{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,3]],"date-time":"2026-11-03T02:56:17Z","timestamp":1793674577697,"version":"4.5.1"},"reference-count":46,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T00:00:00Z","timestamp":1764547200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T00:00:00Z","timestamp":1764547200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T00:00:00Z","timestamp":1764547200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T00:00:00Z","timestamp":1764547200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T00:00:00Z","timestamp":1764547200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T00:00:00Z","timestamp":1764547200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T00:00:00Z","timestamp":1764547200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100002729","name":"Anhui University","doi-asserted-by":"publisher","award":["GXXT-2022-061"],"award-info":[{"award-number":["GXXT-2022-061"]}],"id":[{"id":"10.13039\/501100002729","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100009004","name":"Anhui University of Chinese Medicine","doi-asserted-by":"publisher","award":["2022rcZD004"],"award-info":[{"award-number":["2022rcZD004"]}],"id":[{"id":"10.13039\/501100009004","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21971050"],"award-info":[{"award-number":["21971050"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Colloid and Interface Science"],"published-print":{"date-parts":[[2025,12]]},"DOI":"10.1016\/j.jcis.2025.138528","type":"journal-article","created":{"date-parts":[[2025,7,25]],"date-time":"2025-07-25T15:49:38Z","timestamp":1753458578000},"page":"138528","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":5,"special_numbering":"P3","title":["Coordination immobilization of palladium ions in the novel three-dimensional cerium porphyrin metal-organic framework for enhanced photocatalytic carbon dioxide reduction"],"prefix":"10.1016","volume":"700","author":[{"given":"Yuxuan","family":"Qi","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiquan","family":"Cai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi-Si","family":"Feng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junru","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenhong","family":"Dai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhifei","family":"Cheng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.jcis.2025.138528_bb0005","doi-asserted-by":"crossref","first-page":"12888","DOI":"10.1021\/acs.chemrev.5b00370","article-title":"Light-driven heterogeneous reduction of carbon dioxide: photocatalysts and photoelectrodes","volume":"115","author":"White","year":"2015","journal-title":"Chem. Rev."},{"key":"10.1016\/j.jcis.2025.138528_bb0010","doi-asserted-by":"crossref","DOI":"10.1016\/j.pmatsci.2024.101242","article-title":"Carbon nitride based nanoarchitectonics for nature-inspired photocatalytic CO2 reduction","volume":"142","author":"Sadanandan","year":"2024","journal-title":"Prog. Mater. Sci."},{"key":"10.1016\/j.jcis.2025.138528_bb0015","doi-asserted-by":"crossref","first-page":"364","DOI":"10.1039\/C4EE02853H","article-title":"Co@NH2-MIL-125(Ti): cobaloxime-derived metal\u2013organic framework-based composite for light-driven H2 production","volume":"8","author":"Nasalevich","year":"2015","journal-title":"Energ. Environ. Sci."},{"key":"10.1016\/j.jcis.2025.138528_bb0020","doi-asserted-by":"crossref","first-page":"564","DOI":"10.1038\/s41570-021-00289-y","article-title":"Highlights and challenges in the selective reduction of carbon dioxide to methanol","volume":"5","author":"Navarro-Ja\u00e9n","year":"2021","journal-title":"Nat. Rev. Chem."