{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T21:16:53Z","timestamp":1791494213244,"version":"4.3.4"},"reference-count":38,"publisher":"Elsevier BV","issue":"6","license":[{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"}],"funder":[{"DOI":"10.13039\/501100003995","name":"Natural Science Foundation of Anhui Province","doi-asserted-by":"publisher","award":["2408085QB052"],"award-info":[{"award-number":["2408085QB052"]}],"id":[{"id":"10.13039\/501100003995","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["BX20240358"],"award-info":[{"award-number":["BX20240358"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2025M771119"],"award-info":[{"award-number":["2025M771119"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["WK9990250172"],"award-info":[{"award-number":["WK9990250172"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["WK9990000128"],"award-info":[{"award-number":["WK9990000128"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22125503"],"award-info":[{"award-number":["22125503"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52394201"],"award-info":[{"award-number":["52394201"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["223B2505"],"award-info":[{"award-number":["223B2505"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22405260"],"award-info":[{"award-number":["22405260"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22409132"],"award-info":[{"award-number":["22409132"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100009076","name":"University of Science and Technology of China","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009076","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Science Bulletin"],"published-print":{"date-parts":[[2026,3]]},"DOI":"10.1016\/j.scib.2026.02.004","type":"journal-article","created":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T00:24:31Z","timestamp":1770337471000},"page":"1397-1405","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":4,"title":["Selective CO2 photoreduction to acetate enabled by charge-enriched interface sites confined in metal nanoclusters"],"prefix":"10.1016","volume":"71","author":[{"given":"Juncheng","family":"Zhu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Hu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zijia","family":"Lin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zexun","family":"Hu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingyu","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Runhua","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Zheng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenxiu","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bangwang","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junfa","family":"Zhu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Pan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaping","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongfu","family":"Sun","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Xie","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.scib.2026.02.004_b0005","doi-asserted-by":"crossref","DOI":"10.1002\/advs.201700194","article-title":"CO2 reduction: from the electrochemical to photochemical approach","volume":"4","author":"Wu","year":"2017","journal-title":"Adv Sci"},{"key":"10.1016\/j.scib.2026.02.004_b0010","doi-asserted-by":"crossref","first-page":"2434","DOI":"10.1007\/s11426-024-2074-9","article-title":"Two-dimensional semiconductor heterostructures for photocatalytic CO2 conversion","volume":"67","author":"Wu","year":"2024","journal-title":"Sci China Chem"},{"key":"10.1016\/j.scib.2026.02.004_b0015","doi-asserted-by":"crossref","first-page":"9163","DOI":"10.1021\/jacs.3c14590","article-title":"Efficient photoreduction of CO2 to CO with 100% selectivity by slowing down electron transport","volume":"146","author":"Chen","year":"2024","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2026.02.004_b0020","doi-asserted-by":"crossref","first-page":"12142","DOI":"10.1021\/acscatal.3c02950","article-title":"Extending the \u03c0-conjugated system in conjugated microporous polymers to modulate excitonic effects for metal-free selective CO2 photoreduction to CH4","volume":"13","author":"Meng","year":"2023","journal-title":"ACS Catal"},{"key":"10.1016\/j.scib.2026.02.004_b0025","article-title":"Water-mediated selectivity control of CH3OH versus CO\/CH4 in CO2 photoreduction on single-atom implanted nanotube arrays","volume":"36","author":"Huang","year":"2024","journal-title":"Adv Mater"},{"key":"10.1016\/j.scib.2026.02.004_b0030","doi-asserted-by":"crossref","first-page":"2165","DOI":"10.1021\/acs.iecr.7b03514","article-title":"General techno-economic analysis of CO2 electrolysis systems","volume":"57","author":"Jouny","year":"2018","journal-title":"Ind Eng Chem Res"},{"key":"10.1016\/j.scib.2026.02.004_b0035","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1080\/15422119.2016.1185017","article-title":"Acetic acid production and purification: critical review towards process intensification","volume":"46","author":"Pal","year":"2017","journal-title":"Sep Purif Rev"},{"key":"10.1016\/j.scib.2026.02.004_b0040","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202208904","article-title":"Atomically