{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T11:35:02Z","timestamp":1788521702962,"version":"build-2803163510"},"reference-count":40,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2022,3,1]],"date-time":"2022-03-01T00:00:00Z","timestamp":1646092800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2022,3,1]],"date-time":"2022-03-01T00:00:00Z","timestamp":1646092800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2022,3,1]],"date-time":"2022-03-01T00:00:00Z","timestamp":1646092800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2022,3,1]],"date-time":"2022-03-01T00:00:00Z","timestamp":1646092800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2022,3,1]],"date-time":"2022-03-01T00:00:00Z","timestamp":1646092800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2022,3,1]],"date-time":"2022-03-01T00:00:00Z","timestamp":1646092800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2022,3,1]],"date-time":"2022-03-01T00:00:00Z","timestamp":1646092800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100001655","name":"German Academic Exchange Service","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001655","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004813","name":"Helmholtz-Zentrum f\u00fcr Umweltforschung","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004813","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100017177","name":"Deutscher Akademischer Austauschdienst France","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100017177","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Science of The Total Environment"],"published-print":{"date-parts":[[2022,3]]},"DOI":"10.1016\/j.scitotenv.2021.152065","type":"journal-article","created":{"date-parts":[[2021,12,8]],"date-time":"2021-12-08T10:50:47Z","timestamp":1638960647000},"page":"152065","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":7,"special_numbering":"C","title":["Borohydride and metallic copper as a robust dehalogenation system: Selectivity assessment and system optimization"],"prefix":"10.1016","volume":"810","author":[{"given":"Ali","family":"Shee","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frank-Dieter","family":"Kopinke","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katrin","family":"Mackenzie","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.scitotenv.2021.152065_bb0005","doi-asserted-by":"crossref","first-page":"5734","DOI":"10.1021\/es800330s","article-title":"Permanganate oxidation of sulfur compounds to prevent poisoning of Pd catalysts in water treatment processes","volume":"42","author":"Angeles-Wedler","year":"2008","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0010","doi-asserted-by":"crossref","first-page":"613","DOI":"10.1016\/j.apcatb.2009.04.023","article-title":"Sulphide-induced deactivation of Pd\/Al2O3 as hydrodechlorination catalyst and its oxidative regeneration with permanganate","volume":"90","author":"Angeles-Wedler","year":"2009","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0015","doi-asserted-by":"crossref","first-page":"1459","DOI":"10.1021\/jp973113m","article-title":"Photoeffects on the reduction of carbon tetrachloride by zero-valent iron","volume":"102","author":"Balko","year":"1998","journal-title":"J. Phys. Chem. B"},{"key":"10.1016\/j.scitotenv.2021.152065_bb0020","series-title":"Interaktion von Sorption und Reaktion bei der Dehalogenierung von Halogenorganischen Verbindungen in Wasser. Fakult\u00e4t f\u00fcr Verfahrensund Systemtechnik. PhD. Otto-von-Guericke-Universit\u00e4t Magdeburg, UFZ-Umweltforschungszentrum Leipzig-Halle GmbH","author":"Battke","year":"2006"},{"key":"10.1016\/j.scitotenv.2021.152065_bb0025","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1023\/A:1010354430406","article-title":"Effect of chlorine released during hydrodechlorination of chlorobenzene over Pd, Pt and Rh supported catalysts","volume":"70","author":"Benitez","year":"2000","journal-title":"React. Kinet. Catal. Lett."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0030","doi-asserted-by":"crossref","first-page":"588","DOI":"10.1016\/j.cej.2012.03.021","article-title":"Carbo-Iron\u00ae\u2014Synthesis and stabilization of Fe(0)-doped colloidal activated carbon for in situ groundwater treatment","volume":"191","author":"Bleyl","year":"2012","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0035","doi-asserted-by":"crossref","first-page":"3047","DOI":"10.1021\/es960116o","article-title":"Reductive dechlorination of tetrachloroethylene and trichloroethylene catalyzed by vitamin B12 in homogeneous and heterogeneous systems","volume":"30","author":"Burris","year":"1996","journal-title":"Environmental Science & Technology"},{"key":"10.1016\/j.scitotenv.2021.152065_bb0045","doi-asserted-by":"crossref","first-page":"756","DOI":"10.1021\/es049635e","article-title":"Influence of