{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T14:11:21Z","timestamp":1791727881081,"version":"4.3.4"},"reference-count":43,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2025,4,1]],"date-time":"2025-04-01T00:00:00Z","timestamp":1743465600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2025,4,1]],"date-time":"2025-04-01T00:00:00Z","timestamp":1743465600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2025,4,1]],"date-time":"2025-04-01T00:00:00Z","timestamp":1743465600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2025,4,1]],"date-time":"2025-04-01T00:00:00Z","timestamp":1743465600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,4,1]],"date-time":"2025-04-01T00:00:00Z","timestamp":1743465600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2025,4,1]],"date-time":"2025-04-01T00:00:00Z","timestamp":1743465600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,4,1]],"date-time":"2025-04-01T00:00:00Z","timestamp":1743465600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100000288","name":"Royal Society","doi-asserted-by":"publisher","award":["IES\\\\R1\\\\211133"],"award-info":[{"award-number":["IES\\\\R1\\\\211133"]}],"id":[{"id":"10.13039\/501100000288","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21977060"],"award-info":[{"award-number":["21977060"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Environmental Research"],"published-print":{"date-parts":[[2025,4]]},"DOI":"10.1016\/j.envres.2025.121091","type":"journal-article","created":{"date-parts":[[2025,2,11]],"date-time":"2025-02-11T18:50:45Z","timestamp":1739299845000},"page":"121091","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":10,"special_numbering":"C","title":["Careful attention to the eco-toxicity and secondary water pollution of the degradation by-products"],"prefix":"10.1016","volume":"271","author":[{"given":"Chengyue","family":"Han","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenqi","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiran","family":"Teng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanming","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhihui","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tongguang","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yalin","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Teng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.envres.2025.121091_bib1","doi-asserted-by":"crossref","DOI":"10.1016\/j.mssp.2022.106502","article-title":"Insight into the activation of persulfate with Cu2O\/visible-light: Cu(I) based photo-Fenton and Cu2O surface mediated free radical mechanism","volume":"143","author":"Cai","year":"2022","journal-title":"Mater. Sci. Semicond. Process."},{"key":"10.1016\/j.envres.2025.121091_bib2","doi-asserted-by":"crossref","DOI":"10.1016\/j.watres.2023.120132","article-title":"Deciphering of sulfonamide biodegradation mechanism in wetland sediments: from microbial community and individual populations to pathway and functional genes","volume":"240","author":"Chen","year":"2023","journal-title":"Water Res."},{"key":"10.1016\/j.envres.2025.121091_bib3","doi-asserted-by":"crossref","DOI":"10.1016\/j.chemosphere.2023.137857","article-title":"Visible light enhanced persulfate activation for degradation of tetracycline via boosting adsorption of persulfate by ligand-deficient MIL-101(Fe) icosahedron","volume":"317","author":"Cheng","year":"2023","journal-title":"Chemosphere"},{"key":"10.1016\/j.envres.2025.121091_bib4","doi-asserted-by":"crossref","first-page":"358","DOI":"10.1016\/j.apcatb.2017.03.011","article-title":"Homogeneous photo-Fenton processes at near neutral pH: a review","volume":"209","author":"Clarizia","year":"2017","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121091_bib5","doi-asserted-by":"crossref","first-page":"4706","DOI":"10.1039\/c1nr10665a","article-title":"Strong photo-response in a flip-chip nanowire p-Cu2O\/n-ZnO junction","volume":"3","author":"Deo","year":"2011","journal-title":"Nanoscale"},{"key":"10.1016\/j.envres.2025.121091_bib6","doi-asserted-by":"crossref","DOI":"10.1016\/j.watres.2024.121546","article-title":"Formation of nitrated naphthalene in the sulfate radical oxidation process in the presence of nitrite","volume":"255","author":"Dong","year":"2024","journal-title":"Water Res."