{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T22:36:39Z","timestamp":1789684599749,"version":"4.0.1"},"reference-count":43,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2019,4,1]],"date-time":"2019-04-01T00:00:00Z","timestamp":1554076800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"}],"funder":[{"DOI":"10.13039\/501100002848","name":"CONICYT","doi-asserted-by":"publisher","award":["CONICYT\/FONDAP\/15110019"],"award-info":[{"award-number":["CONICYT\/FONDAP\/15110019"]}],"id":[{"id":"10.13039\/501100002848","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Colloid and Interface Science"],"published-print":{"date-parts":[[2019,4]]},"DOI":"10.1016\/j.jcis.2019.01.118","type":"journal-article","created":{"date-parts":[[2019,1,30]],"date-time":"2019-01-30T01:08:06Z","timestamp":1548810486000},"page":"45-53","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":51,"special_numbering":"C","title":["Heterostructures of mesoporous TiO2 and SnO2 nanocatalyst for improved electrochemical oxidation ability of vitamin B6 in pharmaceutical tablets"],"prefix":"10.1016","volume":"542","author":[{"given":"Devaraj","family":"Manoj","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Saravanan","family":"Rajendran","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8779-1412","authenticated-orcid":false,"given":"Jiaqian","family":"Qin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elumalai","family":"Sundaravadivel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mehmet L\u00fctfi","family":"Yola","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2809-2966","authenticated-orcid":false,"given":"Necip","family":"Atar","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"F.","family":"Gracia","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7424-3425","authenticated-orcid":false,"given":"Rabah","family":"Boukherroub","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M.A.","family":"Gracia-Pinilla","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vinod Kumar","family":"Gupta","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.jcis.2019.01.118_b0005","doi-asserted-by":"crossref","first-page":"574","DOI":"10.1038\/264574a0","article-title":"Effect of riboflavin on red-cell metabolism of vitamin B6","volume":"264","author":"Anderson","year":"1979","journal-title":"Nature"},{"key":"10.1016\/j.jcis.2019.01.118_b0010","first-page":"1","article-title":"Effects of vitamin B6 metabolism on oncogenesis, tumor progression and therapeutic responses","author":"Galluzzi","year":"2013","journal-title":"Oncogene"},{"key":"10.1016\/j.jcis.2019.01.118_b0015","series-title":"Water-soluble Vitamins, in Nutrition","author":"Insel","year":"2002"},{"key":"10.1016\/j.jcis.2019.01.118_b0020","doi-asserted-by":"crossref","first-page":"585","DOI":"10.1038\/bjc.2012.318","article-title":"Short Communication A randomised study evaluating the use of pyridoxine to avoid capecitabine dose modifications","volume":"107","author":"Corrie","year":"2012","journal-title":"British J. Cancer"},{"key":"10.1016\/j.jcis.2019.01.118_b0025","doi-asserted-by":"crossref","first-page":"8","DOI":"10.1016\/j.jelechem.2014.10.026","article-title":"New electrode architectures based on poly (methylene green) and functionalized carbon nanotubes : Characterization and application to detection of acetaminophen and pyridoxine","volume":"736","author":"Barsan","year":"2015","journal-title":"J. Electroanal. Chem."},{"key":"10.1016\/j.jcis.2019.01.118_b0030","doi-asserted-by":"crossref","first-page":"13556","DOI":"10.1021\/jp205724k","article-title":"Theoretical study of pyridoxine (Vitamin B6) photolysis","author":"Wu","year":"2011","journal-title":"J. Phys. Chem. A"},{"key":"10.1016\/j.jcis.2019.01.118_b0035","first-page":"097","article-title":"Spectrophotometric determination of pyridoxine hydrochloride in pharmaceutical samples","volume":"113","author":"Balasubramanian","year":"1988","journal-title":"Analyst"},{"issue":"24","key":"10.1016\/j.jcis.2019.01.118_b0040","doi-asserted-by":"crossref","first-page":"4740","DOI":"10.1002\/jssc.201700933","article-title":"Simultaneous determination of niacinand pyridoxine at trace levels by using diode array high-performance liquid chromatography and liquid chromatography with quadrupole time-of-flight tandem mass spectrometry","volume":"40","author":"Sel","year":"2017","journal-title":"J. Separ. Sci."