":"Efficient degradation of sulfamethazine with CuCo2O4 spinel nanocatalysts for peroxymonosulfate activation","volume":"280","author":"Feng","year":"2015","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib16","doi-asserted-by":"crossref","first-page":"1232","DOI":"10.1021\/acs.est.9b05856","article-title":"New insights into the generation of singlet oxygen in the metal-free peroxymonosulfate activation process, important role of electron-deficient carbon atoms","volume":"54","author":"Gao","year":"2020","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.ecoenv.2021.112189_bib17","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2019.123936","article-title":"Insights into the difference in metal-free activation of peroxymonosulfate and peroxydisulfate","volume":"394","author":"Gao","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib18","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1016\/j.cej.2016.10.064","article-title":"Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants, review","volume":"310","author":"Ghanbari","year":"2017","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib19","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.materresbull.2018.10.044","article-title":"Preparation and oxygen sensing properties of water-soluble silicon nanoparticles assembled SBA-15","volume":"111","author":"Gong","year":"2019","journal-title":"Mater. Res. Bull."},{"key":"10.1016\/j.ecoenv.2021.112189_bib20","doi-asserted-by":"crossref","first-page":"3029","DOI":"10.1021\/acs.chemrev.5b00407","article-title":"Superoxide ion, generation and chemical implications","volume":"116","author":"Hayyan","year":"2016","journal-title":"Chem. Rev."},{"key":"10.1016\/j.ecoenv.2021.112189_bib21","doi-asserted-by":"crossref","first-page":"352","DOI":"10.1016\/j.scitotenv.2018.08.003","article-title":"Application of nickel foam-supported Co3O4-Bi2O3 as a heterogeneous catalyst for BPA removal by peroxymonosulfate activation","volume":"647","author":"Hu","year":"2019","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.ecoenv.2021.112189_bib22","doi-asserted-by":"crossref","DOI":"10.1016\/j.envpol.2019.113809","article-title":"Ball milled biochar effectively removes sulfamethoxazole and sulfapyridine antibiotics from water and wastewater","volume":"258","author":"Huang","year":"2020","journal-title":"Environ. Pollut."},{"key":"10.1016\/j.ecoenv.2021.112189_bib23","doi-asserted-by":"crossref","first-page":"864","DOI":"10.1016\/j.scitotenv.2018.04.321","article-title":"Transformation of antimicrobial agent sulfamethazine by peroxymonosulfate, radical vs. nonradical mechanisms","volume":"636","author":"Jiang","year":"2018","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.ecoenv.2021.112189_bib24","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1016\/j.matchemphys.2015.12.019","article-title":"NiCo2O4 nanospinel and its catalytic activity for oxidation of Rhodamine B at ambient conditions","volume":"170","author":"Kaikhosravi","year":"2016","journal-title":"Mater. Chem. Phys."},{"key":"10.1016\/j.ecoenv.2021.112189_bib25","doi-asserted-by":"crossref","first-page":"549","DOI":"10.1016\/j.chemosphere.2019.05.291","article-title":"Singlet oxygen dominated peroxymonosulfate activation by CuO-CeO2 for organic pollutants degradation, performance and mechanism","volume":"233","author":"Li","year":"2019","journal-title":"Chemosphere"},{"key":"10.1016\/j.ecoenv.2021.112189_bib26","doi-asserted-by":"crossref","first-page":"357","DOI":"10.1016\/j.talanta.2018.10.047","article-title":"Nanostructured hybrid surface enhancement Raman scattering substrate for the rapid determination of SPD in milk samples","volume":"194","author":"Moreno","year":"2019","journal-title":"Talanta"},{"key":"10.1016\/j.ecoenv.2021.112189_bib27","doi-asserted-by":"crossref","first-page":"11302","DOI":"10.1021\/acs.chemrev.7b00161","article-title":"Generation and detection of reactive oxygen species in photocatalysis","volume":"117","author":"Nosaka","year":"2017","journal-title":"Chem. Rev."