{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,29]],"date-time":"2026-10-29T18:54:48Z","timestamp":1793300088323,"version":"4.5.0"},"reference-count":36,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2025,9,1]],"date-time":"2025-09-01T00:00:00Z","timestamp":1756684800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2025,9,1]],"date-time":"2025-09-01T00:00:00Z","timestamp":1756684800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52476185"],"award-info":[{"award-number":["52476185"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2018YFB1501405"],"award-info":[{"award-number":["2018YFB1501405"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Environmental Sciences"],"published-print":{"date-parts":[[2025,9]]},"DOI":"10.1016\/j.jes.2024.12.015","type":"journal-article","created":{"date-parts":[[2024,12,19]],"date-time":"2024-12-19T19:11:51Z","timestamp":1734635511000},"page":"25-36","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":4,"special_numbering":"C","title":["Construction of an SnS-based heterostructure catalyst for electrochemical CO2 reduction to formate over a wide potential window"],"prefix":"10.1016","volume":"155","author":[{"given":"Renzhi","family":"Qi","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoping","family":"Zhong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Huang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fuqiang","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"You","family":"Jia","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuxuan","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zekun","family":"Yun","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qihang","family":"Ye","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"issue":"50","key":"10.1016\/j.jes.2024.12.015_bib0001","doi-asserted-by":"crossref","first-page":"26233","DOI":"10.1002\/anie.202111905","article-title":"Dynamic restructuring of Cu-doped SnS2 nanoflowers for highly selective electrochemical CO2 reduction to formate","volume":"60","author":"Chen","year":"2021","journal-title":"Angew. Chem. Int. Ed."},{"issue":"6","key":"10.1016\/j.jes.2024.12.015_bib0002","doi-asserted-by":"crossref","first-page":"5196","DOI":"10.1039\/D2CP04993G","article-title":"Cu-doped SnS2 nanosheets with superior visible-light photocatalytic CO2 reduction performance","volume":"25","author":"Di","year":"2023","journal-title":"Phys. Chem. Chem. Phys."},{"key":"10.1016\/j.jes.2024.12.015_bib0003","doi-asserted-by":"crossref","first-page":"497","DOI":"10.1016\/j.jechem.2023.03.016","article-title":"Dynamic reconstructuring of CuS\/SnO2-S for promoting CO2 electroreduction to formate","volume":"82","author":"Dou","year":"2023","journal-title":"J. Energy Chem."},{"issue":"6","key":"10.1016\/j.jes.2024.12.015_bib0004","doi-asserted-by":"crossref","first-page":"661","DOI":"10.1007\/s10800-017-1078-x","article-title":"Progress in inorganic cathode catalysts for electrochemical conversion of carbon dioxide into formate or formic acid","volume":"47","author":"Du","year":"2017","journal-title":"J. Appl. Electrochem."},{"issue":"6","key":"10.1016\/j.jes.2024.12.015_bib0005","doi-asserted-by":"crossref","DOI":"10.1016\/j.jece.2021.106394","article-title":"Progress in the electrochemical reduction of CO2 to formic acid: a review on current trends and future prospects","volume":"9","author":"Duarah","year":"2021","journal-title":"J. Environ. Chem. Eng."},{"issue":"3","key":"10.1016\/j.jes.2024.12.015_bib0006","doi-asserted-by":"crossref","first-page":"198","DOI":"10.1038\/s41929-019-0235-5","article-title":"Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products","volume":"2","author":"Gao","year":"2019","journal-title":"Nat. Catal."},{"issue":"2","key":"10.1016\/j.jes.2024.12.015_bib0007","first-page":"513","article-title":"Hydrothermal synthesis of CuS catalysts for electrochemical CO2 reduction: Unraveling the effect of the sulfur precursor","volume":"357","author":"Gao","year":"2023","journal-title":"ACS Appl. Energy Mater."},{"key":"10.1016\/j.jes.2024.12.015_bib0008","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.coelec.2020.01.012","article-title":"Local electrochemical impedance spectroscopy: a window into heterogeneous interfaces","volume":"20","author":"Gharbi","year":"2020","journal-title":"Curr. Opin. Electrochem."},{"issue":"3","key":"10.1016\/j.jes.2024.12.015_bib0009","doi-asserted-by":"crossref","first-page":"875","DOI":"10.1021\/cg0496787","article-title":"Synthesis of copper sulfides of varying morphologies and stoichiometries controlled by chelating and nonchelating solvents in a solvothermal process","volume":"5","author":"Gorai","year":"2005","journal-title":"Cryst. Growth Des."},{"issue":"11","key":"10.1016\/j.jes.2024.12.015_bib0010","doi-asserted-by":"crossref","first-page":"1695","DOI":"10.1246\/cl.1985.1695","article-title":"Production of CO and CH4 in electrochemical reduction of CO2 at metal-electrodes in aqueous hydrogencarbonate solution","author":"Hori","year":"1985","journal-title":"Chem. Lett."