{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,21]],"date-time":"2026-07-21T16:03:14Z","timestamp":1784649794603,"version":"3.55.0"},"reference-count":43,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22161012"],"award-info":[{"award-number":["22161012"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003458","name":"Guizhou Normal University","doi-asserted-by":"publisher","award":["[2022]07"],"award-info":[{"award-number":["[2022]07"]}],"id":[{"id":"10.13039\/501100003458","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy"],"published-print":{"date-parts":[[2025,11]]},"DOI":"10.1016\/j.saa.2025.126383","type":"journal-article","created":{"date-parts":[[2025,5,11]],"date-time":"2025-05-11T17:44:10Z","timestamp":1746985450000},"page":"126383","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":1,"special_numbering":"C","title":["Regulating aggregation and optical properties of rigid-flexible ligand via metal coordination for multifunctional applications"],"prefix":"10.1016","volume":"340","author":[{"given":"Jun","family":"Wang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjing","family":"Shi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Xiong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinsheng","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.saa.2025.126383_b0005","doi-asserted-by":"crossref","first-page":"6715","DOI":"10.1039\/D3CS00251A","article-title":"Aggregation behaviour of pyrene-based luminescent materials, from molecular design and optical properties to application","volume":"52","author":"Feng","year":"2023","journal-title":"Chem. Soc. Rev."},{"key":"10.1016\/j.saa.2025.126383_b0010","doi-asserted-by":"crossref","first-page":"2699","DOI":"10.1021\/acs.chemrev.3c00778","article-title":"Theranostic fluorescent probes","volume":"124","author":"Sharma","year":"2024","journal-title":"Chem. Rev."},{"key":"10.1016\/j.saa.2025.126383_b0015","doi-asserted-by":"crossref","first-page":"18351","DOI":"10.1039\/D2TC03224D","article-title":"Highly stable deep red-to-NIR OLEDs with an external quantum efficiency of 4.9% from room temperature nanostructured columnar fluids based on hetero atom bay-annulated perylene bisimides","volume":"10","author":"Behera","year":"2022","journal-title":"J. Mater. Chem. C"},{"key":"10.1016\/j.saa.2025.126383_b0020","doi-asserted-by":"crossref","first-page":"1541","DOI":"10.1039\/D0QM00825G","article-title":"Review on new horizons of aggregation induced emission: from design to development","volume":"5","author":"Suman","year":"2021","journal-title":"Mater. Chem. Front."},{"key":"10.1016\/j.saa.2025.126383_b0025","doi-asserted-by":"crossref","DOI":"10.1016\/j.pmatsci.2021.100914","article-title":"Light emission of organic luminogens: generation, mechanism and application","volume":"125","author":"Fang","year":"2022","journal-title":"Prog. Mater. Sci."},{"key":"10.1016\/j.saa.2025.126383_b0030","doi-asserted-by":"crossref","first-page":"1740","DOI":"10.1039\/b105159h","article-title":"Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole","author":"Luo","year":"2001","journal-title":"Chem. Commun."},{"key":"10.1016\/j.saa.2025.126383_b0035","article-title":"Molecular engineering toward broad color-tunable emission of pyrene-based aggregation-induced emission luminogens","volume":"12","author":"Liu","year":"2024","journal-title":"Adv. Opt. Mater."},{"key":"10.1016\/j.saa.2025.126383_b0040","doi-asserted-by":"crossref","DOI":"10.1002\/ange.202215652","article-title":"Monomer and excimer emission in a conformational and stacking-adaptable molecular system","volume":"135","author":"Shan","year":"2023","journal-title":"Angew. Chem. Int. Ed."},{"key":"10.1016\/j.saa.2025.126383_b0045","article-title":"Calcium carbonate as an ionic molecular lock for ultrastrong fluorescence of single organic molecules","volume":"64","author":"Zhang","year":"2025","journal-title":"Angew. Chem. Int. Ed."