{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,10]],"date-time":"2026-05-10T14:18:17Z","timestamp":1778422697595,"version":"3.51.4"},"reference-count":46,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2020,11,1]],"date-time":"2020-11-01T00:00:00Z","timestamp":1604188800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2020,11,1]],"date-time":"2020-11-01T00:00:00Z","timestamp":1604188800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy"],"published-print":{"date-parts":[[2020,11]]},"DOI":"10.1016\/j.saa.2020.118650","type":"journal-article","created":{"date-parts":[[2020,6,29]],"date-time":"2020-06-29T04:22:27Z","timestamp":1593404547000},"page":"118650","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":24,"special_numbering":"C","title":["A FRET-based ratiometric fluorescent probe for highly selective detection of hydrogen polysulfides based on a coumarin-rhodol derivative"],"prefix":"10.1016","volume":"241","author":[{"given":"Jingguo","family":"Sun","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yu","family":"Bai","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qiujuan","family":"Ma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hongtao","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mingxia","family":"Wu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chunyan","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Meiju","family":"Tian","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"78","reference":[{"key":"10.1016\/j.saa.2020.118650_bb0005","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1016\/j.plaphy.2012.03.016","article-title":"The biology of reactive sulfur species (RSS)","volume":"59","author":"Gruhlke","year":"2012","journal-title":"Plant Physiol. Biochem."},{"key":"10.1016\/j.saa.2020.118650_bb0010","doi-asserted-by":"crossref","first-page":"375","DOI":"10.1515\/BC.2002.042","article-title":"Reactive sulfur species: an emerging concept in oxidative stress","volume":"383","author":"Giles","year":"2002","journal-title":"Biol. Chem."},{"key":"10.1016\/j.saa.2020.118650_bb0015","doi-asserted-by":"crossref","first-page":"1279","DOI":"10.1016\/S0891-5849(01)00710-9","article-title":"Hypothesis: the role of reactive sulfur species in oxidative stress","volume":"31","author":"Giles","year":"2001","journal-title":"Free Radic. Biol. Med."},{"key":"10.1016\/j.saa.2020.118650_bb0020","doi-asserted-by":"crossref","first-page":"3766","DOI":"10.1039\/C4AN02366H","article-title":"A near-infrared fluorescent probe for the detection of hydrogen polysulfides biosynthetic pathways in living cells and in vivo","volume":"140","author":"Gao","year":"2015","journal-title":"Analyst"},{"key":"10.1016\/j.saa.2020.118650_bb0025","doi-asserted-by":"crossref","first-page":"12234","DOI":"10.1039\/C4CC03312D","article-title":"Fluorescent probes for hydrogen sulfide detection and bioimaging","volume":"50","author":"Yu","year":"2014","journal-title":"Chem. Commun."},{"key":"10.1016\/j.saa.2020.118650_bb0030","doi-asserted-by":"crossref","first-page":"4596","DOI":"10.1039\/C4CS00298A","article-title":"Chemical probes for molecular imaging and detection of hydrogen sulfide and reactive sulfurspecies in biological systems","volume":"44","author":"Lin","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"10.1016\/j.saa.2020.118650_bb0035","doi-asserted-by":"crossref","first-page":"169","DOI":"10.1146\/annurev-pharmtox-010510-100505","article-title":"Hydrogen sulfide and cell signaling","volume":"51","author":"Li","year":"2011","journal-title":"Annu. Rev. Pharmacol. Toxicol."},{"key":"10.1016\/j.saa.2020.118650_bb0040","doi-asserted-by":"crossref","first-page":"791","DOI":"10.1152\/physrev.00017.2011","article-title":"Physiological implications of hydrogen sulfide: a whiff exploration that blossomed","volume":"92","author":"Wang","year":"2012","journal-title":"Physiol. Rev."},{"key":"10.1016\/j.saa.2020.118650_bb0045","doi-asserted-by":"crossref","first-page":"82","DOI":"10.1016\/j.freeradbiomed.2014.09.007","article-title":"Redox chemistry and chemical biology of H2S, hydropersulfides, and derived species: implications of their possible biological activity and utility","volume":"77","author":"Ono","year":"2014","journal-title":"Free Radic. Biol. Med."},{"key":"10.1016\/j.saa.2020.118650_bb0050","doi-asserted-by":"crossref","first-page":"2451","DOI":"10.1096\/fj.12-226415","article-title":"Polysulfides are possible H2S-derived signaling molecules in rat brain","volume":"27","author":"Kimura","year":"2013","journal-title":"FASEB J."