{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,19]],"date-time":"2026-10-19T03:20:54Z","timestamp":1792380054934,"version":"4.4.0"},"reference-count":33,"publisher":"Elsevier BV","issue":"1","license":[{"start":{"date-parts":[[2021,2,1]],"date-time":"2021-02-01T00:00:00Z","timestamp":1612137600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2021,2,1]],"date-time":"2021-02-01T00:00:00Z","timestamp":1612137600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"}],"funder":[{"DOI":"10.13039\/501100001321","name":"National Research Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001321","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Environmental Chemical Engineering"],"published-print":{"date-parts":[[2021,2]]},"DOI":"10.1016\/j.jece.2020.104834","type":"journal-article","created":{"date-parts":[[2020,11,26]],"date-time":"2020-11-26T02:24:00Z","timestamp":1606357440000},"page":"104834","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":69,"title":["The effect of CO2 and H2 adsorption strength and capacity on the performance of Ga and Zr modified Cu-Zn catalysts for CO2 hydrogenation to methanol"],"prefix":"10.1016","volume":"9","author":[{"given":"B.S.","family":"Xaba","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A.S.","family":"Mahomed","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"H.B.","family":"Friedrich","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.jece.2020.104834_bib1","doi-asserted-by":"crossref","first-page":"487","DOI":"10.1021\/jo801260f","article-title":"Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons","volume":"74","author":"Olah","year":"2009","journal-title":"J. Org. Chem."},{"key":"10.1016\/j.jece.2020.104834_bib2","series-title":"Beyond Oil and Gas: The Methanol Economy","author":"Olah","year":"2009"},{"key":"10.1016\/j.jece.2020.104834_bib3","doi-asserted-by":"crossref","first-page":"97","DOI":"10.1016\/0013-7480(77)90080-8","article-title":"Production of synthetic methanol from air and water using controlled thermonuclear reactor power\u2014I. Technology and energy requirement","volume":"17","author":"Steinberg","year":"1977","journal-title":"Energy Convers."},{"key":"10.1016\/j.jece.2020.104834_bib4","series-title":"Beyond Oil and Gas: The Methanol Economy","author":"Olah","year":"2011"},{"key":"10.1016\/j.jece.2020.104834_bib5","doi-asserted-by":"crossref","first-page":"480","DOI":"10.4209\/aaqr.2013.10.0326","article-title":"A review: CO2 utilization","volume":"14","author":"Huang","year":"2014","journal-title":"Aerosol Air Qual. Res."},{"key":"10.1016\/j.jece.2020.104834_bib6","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1016\/j.cattod.2009.07.075","article-title":"Opportunities and prospects in the chemical recycling of carbon dioxide to fuels","volume":"148","author":"Centi","year":"2009","journal-title":"Catal. Today"},{"key":"10.1016\/j.jece.2020.104834_bib7","doi-asserted-by":"crossref","first-page":"80","DOI":"10.1016\/j.cattod.2008.11.022","article-title":"Basic evidences for methanol-synthesis catalyst design","volume":"143","author":"Arena","year":"2009","journal-title":"Catal. Today"},{"key":"10.1016\/j.jece.2020.104834_bib8","article-title":"Chemical hydrogen storage by methanol: challenges for the catalytic methanol synthesis from CO2","author":"Behrens","year":"2015","journal-title":"Recycl. Catal."},{"key":"10.1016\/j.jece.2020.104834_bib9","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1016\/j.enconman.2016.03.075","article-title":"Tuning of catalytic CO2 hydrogenation by changing composition of CuO\u2013ZnO\u2013ZrO2 catalysts","volume":"118","author":"Witoon","year":"2016","journal-title":"Energy Convers. Manag."},{"key":"10.1016\/j.jece.2020.104834_bib10","doi-asserted-by":"crossref","first-page":"8709","DOI":"10.1039\/C6RA28305E","article-title":"Structure\u2013activity relationships of Cu\u2013ZrO 2 catalysts for CO 2 hydrogenation to methanol: interaction effects and reaction mechanism","volume":"7","author":"Wang","year":"2017","journal-title":"RSC Adv."},{"key":"10.1016\/j.jece.2020.104834_bib11","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1016\/j.jcat.2016.03.020","article-title":"Enhanced CO2 hydrogenation to methanol over CuZn nanoalloy in Ga modified Cu\/ZnO catalysts","volume":"343","author":"Li","year":"2016","journal-title":"J. Catal."