{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,10]],"date-time":"2026-11-10T05:07:06Z","timestamp":1794287226988,"version":"4.9.0"},"reference-count":48,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2022,10,1]],"date-time":"2022-10-01T00:00:00Z","timestamp":1664582400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2022,10,1]],"date-time":"2022-10-01T00:00:00Z","timestamp":1664582400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2022,7,4]],"date-time":"2022-07-04T00:00:00Z","timestamp":1656892800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Hazardous Materials"],"published-print":{"date-parts":[[2022,10]]},"DOI":"10.1016\/j.jhazmat.2022.129504","type":"journal-article","created":{"date-parts":[[2022,7,1]],"date-time":"2022-07-01T03:11:30Z","timestamp":1656645090000},"page":"129504","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":69,"special_numbering":"C","title":["Novel Ni foam catalysts for sustainable nitrate to ammonia electroreduction"],"prefix":"10.1016","volume":"439","author":[{"given":"Anna","family":"Iarchuk","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abhijit","family":"Dutta","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Broekmann","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.jhazmat.2022.129504_bib1","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1016\/j.jelechem.2014.06.016","article-title":"Selective and quantitative nitrate electroreduction to ammonium using a porous copper electrode in an electrochemical flow cell","volume":"727","author":"Abdallah","year":"2014","journal-title":"J. Electroanal. Chem."},{"issue":"2","key":"10.1016\/j.jhazmat.2022.129504_bib2","article-title":"Electrified conversion of contaminated water to value: selective conversion of aqueous nitrate to ammonia in a polymer electrolyte membrane cell","volume":"15","author":"Bunea","year":"2022","journal-title":"ChemSusChem"},{"issue":"6001","key":"10.1016\/j.jhazmat.2022.129504_bib3","doi-asserted-by":"crossref","first-page":"192","DOI":"10.1126\/science.1186120","article-title":"The evolution and future of earth nitrogen cycle","volume":"330","author":"Canfield","year":"2010","journal-title":"Science"},{"key":"10.1016\/j.jhazmat.2022.129504_bib4","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2019.122065","article-title":"Electrochemical denitrification of highly contaminated actual nitrate wastewater by Ti\/RuO2 anode and iron cathode","volume":"386","author":"Chauhan","year":"2020","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jhazmat.2022.129504_bib5","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/S0022-0728(02)01443-2","article-title":"Electrocatalytic reduction of nitrate at low concentration on coinage and transition-metal electrodes in acid solutions","volume":"554\u2013555","author":"Dima","year":"2003","journal-title":"J. Electroanal. Chem."},{"issue":"1","key":"10.1016\/j.jhazmat.2022.129504_bib6","doi-asserted-by":"crossref","first-page":"9-","DOI":"10.1007\/s11783-018-1033-z","article-title":"Electrochemical removal of nitrate in industrial wastewater","volume":"12","author":"Dong Xu","year":"2018","journal-title":"Front. Environ. Sci. Eng."},{"issue":"12","key":"10.1016\/j.jhazmat.2022.129504_bib7","doi-asserted-by":"crossref","first-page":"9726","DOI":"10.1039\/c2ee23062c","article-title":"Powering denitrification: the perspectives of electrocatalytic nitrate reduction","volume":"5","author":"Duca","year":"2012","journal-title":"Energy Environ. Sci."},{"issue":"9","key":"10.1016\/j.jhazmat.2022.129504_bib8","doi-asserted-by":"crossref","first-page":"733","DOI":"10.2533\/chimia.2021.733","article-title":"Insights from operando and identical location (IL) techniques on the activation of electrocatalysts for the conversion of CO2: a mini-review","volume":"75","author":"Dutta","year":"2021","journal-title":"Chimia Int. J. Chem."},{"key":"10.1016\/j.jhazmat.2022.129504_bib9","doi-asserted-by":"crossref","DOI":"10.1016\/j.nanoen.2019.104331","article-title":"Activation of bimetallic AgCu foam electrocatalysts for ethanol formation from CO2 by selective Cu oxidation\/reduction","volume":"68","author":"Dutta","year":"2020","journal-title":"Nano Energy"},{"key":"10.1016\/j.jhazmat.2022.129504_bib10","doi-asserted-by":"crossref","first-page":"592","DOI":"10.1016\/j.jcat.2020.06.024","article-title":"CO2 electrolysis \u2013 complementary operando XRD, XAS and Raman spectroscopy study on the stability of CuxO foam catalysts","volume":"389","author":"Dutta","year":"2020","journal-title":"J. Catal."