{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,2]],"date-time":"2026-05-02T10:46:10Z","timestamp":1777718770188,"version":"3.51.4"},"reference-count":37,"publisher":"Elsevier BV","issue":"5","license":[{"start":{"date-parts":[[2021,1,1]],"date-time":"2021-01-01T00:00:00Z","timestamp":1609459200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2021,1,1]],"date-time":"2021-01-01T00:00:00Z","timestamp":1609459200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2022,1,6]],"date-time":"2022-01-06T00:00:00Z","timestamp":1641427200000},"content-version":"am","delay-in-days":370,"URL":"http:\/\/www.elsevier.com\/open-access\/userlicense\/1.0\/"}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["International Journal of Hydrogen Energy"],"published-print":{"date-parts":[[2021,1]]},"DOI":"10.1016\/j.ijhydene.2020.11.026","type":"journal-article","created":{"date-parts":[[2020,12,1]],"date-time":"2020-12-01T01:19:56Z","timestamp":1606785596000},"page":"3615-3628","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":107,"title":["Long-term monitoring of natural hydrogen superficial emissions in a brazilian cratonic environment. Sporadic large pulses versus daily periodic emissions"],"prefix":"10.1016","volume":"46","author":[{"given":"Isabelle","family":"Moretti","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alain","family":"Prinzhofer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jo\u00e3o","family":"Fran\u00e7olin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Cleuton","family":"Pacheco","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maria","family":"Rosanne","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fabian","family":"Rupin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jan","family":"Mertens","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"78","reference":[{"key":"10.1016\/j.ijhydene.2020.11.026_bib1","article-title":"Prospects and impediments for hydrogen and fuel cell vehicles in the transport sector","author":"Ajanovic","year":"2020","journal-title":"Int J Hydrogen Energy"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib2","series-title":"Bacia do S\u00e3o Francisco: geologia e Recursos Naturais. Belo Horizonte, Sociedade Brasileira de Geologia (SBG) \u2013 nucleo MG","first-page":"9","article-title":"A Bacia Intracrat\u00f4nica do S\u00e3o Francisco: arcabou\u00e7o estrutural e cen\u00e1rios evolutivos","author":"Alkmim","year":"2001"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib3","doi-asserted-by":"crossref","first-page":"401","DOI":"10.1111\/j.1365-3121.2007.00764.x","article-title":"Direct dating of the Sete Lagoas cap carbonate (Bambu\u00ed Group, Brazil) and implications for the Neoproterozoic glacial events","volume":"19","author":"Babinski","year":"2007","journal-title":"Terra Nova"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib4","series-title":"The behavior of H2 in aqueous fluids under high temperature and pressure","author":"Bazarkina","year":"2020"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib5","doi-asserted-by":"crossref","first-page":"17","DOI":"10.3389\/feart.2019.00017","article-title":"Hydrothermal production of H2 and magnetite from steel slags: a geo-inspired approach based on olivine serpentinization","volume":"7","author":"Brunet","year":"2019","journal-title":"Front Earth Sci"},{"issue":"4","key":"10.1016\/j.ijhydene.2020.11.026_bib6","first-page":"149","article-title":"What pulsating H2 emissions suggest about the H2 resources in the S\u00e3o Francisco Basin of Brazil","volume":"10","author":"Cathles","year":"2020","journal-title":"Geosciences 10040149, Geosciences"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib7","doi-asserted-by":"crossref","first-page":"345","DOI":"10.1016\/S0009-2541(02)00134-1","article-title":"Geochem-istry of high H2and CH4 vent fluids issuing from ultramafic rocks at the Rain-bow hydrothermal field (36\u25e614N","volume":"191","author":"Charlou","year":"2002","journal-title":"MAR). Chem. Geol."