{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,6]],"date-time":"2026-09-06T17:44:32Z","timestamp":1788716672532,"version":"build-2803163510"},"reference-count":95,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2019,10,1]],"date-time":"2019-10-01T00:00:00Z","timestamp":1569888000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2019,10,1]],"date-time":"2019-10-01T00:00:00Z","timestamp":1569888000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2019,7,24]],"date-time":"2019-07-24T00:00:00Z","timestamp":1563926400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004963","name":"Seventh Framework Programme","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004963","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Contaminant Hydrology"],"published-print":{"date-parts":[[2019,10]]},"DOI":"10.1016\/j.jconhyd.2019.103520","type":"journal-article","created":{"date-parts":[[2019,7,8]],"date-time":"2019-07-08T11:15:51Z","timestamp":1562584551000},"page":"103520","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":18,"special_numbering":"C","title":["Do CSIA data from aquifers inform on natural degradation of chlorinated ethenes in aquitards?"],"prefix":"10.1016","volume":"226","author":[{"given":"H\u00e9lo\u00efse A.A.","family":"Thouement","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tomasz","family":"Kuder","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timo J.","family":"Heimovaara","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Boris M.","family":"van Breukelen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.jconhyd.2019.103520_bb0005","doi-asserted-by":"crossref","first-page":"1588","DOI":"10.1021\/es051128p","article-title":"Does the Rayleigh equation apply to evaluate field isotope data in contaminant hydrogeology?","volume":"40","author":"Abe","year":"2006","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0010","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/j.jconhyd.2009.03.002","article-title":"Evaluating the fate of chlorinated ethenes in streambed sediments by combining stable isotope, geochemical and microbial methods","volume":"107","author":"Abe","year":"2009","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0015","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1111\/gwmr.12090","article-title":"Characterization and source history modeling using low-k zone profiles at two source areas","volume":"35","author":"Adamson","year":"2015","journal-title":"Groundw. Monit. Remediat."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0020","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1016\/j.scitotenv.2016.03.211","article-title":"Implications of matrix diffusion on 1,4-dioxane persistence at contaminated groundwater sites","volume":"562","author":"Adamson","year":"2016","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0025","doi-asserted-by":"crossref","first-page":"3705","DOI":"10.1021\/es903895b","article-title":"Quantifying in situ transformation rates of chlorinated ethenes by combining compound-specific stable isotope analysis, groundwater dating, and carbon isotope mass balances","volume":"44","author":"Aeppli","year":"2010","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0030","doi-asserted-by":"crossref","first-page":"203","DOI":"10.1016\/0169-7722(95)00089-5","article-title":"Non-linear chlorinated-solvent sorption in four aquitards","volume":"22","author":"Allen-King","year":"1996","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0035","doi-asserted-by":"crossref","first-page":"774","DOI":"10.1016\/j.chemosphere.2011.06.063","article-title":"Assessing the transformation of chlorinated ethenes in aquifers with limited potential for natural attenuation: added values of compound-specific carbon isotope analysis and groundwater dating","volume":"85","author":"Amaral","year":"2011","journal-title":"Chemosphere"},{"key":"10.1016\/j.jconhyd.2019.103520_bb0040","doi-asserted-by":"crossref","first-page":"747","DOI":"10.1016\/j.jhazmat.2015.06.052","article-title":"C, Cl and H compound-specific isotope analysis to assess natural versus Fe(0) barrier-induced degradation of chlorinated ethenes at a contaminated site","volume":"299","author":"Aud\u00ed-Mir\u00f3","year":"2015","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0045","doi-asserted-by":"crossref","first-page":"733","DOI":"10.1111\/gwat.12413","article-title":"Scripting MODFLOW model development using python and FloPy","volume":"54","author":"Bakker","year":"2016","journal-title":"Groundw."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0050","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1111\/j.1745-6584.1998.tb01091.x","article-title":"A comparison of zero-order, first-orde, and Monod kinetics biotransformation models","volume":"36","author":"Bekins","year":"1997","journal-title":"Groundw."