},{"key":"10.1016\/j.jcis.2025.138528_bb0025","doi-asserted-by":"crossref","first-page":"430","DOI":"10.1002\/anie.201408862","article-title":"Photochromic Metal\u2013Organic Frameworks: Reversible Control of Singlet Oxygen Generation","volume":"54","author":"Park","year":"2015","journal-title":"Angew. Chem.-Int. Edit."},{"key":"10.1016\/j.jcis.2025.138528_bb0030","doi-asserted-by":"crossref","first-page":"13971","DOI":"10.1039\/D0CC04116E","article-title":"Unravelling a long-lived ligand-to-metal cluster charge transfer state in Ce\u2013TCPP metal organic frameworks","volume":"56","author":"Yang","year":"2020","journal-title":"Chem. Commun."},{"key":"10.1016\/j.jcis.2025.138528_bb0035","doi-asserted-by":"crossref","first-page":"7904","DOI":"10.1021\/jacs.8b03613","article-title":"Cerium Metal\u2013Organic Framework for Photocatalysis","volume":"140","author":"Wu","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.jcis.2025.138528_bb0040","doi-asserted-by":"crossref","first-page":"6842","DOI":"10.1021\/acscatal.4c00625","article-title":"Ce4+\/Ce3+ redox-promoted Electron transfer for efficient neutral H2O2 electrosynthesis from two-Electron oxygen reduction","volume":"14","author":"Kim","year":"2024","journal-title":"ACS Catal."},{"key":"10.1016\/j.jcis.2025.138528_bb0045","article-title":"Ce3+\/Ce4+ ion redox shuttle stabilized Cu\u03b4+ for efficient CO2 electroreduction to C2H4","volume":"64","author":"Liu","year":"2025","journal-title":"Angew. Chem.-Int. Edit."},{"key":"10.1016\/j.jcis.2025.138528_bb0050","doi-asserted-by":"crossref","first-page":"9171","DOI":"10.1021\/acscatal.3c00502","article-title":"Synergic effect of isolated Ce3+ and Pt\u03b4+ species in UiO-66(Ce) for heterogeneous catalysis","volume":"13","author":"Rojas-Buzo","year":"2023","journal-title":"ACS Catal."},{"key":"10.1016\/j.jcis.2025.138528_bb0055","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2022.137102","article-title":"Embedding Cs2AgBiBr6 QDs into Ce-UiO-66-H to in situ construct a novel bifunctional material for capturing and photocatalytic reduction of CO2","volume":"446","author":"Ding","year":"2022","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jcis.2025.138528_bb0060","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2023.142103","article-title":"Functional porous Ce-UiO-66 MOF@keratin composites for the efficient adsorption of trypan blue dye from wastewater: a step towards practical implementations","volume":"461","author":"Hegde","year":"2023","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jcis.2025.138528_bb0065","doi-asserted-by":"crossref","first-page":"1766","DOI":"10.1021\/acs.langmuir.1c02873","article-title":"Mixed-valence bimetallic Ce\/Zr MOF-based nanoarchitecture: a visible-light-active photocatalyst for ciprofloxacin degradation and hydrogen evolution","volume":"38","author":"Tripathy","year":"2022","journal-title":"Langmuir"},{"key":"10.1016\/j.jcis.2025.138528_bb0070","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.119239","article-title":"Novel Cu2ZnSnS4\/Pt\/g-C3N4 heterojunction photocatalyst with straddling band configuration for enhanced solar to fuel conversion","volume":"277","author":"Raza","year":"2020","journal-title":"Appl. Catal. B-Environ."},{"key":"10.1016\/j.jcis.2025.138528_bb0075","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2020.118882","article-title":"Facile synthesis and photocatalytic efficacy of UiO-66\/CdIn2S4 nanocomposites with flowerlike 3D-microspheres towards aqueous phase decontamination of triclosan and H2 evolution","volume":"270","author":"Bariki","year":"2020","journal-title":"Appl. Catal. B-Environ."},{"key":"10.1016\/j.jcis.2025.138528_bb0080","doi-asserted-by":"crossref","DOI":"10.1016\/j.ccr.2022.214700","article-title":"Recent developments of photoactive cu(I) and ag(I) complexes with diphosphine and related ligands","volume":"470","author":"Takeda","year":"2022","journal-title":"Coord. Chem. Rev."