{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,31]],"date-time":"2026-10-31T13:08:06Z","timestamp":1793452086394,"version":"4.5.0"},"reference-count":69,"publisher":"Elsevier BV","issue":"6","license":[{"start":{"date-parts":[[2025,3,1]],"date-time":"2025-03-01T00:00:00Z","timestamp":1740787200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2025,3,1]],"date-time":"2025-03-01T00:00:00Z","timestamp":1740787200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22273108"],"award-info":[{"award-number":["22273108"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22293015"],"award-info":[{"award-number":["22293015"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22121002"],"award-info":[{"award-number":["22121002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011181","name":"Institute of High Energy Physics, Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["2023000034"],"award-info":[{"award-number":["2023000034"]}],"id":[{"id":"10.13039\/501100011181","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004826","name":"Beijing Natural Science Foundation","doi-asserted-by":"publisher","award":["2222043"],"award-info":[{"award-number":["2222043"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["YSBR-050"],"award-info":[{"award-number":["YSBR-050"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Science Bulletin"],"published-print":{"date-parts":[[2025,3]]},"DOI":"10.1016\/j.scib.2024.12.052","type":"journal-article","created":{"date-parts":[[2025,1,5]],"date-time":"2025-01-05T01:36:22Z","timestamp":1736040982000},"page":"889-896","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":42,"title":["Temperature-dependent pathways in carbon dioxide electroreduction"],"prefix":"10.1016","volume":"70","author":[{"given":"Shiqiang","family":"Liu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaoyu","family":"Yin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiahao","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenling","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Zhou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huisheng","family":"Qin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiapeng","family":"Jiao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiyong","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heng\u2019an","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xing","family":"Tong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaofu","family":"Sun","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qinggong","family":"Zhu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maohong","family":"Fan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinchen","family":"Kang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Buxing","family":"Han","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.scib.2024.12.052_b0005","doi-asserted-by":"crossref","first-page":"763","DOI":"10.1038\/s41929-023-01003-5","article-title":"Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis","volume":"6","author":"Fan","year":"2023","journal-title":"Nat Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0010","doi-asserted-by":"crossref","first-page":"1386","DOI":"10.1038\/s41560-023-01389-3","article-title":"A tin-based tandem electrocatalyst for CO2 reduction to ethanol with 80% selectivity","volume":"8","author":"Ding","year":"2023","journal-title":"Nat Energy"},{"key":"10.1016\/j.scib.2024.12.052_b0015","article-title":"Research advances in electrocatalysts, electrolytes, reactors and membranes for the electrocatalytic carbon dioxide reduction reaction","volume":"39","author":"Peng","year":"2023","journal-title":"Acta Phys Chim Sin"},{"key":"10.1016\/j.scib.2024.12.052_b0020","doi-asserted-by":"crossref","first-page":"4993","DOI":"10.1039\/D0CS00071J","article-title":"Electrocatalysis for CO2 conversion: from fundamentals to value-added products","volume":"50","author":"Wang","year":"2021","journal-title":"Chem Soc Rev"},{"key":"10.1016\/j.scib.2024.12.052_b0025","first-page":"46","article-title":"Fundamental of photoelectrochemical CO2 reduction","volume":"4","author":"Jiang","year":"2024","journal-title":"Chem