{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T11:47:34Z","timestamp":1778759254813,"version":"3.51.4"},"reference-count":45,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2024,4,1]],"date-time":"2024-04-01T00:00:00Z","timestamp":1711929600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2024,4,1]],"date-time":"2024-04-01T00:00:00Z","timestamp":1711929600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2024,4,1]],"date-time":"2024-04-01T00:00:00Z","timestamp":1711929600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2024,4,1]],"date-time":"2024-04-01T00:00:00Z","timestamp":1711929600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2024,4,1]],"date-time":"2024-04-01T00:00:00Z","timestamp":1711929600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2024,4,1]],"date-time":"2024-04-01T00:00:00Z","timestamp":1711929600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2024,4,1]],"date-time":"2024-04-01T00:00:00Z","timestamp":1711929600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100009087","name":"Universidad Industrial de Santander","doi-asserted-by":"publisher","award":["3914"],"award-info":[{"award-number":["3914"]}],"id":[{"id":"10.13039\/501100009087","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy"],"published-print":{"date-parts":[[2024,4]]},"DOI":"10.1016\/j.saa.2024.123965","type":"journal-article","created":{"date-parts":[[2024,1,26]],"date-time":"2024-01-26T14:30:23Z","timestamp":1706279423000},"page":"123965","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":5,"special_numbering":"C","title":["Prediction of some physicochemical properties in Colombian crude oils upgraded by catalytic aquathermolysis using UV\u2013VIS spectroscopy associated with chemometric methods"],"prefix":"10.1016","volume":"310","author":[{"given":"Adan Y.","family":"Le\u00f3n","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Keyner S.","family":"N\u00fa\u00f1ez-M\u00e9ndez","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Luis M.","family":"Salas-Chia","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Juan C.","family":"Orozco-Agamez","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dar\u00edo Y.","family":"Pe\u00f1a-Ballesteros","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jaime J.","family":"Mart\u00ednez-Vertel","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Paola A.","family":"Le\u00f3n","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daniel R.","family":"Molina-Velasco","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"78","reference":[{"key":"10.1016\/j.saa.2024.123965_b0005","doi-asserted-by":"crossref","DOI":"10.1016\/j.petrol.2019.106659","article-title":"Experimental study and field demonstration of air-foam flooding for heavy oil EOR","volume":"185","author":"Lang","year":"2020","journal-title":"J. Pet. Sci. Eng."},{"key":"10.1016\/j.saa.2024.123965_b0010","doi-asserted-by":"crossref","first-page":"500","DOI":"10.1016\/j.enpol.2018.10.037","article-title":"OPEC behavior: The volume of oil reserves announced","author":"Behrouzifar","year":"2019","journal-title":"Energy Policy 127"},{"key":"10.1016\/j.saa.2024.123965_b0015","doi-asserted-by":"crossref","first-page":"20086","DOI":"10.1021\/acs.iecr.0c03198","article-title":"Enhancing the conversion of polycyclic aromatic hydrocarbons from naphthenic heavy oil: Novel process design, comparative techno-economic analysis, and life cycle assessment","volume":"59","author":"Zhou","year":"2020","journal-title":"Ind. Eng. Chem. Res."},{"key":"10.1016\/j.saa.2024.123965_b0020","doi-asserted-by":"crossref","first-page":"8643","DOI":"10.1021\/acs.energyfuels.7b00723","article-title":"Design of steam preheating and ignition program of in situ combustion","volume":"31","author":"Yuan","year":"2017","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0025","doi-asserted-by":"crossref","first-page":"5426","DOI":"10.1021\/acs.energyfuels.9b04004","article-title":"Significance of aquathermolysis reaction on heavy oil recovery during the steam-assisted gravity drainage process","volume":"34","author":"Zhang","year":"2020","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0030","doi-asserted-by":"crossref","first-page":"6488","DOI":"10.1021\/acs.energyfuels.8b00347","article-title":"Conversion of heavy oil with different chemical compositions under catalytic aquathermolysis with an amphiphilic Fe-Co-Cu catalyst and kaolin","volume":"32","author":"Kayukova","year":"2018","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0035","doi-asserted-by":"crossref","first-page":"11353","DOI":"10.1021\/acs.energyfuels.0c02062","article-title":"Catalytic