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0055","doi-asserted-by":"crossref","first-page":"2768","DOI":"10.1021\/es991179k","article-title":"Carbon isotope fractionation during microbial dechlorination of trichloroethene, cis -1,2-dichloroethene, and vinyl chloride: implications for assessment of natural attenuation","volume":"34","author":"Bloom","year":"2000","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb2000","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1016\/S0169-7722(01)00138-3","article-title":"Tracer diffusion coefficients in sedimentary rocks: Correlation to porosity and hydraulic conductivity","volume":"53","author":"Boving","year":"2001","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0060","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1002\/rem.21440","article-title":"Application of an adapted version of MT3DMS for modeling back-diffusion remediation timeframes","volume":"25","author":"Carey","year":"2015","journal-title":"Remediat. J."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0065","doi-asserted-by":"crossref","first-page":"476","DOI":"10.1111\/gwat.12406","article-title":"Estimating tortuosity coefficients based on hydraulic conductivity","volume":"54","author":"Carey","year":"2016","journal-title":"Groundw."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0070","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/j.jconhyd.2009.10.008","article-title":"Modeling multi-component transport and enhanced anaerobic dechlorination processes in a single fracture-clay matrix system","volume":"112","author":"Chambon","year":"2010","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0075","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/bit.24714","article-title":"Review of reactive kinetic models describing reductive dechlorination of chlorinated ethenes in soil and groundwater","volume":"110","author":"Chambon","year":"2013","journal-title":"Biotechnol. Bioeng."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0080","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1029\/2005WR004224","article-title":"Plume persistence due to aquitard back diffusion following dense nonaqueous phase liquid source removal or isolation","volume":"41","author":"Chapman","year":"2005","journal-title":"Water Resour. Res."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0085","doi-asserted-by":"crossref","first-page":"106","DOI":"10.1016\/j.jconhyd.2012.04.006","article-title":"Testing high resolution numerical models for analysis of contaminant storage and release from low permeability zones","volume":"136\u2013137","author":"Chapman","year":"2012","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0090","doi-asserted-by":"crossref","first-page":"639","DOI":"10.1016\/j.chemosphere.2007.11.013","article-title":"Variability in microbial carbon isotope fractionation of tetra- and trichloroethene upon reductive dechlorination","volume":"71","author":"Cichocka","year":"2008","journal-title":"Chemosphere"},{"key":"10.1016\/j.jconhyd.2019.103520_bb0095","doi-asserted-by":"crossref","first-page":"2726","DOI":"10.1128\/AEM.68.6.2726-2730.2002","article-title":"Biodegradation of cis-dichloroethene as the sole carbon source by a \u03b2-Proteobacterium","volume":"68","author":"Coleman","year":"2002","journal-title":"Appl. Environ. Microbiol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0100","doi-asserted-by":"crossref","first-page":"6162","DOI":"10.1128\/AEM.68.12.6162-6171.2002","article-title":"Phylogenetic and kinetic diversity of aerobic vinyl chloride-assimilating bacteria from contaminated sites","volume":"68","author":"Coleman","year":"2002","journal-title":"Appl. Environ. Microbiol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0105","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1016\/j.jconhyd.2012.11.010","article-title":"Identification of chlorinated solvents degradation zones in clay till by high resolution chemical, microbial and compound specific isotope analysis","volume":"146","author":"Damgaard","year":"2013","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0110","doi-asserted-by":"crossref","first-page":"48","DOI":"10.1111\/j.1745-6592.2012.01405.x","article-title":"Performance of full-scale enhanced reductive dechlorination in clay till","volume":"33","author":"Damgaard","year":"2013","journal-title":"Groundw. Monit. Remediat."