{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T21:14:00Z","timestamp":1788902040909,"version":"build-2803163510"},"reference-count":48,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T00:00:00Z","timestamp":1754006400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T00:00:00Z","timestamp":1754006400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T00:00:00Z","timestamp":1754006400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T00:00:00Z","timestamp":1754006400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T00:00:00Z","timestamp":1754006400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T00:00:00Z","timestamp":1754006400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T00:00:00Z","timestamp":1754006400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21806016"],"award-info":[{"award-number":["21806016"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["DUT22JC15"],"award-info":[{"award-number":["DUT22JC15"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Environmental Research"],"published-print":{"date-parts":[[2025,8]]},"DOI":"10.1016\/j.envres.2025.121788","type":"journal-article","created":{"date-parts":[[2025,5,7]],"date-time":"2025-05-07T02:51:54Z","timestamp":1746586314000},"page":"121788","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":10,"special_numbering":"P1","title":["Alpha-MnO2 catalyst with high formaldehyde oxidation and moisture resistance by joint cerium modification and phosphoric acid post-treatment"],"prefix":"10.1016","volume":"279","author":[{"given":"Tian-Yun","family":"Chen","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5488-7052","authenticated-orcid":false,"given":"Yang","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhonghong","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xudong","family":"Shen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingjing","family":"Zhan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Zhou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xianliang","family":"Yi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.envres.2025.121788_bib1","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2022.136603","article-title":"Atomic layer deposited Pt\/TiO2-SiO2 and Pt\/ZrO2-SiO2 for sequential adsorption and oxidation of VOCs","volume":"444","author":"Adebayo","year":"2022","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.envres.2025.121788_bib2","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2021.150596","article-title":"The structural evolution of MnOx with calcination temperature and their catalytic performance for propane total oxidation","volume":"565","author":"Cai","year":"2021","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.envres.2025.121788_bib3","doi-asserted-by":"crossref","first-page":"6176","DOI":"10.1021\/acscatal.0c00459","article-title":"Investigation into the catalytic roles of various oxygen species over different crystal phases of MnO2 for C6H6 and HCHO oxidation","volume":"10","author":"Chen","year":"2020","journal-title":"ACS Catal."},{"key":"10.1016\/j.envres.2025.121788_bib4","doi-asserted-by":"crossref","first-page":"10378","DOI":"10.1021\/acs.est.4c01606","article-title":"Efficient and durable oxidation removal of formaldehyde over layered double hydroxide catalysts at room temperature","volume":"58","author":"Chen","year":"2024","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.envres.2025.121788_bib5","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2024.161526","article-title":"Oxidative degradation of formaldehyde by birnessite: synergistic interaction of Mn(\u2162) and oxygen vacancies","volume":"681","author":"Chen","year":"2025","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.envres.2025.121788_bib6","doi-asserted-by":"crossref","first-page":"13430","DOI":"10.1021\/acs.est.8b05002","article-title":"Phosphate-functionalized CeO2 nanosheets for efficient catalytic oxidation of dichloromethane","volume":"52","author":"Dai","year":"2018","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.envres.2025.121788_bib7","doi-asserted-by":"crossref","first-page":"48270","DOI":"10.1007\/s11356-023-25764-5","article-title":"Cardanol-based adhesive with reduced formaldehyde emission to produce particleboards with waste from bean crops","volume":"30","author":"Faria","year":"2023","journal-title":"Environ. Sci. Pollut. Res."},{"key":"10.1016\/j.envres.2025.121788_bib8","doi-asserted-by":"crossref","DOI":"10.1016\/j.mineng.2020.106729","article-title":"In-situ study of the kinetics of phosphoric acid interaction with calcite and fluorapatite by raman spectroscopy and flotation","volume":"162","author":"Filippov","year":"2021","journal-title":"Miner. Eng."