aquathermolysis for altering the rheology of asphaltic crude oil using ionic liquid modified magnetic MWCNT","volume":"34","author":"Betiha","year":"2020","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0040","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1016\/j.fuel.2009.07.021","article-title":"Correlations between SARA fractions and physicochemical properties with 1H NMR spectra of vacuum residues from Colombian crude oils","volume":"89","author":"Molina","year":"2010","journal-title":"Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0045","doi-asserted-by":"crossref","first-page":"209","DOI":"10.1016\/j.ejpe.2016.04.002","article-title":"The relationship between SARA fractions and crude oil stability","volume":"26","author":"Ashoori","year":"2017","journal-title":"Egypt. J. Pet."},{"key":"10.1016\/j.saa.2024.123965_b0050","doi-asserted-by":"crossref","first-page":"7440","DOI":"10.1021\/ef502134p","article-title":"Aquathermolysis of heavy crude oil with amphiphilic nickel and iron catalysts","volume":"28","author":"Wang","year":"2014","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0055","first-page":"49","article-title":"Physicochemical characterization of heavy oil and the precipitated asphaltenes fraction using UV spectroscopy and dynamic light scattering","volume":"6","author":"Banda-Cruz","year":"2017","journal-title":"J. Eng. Technol."},{"key":"10.1016\/j.saa.2024.123965_b0060","first-page":"1","article-title":"Characterization of petroleum crude oils by fourier transform infrared (FT-IR) and gas chromatography-mass spectrometerys","volume":"2","author":"Ahmad","year":"2018","journal-title":"Petroleum & Petrochemical Engineering Journal"},{"issue":"8","key":"10.1016\/j.saa.2024.123965_b0065","doi-asserted-by":"crossref","first-page":"995","DOI":"10.3390\/pr8080995","article-title":"Qualitative and quantitative analysis of heavy crude oil samples and their SARA fractions with 13 C nuclear magnetic resonance","volume":"8","author":"Rakhmatullin","year":"2020","journal-title":"Processes"},{"issue":"1\u20132","key":"10.1016\/j.saa.2024.123965_b0070","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1016\/j.aca.2011.05.048","article-title":"Characterisation of heavy oils using near-infrared spectroscopy: optimisation of pre-processing methods and variable selection","volume":"705","author":"Laxalde","year":"2011","journal-title":"Anal. Chim. Acta"},{"key":"10.1016\/j.saa.2024.123965_b0075","first-page":"113103613","article-title":"Monitoring the extraction process of acidic polysaccharides in Poria cocos by near infrared spectroscopy combined with chemometrics","author":"Hua","year":"2021","journal-title":"Infrared Phys. Technol."},{"key":"10.1016\/j.saa.2024.123965_b0080","doi-asserted-by":"crossref","first-page":"660","DOI":"10.1016\/j.fuel.2016.05.049","article-title":"Determination of some physicochemical properties in Brazilian crude oil by 1H NMR spectroscopy associated to chemometric approach","volume":"181","author":"Duarte","year":"2016","journal-title":"Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0085","doi-asserted-by":"crossref","DOI":"10.1016\/j.saa.2021.120841","article-title":"Near infrared spectroscopy combined with chemometrics for quantitative analysis of corn oil in edible blend oil","volume":"270","author":"Zhang","year":"2022","journal-title":"Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy"},{"key":"10.1016\/j.saa.2024.123965_b0090","doi-asserted-by":"crossref","first-page":"1093","DOI":"10.1016\/j.fuel.2018.09.013","article-title":"Origin based classification of crude oils by infrared spectrometry and chemometrics","volume":"236","author":"Bagheri Garmarudi","year":"2019","journal-title":"Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0095","unstructured":"O.R. Koseoglu, A. Al-Hajji, G. Jamieson, Characterization of crude oil by ultraviolet visible spectroscopy. US2015\/0106034, 2012."},{"key":"10.1016\/j.saa.2024.123965_b0100","doi-asserted-by":"crossref","DOI":"10.1016\/j.fuel.2019.116328","article-title":"In-situ heavy oil viscosity prediction at high temperatures using low-field NMR relaxometry and nonlinear least squares","volume":"260","author":"Markovic","year":"2020","journal-title":"Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0105","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1016\/j.trac.2011.12.006","article-title":"Characterization of petroleum-based products by infrared spectroscopy and chemometrics","volume":"35","author":"Khanmohammadi","year":"2012","journal-title":"TrAC - Trends in Analytical Chemistry"},{"key":"10.1016\/j.saa.2024.123965_b0110","doi-asserted-by":"crossref","first-page":"287","DOI":"10.1016\/j.fuproc.2017.09.018","article-title":"Mid-infrared uncooled sensor for the identification of pure fuel, additives and adulterants in gasoline","volume":"171","author":"Maldonado","year":"2018","journal-title":"Fuel Process. Technol."