},{"key":"10.1016\/j.envres.2025.121091_bib7","doi-asserted-by":"crossref","first-page":"566","DOI":"10.1016\/S1872-2067(17)62996-6","article-title":"Copper-based non-precious metal heterogeneous catalysts for environmental remediation","volume":"39","author":"Fang","year":"2018","journal-title":"Chin. J. Catal."},{"key":"10.1016\/j.envres.2025.121091_bib8","doi-asserted-by":"crossref","first-page":"8613","DOI":"10.1007\/s11356-021-16337-5","article-title":"Enhanced photocatalytic activity of Cu2O for visible light-driven dye degradation by carbon quantum dots","volume":"29","author":"Feng","year":"2022","journal-title":"Environ. Sci. Pollut. Res."},{"key":"10.1016\/j.envres.2025.121091_bib9","doi-asserted-by":"crossref","DOI":"10.1016\/j.coche.2023.100974","article-title":"The application of advanced oxidation processes (AOPs) to treat unconventional water for fit-for-purpose reuse","volume":"42","author":"Gao","year":"2023","journal-title":"Curr. Opin. Chem. Eng."},{"key":"10.1016\/j.envres.2025.121091_bib10","doi-asserted-by":"crossref","first-page":"6822","DOI":"10.1021\/es1010225","article-title":"Effect of halide ions and carbonates on organic contaminant degradation by hydroxyl radical-based advanced oxidation processes in saline waters","volume":"44","author":"Grebel","year":"2010","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.envres.2025.121091_bib11","doi-asserted-by":"crossref","first-page":"13668","DOI":"10.1039\/C8TA01828F","article-title":"Cu2O templating strategy for the synthesis of octahedral Cu2O@Mn(OH)2 core\u2013shell hierarchical structures with a superior performance supercapacitor","volume":"6","author":"Guan","year":"2018","journal-title":"J. Mater. Chem. A"},{"key":"10.1016\/j.envres.2025.121091_bib12","doi-asserted-by":"crossref","first-page":"12137","DOI":"10.1021\/jacs.8b06961","article-title":"Engineered polymer nanoparticles with unprecedented antimicrobial efficacy and therapeutic indices against multidrug-resistant bacteria and biofilms","volume":"140","author":"Gupta","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.envres.2025.121091_bib13","doi-asserted-by":"crossref","DOI":"10.1016\/j.watres.2020.115587","article-title":"Degradation of contaminants of emerging concern by UV\/H2O2 for water reuse: kinetics, mechanisms, and cytotoxicity analysis","volume":"174","author":"Huang","year":"2020","journal-title":"Water Res."},{"key":"10.1016\/j.envres.2025.121091_bib14","series-title":"Developments in Water Science, Water Resources Systems Planning and Management","first-page":"743","article-title":"Chapter 13 - water quality modeling","author":"Jain","year":"2003"},{"key":"10.1016\/j.envres.2025.121091_bib15","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1016\/j.psep.2019.11.041","article-title":"Degradation of pesticide thiamethoxam by heat \u2013 activated and ultrasound \u2013 activated persulfate: effect of key operating parameters and the water matrix","volume":"134","author":"Lebik-Elhadi","year":"2020","journal-title":"Process Saf. Environ. Prot."},{"key":"10.1016\/j.envres.2025.121091_bib16","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2020.122261","article-title":"Recent advances in Cu-Fenton systems for the treatment of industrial wastewaters: role of Cu complexes and Cu composites","volume":"392","author":"Li","year":"2020","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.envres.2025.121091_bib17","article-title":"Ammonium changes the pathway of tetrabromobisphenol S degradation by sulfate radical oxidation","volume":"475","author":"Liu","year":"2023","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.envres.2025.121091_bib18","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2021.120066","article-title":"Improvement of the photo-Fenton process at natural condition of pH using organic fertilizers mixtures: potential application to agricultural reuse of wastewater","volume":"290","author":"L\u00f3pez-Vinent","year":"2021","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121091_bib19","doi-asserted-by":"crossref","first-page":"5060","DOI":"10.1021\/acs.est.6b00327","article-title":"Natural organic matter exposed to sulfate radicals increases its potential to form halogenated disinfection byproducts","volume":"50","author":"Lu","year":"2016","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.envres.2025.121091_bib20","doi-asserted-by":"crossref","first-page":"296","DOI":"10.1016\/j.chemosphere.2017.09.148","article-title":"Impacts of inorganic anions and natural organic matter on thermally activated persulfate oxidation of BTEX in water","volume":"190","author":"Ma","year":"2018","journal-title":"Chemosphere"},{"key":"10.1016\/j.envres.2025.121091_bib21","article-title":"Self-templated formation of uniform F-CuO hollow octahedra for lithium ion batteries","volume":"13","author":"Ma","year":"2017","journal-title":"Small Weinh. Bergstr. Ger."