},{"key":"10.1016\/j.saa.2020.118650_bb0055","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1016\/j.molcel.2011.10.021","article-title":"Hydrogen sulfide-linked sulfhydration of NF-kappa B mediates its antiapoptotic actions","volume":"45","author":"Sen","year":"2012","journal-title":"Mol. Cell"},{"key":"10.1016\/j.saa.2020.118650_bb0060","doi-asserted-by":"crossref","first-page":"457","DOI":"10.1038\/nchembio.1834","article-title":"Biogenesis of reactive sulfur species for signaling by hydrogen sulfide oxidation pathways","volume":"11","author":"Mishanina","year":"2015","journal-title":"Nat. Chem. Biol."},{"key":"10.1016\/j.saa.2020.118650_bb0065","doi-asserted-by":"crossref","first-page":"492","DOI":"10.1016\/j.neuint.2013.09.003","article-title":"Physiological role of hydrogen sulfide and polysulfide in the central nervous system","volume":"63","author":"Kimura","year":"2013","journal-title":"Neurochem. Int."},{"key":"10.1016\/j.saa.2020.118650_bb0070","doi-asserted-by":"crossref","first-page":"575","DOI":"10.1002\/anie.201305876","article-title":"Detection of protein S-sulfhydration by a tag-switch technique","volume":"53","author":"Zhang","year":"2014","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"10.1016\/j.saa.2020.118650_bb0075","doi-asserted-by":"crossref","first-page":"211","DOI":"10.2174\/1385272819666150724233028","article-title":"Polysulfides in biology: from intricate chemistry to an astonishing yet hidden biological activity","volume":"20","author":"Estevam","year":"2016","journal-title":"Curr. Org. Chem."},{"key":"10.1016\/j.saa.2020.118650_bb0080","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1089\/ars.2014.5869","article-title":"Signaling molecules: hydrogen sulfide and polysulfide","volume":"22","author":"Kimura","year":"2015","journal-title":"Antioxid. Redox Signal."},{"key":"10.1016\/j.saa.2020.118650_bb0085","doi-asserted-by":"crossref","first-page":"229","DOI":"10.1007\/s00604-004-0179-5","article-title":"Electrospray ionization mass spectrometric analysis of aqueous polysulfide solutions","volume":"146","author":"Gun","year":"2004","journal-title":"Microchim. Acta"},{"key":"10.1016\/j.saa.2020.118650_bb0090","doi-asserted-by":"crossref","first-page":"1749","DOI":"10.1089\/ars.2012.5041","article-title":"Polysulfides link H2S to protein thiol oxidation","volume":"19","author":"Greiner","year":"2013","journal-title":"Antioxid. Redox Signal."},{"key":"10.1016\/j.saa.2020.118650_bb0095","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1016\/j.freeradbiomed.2017.10.346","article-title":"Analysis of endogenous H2S and H2Sn in mouse brain by high-performance liquid chromatography with fluorescence and tandem mass spectrometric detection","volume":"113","author":"Koike","year":"2017","journal-title":"Free Radic. Biol. Med."},{"key":"10.1016\/j.saa.2020.118650_bb0100","doi-asserted-by":"crossref","first-page":"1355","DOI":"10.1016\/j.bbapap.2014.01.002","article-title":"H2S and its role in redox signaling","volume":"1844","author":"Kabil","year":"2014","journal-title":"Biochim. Biophys. Acta"},{"key":"10.1016\/j.saa.2020.118650_bb0105","doi-asserted-by":"crossref","first-page":"18291","DOI":"10.1021\/jp046977y","article-title":"First evidence of the oxidation and regeneration of polysulfides at a GaAs Electrode, under anodic conditions. A study by in situ UV\u2212visible spectroelectrochemistry","volume":"108","author":"Debiemme-Chouvy","year":"2004","journal-title":"J. Phys. Chem. B"},{"key":"10.1016\/j.saa.2020.118650_bb0110","doi-asserted-by":"crossref","first-page":"4155","DOI":"10.1039\/C8CS01006D","article-title":"Functional synthetic probes for selective targeting and multi-analyte detection and imaging","volume":"48","author":"Yue","year":"2019","journal-title":"Chem. Soc. Rev."},{"key":"10.1016\/j.saa.2020.118650_bb0115","doi-asserted-by":"crossref","first-page":"669","DOI":"10.1089\/ars.2017.7070","article-title":"Fluorescent probes and selective inhibitors for biological studies of hydrogen sulfide- and polysulfide-mediated signaling","volume":"27","author":"Takano","year":"2017","journal-title":"Antioxid. Redox Signal."