dispersed indium-copper dual-metal active sites promoting C\u2212C coupling for CO2 photoreduction to ethanol","volume":"61","author":"Shi","year":"2022","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2026.02.004_b0045","doi-asserted-by":"crossref","first-page":"18233","DOI":"10.1021\/jacs.1c08033","article-title":"Asymmetric triple-atom sites confined in ternary oxide enabling selective CO2 photothermal reduction to acetate","volume":"143","author":"Zhu","year":"2021","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2026.02.004_b0050","doi-asserted-by":"crossref","first-page":"14453","DOI":"10.1021\/acsnano.1c03961","article-title":"Synergistic effect of Cu single atoms and Au-Cu alloy nanoparticles on TiO2 for efficient CO2 photoreduction","volume":"15","author":"Yu","year":"2021","journal-title":"ACS Nano"},{"key":"10.1016\/j.scib.2026.02.004_b0055","doi-asserted-by":"crossref","first-page":"766","DOI":"10.1038\/s41929-022-00839-7","article-title":"Ensemble effect for single-atom, small cluster and nanoparticle catalysts","volume":"5","author":"Guo","year":"2022","journal-title":"Nat Catal"},{"key":"10.1016\/j.scib.2026.02.004_b0060","doi-asserted-by":"crossref","DOI":"10.1016\/j.nanoen.2023.108404","article-title":"Recent progress of metal single-atom catalysts for energy applications","volume":"111","author":"Yang","year":"2023","journal-title":"Nano Energy"},{"key":"10.1016\/j.scib.2026.02.004_b0065","doi-asserted-by":"crossref","first-page":"17097","DOI":"10.1021\/jacs.2c06920","article-title":"Engineering single-atom active sites on covalent organic frameworks for boosting CO2 photoreduction","volume":"144","author":"Ran","year":"2022","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2026.02.004_b0070","doi-asserted-by":"crossref","first-page":"19414","DOI":"10.1039\/D4TA02838D","article-title":"Photocatalytic CO2 reduction to C2+ products by metal-organic framework composited with facet engineered Pd nanoparticles","volume":"12","author":"Lu","year":"2024","journal-title":"J Mater Chem A"},{"key":"10.1016\/j.scib.2026.02.004_b0075","article-title":"Single-cluster functionalized TiO2 nanotube array for boosting water oxidation and CO2 photoreduction to CH3OH","volume":"63","author":"Xu","year":"2024","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2026.02.004_b0080","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202506133","article-title":"Gram-scale green-synthesis of high purity pinacols and amides by continuous tandem photocatalysis via a negative carbon emission process","volume":"37","author":"Ma","year":"2025","journal-title":"Adv Mater"},{"key":"10.1016\/j.scib.2026.02.004_b0085","article-title":"Polyoxometalate confined synthesis of BiVO4 nanocluster for urea production with remarkable O2\/N2 tolerance","volume":"64","author":"Yao","year":"2025","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2026.02.004_b0090","doi-asserted-by":"crossref","first-page":"711","DOI":"10.1002\/smll.200901934","article-title":"Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials","volume":"6","author":"Compton","year":"2010","journal-title":"Small"},{"key":"10.1016\/j.scib.2026.02.004_b0095","doi-asserted-by":"crossref","first-page":"122","DOI":"10.1016\/j.jallcom.2017.04.286","article-title":"Nearly white light photoluminescence from ZnO\/rGO nanocomposite prepared by a one-step hydrothermal method","volume":"715","author":"Li","year":"2017","journal-title":"J Alloys Compd"},{"key":"10.1016\/j.scib.2026.02.004_b0100","doi-asserted-by":"crossref","first-page":"14622","DOI":"10.1039\/c1jm11071c","article-title":"Nano-scale chemical imaging of a single sheet of reduced graphene oxide","volume":"21","author":"Zhou","year":"2011","journal-title":"J Mater Chem"},{"key":"10.1016\/j.scib.2026.02.004_b0105","doi-asserted-by":"crossref","first-page":"543","DOI":"10.1021\/acs.jpcb.7b04609","article-title":"The effect of thickness and chemical reduction of graphene oxide on nanoscale friction","volume":"122","author":"Kwon","year":"2018","journal-title":"J Phys Chem B"},{"key":"10.1016\/j.scib.2026.02.004_b0110","doi-asserted-by":"crossref","DOI":"10.1016\/j.jhazmat.2021.126554","article-title":"Reduced graphene oxide (rGO) aerogel: efficient adsorbent for the elimination of antimony (III) and (V) from wastewater","volume":"420","author":"Nundy","year":"2021","journal-title":"J Hazard Mater"},{"key":"10.1016\/j.scib.2026.02.004_b0115","doi-asserted-by":"crossref","first-page":"869","DOI":"10.1007\/s11426-023-1792-8","article-title":"High-rate CH4-to-C2H6 photoconversion enabled by Au\/ZnO porous nanosheets under oxygen-free system","volume":"67","author":"Zheng","year":"2024","journal-title":"Sci China Chem"},{"key":"10.1016\/j.scib.2026.02.004_b0120","doi-asserted-by":"crossref","first-page":"2550","DOI":"10.1039\/C8EE00936H","article-title":"Selective CO2 reduction to C3 and C4 oxyhydrocarbons on nickel phosphides at overpotentials as low as 10 mV","volume":"11","author":"Calvinho","year":"2018","journal-title":"Energy Environ Sci"},{"key":"10.1016\/j.scib.2026.02.004_b0125","article-title":"Induced C\u2212C coupling by amorphous-crystalline hybrid structure for selective CO2 photoreduction into C2 