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Lett."},{"key":"10.1016\/j.jinorgbio.2024.112551_bb0490","doi-asserted-by":"crossref","first-page":"1572","DOI":"10.1021\/acs.inorgchem.7b02927","article-title":"Reaction chemistry of silver(I) Trifluoromethanesulfonate complexes of nitrogen-confused C-Scorpionates","volume":"57","author":"Gardinier","year":"2018","journal-title":"Inorg. 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