{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,31]],"date-time":"2026-10-31T12:36:14Z","timestamp":1793450174887,"version":"4.5.0"},"reference-count":29,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2025,5,1]],"date-time":"2025-05-01T00:00:00Z","timestamp":1746057600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2025,5,1]],"date-time":"2025-05-01T00:00:00Z","timestamp":1746057600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2025,5,1]],"date-time":"2025-05-01T00:00:00Z","timestamp":1746057600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2025,5,1]],"date-time":"2025-05-01T00:00:00Z","timestamp":1746057600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,5,1]],"date-time":"2025-05-01T00:00:00Z","timestamp":1746057600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2025,5,1]],"date-time":"2025-05-01T00:00:00Z","timestamp":1746057600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,5,1]],"date-time":"2025-05-01T00:00:00Z","timestamp":1746057600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100012165","name":"Key Technologies Research and Development Program","doi-asserted-by":"publisher","award":["2022YFC3901100"],"award-info":[{"award-number":["2022YFC3901100"]}],"id":[{"id":"10.13039\/501100012165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100014718","name":"Innovative Research Group Project of the National Natural Science Foundation of China","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100014718","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51974378"],"award-info":[{"award-number":["51974378"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52200138"],"award-info":[{"award-number":["52200138"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52121004"],"award-info":[{"award-number":["52121004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Colloid and Interface Science"],"published-print":{"date-parts":[[2025,5]]},"DOI":"10.1016\/j.jcis.2025.02.018","type":"journal-article","created":{"date-parts":[[2025,2,3]],"date-time":"2025-02-03T18:55:44Z","timestamp":1738608944000},"page":"970-977","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":5,"special_numbering":"C","title":["Interfacial water activation by Pd promotes SO2 electroreduction to H2S on CuPd bimetallic catalysts"],"prefix":"10.1016","volume":"686","author":[{"given":"Zhujiang","family":"Wang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7067-6917","authenticated-orcid":false,"given":"Jun","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jieyu","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingxue","family":"Fu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaqi","family":"Long","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fenghua","family":"Shen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2192-9631","authenticated-orcid":false,"given":"Hao","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2992-3442","authenticated-orcid":false,"given":"Kaisong","family":"Xiang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liyuan","family":"Chai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"issue":"03","key":"10.1016\/j.jcis.2025.02.018_b0005","first-page":"65","article-title":"Analysis and prospects of air pollution control techniques in the iron and steel industry","volume":"38","author":"Wang","year":"2024","journal-title":"Energy Environ. Protect."},{"issue":"02","key":"10.1016\/j.jcis.2025.02.018_b0010","first-page":"73","article-title":"Research progress on treatment technology of greenhouse gas tetrafluoromethane","volume":"37","author":"Zhu","year":"2023","journal-title":"Energy Environ. Prot."},{"key":"10.1016\/j.jcis.2025.02.018_b0015","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2023.123260","article-title":"Enhanced chlorine enrichment via electron-deficient centers of Co (III) for efficient electrochlorination and ammonia removal","volume":"340","author":"Tian","year":"2024","journal-title":"Appl. Catal. B"},{"key":"10.1016\/j.jcis.2025.02.018_b0020","doi-asserted-by":"crossref","DOI":"10.1016\/j.fuel.2022.125867","article-title":"Looping upcycling SO2 into value-added H2S by fast-induced reduction process for heavy metals treatment in nonferrous smelting industry","volume":"331","author":"Sun","year":"2023","journal-title":"Fuel"},{"issue":"6","key":"10.1016\/j.jcis.2025.02.018_b0025","doi-asserted-by":"crossref","first-page":"3988","DOI":"10.1021\/acs.est.0c07884","article-title":"Production of H2S with a novel short-process for the removal of heavy metals in acidic effluents from smelting flue-gas scrubbing systems","volume":"55","author":"Sun","year":"2021","journal-title":"Environ. Sci. Tech."