},{"key":"10.1016\/j.jcis.2019.01.118_b0045","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1016\/S0003-2670(99)00809-0","article-title":"Determination of melatonin and pyridoxine in pharmaceutical preparations for health-caring purposes by capillary electrophoresis with electrochemical detection","volume":"408","author":"Chen","year":"2000","journal-title":"Anal. Chim. Acta"},{"issue":"7","key":"10.1016\/j.jcis.2019.01.118_b0050","doi-asserted-by":"crossref","first-page":"2891","DOI":"10.1021\/cr0500535","article-title":"Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications","volume":"107","author":"Chen","year":"2007","journal-title":"Chem. Rev."},{"issue":"19","key":"10.1016\/j.jcis.2019.01.118_b0055","doi-asserted-by":"crossref","first-page":"9487","DOI":"10.1021\/cr500201c","article-title":"Three-dimensional titanium dioxide nanomaterials","volume":"114","author":"Fattakhova-rohl","year":"2014","journal-title":"Chem. Rev."},{"key":"10.1016\/j.jcis.2019.01.118_b0060","doi-asserted-by":"crossref","first-page":"1156","DOI":"10.1021\/am3029798","article-title":"Synthesis of fullerene, carbon nanotube, and graphene \u2212 TiO2 nanocomposite photocatalysts for selective oxidation: a comparative study","volume":"5","author":"Yang","year":"2013","journal-title":"ACS Appl. Mater. Interf."},{"issue":"19","key":"10.1016\/j.jcis.2019.01.118_b0065","doi-asserted-by":"crossref","first-page":"9853","DOI":"10.1021\/cr400634p","article-title":"Composite titanium dioxide nanomaterials","volume":"114","author":"Dahl","year":"2014","journal-title":"Chem. Rev."},{"key":"10.1016\/j.jcis.2019.01.118_b0070","doi-asserted-by":"crossref","first-page":"421","DOI":"10.1016\/j.chemosphere.2016.08.117","article-title":"Chemosphere Study on preparation of SnO2 -TiO2 \/ Nano-graphite composite anode and electro-catalytic degradation of ceftriaxone sodium","volume":"164","author":"Guo","year":"2016","journal-title":"Chemosphere"},{"key":"10.1016\/j.jcis.2019.01.118_b0075","doi-asserted-by":"crossref","first-page":"2583","DOI":"10.1016\/j.electacta.2004.11.003","article-title":"Al2O3 -coated SnO2 \/ TiO2 composite electrode for the dye-sensitized solar cell","volume":"50","author":"Liu","year":"2005","journal-title":"Electrochim. Acta."},{"key":"10.1016\/j.jcis.2019.01.118_b0080","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1016\/j.electacta.2011.11.084","article-title":"Electrochimica Acta Fabrication of a composite electrode: CdS decorated Sb \u2013 SnO2\/TiO2 -NTs for efficient photoelectrochemical reactivity","volume":"61","author":"Zhang","year":"2012","journal-title":"Electrochim. Acta"},{"key":"10.1016\/j.jcis.2019.01.118_b0085","doi-asserted-by":"crossref","first-page":"1304","DOI":"10.1016\/j.electacta.2008.09.009","article-title":"Properties of sol \u2013 gel SnO2\/TiO2 electrodes and their photoelectrocatalytic activities under UV and visible light illumination","volume":"54","author":"Chen","year":"2009","journal-title":"Electrochim Acta"},{"key":"10.1016\/j.jcis.2019.01.118_b0090","doi-asserted-by":"crossref","first-page":"251","DOI":"10.1016\/j.snb.2013.07.029","article-title":"Sensitization of TiO2\/SnO2 nanocomposites for gas detection","volume":"189","author":"Kusior","year":"2013","journal-title":"Sensors Actuat. B: Chem."},{"key":"10.1016\/j.jcis.2019.01.118_b0095","doi-asserted-by":"crossref","first-page":"815","DOI":"10.1016\/j.electacta.2017.10.144","article-title":"A robust strategy for stabilizing SnO2:TiO2 -supported and carbon-immobilized TiO2\/SnO2\/C composite towards improved lithium storage","volume":"259","author":"Tian","year":"2018","journal-title":"Electrochim Acta"},{"key":"10.1016\/j.jcis.2019.01.118_b0100","doi-asserted-by":"crossref","first-page":"10652","DOI":"10.1021\/acsami.6b16498","article-title":"Walnut-like porous core\/shell TiO2 with hybridized phases enabling fast and stable lithium storage","volume":"9","author":"Cai","year":"2017","journal-title":"ACS Appl. Mater. Interf."},{"key":"10.1016\/j.jcis.2019.01.118_b0105","doi-asserted-by":"crossref","first-page":"12250","DOI":"10.1039\/C8CC06924G","article-title":"Coherent TiO2\/BaTiO3 heterostructure as a functional reservoir and promoter for polysulfide intermediates","volume":"2","author":"Wang","year":"2018","journal-title":"Chem. Commun."