},{"issue":"51","key":"10.1016\/j.jes.2024.12.015_bib0011","doi-asserted-by":"crossref","first-page":"59524","DOI":"10.1021\/acsami.3c14682","article-title":"Surface-enhanced Raman spectroscopy for boosting electrochemical CO2 reduction on amorphous-surfaced Tin oxide supported by MXene","volume":"15","author":"Jing","year":"2023","journal-title":"ACS Appl. Mater. Interface"},{"issue":"12","key":"10.1016\/j.jes.2024.12.015_bib0012","doi-asserted-by":"crossref","first-page":"11318","DOI":"10.1021\/acsnano.2c12627","article-title":"1T\/1H-SnS2 sheets for electrochemical CO2 reduction to formate","volume":"17","author":"Kawabe","year":"2023","journal-title":"ACS Nano"},{"key":"10.1016\/j.jes.2024.12.015_bib0013","doi-asserted-by":"crossref","first-page":"270","DOI":"10.1016\/j.nanoen.2016.11.004","article-title":"Towards a better Sn: efficient electrocatalytic reduction of CO2 to formate by Sn\/SnS2 derived from SnS2 nanosheets","volume":"31","author":"Li","year":"2017","journal-title":"Nano Energy"},{"issue":"16","key":"10.1016\/j.jes.2024.12.015_bib0014","doi-asserted-by":"crossref","first-page":"9922","DOI":"10.1021\/acscatal.2c02627","article-title":"In situ dynamic construction of a copper tin sulfide catalyst for high-performance electrochemical CO2 conversion to formate","volume":"12","author":"Li","year":"2022","journal-title":"ACS Catal."},{"issue":"18","key":"10.1016\/j.jes.2024.12.015_bib0015","doi-asserted-by":"crossref","first-page":"9032","DOI":"10.1039\/D0TA00569J","article-title":"Electrochemically deposited Sn catalysts with dense tips on a gas diffusion electrode for electrochemical CO2 reduction","volume":"8","author":"Lim","year":"2020","journal-title":"J. Mater. Chem. A"},{"issue":"21","key":"10.1016\/j.jes.2024.12.015_bib0016","doi-asserted-by":"crossref","first-page":"13533","DOI":"10.1021\/acscatal.2c02617","article-title":"Inhibiting sulfur dissolution and enhancing activity of SnS for CO2 electroreduction via electronic state modulation","volume":"12","author":"Liu","year":"2022","journal-title":"ACS Catal."},{"issue":"8","key":"10.1016\/j.jes.2024.12.015_bib0017","doi-asserted-by":"crossref","first-page":"564","DOI":"10.1038\/s41570-021-00289-y","article-title":"Highlights and challenges in the selective reduction of carbon dioxide to methanol","volume":"5","author":"Navarro-Ja\u00e9n","year":"2021","journal-title":"Nat. Rev. Chem."},{"issue":"18","key":"10.1016\/j.jes.2024.12.015_bib0018","doi-asserted-by":"crossref","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","article-title":"Generalized gradient approximation made simple","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"issue":"2","key":"10.1016\/j.jes.2024.12.015_bib0019","doi-asserted-by":"crossref","first-page":"837","DOI":"10.1021\/acscatal.7b03161","article-title":"Sulfur-modified copper catalysts for the electrochemical reduction of carbon dioxide to formate","volume":"8","author":"Shinagawa","year":"2018","journal-title":"ACS Catal."},{"issue":"10","key":"10.1016\/j.jes.2024.12.015_bib0020","doi-asserted-by":"crossref","first-page":"2247","DOI":"10.1002\/cssc.202100543","article-title":"Bi-Sn oxides for highly selective CO2 electroreduction to formate in a wide potential window","volume":"14","author":"Tian","year":"2021","journal-title":"ChemSusChem"},{"issue":"8","key":"10.1016\/j.jes.2024.12.015_bib0021","doi-asserted-by":"crossref","first-page":"1809","DOI":"10.1016\/j.chempr.2018.05.001","article-title":"Surface and interface engineering in copper-based bimetallic materials for selective CO2 electroreduction","volume":"4","author":"Vasileff","year":"2018","journal-title":"Chem"},{"key":"10.1016\/j.jes.2024.12.015_bib0022","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2022.139056","article-title":"Co-regulation of intermediate binding and water activation in sulfur-doped bismuth nanosheets for electrocatalytic CO2 reduction to formate","volume":"451","author":"Wang","year":"2023","journal-title":"Chem. Eng. J."},{"issue":"17","key":"10.1016\/j.jes.2024.12.015_bib0023","doi-asserted-by":"crossref","first-page":"5693","DOI":"10.1021\/acssuschemeng.2c01409","article-title":"Synergistic geometric and electronic effects in Bi-Cu bimetallic catalysts for CO2 electroreduction to formate over a wide potential window","volume":"10","author":"Wang","year":"2022","journal-title":"ACS Sustain. Chem. Eng."},{"issue":"42","key":"10.1016\/j.jes.2024.12.015_bib0024","doi-asserted-by":"crossref","first-page":"22940","DOI":"10.1002\/anie.202110000","article-title":"In situ phase separation into coupled interfaces for promoting CO2 electroreduction to formate over a wide potential window","volume":"60","author":"Wang","year":"2021","journal-title":"Angew. Chem. Int. Ed."