},{"key":"10.1016\/j.saa.2024.123965_b0115","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1016\/j.chemolab.2017.04.007","article-title":"Evaluation of calibration transfer methods using the ATR-FTIR technique to predict density of crude oil","volume":"166","author":"Rodrigues","year":"2017","journal-title":"Chemom. Intel. Lab. Syst."},{"key":"10.1016\/j.saa.2024.123965_b0120","doi-asserted-by":"crossref","first-page":"1592","DOI":"10.1021\/acs.energyfuels.9b03720","article-title":"Prediction of the insolubility number and the solubility blending number of colombian heavy crude oils by 1H nuclear magnetic resonance and partial least squares","volume":"34","author":"Castillo","year":"2020","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0125","doi-asserted-by":"crossref","first-page":"9231","DOI":"10.1021\/acs.energyfuels.0c00200","article-title":"Reactivity of vacuum residues by thermogravimetric analysis and nuclear magnetic resonance spectroscopy","volume":"34","author":"Le\u00f3n","year":"2020","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0130","doi-asserted-by":"crossref","first-page":"359","DOI":"10.1016\/j.fuel.2016.06.097","article-title":"Predicting fuel research octane number using Fourier-transform infrared absorption spectra of neat hydrocarbons","volume":"183","author":"Daly","year":"2016","journal-title":"Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0135","doi-asserted-by":"crossref","DOI":"10.1016\/j.saa.2020.118157","article-title":"Rapid determination and classification of crude oils by ATR-FTIR spectroscopy and chemometric methods","volume":"232","author":"Mohammadi","year":"2020","journal-title":"Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy"},{"key":"10.1016\/j.saa.2024.123965_b0140","doi-asserted-by":"crossref","first-page":"3868","DOI":"10.1021\/acs.energyfuels.7b00078","article-title":"Thermal Cracking and Catalytic Hydrocracking of a Colombian Vacuum Residue and Its Maltenes and Asphaltenes Fractions in Toluene","volume":"31","author":"Le\u00f3n","year":"2017","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0145","doi-asserted-by":"crossref","DOI":"10.1016\/j.infrared.2020.103229","article-title":"FTIR\/PLS and SVM multivariate calibrations to determination of the coke amount into the deactivated catalysts and the product of the methanol to gasoline conversion","volume":"105","author":"Juybar","year":"2020","journal-title":"Infrared Phys. Technol."},{"key":"10.1016\/j.saa.2024.123965_b0150","doi-asserted-by":"crossref","first-page":"5663","DOI":"10.1021\/ef300510h","article-title":"Multivariate curve resolution alternating least-squares as a tool for analyzing crude oil extracted asphaltene samples","volume":"26","author":"Ghatee","year":"2012","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0155","doi-asserted-by":"crossref","first-page":"2874","DOI":"10.1021\/ef400161p","article-title":"Separation and characterization of vanadyl porphyrins in Venezuela Orinoco heavy crude oil","volume":"27","author":"Zhao","year":"2013","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0160","doi-asserted-by":"crossref","first-page":"1674","DOI":"10.1021\/ef060335n","article-title":"Partial least-squares (PLS) correlation between refined product yields and physicochemical properties with the 1H nuclear magnetic resonance (NMR) spectra of Colombian crude oils","volume":"21","author":"Molina","year":"2007","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0165","doi-asserted-by":"crossref","first-page":"2955","DOI":"10.1021\/ef070003y","article-title":"Comparison of probability distribution functions for fitting distillation curves of petroleum","volume":"21","author":"S\u00e1nchez","year":"2007","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0170","doi-asserted-by":"crossref","first-page":"35","DOI":"10.1016\/j.ece.2018.11.001","article-title":"Learning about distillation curves as a way to define a process stream from crude petroleum","volume":"26","author":"G\u00f3mez-Siurana","year":"2019","journal-title":"Educ. Chem. Eng."