},{"issue":"1\u20133","key":"10.1016\/j.jcis.2025.02.018_b0030","doi-asserted-by":"crossref","first-page":"759","DOI":"10.1016\/j.jhazmat.2008.10.053","article-title":"Heavy metals removal from acid mine drainage water using biogenic hydrogen sulphide and effluent from anaerobic treatment: Effect of pH","volume":"165","author":"Jim\u00e9nez-Rodr\u00edguez","year":"2009","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.jcis.2025.02.018_b0035","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2023.123354","article-title":"Direct Electro-oxidation of H2S gas in a membrane electrode assembly cell (MEA): A proof of concept","volume":"311","author":"Arias","year":"2023","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.jcis.2025.02.018_b0040","doi-asserted-by":"crossref","first-page":"943","DOI":"10.1007\/s10800-016-0979-4","article-title":"H2S\/O2 fuel cells using hydrogen sulfide from Black Sea waters","volume":"46","author":"Uzun","year":"2016","journal-title":"J. Appl. Electrochem."},{"issue":"50","key":"10.1016\/j.jcis.2025.02.018_b0045","doi-asserted-by":"crossref","first-page":"58508","DOI":"10.1021\/acsami.3c14546","article-title":"Nafion-mediated proton transfer facilitates the electroreduction of SO2 to H2S","volume":"15","author":"Liu","year":"2023","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"41","key":"10.1016\/j.jcis.2025.02.018_b0050","doi-asserted-by":"crossref","first-page":"22522","DOI":"10.1002\/anie.202109538","article-title":"Polyoxometalate\u2010based metal-organic framework as molecular sieve for highly selective semi\u2010hydrogenation of acetylene on isolated single Pd atom sites","volume":"60","author":"Liu","year":"2021","journal-title":"Angew. Chem. Int. Ed."},{"issue":"7","key":"10.1016\/j.jcis.2025.02.018_b0055","doi-asserted-by":"crossref","first-page":"2594","DOI":"10.1021\/am200425y","article-title":"Photochemical reduction of CO2 using TiO2: effects of organic adsorbates on TiO2 and deposition of Pd onto TiO2","volume":"3","author":"Yui","year":"2011","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"7","key":"10.1016\/j.jcis.2025.02.018_b0060","article-title":"Morphological and compositional design of Pd\u2013Cu bimetallic nanocatalysts with controllable product selectivity toward CO2 electroreduction","volume":"14","author":"Zhu","year":"2018","journal-title":"Small"},{"issue":"43","key":"10.1016\/j.jcis.2025.02.018_b0065","doi-asserted-by":"crossref","first-page":"14345","DOI":"10.1002\/ange.201808964","article-title":"Highly efficient electroreduction of CO2 to methanol on palladium\u2013copper bimetallic aerogels","volume":"130","author":"Lu","year":"2018","journal-title":"Angew. Chem."},{"issue":"9","key":"10.1016\/j.jcis.2025.02.018_b0070","doi-asserted-by":"crossref","first-page":"5275","DOI":"10.1021\/acscatal.2c00646","article-title":"Asymmetrical C-C coupling for electroreduction of CO on bimetallic Cu\u2013Pd catalysts","volume":"12","author":"Shen","year":"2022","journal-title":"ACS Catal."},{"key":"10.1016\/j.jcis.2025.02.018_b0075","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2022.134969","article-title":"Electrocatalytic nitrate reduction on bimetallic palladium-copper nanowires: key surface structure for selective dinitrogen formation","volume":"435","author":"Fu","year":"2022","journal-title":"Chem. Eng. J."},{"issue":"61","key":"10.1016\/j.jcis.2025.02.018_b0080","doi-asserted-by":"crossref","first-page":"7525","DOI":"10.1039\/D1CC02105B","article-title":"Cooperativity of Cu and Pd active sites in CuPd aerogels enhances nitrate electroreduction to ammonia","volume":"57","author":"Xu","year":"2021","journal-title":"Chem. Commun."},{"issue":"7","key":"10.1016\/j.jcis.2025.02.018_b0085","doi-asserted-by":"crossref","first-page":"2671","DOI":"10.1002\/ange.201913122","article-title":"Crystal\u2010phase\u2010engineered PdCu electrocatalyst for enhanced ammonia synthesis","volume":"132","author":"Tong","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"issue":"46","key":"10.1016\/j.jcis.2025.02.018_b0090","doi-asserted-by":"crossref","first-page":"31927","DOI":"10.1021\/jacs.4c11276","article-title":"Atomically isolated Pd sites promote electrochemical CO reduction to acetate through a protonation-regulated mechanism","volume":"146","author":"Li","year":"2024","journal-title":"J. Am. Chem. Soc."