},{"key":"10.1016\/j.jcis.2025.138528_bb0085","article-title":"Doping-mediated energy-level engineering of M@Au12 Superatoms (M=pd, Pt, rh, Ir) for efficient photoluminescence and photocatalysis","volume":"61","author":"Hirai","year":"2022","journal-title":"Angew. Chem.-Int. Edit."},{"key":"10.1016\/j.jcis.2025.138528_bb0090","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2024.149645","article-title":"Methane conversion using spark discharge-assisted laser-induced plasma (SD-LIP) with pd catalyst: non-oxidative hydrogen production","volume":"484","author":"Ahmadinouri","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jcis.2025.138528_bb0095","doi-asserted-by":"crossref","DOI":"10.1002\/smll.202207857","article-title":"Advanced catalyst for CO2 photo-reduction: from controllable product selectivity by architecture engineering to improving charge transfer using stabilized au clusters","volume":"19","author":"Ziarati","year":"2023","journal-title":"Small"},{"key":"10.1016\/j.jcis.2025.138528_bb0100","doi-asserted-by":"crossref","first-page":"22701","DOI":"10.1039\/D2TA04956B","article-title":"Photocatalytic dehydrogenation of organic hydrogen carrier on pd-TiO2(110) surfaces","volume":"10","author":"Kang","year":"2022","journal-title":"J Mater Chem A"},{"key":"10.1016\/j.jcis.2025.138528_bb0105","doi-asserted-by":"crossref","first-page":"5535","DOI":"10.1039\/D2GC00801G","article-title":"Pd doped carbon nitride (pd-g-C3N4): an efficient photocatalyst for hydrogenation via an Al\u2013H2O system and an electrocatalyst towards overall water splitting","volume":"24","author":"Sharma","year":"2022","journal-title":"Green Chem."},{"key":"10.1016\/j.jcis.2025.138528_bb0110","doi-asserted-by":"crossref","first-page":"214","DOI":"10.1016\/j.apcatb.2018.04.074","article-title":"Deposition of pd nanoparticles on TiO2 using a pd(acac)2 precursor for photocatalytic oxidation of CO under UV-LED irradiation","volume":"235","author":"Selishchev","year":"2018","journal-title":"Appl. Catal. B-Environ."},{"key":"10.1016\/j.jcis.2025.138528_bb0115","doi-asserted-by":"crossref","first-page":"2846","DOI":"10.1021\/acsenergylett.8b01853","article-title":"Residual pd enables photocatalytic H2 evolution from conjugated polymers","volume":"3","author":"Kosco","year":"2018","journal-title":"ACS Energy Lett."},{"key":"10.1016\/j.jcis.2025.138528_bb0120","doi-asserted-by":"crossref","first-page":"14","DOI":"10.1016\/j.jcis.2022.03.093","article-title":"Thermal and photocatalytic cascade one-pot synthesis of secondary amine using multifunctional pd decorated MOF-derived CeO2","volume":"619","author":"More","year":"2022","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.jcis.2025.138528_bb0125","article-title":"A highly conjugated nickel(II)-acetylide framework for efficient photocatalytic carbon dioxide reduction","volume":"64","author":"Qin","year":"2025","journal-title":"Angew. Chem.-Int. Edit."},{"key":"10.1016\/j.jcis.2025.138528_bb0130","doi-asserted-by":"crossref","first-page":"165","DOI":"10.1016\/j.jcis.2025.01.056","article-title":"Integration of platinum nanoparticles and pd-porphyrin photosensitiser into a metal\u2013organic framework for effective photocatalytic hydrogen evolution","volume":"685","author":"Xiao","year":"2025","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.jcis.2025.138528_bb0135","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2023.124214","article-title":"Sustainable development in the removal and photocatalytic reduction of heavy metals in wastewaters using environmentally friendly and health benign porphyrin-based metal-organic frameworks","volume":"322","author":"Harvey","year":"2023","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.jcis.2025.138528_bb0140","doi-asserted-by":"crossref","first-page":"4309","DOI":"10.1021\/jacs.3c12275","article-title":"Rapid exciton transport and structural defects in individual Porphyrinic metal organic framework microcrystals","volume":"146","author":"Afrin","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.jcis.2025.138528_bb0145","doi-asserted-by":"crossref","first-page":"2082","DOI":"10.1039\/D2CS00784C","article-title":"Organometallic chemistry confined within a porphyrin-like framework","volume":"52","author":"Bia\u0142ek","year":"2023","journal-title":"Chem. Soc. Rev."