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0115","doi-asserted-by":"crossref","first-page":"6900","DOI":"10.1021\/es304879d","article-title":"Model complexity needed for quantitative analysis of high resolution isotope and concentration data from a toluene-pulse experiment","volume":"47","author":"Eckert","year":"2013","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0120","doi-asserted-by":"crossref","first-page":"129","DOI":"10.1016\/j.jconhyd.2016.07.003","article-title":"Origin of VC-only plumes from naturally enhanced dechlorination in a peat-rich hydrogeologic setting","volume":"192","author":"Filippini","year":"2016","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0125","doi-asserted-by":"crossref","first-page":"895","DOI":"10.1029\/91WR00242","article-title":"Large-scale natural gradient tracer testing sand and gravel, Cape Cod, Massachusetts","volume":"27","author":"Garabedian","year":"1991","journal-title":"Water Resour. Res."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0130","first-page":"23","article-title":"The mineralogy of suspended matter, fresh and Cenozoic sediments in the fluvio-deltaic Rhine-Meuse-Scheldt-Ems area, the Netherlands: an overview and review","volume":"95","author":"Griffioen","year":"2016","journal-title":"Geol. en Mijnbouw\/Netherlands J. Geosci."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0135","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1016\/j.jconhyd.2016.11.002","article-title":"Simulating stable carbon and chlorine isotope ratios in dissolved chlorinated groundwater pollutants with BIOCHLOR-ISO Ethene Ethene Chlorine\u202f: standard approach","volume":"195","author":"H\u00f6hener","year":"2016","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0140","doi-asserted-by":"crossref","first-page":"740","DOI":"10.1016\/j.advwatres.2010.03.016","article-title":"Multidimensional analytical models for isotope ratios in groundwater pollutant plumes of organic contaminants undergoing different biodegradation kinetics","volume":"33","author":"H\u00f6hener","year":"2010","journal-title":"Adv. Water Resour."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0145","doi-asserted-by":"crossref","first-page":"54","DOI":"10.1016\/j.jconhyd.2011.09.006","article-title":"Stable carbon and hydrogen isotope fractionation of dissolved organic groundwater pollutants by equilibrium sorption","volume":"129\u2013130","author":"H\u00f6hener","year":"2012","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0150","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1016\/j.jconhyd.2015.09.006","article-title":"Improved constraints on in situ rates and on quantification of complete chloroethene degradation from stable carbon isotope mass balances in groundwater plumes","volume":"182","author":"H\u00f6hener","year":"2015","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0155","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1111\/gwat.12472","article-title":"Simulating stable isotope ratios in plumes of groundwater pollutants with BIOSCREEN-AT-ISO","volume":"55","author":"H\u00f6hener","year":"2017","journal-title":"Groundw."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0160","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/j.jconhyd.2014.12.005","article-title":"Evolution of carbon isotope signatures during reactive transport of hydrocarbons in heterogeneous aquifers","volume":"174","author":"H\u00f6yng","year":"2015","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0165","doi-asserted-by":"crossref","first-page":"2839","DOI":"10.1021\/es991178s","article-title":"Determination of compound-specific carbon isotope ratios of chlorinated methanes, ethanes, and ethenes in aqueous samples","volume":"34","author":"Hunkeler","year":"2000","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0170","doi-asserted-by":"crossref","first-page":"2733","DOI":"10.1021\/es981282u","article-title":"Monitoring microbial dechlorination of tetrachloroethene (PCE) in groundwater using compound-specific stable carbon isotope ratios: microcosm and field studies","volume":"33","author":"Hunkeler","year":"1999","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0175","doi-asserted-by":"crossref","first-page":"3378","DOI":"10.1021\/es011479d","article-title":"Carbon isotopes as a tool to evaluate the origin and fate of vinyl chloride: laboratory experiments and modeling of isotope evolution","volume":"36","author":"Hunkeler","year":"2002","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0180","doi-asserted-by":"crossref","first-page":"265","DOI":"10.1016\/j.jconhyd.2004.03.003","article-title":"Effect of source variability and transport processes on carbon isotope ratios of TCE and PCE in two sandy aquifers","volume":"74","author":"Hunkeler","year":"2004","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0185","series-title":"A Guide for Assessing Biodegradation and Source Identification of Organic Ground Water Contaminants Using Compound Specific Isotope Analysis (CSIA)","author":"Hunkeler","year":"2008"},{"key":"10.1016\/j.jconhyd.2019.103520_bb0190","doi-asserted-by":"crossref","first-page":"6750","DOI":"10.1021\/es900579z","article-title":"Modeling chlorine isotope trends during sequential transformation of chlorinated