},{"key":"10.1016\/j.envres.2025.121091_bib22","doi-asserted-by":"crossref","first-page":"661","DOI":"10.1126\/science.250.4981.661","article-title":"Hydroxyl radical photoproduction in the sea and its potential impact on marine processes","volume":"250","author":"Mopper","year":"1990","journal-title":"Science"},{"key":"10.1016\/j.envres.2025.121091_bib23","article-title":"Oxidation of emerging organic contaminants by in-situ H2O2 fenton system","author":"Ni","year":"2023","journal-title":"Green Energy Environ."},{"key":"10.1016\/j.envres.2025.121091_bib24","doi-asserted-by":"crossref","DOI":"10.1016\/j.jenvman.2022.115295","article-title":"Advanced oxidation processes: performance, advantages, and scale-up of emerging technologies","volume":"316","author":"Priyadarshini","year":"2022","journal-title":"J. Environ. Manag."},{"key":"10.1016\/j.envres.2025.121091_bib25","doi-asserted-by":"crossref","first-page":"12371","DOI":"10.1021\/acs.chemrev.3c00326","article-title":"Photocatalytic antimicrobials: principles, design strategies, and applications","volume":"123","author":"Ran","year":"2023","journal-title":"Chem. Rev."},{"key":"10.1016\/j.envres.2025.121091_bib26","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2020.125390","article-title":"Plasmon-induced interfacial charge-transfer transition prompts enhanced CO2 photoreduction over Cu\/Cu2O octahedrons","volume":"397","author":"Sayed","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.envres.2025.121091_bib27","doi-asserted-by":"crossref","first-page":"14011","DOI":"10.1021\/acs.iecr.8b02697","article-title":"Degradation of organic dyes over fenton-like Cu2O\u2013Cu\/C catalysts","volume":"57","author":"Sun","year":"2018","journal-title":"Ind. Eng. Chem. Res."},{"key":"10.1016\/j.envres.2025.121091_bib28","doi-asserted-by":"crossref","first-page":"433","DOI":"10.1038\/s44221-023-00070-z","article-title":"Removal of pharmaceutical pollutants from effluent by a plant-based metal\u2013organic framework","volume":"1","author":"Svensson Grape","year":"2023","journal-title":"Nat. Water"},{"key":"10.1016\/j.envres.2025.121091_bib29","doi-asserted-by":"crossref","first-page":"889","DOI":"10.1038\/s41929-019-0338-z","article-title":"Cu2O nanocubes with mixed oxidation-state facets for (photo)catalytic hydrogenation of carbon dioxide","volume":"2","author":"Wan","year":"2019","journal-title":"Nat. Catal."},{"key":"10.1016\/j.envres.2025.121091_bib30","doi-asserted-by":"crossref","first-page":"19","DOI":"10.1016\/j.eng.2022.08.005","article-title":"Photo-based advanced oxidation processes for zero pollution: where are we now?","volume":"23","author":"Wang","year":"2023","journal-title":"Engineering"},{"key":"10.1016\/j.envres.2025.121091_bib31","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2023.132479","article-title":"Mechanism analysis of surface structure-regulated Cu2O in photocatalytic antibacterial process","volume":"461","author":"Wang","year":"2024","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.envres.2025.121091_bib32","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2023.132479","article-title":"Mechanism analysis of surface structure-regulated Cu2O in photocatalytic antibacterial process","volume":"461","author":"Wang","year":"2024","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.envres.2025.121091_bib33","doi-asserted-by":"crossref","first-page":"462","DOI":"10.1038\/s44221-023-00079-4","article-title":"Solar-driven efficient heterogeneous subminute water disinfection nanosystem assembled with fingerprint MoS2","volume":"1","author":"Wu","year":"2023","journal-title":"Nat. Water"},{"key":"10.1016\/j.envres.2025.121091_bib34","doi-asserted-by":"crossref","DOI":"10.1016\/j.reactfunctpolym.2023.105759","article-title":"Supramolecular cellulose-based heavy metal adsorbent for efficient and accurate removal of cobalt (II) for water treatment","volume":"194","author":"Wu","year":"2024","journal-title":"React. Funct. Polym."