},{"key":"10.1016\/j.jcis.2025.138528_bb0150","doi-asserted-by":"crossref","first-page":"3613","DOI":"10.1021\/jacs.7b11788","article-title":"A fully noble metal-free photosystem based on cobalt-polyoxometalates immobilized in a porphyrinic metal\u2013organic framework for water oxidation","volume":"140","author":"Paille","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.jcis.2025.138528_bb0155","doi-asserted-by":"crossref","DOI":"10.1016\/j.jcat.2023.115226","article-title":"Bimetallic synergy significantly enhances the photocatalytic performance of lanthanide porphyrin-based MOFs: efficient photocatalytic oxidation of benzyl alcohol and benzylamine under mild conditions in air","volume":"429","author":"Qi","year":"2024","journal-title":"J. Catal."},{"key":"10.1016\/j.jcis.2025.138528_bb0160","doi-asserted-by":"crossref","first-page":"9217","DOI":"10.1021\/acscatal.4c02326","article-title":"Active site isolation and enhanced electron transfer facilitate photocatalytic CO2 reduction by a multifunctional metal\u2013organic framework","volume":"14","author":"Wang","year":"2024","journal-title":"ACS Catal."},{"key":"10.1016\/j.jcis.2025.138528_bb0165","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2022.121349","article-title":"A novel (Ti\/Ce)UiO-X MOFs@TiO2 heterojunction for enhanced photocatalytic performance: boosting via Ce4+\/Ce3+ and Ti4+\/Ti3+ redox mediators","volume":"310","author":"Parnicka","year":"2022","journal-title":"Appl. Catal. B-Environ."},{"key":"10.1016\/j.jcis.2025.138528_bb0170","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202206887","article-title":"Sustainable synthesis of dual single-atom catalyst of pd-N4\/cu-N4 for partial oxidation of ethylene glycol","volume":"32","author":"Moges","year":"2022","journal-title":"Adv. Funct. Mater."},{"key":"10.1016\/j.jcis.2025.138528_bb0175","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202210702","article-title":"Bimetal Organic Framework\u2013Ti3C2Tx MXene with Metalloporphyrin Electrocatalyst for Lithium\u2013Oxygen Batteries","volume":"33","author":"Nam","year":"2023","journal-title":"Adv. Funct. Mater."},{"key":"10.1016\/j.jcis.2025.138528_bb0180","doi-asserted-by":"crossref","DOI":"10.1038\/s41467-023-40117-z","article-title":"Confining charge-transfer complex in a metal-organic framework for photocatalytic CO2 reduction in water","volume":"14","author":"Karmakar","year":"2023","journal-title":"Nat. Commun."},{"key":"10.1016\/j.jcis.2025.138528_bb0185","doi-asserted-by":"crossref","first-page":"74","DOI":"10.1038\/nature23016","article-title":"Visible-light-driven methane formation from CO2 with a molecular iron catalyst","volume":"548","author":"Rao","year":"2017","journal-title":"Nature"},{"key":"10.1016\/j.jcis.2025.138528_bb0190","doi-asserted-by":"crossref","first-page":"18148","DOI":"10.1021\/jacs.3c07047","article-title":"Thermally Induced Orderly Alignment of Porphyrin Photoactive Motifs in Metal\u2013Organic Frameworks for Boosting Photocatalytic CO2 Reduction","volume":"145","author":"Huang","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.jcis.2025.138528_bb0195","doi-asserted-by":"crossref","first-page":"17836","DOI":"10.1021\/acs.inorgchem.4c02841","article-title":"Photocatalytic CO2 reduction to solar fuels by a chemically stable bimetallic porphyrin-based framework","volume":"63","author":"Jena","year":"2024","journal-title":"Inorg. Chem."