},{"key":"10.1016\/j.saa.2020.118650_bb0120","doi-asserted-by":"crossref","first-page":"6692","DOI":"10.1039\/C7OB01615H","article-title":"Fluorescent probes for hydrogen polysulfides (H2Sn, n\u00a0>\u00a01): from design rationale to applications","volume":"15","author":"Gupta","year":"2017","journal-title":"Org. Biomol. Chem."},{"key":"10.1016\/j.saa.2020.118650_bb0125","doi-asserted-by":"crossref","first-page":"7257","DOI":"10.1021\/ja502968x","article-title":"Rational design and bioimaging applications of highly selective fluorescence probes for hydrogen polysulfides","volume":"136","author":"Liu","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.saa.2020.118650_bb0130","doi-asserted-by":"crossref","first-page":"107877","DOI":"10.1016\/j.dyepig.2019.107877","article-title":"Rational design of a lysosomal-targeted ratiometric two-photon fluorescent probe for imaging hydrogen polysulfides in live cells","volume":"173","author":"Han","year":"2020","journal-title":"Dyes Pigments"},{"key":"10.1016\/j.saa.2020.118650_bb0135","doi-asserted-by":"crossref","first-page":"117579","DOI":"10.1016\/j.saa.2019.117579","article-title":"A highly selective fluorescent probe for hydrogen polysulfides in living cells based on a naphthalene derivative","volume":"227","author":"Wang","year":"2020","journal-title":"Spectrochim. Acta A Mol. Biomol. Spectrosc."},{"key":"10.1016\/j.saa.2020.118650_bb0140","doi-asserted-by":"crossref","first-page":"2776","DOI":"10.1021\/acs.orglett.5b01194","article-title":"A specific nucleophilic ring-opening reaction of aziridines as a unique platform for the construction of hydrogen polysulfides sensors","volume":"17","author":"Chen","year":"2015","journal-title":"Org. Lett."},{"key":"10.1016\/j.saa.2020.118650_bb0145","doi-asserted-by":"crossref","first-page":"7774","DOI":"10.1021\/acs.analchem.9b01189","article-title":"Sequential detection of superoxide anion and hydrogen polysulfides under hypoxic stress via a spectral-response-separated fluorescent probe functioned with a nitrobenzene derivative","volume":"91","author":"Gao","year":"2019","journal-title":"Anal. Chem."},{"key":"10.1016\/j.saa.2020.118650_bb0150","doi-asserted-by":"crossref","first-page":"529","DOI":"10.1016\/j.talanta.2016.12.020","article-title":"Towards perylenequinonoid: effective application to reversible fluorescent probe for monitoring hydrogen persulfide in solvents and living cells","volume":"164","author":"Qiu","year":"2017","journal-title":"Talanta"},{"key":"10.1016\/j.saa.2020.118650_bb0155","doi-asserted-by":"crossref","first-page":"9993","DOI":"10.1002\/anie.201604892","article-title":"A single fluorescent probe to visualize hydrogen sulfide and hydrogen polysulfides with different fluorescence signals","volume":"55","author":"Chen","year":"2016","journal-title":"Angew. Chem. Int. Ed."},{"key":"10.1016\/j.saa.2020.118650_bb0160","doi-asserted-by":"crossref","first-page":"531","DOI":"10.1016\/j.snb.2016.04.008","article-title":"Development of fluorescent probes for hydrogen polysulfides by using cinnamate ester as the recognition unit","volume":"232","author":"Hou","year":"2016","journal-title":"Sensors Actuators B Chem."},{"key":"10.1016\/j.saa.2020.118650_bb0165","doi-asserted-by":"crossref","first-page":"1987","DOI":"10.1021\/acsabm.9b00044","article-title":"Photostable ratiometric two-photon fluorescent probe for visualizing hydrogen polysulfide in mitochondria and its application","volume":"2","author":"Han","year":"2019","journal-title":"ACS Appl. Bio. Mater."},{"key":"10.1016\/j.saa.2020.118650_bb0170","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1016\/j.snb.2017.11.102","article-title":"Rational development of a highly selective ratiometric fluorescent probe for hydrogen polysulfides","volume":"258","author":"Chen","year":"2018","journal-title":"Sensors Actuators B Chem."},{"key":"10.1016\/j.saa.2020.118650_bb0175","doi-asserted-by":"crossref","first-page":"4185","DOI":"10.1039\/C4CS00280F","article-title":"Small molecule-based ratiometric fluorescence probes for cations, anions, and biomolecules","volume":"44","author":"Lee","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"10.1016\/j.saa.2020.118650_bb0180","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1016\/j.aca.2019.03.004","article-title":"A ratiometric fluorescence probe based on a novel recognition mechanism for monitoring endogenous hypochlorite in living cells","volume":"1064","author":"Yan","year":"2019","journal-title":"Anal. Chim. Acta"},{"key":"10.1016\/j.saa.2020.118650_bb0185","doi-asserted-by":"crossref","first-page":"212","DOI":"10.1016\/j.dyepig.2019.02.025","article-title":"A FRET-based probe for detection of the endogenous SO2 in cells","volume":"165","author":"Chen","year":"2019","journal-title":"Dyes Pigments"},{"key":"10.1016\/j.saa.2020.118650_bb0190","doi-asserted-by":"crossref","first-page":"1462","DOI":"10.1021\/ar300273v","article-title":"FRET-based small-molecule fluorescent probes: rational design and bioimaging applications","volume":"46","author":"Yuan","year":"2013","journal-title":"Acc. Chem. Res."