},{"issue":"6","key":"10.1016\/j.jhazmat.2022.129504_bib11","doi-asserted-by":"crossref","first-page":"3804","DOI":"10.1021\/acscatal.6b00770","article-title":"Morphology matters: tuning the product distribution of CO2 electroreduction on oxide-derived Cu foam catalysts","volume":"6","author":"Dutta","year":"2016","journal-title":"ACS Catal."},{"issue":"8","key":"10.1016\/j.jhazmat.2022.129504_bib12","doi-asserted-by":"crossref","first-page":"5431","DOI":"10.1021\/acscatal.7b01548","article-title":"Electrochemical CO2 conversion using skeleton (Sponge) type of Cu catalysts","volume":"7","author":"Dutta","year":"2017","journal-title":"ACS Catal."},{"issue":"9","key":"10.1016\/j.jhazmat.2022.129504_bib13","doi-asserted-by":"crossref","first-page":"4988","DOI":"10.1021\/acscatal.0c05317","article-title":"A tandem (Bi2O3 \u2192 Bmet) catalyst for highly efficient ec-CO2 conversion into formate: operando Raman spectroscopic evidence for a reaction pathway change","volume":"11","author":"Dutta","year":"2021","journal-title":"ACS Catal."},{"key":"10.1016\/j.jhazmat.2022.129504_bib14","doi-asserted-by":"crossref","first-page":"372","DOI":"10.1016\/j.cej.2015.05.010","article-title":"Selective nitrate removal from groundwater using a hybrid nanofiltration\u2013reverse osmosis filtration scheme","volume":"279","author":"Epsztein","year":"2015","journal-title":"Chem. Eng. J."},{"issue":"4","key":"10.1016\/j.jhazmat.2022.129504_bib15","doi-asserted-by":"crossref","first-page":"341","DOI":"10.1641\/0006-3568(2003)053[0341:TNC]2.0.CO;2","article-title":"The nitrogen cascade","volume":"53","author":"Galloway","year":"2003","journal-title":"BioScience"},{"issue":"5878","key":"10.1016\/j.jhazmat.2022.129504_bib16","doi-asserted-by":"crossref","first-page":"889","DOI":"10.1126\/science.1136674","article-title":"Transformation of the nitrogen cycle: recent trends, questions, and potential solutions","volume":"320","author":"Galloway","year":"2008","journal-title":"Science"},{"key":"10.1016\/j.jhazmat.2022.129504_bib17","first-page":"9","article-title":"Sustainable ammonia production processes","author":"Ghavam","year":"2021","journal-title":"Front. Energy Res"},{"issue":"7176","key":"10.1016\/j.jhazmat.2022.129504_bib18","doi-asserted-by":"crossref","first-page":"293","DOI":"10.1038\/nature06592","article-title":"An Earth-system perspective of the global nitrogen cycle","volume":"451","author":"Gruber","year":"2008","journal-title":"Nature"},{"issue":"2","key":"10.1016\/j.jhazmat.2022.129504_bib19","doi-asserted-by":"crossref","first-page":"61","DOI":"10.1007\/BF02381097","article-title":"Nitrogen circulation and nitrate in groundwater in an agricultural catchment in Southern India","volume":"5","author":"Jacks","year":"1983","journal-title":"Environ. Geol."},{"issue":"2","key":"10.1016\/j.jhazmat.2022.129504_bib20","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1016\/j.coche.2013.03.005","article-title":"Electrochemical conversion of CO2 to useful chemicals: current status, remaining challenges, and future opportunities","volume":"2","author":"Jhong","year":"2013","journal-title":"Curr. Opin. Chem. Eng."},{"issue":"2","key":"10.1016\/j.jhazmat.2022.129504_bib21","doi-asserted-by":"crossref","first-page":"237","DOI":"10.5194\/essd-13-237-2021","article-title":"Country-level and gridded estimates of wastewater production, collection, treatment and reuse","volume":"13","author":"Jones","year":"2021","journal-title":"Earth Syst. Sci. Data"},{"key":"10.1016\/j.jhazmat.2022.129504_bib22","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.jelechem.2017.01.020","article-title":"Electrocatalytic nitrate reduction on well-defined surfaces of tin-modified platinum, palladium and platinum-palladium single crystalline electrodes in acidic and neutral media","volume":"800","author":"Kato","year":"2017","journal-title":"J. Electroanal. Chem."},{"issue":"1","key":"10.1016\/j.jhazmat.2022.129504_bib23","doi-asserted-by":"crossref","first-page":"323","DOI":"10.1016\/j.jhazmat.2009.06.005","article-title":"Electrochemical reduction of nitrate and nitrite in simulated liquid nuclear wastes","volume":"171","author":"Katsounaros","year":"2009","journal-title":"J. Hazard. Mater."