},{"key":"10.1016\/j.saa.2025.126383_b0050","doi-asserted-by":"crossref","DOI":"10.1016\/j.dyepig.2022.110958","article-title":"Pillar[5]arene-based light-harvesting assemblies with sequential energy-transfer for tunable emission and photocatalysis","volume":"210","author":"Xiao","year":"2023","journal-title":"Dyes Pigm."},{"key":"10.1016\/j.saa.2025.126383_b0055","doi-asserted-by":"crossref","first-page":"158","DOI":"10.1021\/acs.joc.9b02383","article-title":"Tetraphenylbenzosilole: an AIE building block for deep-blue emitters with high performance in nondoped spin-coating OLEDs","volume":"85","author":"Feng","year":"2020","journal-title":"J. Org. Chem."},{"key":"10.1016\/j.saa.2025.126383_b0060","article-title":"12-Structure-property relationship on aggregation-induced emission properties of simple azine-based AIEgens and its application in metal ions detection","volume":"34","author":"Sun","year":"2023","journal-title":"Chin. Chem. Lett."},{"key":"10.1016\/j.saa.2025.126383_b0065","doi-asserted-by":"crossref","DOI":"10.1038\/s41467-022-34573-2","article-title":"Ultra-fast triplet-triplet-annihilation-mediated high-lying reverse intersystem crossing triggered by participation of n\u03c0*-featured excited states","volume":"13","author":"Luo","year":"2022","journal-title":"Nat. Commun."},{"key":"10.1016\/j.saa.2025.126383_b0070","doi-asserted-by":"crossref","DOI":"10.1002\/agt2.344","article-title":"Ultralong excimer phosphorescence by the self\u2010assembly and confinement of terpyridine derivatives in polymeric matrices","volume":"4","author":"Yin","year":"2023","journal-title":"Aggregate"},{"key":"10.1016\/j.saa.2025.126383_b0075","article-title":"Instantaneous high-resolution visual imaging of latent fingerprints in water using color-tunable AIE pincer complexes","volume":"34","author":"Duan","year":"2022","journal-title":"Adv. Mater."},{"key":"10.1016\/j.saa.2025.126383_b0080","article-title":"Discrete terpyridine-lanthanide molecular and supramolecular complexes","volume":"1","author":"Yu","year":"2022","journal-title":"Supramol. Chem."},{"key":"10.1016\/j.saa.2025.126383_b0085","doi-asserted-by":"crossref","first-page":"1940","DOI":"10.1007\/s11426-023-1601-0","article-title":"Luminescent terpyridine-based metallo-supramolecular systems: from design to applications","volume":"66","author":"Guo","year":"2023","journal-title":"Sci. China Chem."},{"key":"10.1016\/j.saa.2025.126383_b0090","doi-asserted-by":"crossref","first-page":"14638","DOI":"10.1021\/jacs.0c06680","article-title":"Giant concentric metallosupramolecule with aggregation-induced phosphorescent emission","volume":"142","author":"Li","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.saa.2025.126383_b0095","doi-asserted-by":"crossref","unstructured":"J. Zhao, Z. Zhou, G. Li, P.J. Stang, X. Yan, Light-emitting self-assembled metallacages, 8 (2021) nwab045, doi: 10.1093\/nsr\/nwab045.","DOI":"10.1093\/nsr\/nwab045"},{"key":"10.1016\/j.saa.2025.126383_b0100","doi-asserted-by":"crossref","first-page":"6077","DOI":"10.1039\/D3QI01071F","article-title":"Tailoring photoluminescence and multifunctionalities of lanthanide coordination complexes employing ligand-controlled aggregation states","volume":"10","author":"Wang","year":"2023","journal-title":"Inorg. Chem. Front."},{"key":"10.1016\/j.saa.2025.126383_b0105","article-title":"Red-emitting carbon dots for fluorescent and smartphone-assisted dual-mode detection of Cu(II), Hg(II), and Fe(III) and investigation of the sensing mechanism","volume":"41","author":"Wang","year":"2024","journal-title":"Mater. Today Chem."},{"key":"10.1016\/j.saa.2025.126383_b0110","doi-asserted-by":"crossref","DOI":"10.1016\/j.carbpol.2025.123258","article-title":"Alginate-based hydrogel beads for ultrasensitive detection and effective adsorption of terbium and europium in water","volume":"353","author":"Wang","year":"2025","journal-title":"Carbohydr. Polym."