ethenes","volume":"43","author":"Hunkeler","year":"2009","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0195","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/j.jconhyd.2010.09.009","article-title":"Assessing chlorinated ethene degradation in a large scale contaminant plume by dual carbon-chlorine isotope analysis and quantitative PCR","volume":"119","author":"Hunkeler","year":"2011","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0200","doi-asserted-by":"crossref","first-page":"8247","DOI":"10.1021\/es201415k","article-title":"Carbon and chlorine isotope ratios of chlorinated ethenes migrating through a thick unsaturated zone of a sandy aquifer","volume":"45","author":"Hunkeler","year":"2011","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0205","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/j.advwatres.2013.05.009","article-title":"A multiphase flow and multispecies reactive transport model for DNAPL-involved compound specific isotope analysis","volume":"59","author":"Hwang","year":"2013","journal-title":"Adv. Water Resour."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0210","doi-asserted-by":"crossref","first-page":"454","DOI":"10.1016\/j.chemosphere.2014.01.063","article-title":"Carbon and hydrogen isotope fractionation of benzene and toluene during hydrophobic sorption in multistep batch experiments","volume":"107","author":"Imfeld","year":"2014","journal-title":"Chemosphere"},{"key":"10.1016\/j.jconhyd.2019.103520_bb0215","doi-asserted-by":"crossref","first-page":"6141","DOI":"10.1021\/es4046956","article-title":"Diffusive fractionation of BTEX and chlorinated ethenes in aqueous solution: quantification of spatial isotope gradients","volume":"48","author":"Jin","year":"2014","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0220","doi-asserted-by":"crossref","first-page":"896","DOI":"10.1021\/es00029a004","article-title":"Dissolution of dense chlorinated solventsinto groundwater. 2. Source functions for pools of solvent","volume":"26","author":"Johnson","year":"1992","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0225","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1016\/j.jenvman.2004.02.003","article-title":"An overview and analysis of site remediation technologies","volume":"71","author":"Khan","year":"2004","journal-title":"J. Environ. Manag."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0230","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/S0169-7722(02)00011-6","article-title":"Transverse vertical dispersion in groundwater and the capillary fringe","volume":"58","author":"Klenk","year":"2002","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0235","doi-asserted-by":"crossref","first-page":"6052","DOI":"10.1021\/es040096n","article-title":"Carbon isotope fractionation of organic contaminants due to retardation on humic substances: implications for natural attenuation studies in aquifers","volume":"39","author":"Kopinke","year":"2005","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0240","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1029\/2006WR005264","article-title":"Isotopic fractionation by diffusion in groundwater","volume":"44","author":"LaBolle","year":"2008","journal-title":"Water Resour. Res."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0245","doi-asserted-by":"crossref","first-page":"175","DOI":"10.1111\/j.1745-6584.2002.tb02502.x","article-title":"Back diffusion of chlorinated solvent contaminants from a natural aquitard to a remediated aquifer under well-controlled field conditions: predictions and measurements","volume":"40","author":"Liu","year":"2002","journal-title":"Ground Water"},{"key":"10.1016\/j.jconhyd.2019.103520_bb0250","doi-asserted-by":"crossref","first-page":"1467","DOI":"10.1016\/j.chemosphere.2011.03.007","article-title":"Sorption of chlorinated solvents and degradation products on natural clayey tills","volume":"83","author":"Lu","year":"2011","journal-title":"Chemosphere"},{"key":"10.1016\/j.jconhyd.2019.103520_bb0255","doi-asserted-by":"crossref","first-page":"6229","DOI":"10.1021\/es4054016","article-title":"Combined source apportionment and degradation quantification of organic pollutants with CSIA: 2. Model validation and application","volume":"48","author":"Lutz","year":"2014","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0260","doi-asserted-by":"crossref","first-page":"4505","DOI":"10.5194\/hess-17-4505-2013","article-title":"A model-based assessment of the potential use of compound-specific stable isotope analysis in river monitoring of diffuse pesticide pollution","volume":"17","author":"Lutz","year":"2013","journal-title":"Hydrol. Earth Syst. Sci."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0265","doi-asserted-by":"crossref","first-page":"5243","DOI":"10.5194\/hess-21-5243-2017","article-title":"Pesticide fate on catchment scale: conceptual modelling of stream CSIA data","volume":"21","author":"Lutz","year":"2017","journal-title":"Hydrol. Earth Syst. Sci."