},{"issue":"15","key":"10.1016\/j.jhazmat.2022.129504_bib24","doi-asserted-by":"crossref","first-page":"7036","DOI":"10.1021\/jacs.0c00418","article-title":"Efficient ammonia electrosynthesis from nitrate on strained ruthenium nanoclusters","volume":"142","author":"Li","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.jhazmat.2022.129504_bib25","doi-asserted-by":"crossref","first-page":"107094","DOI":"10.1016\/j.elecom.2021.107094","article-title":"Recent development of electrochemical nitrate reduction to ammonia: a mini review","volume":"129","author":"Lu","year":"2021","journal-title":"Electrochem. Commun."},{"issue":"2","key":"10.1016\/j.jhazmat.2022.129504_bib26","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1016\/j.chempr.2018.10.010","article-title":"Electrocatalytic reduction of nitrogen: from Haber-Bosch to ammonia artificial leaf","volume":"5","author":"Mart\u00edn","year":"2019","journal-title":"Chem"},{"issue":"2","key":"10.1016\/j.jhazmat.2022.129504_bib27","doi-asserted-by":"crossref","first-page":"631","DOI":"10.1039\/C3CS60323G","article-title":"A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels","volume":"43","author":"Qiao","year":"2014","journal-title":"Chem. Soc. Rev."},{"issue":"11","key":"10.1016\/j.jhazmat.2022.129504_bib28","doi-asserted-by":"crossref","first-page":"7946","DOI":"10.1021\/acscatal.7b02234","article-title":"Electrochemical Reduction of CO2 into Multicarbon Alcohols on Activated Cu Mesh Catalysts: An Identical Location (IL) Study","volume":"7","author":"Rahaman","year":"2017","journal-title":"ACS Catal."},{"key":"10.1016\/j.jhazmat.2022.129504_bib29","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1016\/j.jelechem.2006.06.012","article-title":"Electrocatalytic reduction of nitrate on copper electrodes prepared by high-energy ball milling","volume":"596","author":"Reyter","year":"2006","journal-title":"J. Electroanal. Chem."},{"issue":"11","key":"10.1016\/j.jhazmat.2022.129504_bib30","doi-asserted-by":"crossref","first-page":"1206","DOI":"10.1016\/j.reactfunctpolym.2006.03.009","article-title":"Removal of nitrate from aqueous solution by nitrate selective ion exchange resins","volume":"66","author":"Samatya","year":"2006","journal-title":"React. Funct. Polym."},{"issue":"3","key":"10.1016\/j.jhazmat.2022.129504_bib31","doi-asserted-by":"crossref","first-page":"237","DOI":"10.1002\/adma.200305660","article-title":"Porous tin oxides prepared using an anodic oxidation process","volume":"16","author":"Shin","year":"2004","journal-title":"Adv. Mater."},{"issue":"25","key":"10.1016\/j.jhazmat.2022.129504_bib32","doi-asserted-by":"crossref","first-page":"5460","DOI":"10.1021\/cm048887b","article-title":"Copper foam structures with highly porous nanostructured walls","volume":"16","author":"Shin","year":"2004","journal-title":"Chem. Mater."},{"key":"10.1016\/j.jhazmat.2022.129504_bib33","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1016\/j.apcatb.2015.06.028","article-title":"The electrochemical reduction of nitrate over micro-architectured metal electrodes with stainless steel scaffold","volume":"180","author":"Su","year":"2016","journal-title":"Appl. Catal. B"},{"key":"10.1016\/j.jhazmat.2022.129504_bib34","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.watres.2017.04.069","article-title":"Electrochemical nitrate reduction by using a novel Co3O4\/Ti cathode","volume":"120","author":"Su","year":"2017","journal-title":"Water Res"},{"issue":"19","key":"10.1016\/j.jhazmat.2022.129504_bib35","doi-asserted-by":"crossref","first-page":"6023","DOI":"10.1016\/j.electacta.2007.03.057","article-title":"Electrochemical reduction of nitrate on Pt(S)[n(111)\u00d7(111)] electrodes in perchloric acid solution","volume":"52","author":"Taguchi","year":"2007","journal-title":"Electrochim. Acta"},{"issue":"2","key":"10.1016\/j.jhazmat.2022.129504_bib36","doi-asserted-by":"crossref","first-page":"290","DOI":"10.1016\/j.joule.2020.12.025","article-title":"Electrocatalytic nitrate reduction for sustainable ammonia production","volume":"5","author":"van Langevelde","year":"2021","journal-title":"Joule"},{"issue":"4","key":"10.1016\/j.jhazmat.2022.129504_bib37","doi-asserted-by":"crossref","first-page":"1039","DOI":"10.1002\/cctc.202001145","article-title":"Hydrogen bubble templated metal foams as efficient catalysts of CO2 electroreduction","volume":"13","author":"Vesztergom","year":"2021","journal-title":"ChemCatChem"},{"issue":"6","key":"10.1016\/j.jhazmat.2022.129504_bib38","doi-asserted-by":"crossref","first-page":"1055","DOI":"10.1016\/j.joule.2018.04.017","article-title":"Greening ammonia toward the solar ammonia refinery","volume":"2","author":"Wang","year":"2018","journal-title":"Joule"},{"issue":"50","key":"10.1016\/j.jhazmat.2022.129504_bib39","doi-asserted-by":"crossref","first-page":"1803309","DOI":"10.1002\/adfm.201803309","article-title":"Nitrogen fixation reaction derived from nanostructured catalytic materials","volume":"28","author":"Wang","year":"2018","journal-title":"Adv. Funct. Mater."