amine buffers on carbon tetrachloride reductive dechlorination by the iron oxide magnetite","volume":"39","author":"Danielsen","year":"2005","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0050","doi-asserted-by":"crossref","DOI":"10.1016\/j.yrtph.2020.104858","article-title":"Evaluation of the carcinogenicity of dichloromethane in rats, mice, hamsters and humans","volume":"120","author":"Dekant","year":"2021","journal-title":"Regul. Toxicol. Pharmacol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0055","doi-asserted-by":"crossref","first-page":"265","DOI":"10.1016\/j.envint.2019.01.030","article-title":"Integration of nanoscale zero-valent iron and functional anaerobic bacteria for groundwater remediation: a review","volume":"124","author":"Dong","year":"2019","journal-title":"Environ. Int."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0060","doi-asserted-by":"crossref","first-page":"2058","DOI":"10.1021\/es034741m","article-title":"Mechanisms and products of surface-mediated reductive dehalogenation of carbon tetrachloride by Fe(II) on goethite","volume":"38","author":"Elsner","year":"2004","journal-title":"Environ.Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0065","doi-asserted-by":"crossref","first-page":"1765","DOI":"10.1016\/j.chemosphere.2006.06.068","article-title":"Iron-mediated reduction rates and pathways of halogenated methanes with nanoscale Pd\/Fe: analysis of linear free energy relationship","volume":"66","author":"Feng","year":"2007","journal-title":"Chemosphere"},{"key":"10.1016\/j.scitotenv.2021.152065_bb0070","doi-asserted-by":"crossref","first-page":"1980","DOI":"10.1021\/es970784p","article-title":"Reaction of 1,1,1-trichloroethane with zero-valent metals and bimetallic reductants","volume":"32","author":"Fennelly","year":"1998","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0075","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/j.apcatb.2016.01.047","article-title":"Trichloroethene hydrodechlorination by Pd-Fe bimetallic nanoparticles: solute-induced catalyst deactivation analyzed by carbon isotope fractionation","volume":"188","author":"Han","year":"2016","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0080","doi-asserted-by":"crossref","first-page":"3254","DOI":"10.1021\/es802726v","article-title":"Highly active Pd-on-magnetite nanocatalysts for aqueous phase hydrodechlorination reactions","volume":"43","author":"Hildebrand","year":"2009","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0085","doi-asserted-by":"crossref","first-page":"2406","DOI":"10.1039\/c1em10370a","article-title":"Catalytic hydrodechlorination of 1,2-dichloroethane using copper nanoparticles under reduction conditions of sodium borohydride","volume":"13","author":"Huang","year":"2011","journal-title":"J. Environ. Monit."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0090","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1016\/j.cej.2012.07.002","article-title":"Zero-valent copper nanoparticles for effective dechlorination of dichloromethane using sodium borohydride as a reductant","volume":"203","author":"Huang","year":"2012","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0095","doi-asserted-by":"crossref","first-page":"311","DOI":"10.1016\/j.cej.2013.01.016","article-title":"Synergistic effect of zero-valent copper nanoparticles on dichloromethane degradation by vitamin B12 under reducing condition","volume":"219","author":"Huang","year":"2013","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0100","doi-asserted-by":"crossref","first-page":"413","DOI":"10.1016\/j.cej.2015.03.064","article-title":"Vitamin B12-mediated hydrodechlorination of dichloromethane by bimetallic Cu\/Al particles","volume":"273","author":"Huang","year":"2015","journal-title":"Chem. Eng. J."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0105","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1021\/es9907358","article-title":"Reductive dechlorination of trichloroethene and carbon tetrachloride using iron and palladized-iron cathodes","volume":"34","author":"Li","year":"2000","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0110","doi-asserted-by":"crossref","first-page":"1471","DOI":"10.1016\/j.chemosphere.2008.07.050","article-title":"Effects of anions on the kinetics and reactivity of nanoscale Pd\/Fe in trichlorobenzene dechlorination","volume":"73","author":"Lim","year":"2008","journal-title":"Chemosphere"},{"key":"10.1016\/j.scitotenv.2021.152065_bb0115","doi-asserted-by":"crossref","first-page":"527","DOI":"10.1016\/j.jpowsour.2008.11.032","article-title":"A review: hydrogen generation from borohydride hydrolysis reaction","volume":"187","author":"Liu","year":"2009","journal-title":"J. Power Sources"},{"key":"10.1016\/j.scitotenv.2021.152065_bb0120","doi-asserted-by":"crossref","first-page":"1905","DOI":"10.1021\/es980963m","article-title":"Hydrodehalogenation