},{"key":"10.1016\/j.ijhydene.2020.11.026_bib8","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1016\/j.chemgeo.2016.06.011","article-title":"The origin of N2-H2-CH4-rich natural gas seepages in ophiolitic context: a major and noble gases study of fluid seepages in New Caledonia","volume":"440","author":"Deville","year":"2016","journal-title":"Chem Geol"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib9","doi-asserted-by":"crossref","first-page":"346","DOI":"10.3390\/geosciences10090346","article-title":"Migration of natural hydrogen from deep-seated sources in the s\u00e3o Francisco basin, Brazil","volume":"10","author":"Donz\u00e9","year":"2020","journal-title":"Geosciences"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib10","doi-asserted-by":"crossref","first-page":"313","DOI":"10.1016\/0377-0273(92)90020-E","article-title":"Chemical composition of natural deep and shallow hydrothermal fluids in the Larderello geothermal field","volume":"49","author":"Duchi","year":"1992","journal-title":"J Volcanol Geoth Res"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib12","article-title":"Bridging ecology and physics: Australian fairy circles regenerate following model assumptions on ecohydrological feedbacks","author":"Getzin","year":"2020","journal-title":"J Ecol"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib13","doi-asserted-by":"crossref","first-page":"8","DOI":"10.2138\/gselements.16.1.8","article-title":"New perspectives in the industrial exploration for native hydrogen","volume":"16","author":"Gaucher","year":"2020","journal-title":"Elements"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib14","doi-asserted-by":"crossref","first-page":"19","DOI":"10.2138\/gselements.16.1.19","article-title":"Abiotic sources of molecular hydrogen on earth","volume":"16","author":"Klein","year":"2020","journal-title":"Elements"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib15","series-title":"Translation","first-page":"247p","article-title":"Hydridic Earth. The new geology of our primordially hydrogen-rich planet","author":"Larin","year":"1993"},{"issue":"3","key":"10.1016\/j.ijhydene.2020.11.026_bib16","doi-asserted-by":"crossref","first-page":"369","DOI":"10.1007\/s11053-014-9257-5","article-title":"Natural molecular hydrogen seepage associated with surficial, rounded depressions on the European craton in Russia","volume":"24","author":"Larin","year":"2015","journal-title":"Nat Resour Res"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib17","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1051\/bsgf\/2019008","article-title":"Hydrogen solubility in aqueous NaCl solutions: from molecular simulation to equation of state","volume":"190","author":"Lopez-Lazaro","year":"2019","journal-title":"Bul Soc Geol France"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib18","series-title":"Natural Hydrogen: a new clean black gold? Pour la Science, special issue in partnership with Engie","author":"Moretti","year":"2018"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib19","first-page":"15","volume":"vol. 442","author":"Moretti","year":"2019"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib20","series-title":"Hydrogen emanations in intracratonic areas","author":"Moretti","year":"2020"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib21","article-title":"H2 dynamics in the soil of an H2-emitting zone (S\u00e3o Francisco Basin, Brazil): microbial uptake quantification and reactive transport modelling","volume":"112","author":"Myagkiy","year":"2019","journal-title":"Appl Geochem"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib22","doi-asserted-by":"crossref","first-page":"pp13","DOI":"10.1051\/bsgf\/2020010","article-title":"Space and time distribution of subsurface H2 concentration in so-called \u201cfairy circles\u201d: insight from a conceptual 2-D transport model","volume":"191","author":"Myagkiy","year":"2020","journal-title":"BSGF"},{"issue":"2","key":"10.1016\/j.ijhydene.2020.11.026_bib23","doi-asserted-by":"crossref","first-page":"1261e4","DOI":"10.1134\/S1028334X16120060","article-title":"Changes in the molecular hydrogen concentration in an underground mine (Lovozero rare-metal deposit, Kola peninsula)","volume":"471","author":"Nivin","year":"2016","journal-title":"Dokl Earth Sci"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib24","series-title":"R\u00e9partition des \u00e9manations d\u2019hydrog\u00e8ne naturel dans la d\u00e9pression des Afars et le rift Ethiopien","author":"Pasquet","year":"2020"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib25","series-title":"Hydrog\u00e8ne naturel. La prochaine r\u00e9volution \u00e9nerg\u00e9tique ?","first-page":"187","author":"Prinzhofer","year":"2015"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib26","doi-asserted-by":"crossref","first-page":"19315","DOI":"10.1016\/j.ijhydene.2018.08.193","article-title":"Discovery of a large accumulation of natural hydrogen in Bourakebougou (Mali)","volume":"43","author":"Prinzhofer","year":"2018","journal-title":"Int J Hydrogen Energy"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib27","doi-asserted-by":"crossref","first-page":"5675","DOI":"10.1016\/j.ijhydene.2019.01.119","article-title":"Natural