},{"key":"10.1016\/j.ecoenv.2021.112189_bib28","doi-asserted-by":"crossref","first-page":"897","DOI":"10.1016\/j.cej.2016.07.027","article-title":"LaCoO3 perovskite oxide activation of peroxymonosulfate for aqueous 2-phenyl-5-sulfobenzimidazole degradation, effect of synthetic method and the reaction mechanism","volume":"304","author":"Pang","year":"2016","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib29","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2020.122316","article-title":"Non-radical PMS activation by the nanohybrid material with periodic confinement of reduced graphene oxide (rGO) and Cu hydroxides","volume":"392","author":"Shahzad","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.ecoenv.2021.112189_bib30","doi-asserted-by":"crossref","first-page":"264","DOI":"10.1016\/j.cej.2013.11.089","article-title":"Synergistic catalysis of Co3O4 and graphene oxide on Co3O4\/GO catalysts for degradation of Orange II in water by advanced oxidation technology based on sulfate radicals","volume":"240","author":"Shi","year":"2014","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib31","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.119005","article-title":"Strategic combination of N-doped graphene and g-C3N4: efficient catalytic peroxymonosulfate-based oxidation of organic pollutants by non-radical-dominated processes","volume":"272","author":"Sun","year":"2020","journal-title":"Appl. Catal. B: Environ."},{"key":"10.1016\/j.ecoenv.2021.112189_bib32","doi-asserted-by":"crossref","first-page":"144","DOI":"10.1016\/j.cej.2017.08.115","article-title":"Controlled synthesis of dandelion-like NiCo2O4 microspheres and their catalytic performance for peroxymonosulfate activation in humic acid degradation","volume":"331","author":"Tian","year":"2018","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib33","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202005158","article-title":"Piezocatalysis and piezo\u2010photocatalysis: catalysts classification and modification strategy, reaction mechanism, and practical application","volume":"30","author":"Tu","year":"2020","journal-title":"Adv. Funct. Mater."},{"key":"10.1016\/j.ecoenv.2021.112189_bib34","doi-asserted-by":"crossref","DOI":"10.1016\/j.scitotenv.2019.135023","article-title":"Degradation of antibiotics by advanced oxidation processes: an overview","volume":"701","author":"Wang","year":"2020","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.ecoenv.2021.112189_bib35","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2019.123554","article-title":"Highly-efficient degradation of triclosan attributed to peroxymonosulfate activation by heterogeneous catalyst g-C3N4\/MnFe2O4","volume":"391","author":"Wang","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib36","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2019.121995","article-title":"A stable and easily prepared copper oxide catalyst for degradation of organic pollutants by peroxymonosulfate activation","volume":"387","author":"Wang","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.ecoenv.2021.112189_bib37","doi-asserted-by":"crossref","DOI":"10.1016\/j.micromeso.2020.110211","article-title":"Simple and controllable preparation of SBA-15 microspheres by poly(vinyl alcohol)-assisted P123 templating system","volume":"302","author":"Wang","year":"2020","journal-title":"Microporous Mesoporous Mater."},{"key":"10.1016\/j.ecoenv.2021.112189_bib38","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.118981","article-title":"Facile synthesis of metal free perylene imide-carbon nitride membranes for efficient photocatalytic degradation of organic pollutants in the presence of peroxymonosulfate","volume":"278","author":"Wang","year":"2020","journal-title":"Appl. Catal. B: Environ."},{"key":"10.1016\/j.ecoenv.2021.112189_bib39","doi-asserted-by":"crossref","first-page":"2","DOI":"10.1590\/S1808-86942012000200001","article-title":"Antibi\u00f3ticos: do uso ao abuso","volume":"78","author":"Weckx","year":"2012","journal-title":"Braz. J. Otorhinolaryngol."