},{"key":"10.1016\/j.envres.2025.121788_bib9","doi-asserted-by":"crossref","first-page":"922","DOI":"10.1021\/jp9097606","article-title":"Synthesis and properties of layered-structured Mn5O8 nanorods","volume":"114","author":"Gao","year":"2010","journal-title":"J. Phys. Chem. C"},{"key":"10.1016\/j.envres.2025.121788_bib10","doi-asserted-by":"crossref","DOI":"10.1016\/j.jclepro.2022.134242","article-title":"Critical review of catalytic degradation of formaldehyde via MnO2: from the perspective of process intensification","volume":"377","author":"Gong","year":"2022","journal-title":"J. Clean. Prod."},{"key":"10.1016\/j.envres.2025.121788_bib11","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.119447","article-title":"Recent advances in VOC elimination by catalytic oxidation technology onto various nanoparticles catalysts: a critical review","volume":"281","author":"Guo","year":"2021","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121788_bib12","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2021.120881","article-title":"Realizing a redox-robust Ag\/MnO2 catalyst for efficient wet catalytic ozonation of S-VOCs: promotional role of Ag(0)\/Ag(I)-Mn based redox shuttle","volume":"303","author":"He","year":"2022","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121788_bib13","doi-asserted-by":"crossref","first-page":"6736","DOI":"10.1039\/c3ta11566f","article-title":"Effect of giant oxygen vacancy defects on the catalytic oxidation of OMS-2 nanorods","volume":"1","author":"Hou","year":"2013","journal-title":"J. Mater. Chem. A"},{"key":"10.1016\/j.envres.2025.121788_bib14","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.119294","article-title":"Oxygen vacancy\u2013engineered \u03b4-MnOx\/activated carbon for room-temperature catalytic oxidation of formaldehyde","volume":"278","author":"Huang","year":"2020","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121788_bib15","doi-asserted-by":"crossref","DOI":"10.1016\/j.buildenv.2022.109380","article-title":"Evaluation of low-cost formaldehyde sensors calibration","volume":"222","author":"Justo Alonso","year":"2022","journal-title":"Build. Environ."},{"key":"10.1016\/j.envres.2025.121788_bib16","doi-asserted-by":"crossref","first-page":"864","DOI":"10.1016\/j.saa.2006.09.001","article-title":"IR spectra of manganese oxides with either layered or tunnel structures","volume":"67","author":"Kang","year":"2007","journal-title":"Spectrochim. Acta, Part A"},{"key":"10.1016\/j.envres.2025.121788_bib17","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.118755","article-title":"Introduce oxygen vacancies into CeO2 catalyst for enhanced coke resistance during photothermocatalytic oxidation of typical VOCs","volume":"269","author":"Kong","year":"2020","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121788_bib18","doi-asserted-by":"crossref","first-page":"763","DOI":"10.1080\/17480272.2022.2056080","article-title":"Recent progress in ultra-low formaldehyde emitting adhesive systems and formaldehyde scavengers in wood-based panels: a review","volume":"18","author":"Kristak","year":"2022","journal-title":"Wood Mater. Sci. Eng."},{"key":"10.1016\/j.envres.2025.121788_bib19","doi-asserted-by":"crossref","first-page":"116","DOI":"10.1016\/j.molcata.2010.11.005","article-title":"Efficient decomposition of organic compounds and reaction mechanism with BiOI photocatalyst under visible light irradiation","volume":"334","author":"Li","year":"2011","journal-title":"J. Mol. Catal. Chem."},{"key":"10.1016\/j.envres.2025.121788_bib20","doi-asserted-by":"crossref","first-page":"15373","DOI":"10.1007\/s11356-019-04909-5","article-title":"The role of surface hydroxyl concentration on calcinated alumina in catalytic ozonation","volume":"26","author":"Li","year":"2019","journal-title":"Environ. Sci. Pollut. Res."},{"key":"10.1016\/j.envres.2025.121788_bib21","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2022.152855","article-title":"Constructing MnO2 alpha\/amorphous heterophase junction by mechanochemically induced phase transformation for formaldehyde oxidation","volume":"589","author":"Li","year":"2022","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.envres.2025.121788_bib22","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2022.121231","article-title":"Defect enhanced CoMnNiOx catalysts derived from spent ternary lithium-ion batteries for low-temperature propane oxidation","volume":"309","author":"Li","year":"2022","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121788_bib23","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2023.123322","article-title":"Efficient HCHO oxidation at room temperature via maximizing catalytic sites in 2D coralloid \u03b4-MnO2@GO","volume":"341","author":"Li","year":"2024","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121788_bib24","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1016\/j.jcis.2008.11.051","article-title":"Effects of calcium ions on surface characteristics and adsorptive properties of hydrous manganese dioxide","volume":"331","author":"Liu","year":"2009","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.envres.2025.121788_bib25","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2021.126769","article-title":"Synergy of surface sodium and hydroxyl on NaTi2HO5 nanotubes accelerating the Pt-dominated ambient HCHO oxidation","volume":"421","author":"Liu","year":"2022","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.envres.2025.121788_bib26","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2022.129207","article-title":"Water durability modification of cerium-manganese oxide by tin shell for efficient airborne benzene oxidation","volume":"436","author":"Liu","year":"2022","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.envres.2025.121788_bib27","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2019.144481","article-title":"MnO2 nanoparticles encapsuled in spheres of Ce-Mn solid solution: efficient catalyst and good water tolerance for low-temperature toluene oxidation","volume":"504","author":"Luo","year":"2020","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.envres.2025.121788_bib28","doi-asserted-by":"crossref","DOI":"10.1016\/j.chemosphere.2021.132293","article-title":"Importance of water content in birnessite-type MnO2 catalysts for HCHO oxidation: mechanistic details and DFT analysis","volume":"287","author":"Mang","year":"2022","journal-title":"Chemosphere"},{"key":"10.1016\/j.envres.2025.121788_bib29","doi-asserted-by":"crossref","first-page":"6908","DOI":"10.1021\/acs.iecr.3c00196","article-title":"Tailoring oxygen vacancies and active surface oxygen species in copper-doped MnO2 catalysts for total catalytic oxidation of VOCs","volume":"62","author":"Nguyen Dinh","year":"2023","journal-title":"Ind. Eng. Chem. Res."},{"key":"10.1016\/j.envres.2025.121788_bib30","doi-asserted-by":"crossref","first-page":"522","DOI":"10.1016\/j.jhazmat.2015.09.026","article-title":"High-surface area mesoporous Pt\/TiO2 hollow chains for efficient formaldehyde decomposition at ambient temperature","volume":"301","author":"Qi","year":"2016","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.envres.2025.121788_bib31","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1007\/s40097-016-0192-3","article-title":"Preparation of nano-structured cryptomelane materials for catalytic oxidation reactions","volume":"6","author":"Said","year":"2016","journal-title":"J. Nanostruct. Chem."},{"key":"10.1016\/j.envres.2025.121788_bib32","doi-asserted-by":"crossref","first-page":"2985","DOI":"10.1246\/bcsj.46.2985","article-title":"Acidic properties of binary matel oxides","volume":"46","author":"Shibata","year":"1973","journal-title":"B. Chem. Soc. JPN."},{"key":"10.1016\/j.envres.2025.121788_bib33","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2023.146251","article-title":"Bimetallic Fe-Mn loaded H-ZSM-5 zeolites for excellent VOCs catalytic oxidation at low-temperatures: synergistic effects and catalytic mechanisms","volume":"475","author":"Soltan","year":"2023","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.envres.2025.121788_bib34","article-title":"Catalytic properties\/performance evolution during sono-hydrothermal design of nanocrystalline ceria over zinc oxide for biofuel production","volume":"430","author":"Vardast","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.envres.2025.121788_bib35","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.119540","article-title":"A simple strategy to improve Pd dispersion and enhance Pd\/TiO2 catalytic activity for formaldehyde oxidation: the roles of surface defects","volume":"282","author":"Wang","year":"2021","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121788_bib36","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2022.135854","article-title":"Two-step hydrothermal synthesis of highly active MnOx-CeO2 for complete oxidation of formaldehyde","volume":"440","author":"Wang","year":"2022","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.envres.2025.121788_bib37","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2023.157917","article-title":"Mn\/HZSM-5 catalyst with high content of Mn4+ and surface hydroxyls for formaldehyde oxidation at room temperature","volume":"637","author":"Wang","year":"2023","journal-title":"Appl. Surf. Sci."