},{"key":"10.1016\/j.envres.2025.121091_bib35","doi-asserted-by":"crossref","first-page":"12153","DOI":"10.1021\/acs.est.3c05153","article-title":"Merits and limitations of radical vs. Nonradical pathways in persulfate-based advanced oxidation processes","volume":"57","author":"Yan","year":"2023","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.envres.2025.121091_bib36","doi-asserted-by":"crossref","DOI":"10.1016\/j.watres.2021.117432","article-title":"Transformation of ammonium to nitrophenolic byproducts by sulfate radical oxidation","volume":"202","author":"Yang","year":"2021","journal-title":"Water Res."},{"key":"10.1016\/j.envres.2025.121091_bib37","doi-asserted-by":"crossref","first-page":"7935","DOI":"10.1021\/acs.est.2c00702","article-title":"Differentiation of pathways of nitrated byproduct formation from ammonium and nitrite during sulfate radical oxidation","volume":"56","author":"Yang","year":"2022","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.envres.2025.121091_bib38","doi-asserted-by":"crossref","first-page":"316","DOI":"10.1016\/j.cej.2019.05.177","article-title":"Photocatalytic degradation of ciprofloxacin using Zn-doped Cu2O particles: analysis of degradation pathways and intermediates","volume":"374","author":"Yu","year":"2019","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.envres.2025.121091_bib39","doi-asserted-by":"crossref","first-page":"2497","DOI":"10.3390\/w14162497","article-title":"Synergistic effect of ferrate with various water processing techniques\u2014a review","volume":"14","author":"Zhang","year":"2022","journal-title":"Water"},{"key":"10.1016\/j.envres.2025.121091_bib40","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2022.121525","article-title":"Resin-based photo-self-Fenton system with intensive mineralization by the synergistic effect of holes and hydroxyl radicals","volume":"315","author":"Zhang","year":"2022","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121091_bib41","doi-asserted-by":"crossref","first-page":"4091","DOI":"10.1039\/D0DT04434B","article-title":"Recent advances in Cu2O-based composites for photocatalysis: a review","volume":"50","author":"Zhang","year":"2021","journal-title":"Dalton Trans"},{"key":"10.1016\/j.envres.2025.121091_bib42","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2019.123297","article-title":"Degradation of triclosan in a peroxymonosulfate\/Br system: identification of reactive species and formation of halogenated byproducts","volume":"384","author":"Zhao","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.envres.2025.121091_bib43","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2024.151502","article-title":"Comparative study of the degradation of meta-chloronitrobenzene by UV\/hydrogen peroxide and UV\/persulfate oxidation: degradation pathways and toxicity","volume":"490","author":"Zhao","year":"2024","journal-title":"Chem. Eng. J."}],"container-title":["Environmental Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0013935125003421?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0013935125003421?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,5,28]],"date-time":"2026-05-28T04:24:43Z","timestamp":1779942283000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0013935125003421"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4]]},"references-count":43,"alternative-id":["S0013935125003421"],"URL":"https:\/\/doi.org\/10.1016\/j.envres.2025.121091","relation":{},"ISSN":["0013-9351"],"issn-type":[{"value":"0013-9351","type":"print"}],"subject":[],"published":{"date-parts":[[2025,4]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Careful attention to the eco-toxicity and secondary water pollution of the degradation by-products","name":"articletitle","label":"Article Title"},{"value":"Environmental Research","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.envres.2025.121091","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 Elsevier Inc. All rights are reserved, including those for text and data mining, AI training, and similar technologies.","name":"copyright","label":"Copyright"}],"article-number":"121091"}}