},{"key":"10.1016\/j.saa.2025.126383_b0115","article-title":"Highly plasticized lanthanide luminescence for information storage and encryption applications","volume":"9","author":"Liu","year":"2022","journal-title":"Adv. Sci."},{"key":"10.1016\/j.saa.2025.126383_b0120","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1002\/jcc.22885","article-title":"Multiwfn: a multifunctional wavefunction analyzer","volume":"33","author":"Lu","year":"2012","journal-title":"J. Comput. Chem."},{"key":"10.1016\/j.saa.2025.126383_b0125","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/0263-7855(96)00018-5","article-title":"VMD: visual molecular dynamics","volume":"14","author":"Humphrey","year":"1996","journal-title":"J. Mol. Graph."},{"key":"10.1016\/j.saa.2025.126383_b0130","doi-asserted-by":"crossref","first-page":"32706","DOI":"10.1021\/acsami.2c07047","article-title":"Imidazolium-modified bispyrene-based fluorescent aggregates for discrimination of multiple anions in aqueous solution","volume":"14","author":"Qiao","year":"2022","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"10.1016\/j.saa.2025.126383_b0135","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202207313","article-title":"Solvent-dependent supramolecular host-guest assemblies of platinum(II) tweezers and a guest system: from discrete molecules to high-ordered oligomers","volume":"61","author":"Yeung","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"key":"10.1016\/j.saa.2025.126383_b0140","doi-asserted-by":"crossref","first-page":"4364","DOI":"10.1039\/D3SC05533G","article-title":"Controllable \u03c0\u2013\u03c0 coupling of intramolecular dimer models in aggregated states","volume":"15","author":"Liao","year":"2024","journal-title":"Chem. Sci."},{"key":"10.1016\/j.saa.2025.126383_b0145","doi-asserted-by":"crossref","first-page":"14775","DOI":"10.1021\/acssuschemeng.9b02791","article-title":"Spongy materials based on supramolecular polymer networks for detection and separation of broad-spectrum pollutants","volume":"7","author":"Lin","year":"2019","journal-title":"ACS Sustain. Chem. Eng."},{"key":"10.1016\/j.saa.2025.126383_b0150","doi-asserted-by":"crossref","first-page":"11419","DOI":"10.1002\/anie.201906507","article-title":"Structural engineering of luminogens with high emission efficiency both in solution and in the solid state","volume":"58","author":"Wu","year":"2019","journal-title":"Angew. Chem. Int. Ed."},{"key":"10.1016\/j.saa.2025.126383_b0155","doi-asserted-by":"crossref","first-page":"685","DOI":"10.1038\/nmat4259","article-title":"Stabilizing triplet excited states for ultralong organic phosphorescence","volume":"14","author":"An","year":"2015","journal-title":"Nat. Mater."},{"key":"10.1016\/j.saa.2025.126383_b0160","article-title":"The key role of molecular packing in luminescence property: from adjacent molecules to molecular aggregates","author":"Liao","year":"2023","journal-title":"Adv. Mater."},{"key":"10.1016\/j.saa.2025.126383_b0165","doi-asserted-by":"crossref","first-page":"9940","DOI":"10.1002\/ange.202000940","article-title":"Principles of aggregation-induced emission: design of deactivation pathways for advanced AIEgens and applications","volume":"132","author":"Suzuki","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"key":"10.1016\/j.saa.2025.126383_b0170","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202410739","article-title":"Sergeant\u2010and-soldier effect in an organic room-temperature phosphorescent host-guest system","volume":"36","author":"Law","year":"2024","journal-title":"Adv. Mater."