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0270","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1016\/j.advwatres.2014.07.007","article-title":"Impacts of transport mechanisms and plume history on tailing of sorbing plumes in heterogeneous porous formations","volume":"73","author":"Maghrebi","year":"2014","journal-title":"Adv. Water Resour."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0275","doi-asserted-by":"crossref","first-page":"149","DOI":"10.1016\/j.jhydrol.2015.07.015","article-title":"Contaminant tailing in highly heterogeneous porous formations: sensitivity on model selection and material properties","volume":"531","author":"Maghrebi","year":"2015","journal-title":"J. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0280","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1016\/j.jconhyd.2012.01.004","article-title":"A remediation performance model for enhanced metabolic reductive dechlorination of chloroethenes in fractured clay till","volume":"131","author":"Manoli","year":"2012","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0285","doi-asserted-by":"crossref","first-page":"913","DOI":"10.1021\/es048839s","article-title":"Critical review polyparameter linear free energy relationships for estimating the equilibrium partition of organic compounds between water and the natural organic matter in soils and sediments","volume":"39","author":"Nguyen","year":"2005","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0290","doi-asserted-by":"crossref","first-page":"92","DOI":"10.1016\/j.jconhyd.2013.06.004","article-title":"A stable isotope approach for source apportionment of chlorinated ethene plumes at a complex multi-contamination events urban site","volume":"153","author":"Nijenhuis","year":"2013","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0295","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1016\/j.jconhyd.2004.02.011","article-title":"Field study of TCE diffusion profiles below DNAPL to assess aquitard integrity","volume":"74","author":"Parker","year":"2004","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0300","doi-asserted-by":"crossref","first-page":"86","DOI":"10.1016\/j.jconhyd.2008.07.003","article-title":"Plume persistence caused by back diffusion from thin clay layers in a sand aquifer following TCE source-zone hydraulic isolation","volume":"102","author":"Parker","year":"2008","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0305","article-title":"User\u2019s guide to PHREEQC (version 2) \u2014 a computer program for speciation, and inverse geochemical calculations","author":"Parkhurst","year":"1999","journal-title":"Exch. Org. Behav. Teach. J."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0310","doi-asserted-by":"crossref","first-page":"164","DOI":"10.1016\/j.apgeochem.2012.09.012","article-title":"Hydrodynamic and isotopic characterization of a site contaminated by chlorinated solvents: Chienti River Valley, Central Italy","volume":"32","author":"Petitta","year":"2013","journal-title":"Appl. Geochem."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0315","first-page":"477","article-title":"PHT3D \u2013 a MODFLOW \/ MT3DMS-based reactive multi-component transport model","author":"Prommer","year":"2001","journal-title":"MODFLOW 2001 Other Model. Odysseys"},{"key":"10.1016\/j.jconhyd.2019.103520_bb0320","doi-asserted-by":"crossref","first-page":"6892","DOI":"10.1021\/es304877h","article-title":"Direct experimental evidence of non- first order degradation kinetics and sorption-induced isotopic fractionation in a mesoscale aquifer: 13 C\/ 12 C analysis of a transient toluene pulse","volume":"47","author":"Qiu","year":"2013","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0325","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1016\/j.jconhyd.2011.08.006","article-title":"Role of back diffusion and biodegradation reactions in sustaining an MTBE\/TBA plume in alluvial media","volume":"126","author":"Rasa","year":"2011","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0330","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1016\/j.jconhyd.2014.09.008","article-title":"Architecture, persistence and dissolution of a 20 to 45year old trichloroethene DNAPL source zone","volume":"170","author":"Rivett","year":"2014","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0335","doi-asserted-by":"crossref","first-page":"6167","DOI":"10.1021\/es101179f","article-title":"Isotopic fractionation by transverse dispersion: flow-through microcosms and reactive transport modeling study","volume":"44","author":"Rolle","year":"2010","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0340","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1016\/j.jconhyd.2008.08.002","article-title":"Effects of reduced contaminant loading on downgradient water quality in an idealized two-layer granular porous media","volume":"102","author":"Sale","year":"2008","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0345","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1016\/j.eti.2016.08.003","article-title":"Naturally occurring dechlorination reactions in rock matrices: impacts on TCE fate and flux","volume":"6","author":"Schaefer","year":"2016","journal-title":"Environ. Technol. Innov."