{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T16:18:29Z","timestamp":1788279509604,"version":"build-2803163510"},"reference-count":47,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22176151"],"award-info":[{"award-number":["22176151"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100020758","name":"Science and Technology Innovation Group of Shanxi Province","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100020758","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Environmental Sciences"],"published-print":{"date-parts":[[2026,10]]},"DOI":"10.1016\/j.jes.2025.12.085","type":"journal-article","created":{"date-parts":[[2025,12,31]],"date-time":"2025-12-31T08:06:25Z","timestamp":1767168385000},"page":"61-71","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":0,"special_numbering":"C","title":["Interface-engineered \u03b3\/\u03b1-hematite homojunction with low contact barrier for boosted photocatalytic peroxymonosulfate activation"],"prefix":"10.1016","volume":"168","author":[{"given":"Xiaobin","family":"Hao","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhixiong","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juyuan","family":"Xing","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guoliang","family":"Tian","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Niannian","family":"Yuan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nianhong","family":"Wan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2061-8532","authenticated-orcid":false,"given":"Gaoke","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.jes.2025.12.085_bib0001","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2020.125813","article-title":"Facile synthesis of Mn-doped BiOCl for metronidazole photodegradation: Optimization, degradation pathway, and mechanism","volume":"400","author":"Cao","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0002","doi-asserted-by":"crossref","DOI":"10.1016\/j.watres.2024.123026","article-title":"How to enhance persulfate processes by external-field effects: From fundamentals to applications","volume":"274","author":"Chen","year":"2025","journal-title":"Water Res."},{"key":"10.1016\/j.jes.2025.12.085_bib0003","first-page":"400","article-title":"Unlocking photocatalytic NO removal potential in an S-type UiO-66-NH2\/ZnS(en)0.5 heterostructure, Interdiscip","volume":"3","author":"Dai","year":"2024","journal-title":"Mater."},{"key":"10.1016\/j.jes.2025.12.085_bib0004","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2022.129845","article-title":"A novel g-C3N4\/g-C3N4\u2212x homojunction with efficient interfacial charge transfer for photocatalytic degradation of atrazine and tetracycline","volume":"441","author":"Feng","year":"2023","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.jes.2025.12.085_bib0005","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2022.121703","article-title":"Electrodeposition of nanostructured Bi2MoO6@Bi2MoO6\u2013x homojunction films for the enhanced visible-light-driven photocatalytic degradation of antibiotics","volume":"317","author":"G\u00f3mez","year":"2022","journal-title":"Appl. Cataly. B: Environ."},{"key":"10.1016\/j.jes.2025.12.085_bib0006","doi-asserted-by":"crossref","first-page":"34","DOI":"10.1016\/j.jmst.2020.05.057","article-title":"Enhanced photocatalytic degradation of organic contaminants over CaFe2O4 under visible LED light irradiation mediated by peroxymonosulfate","volume":"62","author":"Guo","year":"2021","journal-title":"J. Mater. Sci. Technol."},{"key":"10.1016\/j.jes.2025.12.085_bib0007","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2021.125838","article-title":"Enhanced degradation of tetracycline in water over Cu-doped hematite nanoplates by peroxymonosulfate activation under visible light irradiation","volume":"416","author":"Guo","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.jes.2025.12.085_bib0008","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2021.119883","article-title":"Efficient persulfate activation by hematite nanocrystals for degradation of organic pollutants under visible light irradiation: Facet-dependent catalytic performance and degradation mechanism","volume":"286","author":"Guo","year":"2021","journal-title":"Appl. Cataly. B Environ."},{"key":"10.1016\/j.jes.2025.12.085_bib0009","doi-asserted-by":"crossref","DOI":"10.1016\/j.snb.2023.134550","article-title":"Phase boundary induced drastic sensing performance enhancement of mixed-phase N-Fe2O3 (\u03b1\/\u03b3) gas sensors for acetone","volume":"396","author":"Hu","year":"2023","journal-title":"Sens. Actuators B Chem."