},{"key":"10.1016\/j.saa.2020.118650_bb0195","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1016\/j.aca.2018.11.052","article-title":"A FRET-based ratiometric fluorescent probe for detection of intrinsically generated SO2 derivatives in mitochondria","volume":"1053","author":"Song","year":"2019","journal-title":"Anal. Chim. Acta"},{"key":"10.1016\/j.saa.2020.118650_bb0200","doi-asserted-by":"crossref","first-page":"133","DOI":"10.1016\/j.aca.2018.12.042","article-title":"A mitochondria-targeted and FRET-based ratiometric fluorescent probe for detection of SO2 derivatives in water","volume":"1055","author":"Zhang","year":"2019","journal-title":"Anal. Chim. Acta"},{"key":"10.1016\/j.saa.2020.118650_bb0205","doi-asserted-by":"crossref","first-page":"875","DOI":"10.1016\/j.snb.2017.01.169","article-title":"A ratiometric fluorescent probe for sensing Cu2+ based on new imidazo[1,5-a]pyridine fluorescent dye","volume":"245","author":"Ge","year":"2017","journal-title":"Sensors Actuators B Chem."},{"key":"10.1016\/j.saa.2020.118650_bb0210","doi-asserted-by":"crossref","first-page":"11892","DOI":"10.1021\/acs.analchem.6b03702","article-title":"Ratiometric two-photon fluorescent probe for in vivo hydrogen polysulfides detection and imaging during lipopolysaccharide-induced acute organs injury","volume":"88","author":"Zhang","year":"2016","journal-title":"Anal. Chem."},{"key":"10.1016\/j.saa.2020.118650_bb0215","doi-asserted-by":"crossref","first-page":"4558","DOI":"10.1039\/C7AY01249G","article-title":"A novel two-photon fluorescent probe for the selective detection of hydrogen peroxide based on a naphthalene derivative","volume":"9","author":"Ma","year":"2017","journal-title":"Anal. Methods"},{"key":"10.1016\/j.saa.2020.118650_bb0220","doi-asserted-by":"crossref","first-page":"14763","DOI":"10.1039\/C9NJ03375K","article-title":"A FRET-based ratiometric fluorescent probe for highly selective detection of cysteine based on a coumarin\u2013rhodol derivative","volume":"43","author":"Bai","year":"2019","journal-title":"New J. Chem."},{"key":"10.1016\/j.saa.2020.118650_bb0225","doi-asserted-by":"crossref","first-page":"733","DOI":"10.1039\/C5CC08695G","article-title":"A FRET-based ratiometric two-photon fluorescent probe for dual-channel imaging of nitroxyl in living cells and tissues","volume":"52","author":"Zhu","year":"2016","journal-title":"Chem. Commun."},{"key":"10.1016\/j.saa.2020.118650_bb0230","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1016\/j.snb.2019.03.122","article-title":"A dual-site modulated FRET-based two-photon ratiometric fluorescent probe for tracking lysosomal pH changes in living cells, tissues and zebrafish","volume":"290","author":"Zhao","year":"2019","journal-title":"Sensors Actuators B Chem."}],"container-title":["Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1386142520306296?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1386142520306296?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,10,25]],"date-time":"2025-10-25T01:27:16Z","timestamp":1761355636000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S1386142520306296"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,11]]},"references-count":46,"alternative-id":["S1386142520306296"],"URL":"https:\/\/doi.org\/10.1016\/j.saa.2020.118650","relation":{},"ISSN":["1386-1425"],"issn-type":[{"value":"1386-1425","type":"print"}],"subject":[],"published":{"date-parts":[[2020,11]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"A FRET-based ratiometric fluorescent probe for highly selective detection of hydrogen polysulfides based on a coumarin-rhodol derivative","name":"articletitle","label":"Article Title"},{"value":"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.saa.2020.118650","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2020 Elsevier B.V. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"118650"}}