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0350","doi-asserted-by":"crossref","first-page":"4291","DOI":"10.1021\/es400457s","article-title":"Coupled diffusion and abiotic reaction of trichlorethene in minimally disturbed rock matrices","volume":"47","author":"Schaefer","year":"2013","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0355","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/j.jconhyd.2017.09.007","article-title":"Abiotic dechlorination of chlorinated ethenes in natural clayey soils: impacts of mineralogy and temperature","volume":"206","author":"Schaefer","year":"2017","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0360","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/j.jconhyd.2012.03.010","article-title":"Relative contribution of DNAPL dissolution and matrix diffusion to the long-term persistence of chlorinated solvent source zones","volume":"134\u2013135","author":"Seyedabbasi","year":"2012","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0365","doi-asserted-by":"crossref","first-page":"5669","DOI":"10.1021\/ac000691h","article-title":"Carbon isotope effects resulting from equilibrium sorption of dissolved VOCs","volume":"72","author":"Slater","year":"2000","journal-title":"Anal. Chem."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0370","doi-asserted-by":"crossref","first-page":"14","DOI":"10.1016\/j.jconhyd.2011.01.003","article-title":"Comparative study of microbial dechlorination of chlorinated ethenes in an aquifer and a clayey aquitard","volume":"124","author":"Takeuchi","year":"2011","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb3000","doi-asserted-by":"crossref","first-page":"225","DOI":"10.1023\/A:1006006528573","article-title":"Partition constants and adsorption desorption hysteresis for volatile organic compounds on soil from a Louisiana superfund site","volume":"58","author":"Valsaraj","year":"1999","journal-title":"Environ. Monit. Assess."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0375","doi-asserted-by":"crossref","first-page":"4004","DOI":"10.1021\/es0628452","article-title":"Extending the Rayleigh equation to allow competing isotope fractionating pathways to improve quantification of biodegradation","volume":"41","author":"Van Breukelen","year":"2007","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0380","doi-asserted-by":"crossref","first-page":"2457","DOI":"10.1021\/es071981j","article-title":"Beyond the rayleigh equation: reactive transport modeling of isotope fractionation effects to improve quantification of biodegradation","volume":"42","author":"Van Breukelen","year":"2008","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0385","doi-asserted-by":"crossref","first-page":"7700","DOI":"10.1021\/es301058z","article-title":"Transverse hydrodynamic dispersion effects on isotope signals in groundwater chlorinated solvents plumes","volume":"46","author":"Van Breukelen","year":"2012","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0390","doi-asserted-by":"crossref","first-page":"4189","DOI":"10.1021\/es048973c","article-title":"Quantification of sequential chlorinated ethene degradation by use of a reactive transport model incorporating isotope fractionation","volume":"39","author":"Van Breukelen","year":"2005","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0395","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1016\/j.jconhyd.2017.07.003","article-title":"Modeling 3D-CSIA data\u202f: carbon, chlorine, and hydrogen isotope fractionation during reductive dechlorination of TCE to ethene","volume":"204","author":"Van Breukelen","year":"2017","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0400","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1080\/10889868.2014.978836","article-title":"A long-term field study of in situ bioremediation in a fractured conglomerate trichloroethene source zone","volume":"19","author":"Verce","year":"2015","journal-title":"Bioremediat. J."