{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T03:52:21Z","timestamp":1789617141552,"version":"build-2803163510"},"reference-count":43,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100004763","name":"Natural Science Foundation of Inner Mongolia Autonomous Region","doi-asserted-by":"publisher","award":["2026MS0797"],"award-info":[{"award-number":["2026MS0797"]}],"id":[{"id":"10.13039\/501100004763","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004763","name":"Natural Science Foundation of Inner Mongolia Autonomous Region","doi-asserted-by":"publisher","award":["2022ZY0081"],"award-info":[{"award-number":["2022ZY0081"]}],"id":[{"id":"10.13039\/501100004763","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22065029"],"award-info":[{"award-number":["22065029"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Environmental Management"],"published-print":{"date-parts":[[2026,7]]},"DOI":"10.1016\/j.jenvman.2026.130187","type":"journal-article","created":{"date-parts":[[2026,6,22]],"date-time":"2026-06-22T16:57:59Z","timestamp":1782147479000},"page":"130187","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":1,"special_numbering":"C","title":["MIL-88A(Fe)-derived Co9S8\/Fe2O3 nanotubes: Construction of Schottky junction for enhanced pesticide removal"],"prefix":"10.1016","volume":"412","author":[{"given":"Luyao","family":"Wang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-8409-1783","authenticated-orcid":false,"given":"Quanquan","family":"Shi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Xiong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gao","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1408-464X","authenticated-orcid":false,"given":"Alfons","family":"Baiker","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.jenvman.2026.130187_bib2","doi-asserted-by":"crossref","first-page":"3019","DOI":"10.1038\/s41467-025-58392-3","article-title":"Dynamic in-situ reconstruction of active site circulators for photo-fenton-like reactions","volume":"16","author":"Bai","year":"2025","journal-title":"Nat. Commun."},{"key":"10.1016\/j.jenvman.2026.130187_bib1","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2023.132473","article-title":"Co-Mn-Fe spinel-carbon composite catalysts enhanced persulfate activation for degradation of neonicotinoid insecticides: (non) radical path identification, degradation pathway, and toxicity analysis","volume":"460","author":"Bai","year":"2023","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.jenvman.2026.130187_bib3","doi-asserted-by":"crossref","DOI":"10.1016\/j.envpol.2024.123303","article-title":"Removal of neonicotinoid insecticides in a large-scale constructed wetland system","volume":"344","author":"Cao","year":"2024","journal-title":"Environ. Pollut."},{"key":"10.1016\/j.jenvman.2026.130187_bib4","doi-asserted-by":"crossref","DOI":"10.1016\/j.jenvman.2024.120326","article-title":"Strategies for mitigation of pesticides from the environment through alternative approaches: a review of recent developments and future prospects","volume":"354","author":"Chaudhary","year":"2024","journal-title":"J. Environ. Manag."},{"key":"10.1016\/j.jenvman.2026.130187_bib5","doi-asserted-by":"crossref","first-page":"770","DOI":"10.1021\/jp973149e","article-title":"Ultrafast Studies of photoexcited electron dynamics in \u03b3- and \u03b1-Fe2O3 semiconductor nanoparticles","volume":"102","author":"Cherepy","year":"1998","journal-title":"J. Phys. Chem. B"},{"key":"10.1016\/j.jenvman.2026.130187_bib6","doi-asserted-by":"crossref","first-page":"2553","DOI":"10.1007\/s11164-025-05555-y","article-title":"Construction of Co9S8\/Cd0.5Zn0.5S heterojunction photocatalysts with highly efficient photocatalytic activity","volume":"51","author":"Du","year":"2025","journal-title":"Res. Chem. Intermed."},{"key":"10.1016\/j.jenvman.2026.130187_bib7","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2025.138669","article-title":"Visible light for enhancing the reusability of MOF-derived Fe2O3@MoS2 heterojunction in the rapid degradation of Cu-EDTA by activated peroxymonosulfate: performance and mechanism","volume":"494","author":"Guo","year":"2025","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.jenvman.2026.130187_bib8","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202504426","article-title":"Electron-Delocalized Cu2+ activates spin channels in spinel oxides to selectively produce 1O2 for Wastewater Treattent","volume":"64","author":"Hao","year":"2025","journal-title":"Angew. Chem. Int. Ed."