},{"key":"10.1016\/j.jcis.2025.138528_bb0200","doi-asserted-by":"crossref","first-page":"8558","DOI":"10.1021\/acscatal.2c01519","article-title":"Photocatalytic reduction of carbon dioxide to methane at the pd-supported TiO2 Interface: mechanistic insights from theoretical studies","volume":"12","author":"Yang","year":"2022","journal-title":"ACS Catal."},{"key":"10.1016\/j.jcis.2025.138528_bb0205","doi-asserted-by":"crossref","first-page":"6965","DOI":"10.1039\/D2CS00183G","article-title":"Porphyrins and phthalocyanines as biomimetic tools for photocatalytic H2 production and CO2 reduction","volume":"51","author":"Nikoloudakis","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"10.1016\/j.jcis.2025.138528_bb0210","doi-asserted-by":"crossref","first-page":"6301","DOI":"10.1021\/acs.inorgchem.0c00407","article-title":"Encapsulation of Single Iron Sites in a Metal\u2013Porphyrin Framework for High-Performance Photocatalytic CO2 Reduction","volume":"59","author":"Wang","year":"2020","journal-title":"Inorg. Chem."},{"key":"10.1016\/j.jcis.2025.138528_bb0215","article-title":"Facilitated Photocatalytic CO2 Reduction in Aerobic Environment on a Copper-Porphyrin Metal\u2013Organic Framework","volume":"62","author":"Xie","year":"2023","journal-title":"Angew. Chem.-Int. Edit."},{"key":"10.1016\/j.jcis.2025.138528_bb0220","doi-asserted-by":"crossref","first-page":"10977","DOI":"10.1021\/acscatal.9b03891","article-title":"Low-temperature oxidation of methanol to formaldehyde on a model single-atom catalyst: pd atoms on Fe3O4(001)","volume":"9","author":"Marcinkowski","year":"2019","journal-title":"ACS Catal."},{"key":"10.1016\/j.jcis.2025.138528_bb0225","doi-asserted-by":"crossref","first-page":"15660","DOI":"10.1021\/acssuschemeng.9b03773","article-title":"Integration of Copper(II)-Porphyrin Zirconium Metal\u2013Organic Framework and Titanium Dioxide to Construct Z-Scheme System for Highly Improved Photocatalytic CO2 Reduction","volume":"7","author":"Wang","year":"2019","journal-title":"ACS Sustain. Chem. Eng."},{"key":"10.1016\/j.jcis.2025.138528_bb0230","doi-asserted-by":"crossref","first-page":"4703","DOI":"10.3390\/molecules28124703","article-title":"In situ encapsulation of graphene quantum dots in highly stable porphyrin metal-organic frameworks for efficient photocatalytic CO2 reduction","volume":"28","author":"Yu","year":"2023","journal-title":"Molecules"}],"container-title":["Journal of Colloid and Interface Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0021979725019198?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0021979725019198?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,5,25]],"date-time":"2026-05-25T08:08:42Z","timestamp":1779696522000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0021979725019198"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,12]]},"references-count":46,"alternative-id":["S0021979725019198"],"URL":"https:\/\/doi.org\/10.1016\/j.jcis.2025.138528","relation":{},"ISSN":["0021-9797"],"issn-type":[{"value":"0021-9797","type":"print"}],"subject":[],"published":{"date-parts":[[2025,12]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Coordination immobilization of palladium ions in the novel three-dimensional cerium porphyrin metal-organic framework for enhanced photocatalytic carbon dioxide reduction","name":"articletitle","label":"Article Title"},{"value":"Journal of Colloid and Interface Science","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jcis.2025.138528","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 Elsevier Inc. All rights are reserved, including those for text and data mining, AI training, and similar technologies.","name":"copyright","label":"Copyright"}],"article-number":"138528"}}