Synth"},{"key":"10.1016\/j.scib.2024.12.052_b0030","doi-asserted-by":"crossref","first-page":"44","DOI":"10.20517\/cs.2024.11","article-title":"Selective electroreduction of CO2 to C2+ products on cobalt decorated copper catalysts","volume":"4","author":"Soodi","year":"2024","journal-title":"Chem Synth"},{"key":"10.1016\/j.scib.2024.12.052_b0035","doi-asserted-by":"crossref","first-page":"15917","DOI":"10.1021\/jacs.4c02607","article-title":"Steering the reaction pathway of CO2 electroreduction by tuning the coordination number of copper catalysts","volume":"146","author":"Jiao","year":"2024","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0040","doi-asserted-by":"crossref","first-page":"1711","DOI":"10.1038\/s41467-024-45988-4","article-title":"Coverage enhancement accelerates acidic CO2 electrolysis at ampere-level current with high energy and carbon efficiencies","volume":"15","author":"Yu","year":"2024","journal-title":"Nat Commun"},{"key":"10.1016\/j.scib.2024.12.052_b0045","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202404574","article-title":"Reaction environment regulation for electrocatalytic CO2 reduction in acids","volume":"63","author":"Zeng","year":"2024","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2024.12.052_b0050","doi-asserted-by":"crossref","first-page":"6036","DOI":"10.1021\/acscatal.2c00087","article-title":"Selective enhancement of methane formation in electrochemical CO2 reduction enabled by a Raman-inactive oxygen-containing species on Cu","volume":"12","author":"He","year":"2022","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0055","doi-asserted-by":"crossref","first-page":"259","DOI":"10.1038\/s41929-022-00760-z","article-title":"Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses","volume":"5","author":"Timoshenko","year":"2022","journal-title":"Nat Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0060","doi-asserted-by":"crossref","first-page":"4720","DOI":"10.1039\/c3cp54822h","article-title":"Trends in electrochemical CO2 reduction activity for open and close-packed metal surfaces","volume":"16","author":"Shi","year":"2014","journal-title":"Phys Chem Chem Phys"},{"key":"10.1016\/j.scib.2024.12.052_b0065","doi-asserted-by":"crossref","first-page":"3457","DOI":"10.1021\/acscatal.3c05880","article-title":"Strong hydrogen-bonded interfacial water inhibiting hydrogen evolution kinetics to promote electrochemical CO2 reduction to C2+","volume":"14","author":"Wang","year":"2024","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0070","doi-asserted-by":"crossref","first-page":"9857","DOI":"10.1021\/jacs.3c02428","article-title":"Improving CO2-to-C2+ product electroreduction efficiency via atomic Lanthanide dopant-induced tensile-strained CuOx catalysts","volume":"145","author":"Feng","year":"2023","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0075","doi-asserted-by":"crossref","first-page":"6613","DOI":"10.1021\/jacs.2c02486","article-title":"Dynamically formed surfactant assembly at the electrified electrode\u2013electrolyte interface boosting CO2 electroreduction","volume":"144","author":"Ge","year":"2022","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0080","article-title":"Polymer modification strategy to modulate reaction microenvironment for enhanced CO2 electroreduction to ethylene","volume":"63","author":"Deng","year":"2024","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2024.12.052_b0085","doi-asserted-by":"crossref","first-page":"3676","DOI":"10.1021\/acscatal.2c06120","article-title":"Temperature-dependent electrosynthesis of C2 oxygenates from oxalic acid using gallium tin oxides","volume":"13","author":"Cheng","year":"2023","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0090","article-title":"Nickel-catalyzed switchable site-selective alkene hydroalkylation by temperature regulation","volume":"61","author":"Wang","year":"2022","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2024.12.052_b0095","article-title":"Electrocatalytic CO2 reduction to C2+ products in flow cells","volume":"36","author":"Chen","year":"2023","journal-title":"Adv