},{"key":"10.1016\/j.jenvman.2026.130187_bib9","doi-asserted-by":"crossref","DOI":"10.1016\/j.jwpe.2025.107105","article-title":"Mechanism insights and interfacial engineering of S-scheme \u03b1-Fe2O3\/BiVO4 heterojunction for effective persulfates activation","volume":"70","author":"Hou","year":"2025","journal-title":"J. Water Process Eng."},{"key":"10.1016\/j.jenvman.2026.130187_bib10","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2023.148501","article-title":"Construction of 1D\/3D Co9S8\/Mn0.3Cd0.7S Schottky heterojunction for dramatically boosted photocatalytic H2 evolution performance","volume":"481","author":"Huang","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jenvman.2026.130187_bib11","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2023.124842","article-title":"Multi-phase CdS loaded on biochar for photocatalytic activation of peroxymonosulfate for thiamethoxam degradation: \u03c0-conjugation improves PMS adsorption","volume":"326","author":"Jiang","year":"2023","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.jenvman.2026.130187_bib12","doi-asserted-by":"crossref","first-page":"794","DOI":"10.1016\/j.jcis.2021.05.084","article-title":"Interface engineering of Co9S8\/CdIn2S4 ohmic junction for efficient photocatalytic H2 evolution under visible light","volume":"600","author":"Li","year":"2021","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.jenvman.2026.130187_bib14","doi-asserted-by":"crossref","first-page":"7247","DOI":"10.1007\/s10853-025-10860-3","article-title":"In-situ construction of dual Z-scheme TiO2\/CuBi2O4\/Bi2O2CO3 heterojunction for exceptional visible-light photocatalytic tetracycline removal","volume":"60","author":"Li","year":"2025","journal-title":"J. Mater. Sci."},{"key":"10.1016\/j.jenvman.2026.130187_bib13","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2024.123950","article-title":"Understanding the unique Ohmic-junction for enhancing the photocatalytic activity of CoS2\/MgIn2S4 towards hydrogen production","volume":"351","author":"Li","year":"2024","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.jenvman.2026.130187_bib15","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2025.164671","article-title":"Tailoring a donor-acceptor structure in oxygen- and cyano group co-modified carbon nitride for enhanced photocatalytic imidacloprid degradation","volume":"518","author":"Li","year":"2025","journal-title":"Chem. Eng. J."},{"issue":"5","key":"10.1016\/j.jenvman.2026.130187_bib16","first-page":"883","article-title":"A review on environmental behavior of thiamethoxam in farmland soils","volume":"52","author":"Liu","year":"2020","journal-title":"Soils"},{"key":"10.1016\/j.jenvman.2026.130187_bib17","article-title":"H. High-efficiency and stable Z-scheme heterojunction of Co9S8 anchored by g-C3N4 for peroxymonosulfate activation","volume":"12","author":"Lu","year":"2024","journal-title":"J. Environ. Chem. Eng. J."},{"key":"10.1016\/j.jenvman.2026.130187_bib18","doi-asserted-by":"crossref","first-page":"388","DOI":"10.1016\/j.scitotenv.2013.04.041","article-title":"Photocatalytic degradation of a widely used insecticide Thiamethoxam in aqueous suspension of TiO2: adsorption, kinetics, product analysis, and toxicity assessment","volume":"458\u2013460","author":"Mir","year":"2013","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.jenvman.2026.130187_bib20","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcata.2019.117377","article-title":"Revealing the size effect of metallic CoS2 on CdS nanorods for photocatalytic hydrogen evolution based on Schottky junction","volume":"592","author":"Qiu","year":"2020","journal-title":"Appl. Catal.A-General"},{"key":"10.1016\/j.jenvman.2026.130187_bib22","doi-asserted-by":"crossref","first-page":"527","DOI":"10.1016\/j.jcis.2024.06.064","article-title":"Integrating the 2D\/2D heterostructure of the MXene monolayer and BiOBr nano-sheets for superior photo-catalysis","volume":"673","author":"Shi","year":"2024","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.jenvman.2026.130187_bib21","doi-asserted-by":"crossref","first-page":"20270","DOI":"10.1039\/D4TA03849E","article-title":"Stannum vacancies at precise interface of 2D\/2D g-C3N4\/SnS S-scheme heterojunction boost up photocatalysis","volume":"12","author":"Shi","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"10.1016\/j.jenvman.2026.130187_bib23","doi-asserted-by":"crossref","DOI":"10.1016\/j.jenvman.2025.124929","article-title":"Visible light photocatalytic degradation of pesticides and antibiotics by H3PO4-activated biochar combined with g-C3N4: effects, mechanism, degradation pathway, and toxicity assessment","volume":"380","author":"Shi","year":"2025","journal-title":"J. Environ. Manag."