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0405","doi-asserted-by":"crossref","first-page":"198","DOI":"10.1016\/j.gca.2015.02.034","article-title":"Carbon and chlorine isotopologue fractionation of chlorinated hydrocarbons during diffusion in water and low permeability sediments","volume":"157","author":"Wanner","year":"2015","journal-title":"Geochim. Cosmochim. Acta"},{"key":"10.1016\/j.jconhyd.2019.103520_bb0410","doi-asserted-by":"crossref","first-page":"5622","DOI":"10.1021\/acs.est.5b06330","article-title":"Quantification of degradation of chlorinated hydrocarbons in saturated low permeability sediments using compound-specific isotope analysis","volume":"50","author":"Wanner","year":"2016","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0415","doi-asserted-by":"crossref","first-page":"348","DOI":"10.1016\/j.apgeochem.2017.07.016","article-title":"Does sorption influence isotope ratios of chlorinated hydrocarbons under field conditions?","volume":"84","author":"Wanner","year":"2017","journal-title":"Appl. Geochem."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0420","doi-asserted-by":"crossref","DOI":"10.1021\/acs.est.8b01173","article-title":"Identification of degradation pathways of chlorohydrocarbons in saturated low-permeability sediments using compound-specific isotope analysis","volume":"52","author":"Wanner","year":"2018","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0425","doi-asserted-by":"crossref","first-page":"1602","DOI":"10.1016\/j.scitotenv.2018.03.192","article-title":"Assessing the effect of chlorinated hydrocarbon degradation in aquitards on plume persistence due to back-diffusion","volume":"633","author":"Wanner","year":"2018","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0430","doi-asserted-by":"crossref","first-page":"416","DOI":"10.1111\/j.1745-6584.2009.00662.x","article-title":"Plume detachment and recession times in fractured rock","volume":"48","author":"West","year":"2010","journal-title":"Groundw."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0435","doi-asserted-by":"crossref","DOI":"10.1021\/es3016843","article-title":"Dual carbon-chlorine stable isotope investigation of sources and fate of chlorinated ethenes in contaminated groundwater","author":"Wiegert","year":"2012","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0440","doi-asserted-by":"crossref","first-page":"6449","DOI":"10.1021\/es305236y","article-title":"Carbon and chlorine isotope fractionation during microbial degradation of tetra- and trichloroethene","volume":"47","author":"Wiegert","year":"2013","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0445","first-page":"289","article-title":"Eine neue Gleichung zur Berechnung von Diffusionskoeffizienten gel\u00f6ster Stoffe","volume":"81","author":"Worch","year":"1993","journal-title":"Vom Wasser"},{"key":"10.1016\/j.jconhyd.2019.103520_bb0450","doi-asserted-by":"crossref","first-page":"1085","DOI":"10.1016\/j.scitotenv.2017.06.195","article-title":"Rethinking aqueous phase diffusion related isotope fractionation: contrasting theoretical effects with observations at the field scale","volume":"607\u2013608","author":"Xu","year":"2017","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0455","doi-asserted-by":"crossref","first-page":"415","DOI":"10.1021\/es5045634","article-title":"Back diffusion from thin low permeability zones","volume":"49","author":"Yang","year":"2015","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0460","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1016\/j.jconhyd.2017.05.001","article-title":"Field-scale forward and back-diffusion through low-permeability zones","volume":"202","author":"Yang","year":"2017","journal-title":"J. Contam. Hydrol."},{"key":"10.1016\/j.jconhyd.2019.103520_bb0465","doi-asserted-by":"crossref","first-page":"1549","DOI":"10.13031\/2013.42263","article-title":"MT3DMS: model use, calibration, and validation","volume":"55","author":"Zheng","year":"2012","journal-title":"Trans. ASABE"}],"container-title":["Journal of Contaminant Hydrology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0169772218302316?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0169772218302316?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,9,30]],"date-time":"2025-09-30T15:18:02Z","timestamp":1759245482000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0169772218302316"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,10]]},"references-count":95,"alternative-id":["S0169772218302316"],"URL":"https:\/\/doi.org\/10.1016\/j.jconhyd.2019.103520","relation":{},"ISSN":["0169-7722"],"issn-type":[{"value":"0169-7722","type":"print"}],"subject":[],"published":{"date-parts":[[2019,10]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Do CSIA data from aquifers inform on natural degradation of chlorinated ethenes in aquitards?","name":"articletitle","label":"Article Title"},{"value":"Journal of Contaminant Hydrology","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jconhyd.2019.103520","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2019 The Authors. Published by Elsevier B.V.","name":"copyright","label":"Copyright"}],"article-number":"103520"}}