},{"key":"10.1016\/j.ecoenv.2021.112189_bib40","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1016\/j.vacuum.2013.01.005","article-title":"Synthesis and adsorption properties of high specific surface area strontium ferrite from industrial strontium residue","volume":"93","author":"Xie","year":"2013","journal-title":"Vacuum"},{"key":"10.1016\/j.ecoenv.2021.112189_bib41","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2019.143577","article-title":"FeCoOX\/FeCoPX nanoparticles encapsulated N, S-doped porous carbon microspheres as catalysts for the elimination of organic pollutants","volume":"495","author":"Xu","year":"2019","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.ecoenv.2021.112189_bib42","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2019.118549","article-title":"Novel magnetic rod-like Mn-Fe oxycarbide toward peroxymonosulfate activation for efficient oxidation of butyl paraben: radical oxidation versus singlet oxygenation","volume":"268","author":"Yang","year":"2020","journal-title":"Appl. Catal. B: Environ."},{"key":"10.1016\/j.ecoenv.2021.112189_bib43","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.118850","article-title":"Nitrogen-doped biochar fiber with graphitization from Boehmeria nivea for promoted peroxymonosulfate activation and non-radical degradation pathways with enhancing electron transfer","volume":"269","author":"Ye","year":"2020","journal-title":"Appl. Catal. B: Environ."},{"key":"10.1016\/j.ecoenv.2021.112189_bib44","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2019.121998","article-title":"Copper substituted zinc ferrite with abundant oxygen vacancies for enhanced ciprofloxacin degradation via peroxymonosulfate activation","volume":"390","author":"Yu","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.ecoenv.2021.112189_bib45","doi-asserted-by":"crossref","first-page":"1430","DOI":"10.1016\/j.cej.2017.11.078","article-title":"Degradation of organic pollutants by Co3O4-mediated peroxymonosulfate oxidation, roles of high-energy {0\u00a00\u00a01}-exposed TiO2 support","volume":"334","author":"Zhang","year":"2018","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib46","doi-asserted-by":"crossref","first-page":"834","DOI":"10.1016\/j.cej.2019.03.132","article-title":"Enhanced removal of lomefloxacin based on peroxymonosulfate activation by Co3O4\/\u03b4-FeOOH composite","volume":"369","author":"Zhang","year":"2019","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib47","doi-asserted-by":"crossref","DOI":"10.1016\/j.matdes.2020.108772","article-title":"Boosting visible-light-driven photocatalytic activity of BiPO4 via constructing Schottky junction with Ti3C2 MXene","volume":"192","author":"Zhang","year":"2020","journal-title":"Mater. Des."},{"key":"10.1016\/j.ecoenv.2021.112189_bib48","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2019.122148","article-title":"Electricity generating & high efficiency advanced oxidation process including peroxymonosulfate activation in photocatalytic fuel cell","volume":"378","author":"Zhang","year":"2019","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.ecoenv.2021.112189_bib49","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202003947","article-title":"Confinement of CoP nanoparticles in nitrogen-doped yolk-shell porous carbon polyhedron for ultrafast catalytic oxidation","volume":"30","author":"Zhu","year":"2020","journal-title":"Adv. Funct. Mater."}],"container-title":["Ecotoxicology and Environmental Safety"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0147651321003006?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0147651321003006?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,9,27]],"date-time":"2025-09-27T05:29:23Z","timestamp":1758950963000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0147651321003006"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,6]]},"references-count":49,"alternative-id":["S0147651321003006"],"URL":"https:\/\/doi.org\/10.1016\/j.ecoenv.2021.112189","relation":{},"ISSN":["0147-6513"],"issn-type":[{"value":"0147-6513","type":"print"}],"subject":[],"published":{"date-parts":[[2021,6]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Enhanced peroxymonosulfate activation over heterogeneous catalyst Cu0.76Co2.24O4\/SBA-15 for efficient degradation of sulfapyridine antibiotic","name":"articletitle","label":"Article Title"},{"value":"Ecotoxicology and Environmental Safety","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.ecoenv.2021.112189","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2021 The Author(s). Published by Elsevier Inc.","name":"copyright","label":"Copyright"}],"article-number":"112189"}}