},{"key":"10.1016\/j.jcis.2019.01.118_b0110","doi-asserted-by":"crossref","first-page":"25056","DOI":"10.1039\/C7TA08616D","article-title":"rGO\/SnS2\/TiO2 heterostructured composite with dual-confinement for enhanced lithium-ion storage","volume":"5","author":"Online","year":"2017","journal-title":"J. Mater. Chem. A"},{"key":"10.1016\/j.jcis.2019.01.118_b0115","doi-asserted-by":"crossref","first-page":"15505","DOI":"10.1039\/C8NR04661A","article-title":"SnS2\/TiO2 nanohybrids chemically bonded on nitrogen-doped graphene for lithium\u2013sulfur batteries: synergy of vacancy defects and heterostructures","volume":"10","author":"Li","year":"2018","journal-title":"Nanoscale"},{"key":"10.1016\/j.jcis.2019.01.118_b0120","doi-asserted-by":"crossref","first-page":"1927","DOI":"10.1007\/s11581-016-1711-4","article-title":"Semiconducting SnO2 -TiO2 (S-T) composites for detection of SO2 gas","volume":"22","author":"Mulmi","year":"2016","journal-title":"Ionics"},{"key":"10.1016\/j.jcis.2019.01.118_b0125","doi-asserted-by":"crossref","first-page":"1345","DOI":"10.1016\/j.physb.2009.11.086","article-title":"Gas-sensing properties of SnO2 \u2013 TiO2 -based sensor for volatile organic compound gas and its sensing mechanism","volume":"405","author":"Wen","year":"2010","journal-title":"Phys. B Phys. Condens. Matter."},{"key":"10.1016\/j.jcis.2019.01.118_b0130","doi-asserted-by":"crossref","first-page":"277","DOI":"10.1016\/j.matchemphys.2010.09.030","article-title":"ZnO\/CdO composite nanorods for photocatalytic degradation of methylene blue under visible light","volume":"125","author":"Saravanan","year":"2011","journal-title":"Mater. Chem. Phys."},{"key":"10.1016\/j.jcis.2019.01.118_b0135","doi-asserted-by":"crossref","first-page":"91","DOI":"10.1016\/j.msec.2012.08.011","article-title":"Enhanced photocatalytic activity of ZnO\/CuO nanocomposites for the degradation of textile dye on visible light illumination","volume":"33","author":"Saravanan","year":"2013","journal-title":"Mater. Sci. Eng.: C"},{"key":"10.1016\/j.jcis.2019.01.118_b0140","doi-asserted-by":"crossref","first-page":"27024","DOI":"10.1039\/C7RA04041E","article-title":"Controlled synthesis of Sn-based oxides via a hydrothermal method and their visible light photocatalytic performances","volume":"7","author":"Wang","year":"2017","journal-title":"RSC Adv."},{"issue":"15","key":"10.1016\/j.jcis.2019.01.118_b0145","doi-asserted-by":"crossref","first-page":"7261","DOI":"10.1021\/ic9005983","article-title":"SnO2 nanostructuresTiO2 nanofibers heterostructures. Controlled fabrication and high photocatalytic properties","volume":"48","author":"Wang","year":"2009","journal-title":"Inorg. Chem."},{"key":"10.1016\/j.jcis.2019.01.118_b0150","doi-asserted-by":"crossref","first-page":"150","DOI":"10.1016\/j.talanta.2015.02.025","article-title":"Talanta Protein\/ionic liquid \/ glassy carbon sensors following analyte focusing by ionic liquid micelle collapse for simultaneous determination of water soluble vitamins in plasma matrices","volume":"139","author":"El-hady","year":"2015","journal-title":"Talanta"},{"key":"10.1016\/j.jcis.2019.01.118_b0155","doi-asserted-by":"crossref","first-page":"244","DOI":"10.1016\/j.bios.2013.06.057","article-title":"Enhanced sensitivity for electrochemical simultaneous determination of vitamins B 2, B 6 and C","volume":"50","author":"Nie","year":"2013","journal-title":"Biosens. Bioelectron."},{"issue":"13","key":"10.1016\/j.jcis.2019.01.118_b0160","doi-asserted-by":"crossref","first-page":"B730","DOI":"10.1149\/2.1981713jes","article-title":"Effective and facile determination of vitamin B6 in human serum with CuO nanoparticles\/ionic liquid crystal carbon based sensors","volume":"164","author":"Atta","year":"2017","journal-title":"J. Electrochem. Soc."},{"key":"10.1016\/j.jcis.2019.01.118_b0165","doi-asserted-by":"crossref","first-page":"184","DOI":"10.1016\/j.diamond.2016.02.018","article-title":"Determination of pyridoxine (vitamin B6) in pharmaceuticals and urine samples using unmodi fi ed boron-doped diamond electrode","volume":"64","author":"Kuzmanovi","year":"2016","journal-title":"Diamond Related Mater."},{"key":"10.1016\/j.jcis.2019.01.118_b0170","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1007\/s13204-012-0093-9","article-title":"Impact of CuO nanoleaves on MWCNTs\/GCE nanocomposite film modified electrode for the electrochemical oxidation of folic acid","author":"Manoj","year":"2012","journal-title":"Appl. Nanosci."