},{"key":"10.1016\/j.jes.2025.12.085_bib0010","article-title":"Chemically bonded BiVO4\/Bi19Cl3S27 heterojunction with fast hole extraction dynamics for continuous CO2 photoreduction","volume":"3","author":"Huang","year":"2024","journal-title":"Adv. Powder Mater."},{"key":"10.1016\/j.jes.2025.12.085_bib0011","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2021.130743","article-title":"Nonradical activation of peroxymonosulfate by hematite for oxidation of organic compounds: A novel mechanism involving high-valent iron species","volume":"426","author":"Kang","year":"2021","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0012","doi-asserted-by":"crossref","first-page":"3064","DOI":"10.1021\/acs.est.9b07082","article-title":"Persulfate-based advanced oxidation: Critical assessment of opportunities and roadblocks","volume":"54","author":"Lee","year":"2020","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jes.2025.12.085_bib0013","doi-asserted-by":"crossref","first-page":"6838","DOI":"10.1021\/acs.est.5b00623","article-title":"Heterogeneous degradation of organic pollutants by persulfate activated by CuO-Fe3O4: Mechanism, stability, and effects of pH and bicarbonate ions","volume":"49","author":"Lei","year":"2015","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.jes.2025.12.085_bib0014","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2024.156429","article-title":"Enhanced photocatalytic CO2 reduction to CH4 on oxygen vacancy-rich NiCo2O4 with surface pits: Synthesis, DFT calculations, and mechanistic insights","volume":"499","author":"Li","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0015","doi-asserted-by":"crossref","DOI":"10.1016\/j.jclepro.2022.133420","article-title":"Research progress of photocatalytic activated persulfate removal of environmental organic pollutants by metal and nonmetal based photocatalysts","volume":"372","author":"Li","year":"2022","journal-title":"J. Clean. Prod."},{"key":"10.1016\/j.jes.2025.12.085_bib0016","doi-asserted-by":"crossref","DOI":"10.1016\/j.watres.2022.118896","article-title":"Influences and mechanisms of phosphate ions onto persulfate activation and organic degradation in water treatment: A review","volume":"222","author":"Li","year":"2022","journal-title":"Water Res."},{"key":"10.1016\/j.jes.2025.12.085_bib0017","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2021.118928","article-title":"Sulfite activation by Fe-doped g-C3N4 for metronidazole degradation","volume":"272","author":"Li","year":"2021","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.jes.2025.12.085_bib0018","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2024.157678","article-title":"Construction of Cu-doped \u03b1-Fe2O3\/\u03b3-Fe2O3 hetero-phase junction composite and its photocatalytic performance","volume":"501","author":"Li","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0019","doi-asserted-by":"crossref","DOI":"10.1016\/j.ces.2023.119148","article-title":"In-situ generation of hollowed nanorods array with TiN\/TiO2 heterostructures for electrocatalytic degradation of metronidazole","volume":"281","author":"Liu","year":"2023","journal-title":"Chem. Eng. Sci."},{"key":"10.1016\/j.jes.2025.12.085_bib0020","article-title":"Efficient photocatalytic degradation of microplastics by constructing a novel Z-scheme Fe-doped BiO2\u2212x\/BiOI heterojunction with full-spectrum response: Mechanistic insights and theory calculations","volume":"480","author":"Liu","year":"2024","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.jes.2025.12.085_bib0021","first-page":"530","article-title":"Polar materials for photocatalytic applications: A critical review","volume":"3","author":"Liu","year":"2024","journal-title":"Interdiscip. Mater."},{"key":"10.1016\/j.jes.2025.12.085_bib0022","article-title":"Internal electric field triggered charge redistribution in CuO\/Fe2O3 composite to regulate the peroxymonosulfate activation for enhancing the degradation of organic pollutants","volume":"367","author":"Lv","year":"2025","journal-title":"Environ. Pullut."