},{"key":"10.1016\/j.jece.2020.104834_bib12","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1016\/j.apcata.2006.05.035","article-title":"Effect of metal oxide additives on the activity and stability of Cu\/ZnO\/ZrO2 catalysts in the synthesis of methanol from CO2 and H2","volume":"310","author":"S\u0142oczy\u0144ski","year":"2006","journal-title":"Appl. Catal. Gen."},{"key":"10.1016\/j.jece.2020.104834_bib13","doi-asserted-by":"crossref","DOI":"10.3390\/catal5041846","article-title":"Catalytic hydrogenation of CO2 to methanol: study of synergistic effect on adsorption properties of CO2 and H2 in CuO\/ZnO\/ZrO2 system","volume":"5","author":"Huang","year":"2015","journal-title":"Catalysts"},{"key":"10.1016\/j.jece.2020.104834_bib14","doi-asserted-by":"crossref","first-page":"577","DOI":"10.1016\/0196-8904(95)00071-K","article-title":"Development of Cu\/ZnO-based high performance catalysts for methanol synthesis by CO2 hydrogenation","volume":"36","author":"Saito","year":"1995","journal-title":"Energy Convers. Manag."},{"key":"10.1016\/j.jece.2020.104834_bib15","doi-asserted-by":"crossref","first-page":"311","DOI":"10.1016\/0926-860X(95)00305-3","article-title":"Development of copper\/zinc oxide-based multicomponent catalysts for methanol synthesis from carbon dioxide and hydrogen","volume":"138","author":"Saito","year":"1996","journal-title":"Appl. Catal. Gen."},{"key":"10.1016\/j.jece.2020.104834_bib16","doi-asserted-by":"crossref","first-page":"133","DOI":"10.1016\/S1381-1169(97)00117-9","article-title":"Copper-catalyzed synthesis of methylamines from CO2, H2 and NH3. Influence of support","volume":"127","author":"Gredig","year":"1997","journal-title":"J. Mol. Catal. Chem."},{"key":"10.1016\/j.jece.2020.104834_bib17","doi-asserted-by":"crossref","first-page":"1943","DOI":"10.1007\/s10562-016-1849-8","article-title":"Structure\u2013activity relationships of hierarchical meso\u2013macroporous alumina supported copper catalysts for CO2 hydrogenation: effects of calcination temperature of alumina support","volume":"146","author":"Kanjanasoontorn","year":"2016","journal-title":"Catal. Lett."},{"key":"10.1016\/j.jece.2020.104834_bib18","doi-asserted-by":"crossref","first-page":"13313","DOI":"10.1039\/C5NR02369F","article-title":"Phase dependent thermal and spectroscopic responses of Al2O3 nanostructures with different morphogenesis","volume":"7","author":"Gangwar","year":"2015","journal-title":"Nanoscale"},{"key":"10.1016\/j.jece.2020.104834_bib19","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1016\/S0926-3373(00)00205-8","article-title":"Highly effective conversion of CO2 to methanol over supported and promoted copper-based catalysts: influence of support and promoter","volume":"29","author":"Toyir","year":"2001","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.jece.2020.104834_bib20","doi-asserted-by":"crossref","first-page":"3360","DOI":"10.1016\/j.enconman.2006.01.010","article-title":"Methanol synthesis from CO2 hydrogenation over Cu based catalyst supported on zirconia modified \u03b3-Al2O3","volume":"47","author":"Zhang","year":"2006","journal-title":"Energy Convers. Manag."},{"key":"10.1016\/j.jece.2020.104834_bib21","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1016\/j.fuel.2015.09.082","article-title":"Hydrogenation of CO2 to CH3OH over CuO\/ZnO\/Al2O3 catalysts prepared via a solvent-free routine","volume":"164","author":"Lei","year":"2016","journal-title":"Fuel"},{"key":"10.1016\/j.jece.2020.104834_bib22","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/0920-5861(92)80122-4","article-title":"Methanol synthesis","volume":"15","author":"Waugh","year":"1992","journal-title":"Catal. Today"},{"key":"10.1016\/j.jece.2020.104834_bib23","doi-asserted-by":"crossref","first-page":"886","DOI":"10.1016\/j.enconman.2015.07.033","article-title":"Effect of hierarchical meso\u2013macroporous alumina-supported copper catalyst for methanol synthesis from CO2 hydrogenation","volume":"103","author":"Witoon","year":"2015","journal-title":"Energy Convers. Manag."},{"key":"10.1016\/j.jece.2020.104834_bib24","doi-asserted-by":"crossref","first-page":"442","DOI":"10.1016\/j.apcata.2013.09.026","article-title":"Influence of modifier (Mn, La, Ce, Zr and Y) on the performance of Cu\/Zn\/Al catalysts via hydrotalcite-like precursors for CO2 hydrogenation to methanol","volume":"468","author":"Gao","year":"2013","journal-title":"Appl. Catal. Gen."