},{"key":"10.1016\/j.jcis.2019.01.118_b0175","doi-asserted-by":"crossref","first-page":"3503","DOI":"10.1039\/c3ay40209f","article-title":"Controlled growth and molecular self-assembly of Au nanoparticles to Au nanochains: application towards enhancement for the electrochemical determination of paracetamol","author":"Devaraj","year":"2013","journal-title":"Anal. Meth."},{"key":"10.1016\/j.jcis.2019.01.118_b0180","doi-asserted-by":"crossref","first-page":"104","DOI":"10.1016\/j.bios.2017.12.030","article-title":"Aldehyde functionalized ionic liquid on electrochemically reduced graphene oxide as a versatile platform for covalent immobilization of biomolecules and biosensing","volume":"103","author":"Manoj","year":"2018","journal-title":"Biosens. Bioelectron."},{"key":"10.1016\/j.jcis.2019.01.118_b0185","doi-asserted-by":"crossref","first-page":"631","DOI":"10.1016\/j.jpba.2004.07.016","article-title":"Voltammetric determination of pyridoxine (Vitamin B 6) by use of a chemically-modified glassy carbon electrode","volume":"36","author":"Qu","year":"2004","journal-title":"J. Pharma. Biomed. Anal."},{"key":"10.1016\/j.jcis.2019.01.118_b0190","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1007\/BF03246189","article-title":"Voltammetric determination of vitamin B 6 (Pyridoxine) using multi wall carbon nanotube modified carbon-ceramic electrode","volume":"7","author":"Habibi","year":"2010","journal-title":"JICS"},{"key":"10.1016\/j.jcis.2019.01.118_b0195","doi-asserted-by":"crossref","first-page":"549","DOI":"10.1007\/s12161-014-9926-3","article-title":"A voltammetric sensor for simultaneous determination of vitamin C and vitamin B 6 in food samples using ZrO2 nanoparticle\/ionic liquids carbon paste electrode","author":"Baghizadeh","year":"2015","journal-title":"Food Anal. Methods"},{"issue":"508","key":"10.1016\/j.jcis.2019.01.118_b0200","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1016\/j.aca.2003.11.046","article-title":"Voltammetric determination of pyridoxine (Vitamin B 6) at a carbon paste electrode modified with vanadyl (IV)\u2013 Salen complex","volume":"50","author":"Teixeira","year":"2004","journal-title":"Anal. Chim. Acta"},{"key":"10.1016\/j.jcis.2019.01.118_b0205","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1016\/j.jcis.2016.04.025","article-title":"Highly sensitive interference-free electrochemical determination of pyridoxine at graphene modified electrode: importance in parkinson and asthma treatments","volume":"474","author":"Raj","year":"2016","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.jcis.2019.01.118_b0210","doi-asserted-by":"crossref","first-page":"186","DOI":"10.1016\/j.microc.2011.05.003","article-title":"Exploiting ion-pair formation for the enhancement of electroanalytical determination of pyridoxine (B 6) onto polyurethane-graphite electrodes","volume":"99","author":"Fonseca","year":"2011","journal-title":"Microchem. J."},{"key":"10.1016\/j.jcis.2019.01.118_b0215","doi-asserted-by":"crossref","first-page":"514","DOI":"10.1016\/j.electacta.2015.07.034","article-title":"Electrochimica acta Au-CuO core-shell nanoparticles design and development for the selective determination of vitamin B 6","volume":"176","author":"Ranjith","year":"2015","journal-title":"Electrochim. Acta."}],"container-title":["Journal of Colloid and Interface Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0021979719301390?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0021979719301390?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2019,8,7]],"date-time":"2019-08-07T18:42:06Z","timestamp":1565203326000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0021979719301390"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,4]]},"references-count":43,"alternative-id":["S0021979719301390"],"URL":"https:\/\/doi.org\/10.1016\/j.jcis.2019.01.118","relation":{},"ISSN":["0021-9797"],"issn-type":[{"value":"0021-9797","type":"print"}],"subject":[],"published":{"date-parts":[[2019,4]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Heterostructures of mesoporous TiO2 and SnO2 nanocatalyst for improved electrochemical oxidation ability of vitamin B6 in pharmaceutical tablets","name":"articletitle","label":"Article Title"},{"value":"Journal of Colloid and Interface Science","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jcis.2019.01.118","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2019 Elsevier Inc. All rights reserved.","name":"copyright","label":"Copyright"}]}}