},{"issue":"6","key":"10.1016\/j.jes.2024.12.015_bib0025","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/cctc.202101873","article-title":"Enhanced electroconversion CO2-to-formate by oxygen-vacancy-rich ultrasmall Bi-based catalyst over a wide potential window","volume":"14","author":"Wang","year":"2022","journal-title":"ChemCatChem"},{"issue":"46","key":"10.1016\/j.jes.2024.12.015_bib0026","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202005798","article-title":"Designing copper-based catalysts for efficient carbon dioxide electroreduction","volume":"33","author":"Wang","year":"2021","journal-title":"Adv. Mater."},{"issue":"31","key":"10.1016\/j.jes.2024.12.015_bib0027","article-title":"Orbital interactions in Bi-Sn bimetallic electrocatalysts for highly selective electrochemical CO2 reduction toward formate production","volume":"8","author":"Wen","year":"2018","journal-title":"Adv. Energy Mater."},{"key":"10.1016\/j.jes.2024.12.015_bib0028","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1016\/j.jcis.2022.05.054","article-title":"Indium doped bismuth subcarbonate nanosheets for efficient electrochemical reduction of carbon dioxide to formate in a wide potential window","volume":"624","author":"Wu","year":"2022","journal-title":"J. Colloid Interface Sci."},{"issue":"2","key":"10.1016\/j.jes.2024.12.015_bib0029","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202105690","article-title":"Amine-functionalized carbon nanodot electrocatalysts converting carbon dioxide to methane","volume":"34","author":"Yadav","year":"2022","journal-title":"Adv. Mater."},{"issue":"59","key":"10.1016\/j.jes.2024.12.015_bib0030","doi-asserted-by":"crossref","first-page":"9017","DOI":"10.1039\/D3CC02531D","article-title":"Sn-based electrocatalysts for electrochemical CO2 reduction","volume":"59","author":"Yao","year":"2023","journal-title":"Chem. Commun."},{"key":"10.1016\/j.jes.2024.12.015_bib0031","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2022.138254","article-title":"Ru decorated Co nanoparticles supported by N-doped carbon sheet implements Pt-like hydrogen evolution performance in wide pH range","volume":"450","author":"Zhao","year":"2022","journal-title":"Chem. Eng. J."},{"issue":"1","key":"10.1016\/j.jes.2024.12.015_bib0032","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1007\/s40820-019-0293-x","article-title":"Advances in Sn-based catalysts for electrochemical CO2 reduction","volume":"11","author":"Zhao","year":"2019","journal-title":"Nano Micro Lett."},{"issue":"2","key":"10.1016\/j.jes.2024.12.015_bib0033","doi-asserted-by":"crossref","first-page":"2257","DOI":"10.1021\/acsanm.0c03361","article-title":"SnS nanoparticles grown on Sn-atom-modified N,S-codoped mesoporous carbon nanosheets as electrocatalysts for CO2 reduction to formate","volume":"4","author":"Zhao","year":"2021","journal-title":"ACS Appl. Nano Mater."},{"issue":"16","key":"10.1016\/j.jes.2024.12.015_bib0034","doi-asserted-by":"crossref","first-page":"6907","DOI":"10.1021\/acs.nanolett.1c02053","article-title":"Spontaneously Sn-doped Bi\/BiOx core-shell nnowires toward high-performance CO2 elctroreduction to lquid fuel","volume":"21","author":"Zhao","year":"2021","journal-title":"Nano Lett."},{"key":"10.1016\/j.jes.2024.12.015_bib0035","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.jcis.2019.04.077","article-title":"Recent advances in different-dimension electrocatalysts for carbon dioxide reduction","volume":"550","author":"Zhou","year":"2019","journal-title":"J. Colloid Interface Sci."},{"issue":"15","key":"10.1016\/j.jes.2024.12.015_bib0036","doi-asserted-by":"crossref","DOI":"10.1002\/advs.202004521","article-title":"Boosting formate production from CO2 at high current densities over a wide electrochemical potential window on a SnS catalyst","volume":"8","author":"Zou","year":"2021","journal-title":"Adv. Sci."}],"container-title":["Journal of Environmental Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1001074224005795?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1001074224005795?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,11,5]],"date-time":"2025-11-05T13:46:09Z","timestamp":1762350369000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S1001074224005795"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9]]},"references-count":36,"alternative-id":["S1001074224005795"],"URL":"https:\/\/doi.org\/10.1016\/j.jes.2024.12.015","relation":{},"ISSN":["1001-0742"],"issn-type":[{"value":"1001-0742","type":"print"}],"subject":[],"published":{"date-parts":[[2025,9]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Construction of an SnS-based heterostructure catalyst for electrochemical CO2 reduction to formate over a wide potential window","name":"articletitle","label":"Article Title"},{"value":"Journal of Environmental Sciences","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jes.2024.12.015","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.","name":"copyright","label":"Copyright"}]}}