},{"key":"10.1016\/j.saa.2024.123965_b0175","doi-asserted-by":"crossref","first-page":"6083","DOI":"10.1021\/acs.energyfuels.9b00724","article-title":"Applicability of simulated distillation for heavy oils","volume":"33","author":"Diaz","year":"2019","journal-title":"Energy Fuel"},{"key":"10.1016\/j.saa.2024.123965_b0180","doi-asserted-by":"crossref","first-page":"5231","DOI":"10.1021\/acs.energyfuels.0c04142","article-title":"Effect of the Catalytic Aquathermolysis Process on the Physicochemical Properties of a Colombian Crude Oil","volume":"35","author":"N\u00fa\u00f1ez-M\u00e9ndez","year":"2021","journal-title":"Energy & Fuels"},{"issue":"14","key":"10.1016\/j.saa.2024.123965_b0185","doi-asserted-by":"crossref","first-page":"1523","DOI":"10.1080\/10916466.2017.1358279","article-title":"Extending the true boiling point curve of a heavy crude oil by means of molecular distillation and characterization of the products obtained","volume":"35","author":"Lopes","year":"2017","journal-title":"Pet. Sci. Technol."},{"key":"10.1016\/j.saa.2024.123965_b0190","doi-asserted-by":"crossref","DOI":"10.1016\/j.chemolab.2020.104220","article-title":"Estimation of asphaltene adsorption on MgO nanoparticles using ensemble learning","volume":"208","author":"Ali","year":"2021","journal-title":"Chemom. Intel. Lab. Syst."},{"key":"10.1016\/j.saa.2024.123965_b0195","doi-asserted-by":"crossref","DOI":"10.1088\/1742-6596\/687\/1\/012093","article-title":"Prediction and extension of curves of distillation of vacuum residue using probability functions","volume":"687","author":"Le\u00f3n","year":"2016","journal-title":"J. Phys. Conf. Ser."},{"issue":"1","key":"10.1016\/j.saa.2024.123965_b0200","first-page":"83","article-title":"Multivariate spectra analysis: PLSR vs. PCA+ MLR","volume":"2","author":"Vervoort","year":"2020","journal-title":"Engineering Proceedings."},{"issue":"3","key":"10.1016\/j.saa.2024.123965_b0205","doi-asserted-by":"crossref","first-page":"829","DOI":"10.3390\/pr11030829","article-title":"Practical online characterization of the properties of hydrocracking bottom oil via near-infrared spectroscopy","volume":"11","author":"Long","year":"2023","journal-title":"Processes"},{"key":"10.1016\/j.saa.2024.123965_b0210","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1007\/s13203-014-0092-8","article-title":"Slurry-phase hydrocracking of heavy oil and model reactant: effect of dispersed Mo catalyst","volume":"5","author":"Du","year":"2015","journal-title":"Appl. Petrochem. Res."},{"key":"10.1016\/j.saa.2024.123965_b0215","article-title":"Aquathermolysis: a synopsis of work on the chemical reaction between water (steam) and heavy oil sands during simulated steam stimulation","volume":"55","author":"Hyne","year":"1986","journal-title":"AOSTRA Publication Series"},{"issue":"6","key":"10.1016\/j.saa.2024.123965_b0220","doi-asserted-by":"crossref","first-page":"684","DOI":"10.1016\/S1872-5813(11)60004-2","article-title":"Mechanism for reducing the viscosity of extra-heavy oil by aquathermolysis with an amphiphilic catalyst","volume":"38","author":"Chuan","year":"2010","journal-title":"J. Fuel Chem. Technol."},{"key":"10.1016\/j.saa.2024.123965_b0225","doi-asserted-by":"crossref","first-page":"420","DOI":"10.1016\/j.fuel.2019.02.063","article-title":"Morphological insights into the catalytic aquathermolysis of crude oil with an easily prepared high-efficiency Fe3O4-containing catalyst","volume":"245","author":"Lin","year":"2019","journal-title":"Fuel"}],"container-title":["Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1386142524001318?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1386142524001318?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,10,25]],"date-time":"2025-10-25T02:43:47Z","timestamp":1761360227000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S1386142524001318"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,4]]},"references-count":45,"alternative-id":["S1386142524001318"],"URL":"https:\/\/doi.org\/10.1016\/j.saa.2024.123965","relation":{},"ISSN":["1386-1425"],"issn-type":[{"value":"1386-1425","type":"print"}],"subject":[],"published":{"date-parts":[[2024,4]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Prediction of some physicochemical properties in Colombian crude oils upgraded by catalytic aquathermolysis using UV\u2013VIS spectroscopy associated with chemometric methods","name":"articletitle","label":"Article Title"},{"value":"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.saa.2024.123965","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2024 Elsevier B.V. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"123965"}}