},{"key":"10.1016\/j.jece.2020.104834_bib25","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1007\/s11814-017-0230-y","article-title":"Cu\/ZnO\/AlOOH catalyst for methanol synthesis through CO2 hydrogenation","volume":"35","author":"Choi","year":"2018","journal-title":"Korean J. Chem. Eng."},{"key":"10.1016\/j.jece.2020.104834_bib26","doi-asserted-by":"crossref","first-page":"150","DOI":"10.1016\/j.jcou.2016.07.001","article-title":"A graphene-supported copper-based catalyst for the hydrogenation of carbon dioxide to form methanol","volume":"16","author":"Fan","year":"2016","journal-title":"J. CO2 Util."},{"key":"10.1016\/j.jece.2020.104834_bib27","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1016\/j.apcata.2011.12.013","article-title":"Effect of promoter SiO2, TiO2 or SiO2-TiO2 on the performance of CuO-ZnO-Al2O3 catalyst for methanol synthesis from CO2 hydrogenation, Appl. Catal","volume":"415\u2013416","author":"Zhang","year":"2012","journal-title":"Appl. Catal. Gen."},{"key":"10.1016\/j.jece.2020.104834_bib28","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1016\/j.fuproc.2013.04.024","article-title":"CO2 hydrogenation to methanol over Cu\/ZnO nanocatalysts prepared via a chitosan-assisted co-precipitation method","volume":"116","author":"Witoon","year":"2013","journal-title":"Fuel Process Technol."},{"key":"10.1016\/j.jece.2020.104834_bib29","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1007\/s11144-013-0587-9","article-title":"Methanol synthesis from CO2 hydrogenation over copper based catalysts","volume":"110","author":"Ahouari","year":"2013","journal-title":"React. Kinet. Mech. Catal."},{"key":"10.1016\/j.jece.2020.104834_bib30","doi-asserted-by":"crossref","first-page":"1667","DOI":"10.1021\/cs300008g","article-title":"Active sites and structure\u2013activity relationships of copper-based catalysts for carbon dioxide hydrogenation to methanol","volume":"2","author":"Natesakhawat","year":"2012","journal-title":"ACS Catal."},{"key":"10.1016\/j.jece.2020.104834_bib31","doi-asserted-by":"crossref","first-page":"74","DOI":"10.1016\/j.jcat.2019.02.021","article-title":"Synergy between active sites of Cu-In-Zr-O catalyst in CO2 hydrogenation to methanol","volume":"372","author":"Yao","year":"2019","journal-title":"J. Catal."},{"key":"10.1016\/j.jece.2020.104834_bib32","doi-asserted-by":"crossref","first-page":"9804","DOI":"10.1021\/acs.chemrev.6b00816","article-title":"Challenges in the greener production of formates\/formic acid, methanol, and DME by heterogeneously catalyzed CO2 hydrogenation processes","volume":"117","author":"\u00c1lvarez","year":"2017","journal-title":"Chem. Rev."},{"key":"10.1016\/j.jece.2020.104834_bib33","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1023\/A:1018916806816","article-title":"Effects of zirconia promotion on the activity of Cu\/SiO2 for methanol synthesis from CO\/H2 and CO2\/H2","volume":"44","author":"Fisher","year":"1997","journal-title":"Catal. Lett."}],"container-title":["Journal of Environmental Chemical Engineering"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2213343720311830?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2213343720311830?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T07:32:31Z","timestamp":1761982351000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S2213343720311830"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,2]]},"references-count":33,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2021,2]]}},"alternative-id":["S2213343720311830"],"URL":"https:\/\/doi.org\/10.1016\/j.jece.2020.104834","relation":{},"ISSN":["2213-3437"],"issn-type":[{"value":"2213-3437","type":"print"}],"subject":[],"published":{"date-parts":[[2021,2]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"The effect of CO2 and H2 adsorption strength and capacity on the performance of Ga and Zr modified Cu-Zn catalysts for CO2 hydrogenation to methanol","name":"articletitle","label":"Article Title"},{"value":"Journal of Environmental Chemical Engineering","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jece.2020.104834","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2020 Elsevier Ltd. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"104834"}}