},{"key":"10.1016\/j.envres.2025.121788_bib38","doi-asserted-by":"crossref","first-page":"4598","DOI":"10.1021\/acs.est.3c00420","article-title":"Unveiling the position effect of Ce within layered MnO2 to prolong the ambient removal of indoor HCHO","volume":"57","author":"Wang","year":"2023","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.envres.2025.121788_bib39","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2024.134114","article-title":"A facile method for preparing the CeMnO3 catalyst with high activity and stability of toluene oxidation: the critical role of small crystal size and Mn3+-Ov-Ce4+ sites","volume":"470","author":"Wang","year":"2024","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.envres.2025.121788_bib40","doi-asserted-by":"crossref","DOI":"10.1016\/j.jece.2022.108277","article-title":"Effect of Fe doping on the surface properties of \u03b4-MnO2 nanomaterials and its decomposition of formaldehyde at room temperature","volume":"10","author":"Wu","year":"2022","journal-title":"J. Environ. Chem. Eng."},{"key":"10.1016\/j.envres.2025.121788_bib41","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.119279","article-title":"Controllable redox-induced in-situ growth of MnO2 over Mn2O3 for toluene oxidation: active heterostructure interfaces","volume":"278","author":"Yang","year":"2020","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121788_bib42","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2019.118150","article-title":"Comparative study of \u03b1-, \u03b2-, \u03b3- and \u03b4-MnO2 on toluene oxidation: oxygen vacancies and reaction intermediates","volume":"260","author":"Yang","year":"2020","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.envres.2025.121788_bib43","doi-asserted-by":"crossref","DOI":"10.1016\/j.envres.2022.114938","article-title":"Enhanced oxidative ability, recyclability, water tolerance and aromatic resistance of \u03b1-MnO2 catalyst for room-temperature formaldehyde oxidation via simple oxalic acid treatment","volume":"217","author":"Yang","year":"2023","journal-title":"Environ. Res."},{"key":"10.1016\/j.envres.2025.121788_bib44","article-title":"Synergy between platinum and gold nanoparticles in oxygen activation for enhanced room\u2010temperature formaldehyde oxidation","volume":"32","author":"Ye","year":"2021","journal-title":"Adv. Funct. Mater."},{"key":"10.1016\/j.envres.2025.121788_bib45","article-title":"Three-dimensional Ni foam supported Pt\/NiFe LDH catalyst with enhanced oxygen activation for room-temperature formaldehyde oxidation","volume":"474","author":"M","year":"2024","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.envres.2025.121788_bib46","doi-asserted-by":"crossref","first-page":"1793","DOI":"10.1016\/j.chempr.2019.03.021","article-title":"Deciphering the atomic patterns leading to MnO2 polymorphism","volume":"5","author":"Yuan","year":"2019","journal-title":"Chem"},{"key":"10.1016\/j.envres.2025.121788_bib47","doi-asserted-by":"crossref","first-page":"10916","DOI":"10.1021\/acs.est.2c01278","article-title":"Effect of hydroxyl groups on metal anchoring and formaldehyde oxidation performance of Pt\/Al2O3","volume":"56","author":"Zhang","year":"2022","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.envres.2025.121788_bib48","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2024.134710","article-title":"Insight into the effect of exposed crystal facets of anatase TiO2 on HCHO catalytic oxidation of Mn-Ce\/TiO2","volume":"474","author":"Zheng","year":"2024","journal-title":"J. Hazard. Mater."}],"container-title":["Environmental Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0013935125010394?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0013935125010394?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,5,11]],"date-time":"2026-05-11T04:40:54Z","timestamp":1778474454000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0013935125010394"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,8]]},"references-count":48,"alternative-id":["S0013935125010394"],"URL":"https:\/\/doi.org\/10.1016\/j.envres.2025.121788","relation":{},"ISSN":["0013-9351"],"issn-type":[{"value":"0013-9351","type":"print"}],"subject":[],"published":{"date-parts":[[2025,8]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Alpha-MnO2 catalyst with high formaldehyde oxidation and moisture resistance by joint cerium modification and phosphoric acid post-treatment","name":"articletitle","label":"Article Title"},{"value":"Environmental Research","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.envres.2025.121788","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 Elsevier Inc. All rights are reserved, including those for text and data mining, AI training, and similar technologies.","name":"copyright","label":"Copyright"}],"article-number":"121788"}}