},{"issue":"9","key":"10.1016\/j.jcis.2025.02.018_b0095","doi-asserted-by":"crossref","first-page":"4927","DOI":"10.1039\/C5NR07516E","article-title":"Scalable synthesis of Cu-based ultrathin nanowire networks and their electrocatalytic properties","volume":"8","author":"Hong","year":"2016","journal-title":"Nanoscale"},{"issue":"1\u20132","key":"10.1016\/j.jcis.2025.02.018_b0100","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1016\/j.memsci.2003.07.008","article-title":"A comparison of hydrogen diffusivities in Pd and CuPd alloys using density functional theory","volume":"225","author":"Kamakoti","year":"2003","journal-title":"J. Membr. Sci."},{"issue":"17","key":"10.1016\/j.jcis.2025.02.018_b0105","doi-asserted-by":"crossref","DOI":"10.1002\/ange.202401434","article-title":"Efficient homolytic cleavage of H2O2 on hydroxyl\u2010enriched spinel CuFe2O4 with dual lewis acid sites","volume":"136","author":"Tian","year":"2024","journal-title":"Angew. Chem."},{"key":"10.1016\/j.jcis.2025.02.018_b0110","article-title":"Constructing built-in electric field via CuO\/NiO heterojunction for electrocatalytic reduction of nitrate at low concentrations to ammonia","author":"Chen","year":"2024","journal-title":"Chin. Chem. Lett."},{"issue":"31","key":"10.1016\/j.jcis.2025.02.018_b0115","doi-asserted-by":"crossref","first-page":"9176","DOI":"10.1002\/ange.201603022","article-title":"Ordered PdCu\u2010based nanoparticles as bifunctional oxygen\u2010reduction and ethanol\u2010oxidation electrocatalysts","volume":"128","author":"Jiang","year":"2016","journal-title":"Angew. Chem."},{"issue":"3","key":"10.1016\/j.jcis.2025.02.018_b0120","doi-asserted-by":"crossref","first-page":"4072","DOI":"10.1021\/acsami.0c20994","article-title":"Surface ligand environment boosts the electrocatalytic hydrodechlorination reaction on palladium nanoparticles","volume":"13","author":"Jiang","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"9","key":"10.1016\/j.jcis.2025.02.018_b0125","doi-asserted-by":"crossref","first-page":"3367","DOI":"10.1021\/acsenergylett.1c01302","article-title":"Quasi-two-dimensional earth-abundant bimetallic electrocatalysts for oxygen evolution reactions","volume":"6","author":"Zhao","year":"2021","journal-title":"ACS Energy Lett."},{"issue":"2","key":"10.1016\/j.jcis.2025.02.018_b0130","doi-asserted-by":"crossref","DOI":"10.1063\/1.5135913","article-title":"Kinetics of photo-isomerization of azobenzene containing surfactants","volume":"152","author":"Arya","year":"2020","journal-title":"J. Chem. Phys."},{"key":"10.1016\/j.jcis.2025.02.018_b0135","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1007\/b13181","article-title":"Elemental sulfur and sulfur-rich compounds II","volume":"231","author":"Eckert","year":"2003","journal-title":"Top. Curr. Chem."},{"issue":"8","key":"10.1016\/j.jcis.2025.02.018_b0140","first-page":"1112","article-title":"Vibrational and electronic spectroscopy of sulfuric acid vapor","volume":"107","author":"Hintze","year":"2003","journal-title":"Chem. A Eur. J."},{"key":"10.1016\/j.jcis.2025.02.018_b0145","article-title":"Hydrogen\u2010induced disproportionation of samarium\u2010cobalt intermetallics enabling promoted hydrogen evolution reaction activity and durability in alkaline media","author":"Chen","year":"2024","journal-title":"Adv. Funct. Mater."}],"container-title":["Journal of Colloid and Interface Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0021979725003510?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0021979725003510?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T21:21:21Z","timestamp":1777411281000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0021979725003510"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5]]},"references-count":29,"alternative-id":["S0021979725003510"],"URL":"https:\/\/doi.org\/10.1016\/j.jcis.2025.02.018","relation":{},"ISSN":["0021-9797"],"issn-type":[{"value":"0021-9797","type":"print"}],"subject":[],"published":{"date-parts":[[2025,5]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Interfacial water activation by Pd promotes SO2 electroreduction to H2S on CuPd bimetallic catalysts","name":"articletitle","label":"Article Title"},{"value":"Journal of Colloid and Interface Science","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jcis.2025.02.018","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 Elsevier Inc. All rights are reserved, including those for text and data mining, AI training, and similar technologies.","name":"copyright","label":"Copyright"}]}}