Mater"},{"key":"10.1016\/j.scib.2024.12.052_b0100","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202309351","article-title":"Breaking K+ concentration limit on Cu nanoneedles for acidic electrocatalytic CO2 reduction to multi-carbon products","volume":"62","author":"Zi","year":"2023","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2024.12.052_b0105","doi-asserted-by":"crossref","first-page":"3039","DOI":"10.1021\/jacs.1c11253","article-title":"Accelerating CO2 electroreduction to multicarbon products via synergistic electric\u2013thermal field on copper nanoneedles","volume":"144","author":"Yang","year":"2022","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0110","doi-asserted-by":"crossref","first-page":"382","DOI":"10.1038\/nature19060","article-title":"Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration","volume":"537","author":"Liu","year":"2016","journal-title":"Nature"},{"key":"10.1016\/j.scib.2024.12.052_b0115","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1016\/S0022-0728(97)00438-5","article-title":"Electrochemical reduction of CO2 on Au in KOH + methanol at low temperature","volume":"441","author":"Kaneco","year":"1998","journal-title":"J Electroanal Chem"},{"key":"10.1016\/j.scib.2024.12.052_b0120","doi-asserted-by":"crossref","first-page":"573","DOI":"10.1016\/S0013-4686(98)00178-9","article-title":"Electrochemical reduction of CO2 at an Ag electrode in KOH-methanol at low temperature","volume":"44","author":"Kaneco","year":"1998","journal-title":"Electrochim Acta"},{"key":"10.1016\/j.scib.2024.12.052_b0125","doi-asserted-by":"crossref","first-page":"9346","DOI":"10.1021\/acscatal.3c01444","article-title":"Superhydrophobicity-enabled efficient electrocatalytic CO2 reduction at a high temperature","volume":"13","author":"Li","year":"2023","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0130","doi-asserted-by":"crossref","first-page":"15448","DOI":"10.1021\/acscatal.3c03797","article-title":"Selectivity of electrochemical CO2 reduction toward ethanol and ethylene: the key role of surface-active hydrogen","volume":"13","author":"Ouyang","year":"2023","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0135","doi-asserted-by":"crossref","first-page":"1795","DOI":"10.1073\/pnas.1612106114","article-title":"Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K","volume":"114","author":"Cheng","year":"2017","journal-title":"Proc Natl Acad Sci USA"},{"key":"10.1016\/j.scib.2024.12.052_b0140","doi-asserted-by":"crossref","first-page":"7282","DOI":"10.1002\/anie.201301470","article-title":"Theoretical considerations on the electroreduction of CO to C2 species on Cu(100) electrodes","volume":"52","author":"Calle-Vallejo","year":"2013","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2024.12.052_b0145","doi-asserted-by":"crossref","first-page":"26038","DOI":"10.1021\/jacs.3c06888","article-title":"Enhanced CO2 reactive capture and conversion using aminothiolate ligand-metal interface","volume":"145","author":"Wan","year":"2023","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0150","doi-asserted-by":"crossref","first-page":"26582","DOI":"10.1002\/anie.202113135","article-title":"Temperature-dependent CO2 electroreduction over Fe-N-C and Ni-N-C single-atom catalysts","volume":"60","author":"Lin","year":"2021","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2024.12.052_b0155","doi-asserted-by":"crossref","first-page":"8080","DOI":"10.1021\/acscatal.3c00706","article-title":"How temperature affects the selectivity of the electrochemical CO2 reduction on copper","volume":"13","author":"Vos","year":"2023","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0160","doi-asserted-by":"crossref","first-page":"5122","DOI":"10.1021\/acscatal.3c00311","article-title":"Highly selective reduction of CO2 to methane induced by subzero depression of the electrode surface temperature","volume":"13","author":"Jo","year":"2023","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0165","doi-asserted-by":"crossref","DOI":"10.1002\/celc.202200239","article-title":"The effect of temperature on the cation-promoted