},{"key":"10.1016\/j.jes.2025.12.085_bib0023","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2025.164605","article-title":"Synergetic photocatalytic activation of persulfate by Ti3C2\/g-C3N4 for sterilization and antibiotic degradation","volume":"518","author":"Mao","year":"2025","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0024","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2021.130296","article-title":"Photocatalytic activation of peroxymonosulfate by carbon quantum dots functionalized carbon nitride for efficient degradation of bisphenol A under visible-light irradiation","volume":"424","author":"Ming","year":"2021","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0025","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2022.121341","article-title":"Tailored poly-heptazine units in carbon nitride for activating peroxymonosulfate to degrade organic contaminants with visible light","volume":"311","author":"Ming","year":"2022","journal-title":"Appl. Cataly. B Environ. Energy"},{"key":"10.1016\/j.jes.2025.12.085_bib0026","first-page":"935","article-title":"Facile synthesis of Pt clusters decorated TiO2 nanoparticles for efficient photocatalytic degradation of antibiotics","volume":"3","author":"Pan","year":"2024","journal-title":"Interdiscip. Mater."},{"key":"10.1016\/j.jes.2025.12.085_bib0027","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2024.154055","article-title":"Palygorskite supported nanometer spherical Fe2O3 composite as an effective photocatalyst for peroxymonosulfate activation: Promotion of the Fe(III)\/Fe(II) cycle by photogenerated electrons under visible light","volume":"496","author":"Tang","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0028","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2024.127443","article-title":"Built-in electric field intensified by SPR effect to drive charge separation over Ag-AgI\/Sb2S3 heterojunction for high-efficiency photocatalytic metronidazole mineralization","volume":"346","author":"Tian","year":"2024","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.jes.2025.12.085_bib0029","doi-asserted-by":"crossref","first-page":"6987","DOI":"10.1007\/s12274-022-4329-z","article-title":"Electrostatic self-assembly of 2D\/2D CoWO4\/g-C3N4 p-n heterojunction for improved photocatalytic hydrogen evolution: Built-in electric field modulated charge separation and mechanism unveiling","volume":"15","author":"Wang","year":"2022","journal-title":"Nano Res."},{"key":"10.1016\/j.jes.2025.12.085_bib0030","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2023.123584","article-title":"Sulfamethoxazole degradation by Ni2+ doped Fe2O3 on a nickel foam in peroxymonosulfate assisting photoelectrochemical oxidation system: Performance, mechanism and degradation pathway","volume":"314","author":"Wang","year":"2023","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.jes.2025.12.085_bib0031","article-title":"Support-modulated coordination environments direct divergent PMS activation pathways in Co single-atom catalysts","volume":"381","author":"Wang","year":"2026","journal-title":"Appl. Catal. B Environ. Energy"},{"key":"10.1016\/j.jes.2025.12.085_bib0032","article-title":"Cobalt-silicon coordination-induced nonradical activation of peroxymonosulfate for enhancing the degradation of organic pollutants in real wastewater","volume":"21","author":"Wang","year":"2025","journal-title":"Small"},{"key":"10.1016\/j.jes.2025.12.085_bib0033","article-title":"Synergistic effect of confinement and photocatalysis-endowed adjustable peroxymonosulfate activation pathway to degrade antibiotics","volume":"497","author":"Wang","year":"2024","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0034","first-page":"1545","article-title":"Enhanced peroxymonosulfate activation by copper-doped bismuth oxides for the efficient photo-degradation of ciprofloxacin: Crucial role of copper sites, theoretical calculation and mechanism insight","volume":"12","author":"Wang","year":"2025","journal-title":"Environ. Sci.: Nano"},{"key":"10.1016\/j.jes.2025.12.085_bib0035","doi-asserted-by":"crossref","first-page":"311","DOI":"10.1016\/j.jcis.2022.04.003","article-title":"In situ synthesized \u03b1-Fe2O3\/BCN heterojunction for promoting photocatalytic CO2 reduction performance","volume":"621","author":"Wang","year":"2022","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.jes.2025.12.085_bib0036","doi-asserted-by":"crossref","DOI":"10.1016\/j.apcatb.2022.121895","article-title":"Efficient photocatalytic CO2 conversion over 2D\/2D Ni-doped CsPbBr3\/Bi3O4Br Z-scheme heterojunction: Critical role of Ni doping, boosted charge separation and mechanism study","volume":"319","author":"Wang","year":"2022","journal-title":"Appl. Catal. B. Environ."