},{"key":"10.1016\/j.jenvman.2026.130187_bib24","doi-asserted-by":"crossref","first-page":"23621","DOI":"10.1021\/jp508273f","article-title":"Ultrafast carrier dynamics in hematite films: the role of photoexcited electrons in the transient optical response","volume":"118","author":"Sorenson","year":"2014","journal-title":"J. Phys. Chem. C"},{"key":"10.1016\/j.jenvman.2026.130187_bib25","doi-asserted-by":"crossref","first-page":"24806","DOI":"10.1021\/acsami.4c04063","article-title":"Efficient Homojunction\/Heterojunction photocatalyst via integrating CsPbBr3 quantum dot homojunction with TiO2 for degradation of organic dyes","volume":"16","author":"Sun","year":"2024","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"10.1016\/j.jenvman.2026.130187_bib26","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2024.158124","article-title":"Fabricated S-scheme CoS\/CeO2 heterojunction photocatalyst efficiently activates peroxymonosulfate for polyethylene terephthalate plastic degradation: insight into radicals and electron transfer","volume":"502","author":"Wan","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jenvman.2026.130187_bib27","article-title":"Plasmonic-induced Biochar@WO3\/Cu composites for boosted photocatalytic antibiotic removal","volume":"44","author":"Wang","year":"2025","journal-title":"Sustain. Mater. Technol."},{"key":"10.1016\/j.jenvman.2026.130187_bib28","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2025.133047","article-title":"A bifunctional material derived from a Cu\/Mn-MOF for the detection and degradation of thiamethoxam residues at effective concentrations: condition optimization, mechanism exploration, and toxicity analysis","volume":"368","author":"Wang","year":"2025","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.jenvman.2026.130187_bib29","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2025.172441","article-title":"Mechanism insights into the degradation of thiamethoxam based on partial Fe-substituted Co3S4 for effective activation of PMS: experimental and theoretical calculations","volume":"528","author":"Wang","year":"2026","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jenvman.2026.130187_bib30","first-page":"4852","article-title":"Potential toxic mechanisms of neonicotinoid insecticides in rice: inhibiting auxin-mediated signal transduction","author":"Wu","year":"2025","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jenvman.2026.130187_bib31","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2022.130247","article-title":"Enhanced biodegradation of thiamethoxam with a novel polyvinyl alcohol (PVA)\/sodium alginate (SA)\/biochar immobilized Chryseobacterium sp H5","volume":"443","author":"Xiang","year":"2023","journal-title":"J. Hazard Mater."},{"key":"10.1016\/j.jenvman.2026.130187_bib32","doi-asserted-by":"crossref","first-page":"1365","DOI":"10.1016\/j.jcis.2023.10.141","article-title":"Visible-light S-scheme heterojunction of copper bismuthate quantum dots decorated Titania-spindles for exceptional tetracycline degradation","volume":"654","author":"Xiong","year":"2024","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.jenvman.2026.130187_bib33","article-title":"Biochar-supported Co(OH)2 nanosheets activated persulfate: enhanced removal of ciprofloxacin and membrane purification","volume":"42","author":"Xiong","year":"2024","journal-title":"Sustain. Mater. Technol."},{"key":"10.1016\/j.jenvman.2026.130187_bib34","doi-asserted-by":"crossref","first-page":"164","DOI":"10.1016\/S1872-2067(25)64756-5","article-title":"Facet-induced reduction directed AgBr\/Ag0\/TiO2{100} Z-scheme heterojunction for tetracycline removal","volume":"75","author":"Xiong","year":"2025","journal-title":"Chin. J. Catal."