electrochemical CO2 reduction on gold","volume":"9","author":"Vos","year":"2022","journal-title":"ChemElectroChem"},{"key":"10.1016\/j.scib.2024.12.052_b0170","doi-asserted-by":"crossref","first-page":"24","DOI":"10.1016\/j.cattod.2016.09.028","article-title":"Electroreduction of CO2 on polycrystalline copper: effect of temperature on product selectivity","volume":"288","author":"Ahn","year":"2017","journal-title":"Catal Today"},{"key":"10.1016\/j.scib.2024.12.052_b0175","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","article-title":"Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set","volume":"6","author":"Kresse","year":"1996","journal-title":"Comput Mater Sci"},{"key":"10.1016\/j.scib.2024.12.052_b0180","doi-asserted-by":"crossref","first-page":"13115","DOI":"10.1103\/PhysRevB.48.13115","article-title":"Ab initio molecular dynamics for open-shell transition metals","volume":"48","author":"Kresse","year":"1993","journal-title":"Phys Rev B"},{"key":"10.1016\/j.scib.2024.12.052_b0185","doi-asserted-by":"crossref","first-page":"6671","DOI":"10.1103\/PhysRevB.46.6671","article-title":"Atoms, molecules, solids, and surfaces: applications of the generalized gradient approximation for exchange and correlation","volume":"46","author":"Perdew","year":"1992","journal-title":"Phys Rev B"},{"key":"10.1016\/j.scib.2024.12.052_b0190","doi-asserted-by":"crossref","first-page":"13244","DOI":"10.1103\/PhysRevB.45.13244","article-title":"Accurate and simple analytic representation of the electron-gas correlation energy","volume":"45","author":"Perdew","year":"1992","journal-title":"Phys Rev B"},{"key":"10.1016\/j.scib.2024.12.052_b0195","doi-asserted-by":"crossref","first-page":"17953","DOI":"10.1103\/PhysRevB.50.17953","article-title":"Projector augmented-wave method","volume":"50","author":"Bl\u00f6chl","year":"1994","journal-title":"Phys Rev B"},{"key":"10.1016\/j.scib.2024.12.052_b0200","doi-asserted-by":"crossref","first-page":"5188","DOI":"10.1103\/PhysRevB.13.5188","article-title":"Special points for Brillouin-zone integrations","volume":"13","author":"Monkhorst","year":"1976","journal-title":"Phys Rev B"},{"key":"10.1016\/j.scib.2024.12.052_b0205","doi-asserted-by":"crossref","DOI":"10.1063\/1.3382344","article-title":"Consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu","volume":"132","author":"Grimme","year":"2010","journal-title":"J Chem Phys"},{"key":"10.1016\/j.scib.2024.12.052_b0210","doi-asserted-by":"crossref","DOI":"10.1063\/1.4865107","article-title":"Implicit solvation model for density-functional study of nanocrystal surfaces and reaction pathways","volume":"140","author":"Mathew","year":"2014","journal-title":"J Chem Phys"},{"key":"10.1016\/j.scib.2024.12.052_b0215","doi-asserted-by":"crossref","first-page":"1808","DOI":"10.1002\/anie.199718081","article-title":"ELF: the electron localization function","volume":"36","author":"Savin","year":"1997","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2024.12.052_b0220","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1016\/j.cpc.2008.07.018","article-title":"Critic: a new program for the topological analysis of solid-state electron densities","volume":"180","author":"Otero-de-la-Roza","year":"2009","journal-title":"Comput Phys Commun"},{"key":"10.1016\/j.scib.2024.12.052_b0225","doi-asserted-by":"crossref","first-page":"1007","DOI":"10.1016\/j.cpc.2013.10.026","article-title":"Critic2: a program for real-space analysis of quantum chemical interactions in solids","volume":"185","author":"Otero-de-la-Roza","year":"2014","journal-title":"Comput Phys Commun"},{"key":"10.1016\/j.scib.2024.12.052_b0230","doi-asserted-by":"crossref","first-page":"8617","DOI":"10.1021\/j100135a014","article-title":"Crystal orbital Hamilton populations (COHP): energy-resolved visualization of chemical bonding in solids based on density-functional calculations","volume":"97","author":"Dronskowski","year":"1993","journal-title":"J Phys Chem"},{"key":"10.1016\/j.scib.2024.12.052_b0235","doi-asserted-by":"crossref","first-page":"1931","DOI":"10.1002\/jcc.26353","article-title":"LOBSTER: local orbital projections, atomic