},{"key":"10.1016\/j.jes.2025.12.085_bib0037","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2019.123265","article-title":"Iron-mediated activation of persulfate and peroxymonosulfate in both homogeneous and heterogeneous ways: A review","volume":"384","author":"Xiao","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0038","doi-asserted-by":"crossref","first-page":"691","DOI":"10.1021\/acsestengg.4c00637","article-title":"Efficient degradation of metronidazole by in situ high-valent iron-oxo species in nanoclustered iron\u2013carbon particles","volume":"5","author":"Xue","year":"2025","journal-title":"ACS EST Eng."},{"key":"10.1016\/j.jes.2025.12.085_bib0039","doi-asserted-by":"crossref","first-page":"204","DOI":"10.1016\/j.jes.2023.07.010","article-title":"Facet-dependent activation of oxalic acid over hematite nanocrystals under the irradiation of visible light for efficient degradation of pollutants","volume":"142","author":"Yang","year":"2024","journal-title":"J. Environ. Sci."},{"key":"10.1016\/j.jes.2025.12.085_bib0040","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1016\/j.jmst.2024.06.053","volume":"216","author":"Yang","year":"2025","journal-title":"J. Mater. Sci. Technol."},{"key":"10.1016\/j.jes.2025.12.085_bib0041","doi-asserted-by":"crossref","first-page":"327","DOI":"10.1016\/j.jcis.2025.01.242","article-title":"Efficient photocatalytic degradation of polystyrene microplastics in water over core\u2013shell BiO2\u2212x\/CuBi2O4 heterojunction with full spectrum light response","volume":"686","author":"Yang","year":"2025","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.jes.2025.12.085_bib0042","doi-asserted-by":"crossref","DOI":"10.1016\/j.jcis.2025.138713","article-title":"Oxygen\/methyl-modified carbon nitride as an efficient metal-free photocatalyst for phenolic pollutant removal via peroxymonosulfate activation","volume":"701","author":"Yuan","year":"2026","journal-title":"J. Colloid Interface Sci."},{"key":"10.1016\/j.jes.2025.12.085_bib0043","doi-asserted-by":"crossref","DOI":"10.1016\/j.jclepro.2023.138199","article-title":"Conjugated polymers S-scheme homojunction with large internal electric field and matching interface for efficient visible light photocatalytic degradation of ciprofloxacin","volume":"419","author":"Zhang","year":"2023","journal-title":"J. Cleaner Prod."},{"key":"10.1016\/j.jes.2025.12.085_bib0044","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2023.130873","article-title":"Activation of sulfite by micron-scale iron-carbon composite for metronidazole degradation: Theoretical and experimental studies","volume":"448","author":"Zhao","year":"2023","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.jes.2025.12.085_bib0045","article-title":"Low Concentration of Peroxymonosulfate triggers dissolved oxygen conversion over single atomic Fe-N3O1 sites for water decontamination","volume":"19","author":"Zhao","year":"2023","journal-title":"Small"},{"key":"10.1016\/j.jes.2025.12.085_bib0046","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2023.145507","article-title":"Facet engineering of BiVO4 photocatalyst for the synergetic adsorption and activation of persulfate for organic pollutants degradation","volume":"473","author":"Zheng","year":"2023","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jes.2025.12.085_bib0047","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2022.120799","article-title":"Removal of metronidazole from wastewater by electrocoagulation with chloride ions electrolyte: The role of reactive chlorine species and process optimization","volume":"290","author":"Zhou","year":"2022","journal-title":"Sep. Purif. Technol."}],"container-title":["Journal of Environmental Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1001074225008654?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1001074225008654?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T15:32:22Z","timestamp":1788276742000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S1001074225008654"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10]]},"references-count":47,"alternative-id":["S1001074225008654"],"URL":"https:\/\/doi.org\/10.1016\/j.jes.2025.12.085","relation":{},"ISSN":["1001-0742"],"issn-type":[{"value":"1001-0742","type":"print"}],"subject":[],"published":{"date-parts":[[2026,10]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Interface-engineered \u03b3\/\u03b1-hematite homojunction with low contact barrier for boosted photocatalytic peroxymonosulfate activation","name":"articletitle","label":"Article Title"},{"value":"Journal of Environmental Sciences","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jes.2025.12.085","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2026 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.","name":"copyright","label":"Copyright"}]}}