hydrogen continuous emission from sedimentary basins: the example of a Brazilian H2-emitting structure","volume":"44","author":"Prinzhofer","year":"2019","journal-title":"Int J Hydrogen Energy"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib28","series-title":"S\u00e3o Francisco Craton, Eastern Brazil: tectonic genealogy of a miniature continent","first-page":"117","article-title":"The s\u00e3o Francisco basin","author":"Reis","year":"2017"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib29","series-title":"PARHyS System: a new approach to H2 concentration measurements in the subsurface","author":"Rosanne","year":"2020"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib30","first-page":"12315e26","article-title":"Monitoring of hydrogen along the san Andreas and Calaveras faults in central California in 1980-1984","volume":"91","author":"Sato","year":"1986","journal-title":"J Geophys Res"},{"issue":"2","key":"10.1016\/j.ijhydene.2020.11.026_bib31","first-page":"120","article-title":"Occurrence of hydrogen in subsurface fluids and the relashioship of anomalous concentrations to deep faults in the USSR","volume":"20","author":"Shchebakov","year":"1986","journal-title":"Geotectonics"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib32","doi-asserted-by":"crossref","first-page":"379","DOI":"10.1038\/nature14017","article-title":"The contribution of the Precambrian continental lithosphere to global H2 production","volume":"516","author":"Sherwood Lollar","year":"2014","journal-title":"Nature"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib33","doi-asserted-by":"crossref","first-page":"653","DOI":"10.1144\/gsjgs.131.6.0653","article-title":"Seismic pumping - a hydrothermal fluid transport mechanism","volume":"131","author":"Sibson","year":"1975","journal-title":"J Geol Soc"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib35","doi-asserted-by":"crossref","first-page":"186","DOI":"10.1016\/j.epsl.2018.04.038","article-title":"Clay minerals trap hydrogen in the Earth's crust: evidence from the Cigar Lake uranium deposit","volume":"493","author":"Truche","year":"2018","journal-title":"Athabascah. Earth and Planetary Science Letters"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib36","doi-asserted-by":"crossref","first-page":"437e61","DOI":"10.1016\/j.gca.2017.12.018","article-title":"A. Reduced gas seepages in ophiolitic complexes: evidences for multiple origins of the H2-CH4-N2 gas mixtures","volume":"223","author":"Vacquand","year":"2018","journal-title":"Geochem Cosmochim Acta"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib37","author":"Worman"},{"key":"10.1016\/j.ijhydene.2020.11.026_bib38","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1186\/s40645-015-0062-5","article-title":"Evidence for natural molecular hydrogen seepage associated with Carolina bays (surficial, ovoid depressions on the Atlantic Coastal Plain Province of the USA)","volume":"2","author":"Zgonnik","year":"2015","journal-title":"Prog. Earth Planet. Sci."},{"key":"10.1016\/j.ijhydene.2020.11.026_bib39","doi-asserted-by":"crossref","DOI":"10.1016\/j.earscirev.2020.103140","article-title":"The occurrence and geoscience of natural hydrogen: a comprehensive review","volume":"203","author":"Zgonnik","year":"2020","journal-title":"Earth Sci Rev"}],"container-title":["International Journal of Hydrogen Energy"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0360319920341987?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0360319920341987?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T11:52:10Z","timestamp":1759751530000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0360319920341987"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,1]]},"references-count":37,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2021,1]]}},"alternative-id":["S0360319920341987"],"URL":"https:\/\/doi.org\/10.1016\/j.ijhydene.2020.11.026","relation":{},"ISSN":["0360-3199"],"issn-type":[{"value":"0360-3199","type":"print"}],"subject":[],"published":{"date-parts":[[2021,1]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Long-term monitoring of natural hydrogen superficial emissions in a brazilian cratonic environment. Sporadic large pulses versus daily periodic emissions","name":"articletitle","label":"Article Title"},{"value":"International Journal of Hydrogen Energy","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.ijhydene.2020.11.026","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.","name":"copyright","label":"Copyright"}]}}