charges, and chemical-bonding analysis from projector-augmented-wave-based density-functional theory","volume":"41","author":"Nelson","year":"2020","journal-title":"J Comput Chem"},{"key":"10.1016\/j.scib.2024.12.052_b0240","doi-asserted-by":"crossref","first-page":"9901","DOI":"10.1063\/1.1329672","article-title":"A climbing image nudged elastic band method for finding saddle points and minimum energy paths","volume":"113","author":"Henkelman","year":"2000","journal-title":"J Chem Phys"},{"key":"10.1016\/j.scib.2024.12.052_b0245","doi-asserted-by":"crossref","first-page":"7010","DOI":"10.1063\/1.480097","article-title":"A dimer method for finding saddle points on high dimensional potential surfaces using only first derivatives","volume":"111","author":"Henkelman","year":"1999","journal-title":"J Chem Phys"},{"key":"10.1016\/j.scib.2024.12.052_b0250","doi-asserted-by":"crossref","DOI":"10.1063\/1.2815812","article-title":"Superlinearly converging dimer method for transition state search","volume":"128","author":"K\u00e4stner","year":"2008","journal-title":"J Chem Phys"},{"key":"10.1016\/j.scib.2024.12.052_b0255","doi-asserted-by":"crossref","DOI":"10.1063\/1.2408420","article-title":"Canonical sampling through velocity rescaling","volume":"126","author":"Bussi","year":"2007","journal-title":"J Chem Phys"},{"key":"10.1016\/j.scib.2024.12.052_b0260","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1063\/1.447334","article-title":"A unified formulation of the constant temperature molecular dynamics methods","volume":"81","author":"Nos\u00e9","year":"1984","journal-title":"J Chem Phys"},{"key":"10.1016\/j.scib.2024.12.052_b0265","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1038\/s41929-023-01070-8","article-title":"Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction","volume":"7","author":"Vavra","year":"2024","journal-title":"Nat Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0270","doi-asserted-by":"crossref","first-page":"6152","DOI":"10.1021\/jacs.1c00880","article-title":"Revisiting understanding of electrochemical CO2 reduction on Cu(111): competing proton-coupled electron transfer reaction mechanisms revealed by embedded correlated wavefunction theory","volume":"143","author":"Zhao","year":"2021","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0275","doi-asserted-by":"crossref","first-page":"14936","DOI":"10.1021\/jacs.2c06820","article-title":"Electrocatalytic CO2-to-C2+ with ampere-level current on heteroatom-engineered copper via tuning *CO intermediate coverage","volume":"144","author":"Zheng","year":"2022","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0280","doi-asserted-by":"crossref","first-page":"564","DOI":"10.1038\/s41929-022-00788-1","article-title":"High carbon utilization in CO2 reduction to multi-carbon products in acidic media","volume":"5","author":"Xie","year":"2022","journal-title":"Nat Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0285","doi-asserted-by":"crossref","first-page":"4591","DOI":"10.1021\/acs.jpclett.6b02513","article-title":"Both inter- and intramolecular coupling of O\u2013H groups determine the vibrational response of the water\/air interface","volume":"7","author":"Schaefer","year":"2016","journal-title":"J Phys Chem Lett"},{"key":"10.1016\/j.scib.2024.12.052_b0290","doi-asserted-by":"crossref","first-page":"5532","DOI":"10.1021\/jacs.3c13602","article-title":"Cation-induced interfacial hydrophobic microenvironment promotes the C\u2013C coupling in electrochemical CO2 reduction","volume":"146","author":"Yang","year":"2024","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0295","doi-asserted-by":"crossref","first-page":"12924","DOI":"10.1021\/acscatal.2c06115","article-title":"Theoretical insights into the effects of KOH concentration and the role of OH\u2013 in the electrocatalytic reduction of CO2 on Au","volume":"13","author":"Gorthy","year":"2023","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0300","doi-asserted-by":"crossref","first-page":"3754","DOI":"10.1038\/s41467-022-31427-9","article-title":"Boosting electrocatalytic CO2-to-ethanol production via