},{"issue":"12","key":"10.1016\/j.jhazmat.2022.129504_bib40","doi-asserted-by":"crossref","first-page":"5702","DOI":"10.1021\/jacs.9b13347","article-title":"Enhanced nitrate-to-ammonia activity on copper\u2013nickel alloys via tuning of intermediate adsorption","volume":"142","author":"Wang","year":"2020","journal-title":"J. Am. Chem. Soc."},{"issue":"13","key":"10.1016\/j.jhazmat.2022.129504_bib41","doi-asserted-by":"crossref","first-page":"5350","DOI":"10.1002\/anie.201915992","article-title":"Unveiling the activity origin of a copper-based electrocatalyst for selective nitrate reduction to ammonia","volume":"59","author":"Wang","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"issue":"24","key":"10.1016\/j.jhazmat.2022.129504_bib42","doi-asserted-by":"crossref","first-page":"3451","DOI":"10.1021\/jz1012627","article-title":"Prospects of CO2 utilization via direct heterogeneous electrochemical reduction","volume":"1","author":"Whipple","year":"2010","journal-title":"J. Phys. Chem. Lett."},{"issue":"17","key":"10.1016\/j.jhazmat.2022.129504_bib43","doi-asserted-by":"crossref","first-page":"2148","DOI":"10.1039\/C3CC49224A","article-title":"pH dependence of the electroreduction of nitrate on Rh and Pt polycrystalline electrodes","volume":"50","author":"Yang","year":"2014","journal-title":"Chem. Commun."},{"issue":"10","key":"10.1016\/j.jhazmat.2022.129504_bib44","doi-asserted-by":"crossref","first-page":"1418","DOI":"10.1002\/2016GB005421","article-title":"The anthropogenic perturbation of the marine nitrogen cycle by atmospheric deposition: Nitrogen cycle feedbacks and the 15N Haber-Bosch effect","volume":"30","author":"Yang","year":"2016","journal-title":"Glob. Biogeochem. Cycles"},{"key":"10.1016\/j.jhazmat.2022.129504_bib45","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2020.126269","article-title":"Recent advances in non-noble metal electrocatalysts for nitrate reduction","volume":"403","author":"Zhang","year":"2021","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.jhazmat.2022.129504_bib46","doi-asserted-by":"crossref","first-page":"151","DOI":"10.1016\/j.electacta.2018.08.154","article-title":"Electrochemical reduction of nitrate via Cu\/Ni composite cathode paired with Ir-Ru\/Ti anode: High efficiency and N2 selectivity","volume":"291","author":"Zhang","year":"2018","journal-title":"Electrochim. Acta"},{"issue":"19","key":"10.1016\/j.jhazmat.2022.129504_bib47","doi-asserted-by":"crossref","first-page":"13231","DOI":"10.1021\/acs.est.1c02278","article-title":"Self-activated Ni cathode for electrocatalytic nitrate reduction to ammonia: from fundamentals to scale-up for treatment of industrial wastewater","volume":"55","author":"Zheng","year":"2021","journal-title":"Environ. Sci. Technol."},{"issue":"10","key":"10.1016\/j.jhazmat.2022.129504_bib48","doi-asserted-by":"crossref","first-page":"1721","DOI":"10.1002\/cctc.201601607","article-title":"Design and application of foams for electrocatalysis","volume":"9","author":"Zhu","year":"2017","journal-title":"ChemCatChem"}],"container-title":["Journal of Hazardous Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0304389422012973?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0304389422012973?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,10,4]],"date-time":"2025-10-04T19:07:49Z","timestamp":1759604869000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0304389422012973"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,10]]},"references-count":48,"alternative-id":["S0304389422012973"],"URL":"https:\/\/doi.org\/10.1016\/j.jhazmat.2022.129504","relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2022-6x1v6","asserted-by":"object"}]},"ISSN":["0304-3894"],"issn-type":[{"value":"0304-3894","type":"print"}],"subject":[],"published":{"date-parts":[[2022,10]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Novel Ni foam catalysts for sustainable nitrate to ammonia electroreduction","name":"articletitle","label":"Article Title"},{"value":"Journal of Hazardous Materials","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jhazmat.2022.129504","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2022 The Authors. Published by Elsevier B.V.","name":"copyright","label":"Copyright"}],"article-number":"129504"}}