},{"key":"10.1016\/j.saa.2025.126383_b0175","doi-asserted-by":"crossref","first-page":"13689","DOI":"10.1021\/jacs.0c06666","article-title":"Hierarchical self-assembly of a pyrene-based discrete organoplatinum(II) double-metallacycle with triflate anions via hydrogen bonding and its tunable fluorescence emission","volume":"142","author":"Yang","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.saa.2025.126383_b0180","doi-asserted-by":"crossref","DOI":"10.1002\/adom.202300289","article-title":"Necessary and sufficient condition for organic room-temperature phosphorescence from host-guest doped crystalline systems","volume":"11","author":"Demangeat","year":"2023","journal-title":"Adv. Optical Mater."},{"key":"10.1016\/j.saa.2025.126383_b0185","doi-asserted-by":"crossref","DOI":"10.1016\/j.saa.2022.121998","article-title":"Reversible detection of Hg(II) in pure water based on thymine modified nitrogen, sulfur co-doped carbon dots combined with antidote","volume":"286","author":"Chen","year":"2023","journal-title":"Spectrochim. Acta A Mol. Biomol. Spectrosc."},{"key":"10.1016\/j.saa.2025.126383_b0190","doi-asserted-by":"crossref","first-page":"6786","DOI":"10.1002\/anie.201800119","article-title":"Reversible response of luminescent terbium(III)-nanocellulose hydrogels to anions for latent fingerprint detection and encryption","volume":"57","author":"Hai","year":"2018","journal-title":"Angew. Chem. Int. Ed."},{"key":"10.1016\/j.saa.2025.126383_b0195","doi-asserted-by":"crossref","first-page":"19767","DOI":"10.1021\/acsanm.3c03578","article-title":"Rare-earth ion-activated nanostructured fluorescent marker for easy naked eye detection and swift imaging of latent fingerprints","volume":"6","author":"Pradhan","year":"2023","journal-title":"ACS Appl. Nano Mater."},{"key":"10.1016\/j.saa.2025.126383_b0200","doi-asserted-by":"crossref","DOI":"10.1002\/adom.202001362","article-title":"Photo-responsive fluorescent materials with aggregation-induced emission characteristics","volume":"8","author":"Luo","year":"2020","journal-title":"Adv. Optical Mater."},{"key":"10.1016\/j.saa.2025.126383_b0205","doi-asserted-by":"crossref","DOI":"10.1016\/j.ccr.2023.215328","article-title":"Advances and challenges of metal ions sensors based on AIE effect","volume":"493","author":"Ye","year":"2023","journal-title":"Coord. Chem. Rev."},{"key":"10.1016\/j.saa.2025.126383_b0210","doi-asserted-by":"crossref","DOI":"10.1016\/j.dyepig.2023.111428","article-title":"Enhancing water sensing via aggregation-induced emission (AIE) and solvatofluorochromic studies using two new dansyl derivatives containing a disulfide bound: pollutant metal ions detection and preparation of water-soluble fluorescent polymeric particles","volume":"218","author":"Duarte","year":"2023","journal-title":"Dyes Pigm."},{"key":"10.1016\/j.saa.2025.126383_b0215","series-title":"Gaussian 03","author":"Frisch","year":"2004"}],"container-title":["Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1386142525006894?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1386142525006894?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,6,11]],"date-time":"2025-06-11T03:17:23Z","timestamp":1749611843000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S1386142525006894"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11]]},"references-count":43,"alternative-id":["S1386142525006894"],"URL":"https:\/\/doi.org\/10.1016\/j.saa.2025.126383","relation":{},"ISSN":["1386-1425"],"issn-type":[{"value":"1386-1425","type":"print"}],"subject":[],"published":{"date-parts":[[2025,11]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Regulating aggregation and optical properties of rigid-flexible ligand via metal coordination for multifunctional applications","name":"articletitle","label":"Article Title"},{"value":"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.saa.2025.126383","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 Elsevier B.V. All rights are reserved, including those for text and data mining, AI training, and similar technologies.","name":"copyright","label":"Copyright"}],"article-number":"126383"}}