asymmetric C-C coupling","volume":"13","author":"Wang","year":"2022","journal-title":"Nat Commun"},{"key":"10.1016\/j.scib.2024.12.052_b0305","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202207691","article-title":"V-Doped Cu2Se hierarchical nanotubes enabling flow-cell CO2 electroreduction to ethanol with high efficiency and selectivity","volume":"34","author":"Sun","year":"2022","journal-title":"Adv Mater"},{"key":"10.1016\/j.scib.2024.12.052_b0310","doi-asserted-by":"crossref","first-page":"259","DOI":"10.1021\/jacs.1c09508","article-title":"Identification of Cu(100)\/Cu(111) interfaces as superior active sites for CO dimerization during CO2 electroreduction","volume":"144","author":"Wu","year":"2022","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0315","doi-asserted-by":"crossref","first-page":"13254","DOI":"10.1021\/jacs.2c04081","article-title":"Catalyst regeneration via chemical oxidation enables long-term electrochemical carbon dioxide reduction","volume":"144","author":"Nguyen","year":"2022","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2024.12.052_b0320","doi-asserted-by":"crossref","first-page":"2387","DOI":"10.1038\/s41467-023-37898-8","article-title":"Surface hydroxide promotes CO2 electrolysis to ethylene in acidic conditions","volume":"14","author":"Cao","year":"2023","journal-title":"Nat Commun"},{"key":"10.1016\/j.scib.2024.12.052_b0325","doi-asserted-by":"crossref","first-page":"837","DOI":"10.1038\/s41929-023-01009-z","article-title":"Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions","volume":"6","author":"Amirbeigiarab","year":"2023","journal-title":"Nat Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0330","article-title":"In situ Raman spectroscopy studies for electrochemical CO2 reduction over Cu catalysts","volume":"34","author":"Li","year":"2022","journal-title":"Curr Opin Green Sustain Chem"},{"key":"10.1016\/j.scib.2024.12.052_b0335","doi-asserted-by":"crossref","first-page":"11625","DOI":"10.1021\/acscatal.3c02451","article-title":"NxC-induced switching of methane and ethylene products\u2019 selectivity from CO2 electroreduction over Cu catalyst","volume":"13","author":"Cui","year":"2023","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0340","doi-asserted-by":"crossref","first-page":"10656","DOI":"10.1021\/acscatal.9b03300","article-title":"Optimizing alkyne hydrogenation performance of Pd on carbon in situ decorated with oxygen-deficient TiO2 by integrating the reaction and diffusion","volume":"9","author":"Wei","year":"2019","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2024.12.052_b0345","doi-asserted-by":"crossref","first-page":"3264","DOI":"10.1038\/s41467-021-23582-2","article-title":"Electrokinetic and in situ spectroscopic investigations of CO electrochemical reduction on copper","volume":"12","author":"Li","year":"2021","journal-title":"Nat Commun"}],"container-title":["Science Bulletin"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2095927324009897?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2095927324009897?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T09:41:44Z","timestamp":1778838104000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S2095927324009897"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,3]]},"references-count":69,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2025,3]]}},"alternative-id":["S2095927324009897"],"URL":"https:\/\/doi.org\/10.1016\/j.scib.2024.12.052","relation":{},"ISSN":["2095-9273"],"issn-type":[{"value":"2095-9273","type":"print"}],"subject":[],"published":{"date-parts":[[2025,3]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Temperature-dependent pathways in carbon dioxide electroreduction","name":"articletitle","label":"Article Title"},{"value":"Science Bulletin","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.scib.2024.12.052","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 Science China Press. Published by Elsevier B.V. and Science China Press. All rights are reserved, including those for text and data mining, AI training, and similar technologies.","name":"copyright","label":"Copyright"}]}}