fuels","volume":"5","author":"He","year":"2024","journal-title":"Adv Energy Mater"},{"key":"10.1016\/j.scib.2026.02.004_b0130","article-title":"3D In2S3\/C\/Fe3C nanofibers for Z-scheme photocatalytic CO2 conversion to acetate","volume":"3","author":"Liao","year":"2023","journal-title":"Mater Today Chem"},{"key":"10.1016\/j.scib.2026.02.004_b0135","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2022.138801","article-title":"Single-atom copper modified hexagonal tungsten oxide for efficient photocatalytic CO2 reduction to acetic acid","volume":"451","author":"Zeng","year":"2023","journal-title":"Chem Eng J"},{"key":"10.1016\/j.scib.2026.02.004_b0140","doi-asserted-by":"crossref","first-page":"4922","DOI":"10.1021\/acsnano.2c11977","article-title":"Selective CO2 Photoreduction to acetate at asymmetric ternary bridging sites","volume":"17","author":"Gong","year":"2023","journal-title":"ACS Nano"},{"key":"10.1016\/j.scib.2026.02.004_b0145","doi-asserted-by":"crossref","DOI":"10.1016\/j.jece.2022.107291","article-title":"Role of Cu0-TiO2 interaction in catalyst stability in CO2 photoreduction process","volume":"10","author":"Torres","year":"2022","journal-title":"J Environ Chem Eng"},{"key":"10.1016\/j.scib.2026.02.004_b0150","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202206817","article-title":"Asymmetric coupled dual-atom sites for selective photoreduction of carbon dioxide to acetic acid","volume":"32","author":"Jia","year":"2022","journal-title":"Adv Funct Mater"},{"key":"10.1016\/j.scib.2026.02.004_b0155","article-title":"Highly active photoreduction of atmospheric-concentration CO2 into CH3COOH over palladium particles on Nb2O5 nanosheets","volume":"64","author":"Ding","year":"2024","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2026.02.004_b0160","doi-asserted-by":"crossref","first-page":"6474","DOI":"10.1021\/jacs.8b03316","article-title":"Ultrathin WO3\u00b70.33H2O nanotubes for CO2 photoreduction to acetate with high selectivity","volume":"140","author":"Sun","year":"2018","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2026.02.004_b0165","doi-asserted-by":"crossref","first-page":"305","DOI":"10.1038\/s41467-023-44493-4","article-title":"One-dimensional single atom arrays on ferroelectric nanosheets for enhanced CO2 photoreduction","volume":"15","author":"Liu","year":"2024","journal-title":"Nat Commun"},{"key":"10.1016\/j.scib.2026.02.004_b0170","doi-asserted-by":"crossref","first-page":"7834","DOI":"10.1021\/jp001470i","article-title":"Mechanistic study of CO2 photoreduction in Ti silicalite molecular sieve by FT-IR spectroscopy","volume":"104","author":"Ulagappan","year":"2000","journal-title":"J Phys Chem A"},{"key":"10.1016\/j.scib.2026.02.004_b0175","doi-asserted-by":"crossref","first-page":"3621","DOI":"10.1002\/anie.201700580","article-title":"Spectroscopic observation of a hydrogenated CO dimer intermediate during CO reduction on Cu(100) electrodes","volume":"56","author":"P\u00e9rez","year":"2017","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2026.02.004_b0180","doi-asserted-by":"crossref","first-page":"6104","DOI":"10.1002\/anie.201800729","article-title":"Selective hydrogenation of CO2 to ethanol over cobalt catalysts","volume":"57","author":"Wang","year":"2018","journal-title":"Angew Chem Int Ed"},{"key":"10.1016\/j.scib.2026.02.004_b0185","doi-asserted-by":"crossref","first-page":"15664","DOI":"10.1021\/jacs.7b10462","article-title":"Direct observation on reaction intermediates and the role of bicarbonate anions in CO2 electrochemical reduction reaction on Cu surfaces","volume":"139","author":"Zhu","year":"2017","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.scib.2026.02.004_b0190","doi-asserted-by":"crossref","first-page":"7610","DOI":"10.1021\/acs.chemrev.8b00705","article-title":"Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte","volume":"119","author":"Nitopi","year":"2019","journal-title":"Chem Rev"}],"container-title":["Science Bulletin"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2095927326001507?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2095927326001507?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,6,24]],"date-time":"2026-06-24T19:40:27Z","timestamp":1782330027000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S2095927326001507"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,3]]},"references-count":38,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2026,3]]}},"alternative-id":["S2095927326001507"],"URL":"https:\/\/doi.org\/10.1016\/j.scib.2026.02.004","relation":{},"ISSN":["2095-9273"],"issn-type":[{"value":"2095-9273","type":"print"}],"subject":[],"published":{"date-parts":[[2026,3]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Selective CO2 photoreduction to acetate enabled by charge-enriched interface sites confined in metal nanoclusters","name":"articletitle","label":"Article Title"},{"value":"Science Bulletin","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.scib.2026.02.004","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2026 Science China Press. Published by Elsevier B.V. and Science China Press. All rights are reserved, including those for text and data mining, AI training, and similar technologies.","name":"copyright","label":"Copyright"}]}}