},{"key":"10.1016\/j.jenvman.2026.130187_bib35","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2024.152153","article-title":"Mn-S chemical bond mediated Z-scheme photocatalyst boosting efficient H2 evolution with apparent quantum yield exceeding 32% under visible light","volume":"491","author":"Yan","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jenvman.2026.130187_bib36","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2023.145051","article-title":"Efficient degradation of thiamethoxam pesticide in water by iron and manganese oxide composite biochar activated persulfate","volume":"473","author":"Yang","year":"2023","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jenvman.2026.130187_bib37","article-title":"In-suit generated Cu-ligand inducing full-spectrum selective photocatalytic degradation of organic pollutants containing phenol groups over Cu doping BiO2-x nanosheet: the synergistic effects of Cu-ligand and oxygen vacancies, and mechanism study","volume":"499","author":"Yang","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jenvman.2026.130187_bib38","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2024.154713","article-title":"The cooperative p-n heterojunction and Schottky junction in Au-decorated hierarchical CuS@SnS2 hollow cubes for boosted charge transport and CO2 photoreduction","volume":"497","author":"Yin","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jenvman.2026.130187_bib39","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2025.125098","article-title":"Zinc-mediated electronic structure of CoP toward photocatalytic H2 evolution","volume":"367","author":"Yu","year":"2025","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.jenvman.2026.130187_bib43","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2025.131989","article-title":"Degradation of norfloxacin by highly magnetic CoFe2O4-loaded 0D-CQDS-activated PMS: mechanistic analysis and environmental impacts","volume":"362","author":"Zhang","year":"2025","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.jenvman.2026.130187_bib41","article-title":"Construction of g-C3N4\/Ti3C2\/\u03b1-Fe2O3 ternary composite: synergistic enhancement of photocatalytic performance by Schottky junction\/Z-scheme heterojunction-structure and wide light absorption range","volume":"1010","author":"Zhang","year":"2025","journal-title":"J. Alloys Compd."},{"key":"10.1016\/j.jenvman.2026.130187_bib40","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2021.131927","article-title":"Photocatalysis activation of peroxodisulfate over the supported Fe3O4 catalyst derived from MIL-88A(Fe) for efficient tetracycline hydrochloride degradation","volume":"426","author":"Zhang","year":"2021","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jenvman.2026.130187_bib42","doi-asserted-by":"crossref","DOI":"10.1016\/j.jenvman.2025.127300","article-title":"Z-scheme MIL-88A@LaFeO3 heterojunction-enabled synergistic photo-Fenton system for acetamiprid degradation: mechanism and toxicity assessment","volume":"393","author":"Zhang","year":"2025","journal-title":"J. Environ. Manag."},{"key":"10.1016\/j.jenvman.2026.130187_bib44","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2024.161141","article-title":"Investigation into the adsorption mechanism of Fe (III) by biomass carbon derived from tea residue and its high-value conversion into bismuth ferrite for enhanced activation of peroxymonosulfate towards antibiotics degradation","volume":"678","author":"Zhong","year":"2024","journal-title":"Appl. Surf. Sci."}],"container-title":["Journal of Environmental Management"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0301479726016476?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0301479726016476?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:52:19Z","timestamp":1785891139000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0301479726016476"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7]]},"references-count":43,"alternative-id":["S0301479726016476"],"URL":"https:\/\/doi.org\/10.1016\/j.jenvman.2026.130187","relation":{},"ISSN":["0301-4797"],"issn-type":[{"value":"0301-4797","type":"print"}],"subject":[],"published":{"date-parts":[[2026,7]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"MIL-88A(Fe)-derived Co9S8\/Fe2O3 nanotubes: Construction of Schottky junction for enhanced pesticide removal","name":"articletitle","label":"Article Title"},{"value":"Journal of Environmental Management","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jenvman.2026.130187","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2026 Elsevier Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies.","name":"copyright","label":"Copyright"}],"article-number":"130187"}}