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Soc."},{"key":"10.1016\/j.jinorgbio.2024.112737_bb0225","first-page":"523","article-title":"Jikken Kagaku Koza (lecture on experimental chemistry)","volume":"11","author":"Hosoya","year":"1967","journal-title":"Chem. Soc. Jpn."},{"key":"10.1016\/j.jinorgbio.2024.112737_bb0230","doi-asserted-by":"crossref","first-page":"7178","DOI":"10.1021\/ja00464a013","volume":"99","author":"Snyder","year":"1977","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.jinorgbio.2024.112737_bb0235","doi-asserted-by":"crossref","first-page":"5552","DOI":"10.1021\/ja00434a024","volume":"98","author":"Walker","year":"1978","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.jinorgbio.2024.112737_bb0240","unstructured":"As often reiterated (see for example, J. Mack, M.J. Stillman, in \u201cThe Porphyrin Handbook\u201d eds. K. M. Kadish, K. M. Smith, R. Guilard, Academic Press, New York, 16 (2003) 43\u2013116), TBP derivatives show spectroscopic properties in-between those of normal porphyrins such as TPPs or OEP and phthalocyanines. With respect to iron complexes also, it was reported in ref. 49, that tetrabenzoporphinatoiron(III) chrolide, ClFe(III)TBP, reveals intermediary character between ordinary iron(III) porphyrins and Fe(III)TDPc or FeODPc in many respects. For example, the degree of dissociation of Fe-Cl bond in ClFe(III)TBP is known to be much larger than that in ClFe(III)TPP. Accordingly, though the halide counter anion was not detected in the elemental analyses of Fe(III)TDPc or Fe(III)ODPc, it seems probable in the above sense that Fe-X bond in high-spin iron(III) phthalocyanines is very weak, if present at all or fully dissociated. Furthermore, support of this speculation is that the difficulty of detecting Fe(III) high-spin signal in EPR spectroscopy increases in the sequence, ClFe(III)TPP, ClFe(III)TBP, and Fe(III)TDPc or Fe(III)ODPc. Their high-spin signal in CH2Cl2 can be discernible at ca. 77, 20, and lower than ca. 10 K, respectively."},{"key":"10.1016\/j.jinorgbio.2024.112737_bb0245","doi-asserted-by":"crossref","first-page":"2502","DOI":"10.1021\/ic00210a009","volume":"24","author":"Kobayashi","year":"1985","journal-title":"Inorg. Chem."},{"key":"10.1016\/j.jinorgbio.2024.112737_bb0250","doi-asserted-by":"crossref","first-page":"4342","DOI":"10.1021\/j100219a013","volume":"86","author":"Sabelli","year":"1982","journal-title":"J. Phys. Chem."},{"key":"10.1016\/j.jinorgbio.2024.112737_bb0255","doi-asserted-by":"crossref","first-page":"1145","DOI":"10.1021\/ic50183a011","volume":"17","author":"Lever","year":"1978","journal-title":"Inorg. 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