of 1- to 3-carbon halogenated organic compounds in water using a palladium catalyst and hydrogen gas","volume":"33","author":"Lowry","year":"1999","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0125","doi-asserted-by":"crossref","first-page":"3217","DOI":"10.1021\/es991416j","article-title":"Pd-catalyzed TCE dechlorination in groundwater: solute effects, biological control, and oxidative catalyst regeneration","volume":"34","author":"Lowry","year":"2000","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0130","doi-asserted-by":"crossref","first-page":"161","DOI":"10.1016\/j.apcatb.2005.10.004","article-title":"Hydrodehalogenation of halogenated hydrocarbons in water with pd catalysts: reaction rates and surface competition","volume":"63","author":"Mackenzie","year":"2006","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0135","doi-asserted-by":"crossref","first-page":"3817","DOI":"10.1016\/j.watres.2012.04.013","article-title":"Carbo-iron - an Fe\/AC composite - as alternative to nano-iron for groundwater treatment","volume":"46","author":"Mackenzie","year":"2012","journal-title":"Water Res."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0140","series-title":"Biotic and Abiotic Transformations of Alkyl Halides in Iron Reducing Environments. Health and Environmental Sciences","first-page":"281","author":"McCormick","year":"2002"},{"key":"10.1016\/j.scitotenv.2021.152065_bb0145","doi-asserted-by":"crossref","first-page":"1045","DOI":"10.1021\/es030487m","article-title":"Carbon tetrachloride transformation on the surface of nanoscale biogenic magnetite particles","volume":"38","author":"McCormick","year":"2004","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0150","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1016\/S0926-3373(99)00119-8","article-title":"Hydrodechlorination of aliphatic organochlorinated compounds over commercial hydrogenation catalysts","volume":"25","author":"Ord\u00f3\u00f1ez","year":"2000","journal-title":"Appl. Catal. B Environ."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0160","doi-asserted-by":"crossref","first-page":"9772","DOI":"10.1016\/j.ijhydene.2011.04.223","article-title":"Kinetics of hydrolysis of sodium borohydride for hydrogen production in fuel cell applications: a review","volume":"36","author":"Retnamma","year":"2011","journal-title":"Int. J. Hydrog. Energy"},{"key":"10.1016\/j.scitotenv.2021.152065_bb0165","doi-asserted-by":"crossref","first-page":"114","DOI":"10.1289\/ehp.1308030","article-title":"Human health effects of dichloromethane: key findings and scientific issues","volume":"123","author":"Schlosser","year":"2015","journal-title":"Environ. Health Perspect."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0170","doi-asserted-by":"crossref","first-page":"12403","DOI":"10.1021\/ja0055965","article-title":"Mechanistic studies on the vitamin B12-catalyzed dechlorination of chlorinated alkenes","volume":"122","author":"Shey","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0175","doi-asserted-by":"crossref","first-page":"859","DOI":"10.1246\/bcsj.78.859","article-title":"Hydrophobic vitamin B12. Part 20: supernucleophilicity of Co(I) heptamethyl cobyrinate toward various organic halides","volume":"78","author":"Shimakoshi","year":"2005","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0185","doi-asserted-by":"crossref","first-page":"6237","DOI":"10.1021\/es048262e","article-title":"Reduction of chlorinated ethanes by nanosized zero-valent iron: kinetics, pathways, and effects of reaction conditions","volume":"39","author":"Song","year":"2005","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0190","doi-asserted-by":"crossref","first-page":"272","DOI":"10.1089\/ees.2006.23.272","article-title":"Reduction of chlorinated methanes by nano-sized zero-valent iron. Kinetics, pathways, and effect of reaction conditions","volume":"23","author":"Song","year":"2006","journal-title":"Environ. Eng. Sci."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0195","doi-asserted-by":"crossref","first-page":"329","DOI":"10.1016\/S1381-1169(01)00157-1","article-title":"Hydrogenolysis of organohalogen compounds over palladium supported catalysts","volume":"173","author":"Urbano","year":"2001","journal-title":"J. Mol. Catal. A Chem."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0200","doi-asserted-by":"crossref","first-page":"4474","DOI":"10.1002\/aic.14250","article-title":"Chloroform hydrodechlorination behavior of alumina-supported pd and PdAu catalysts","volume":"59","author":"Vel\u00e1zquez","year":"2013","journal-title":"AIChE J."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0210","doi-asserted-by":"crossref","first-page":"1027","DOI":"10.1016\/j.scitotenv.2018.01.310","article-title":"Combined chemical and microbiological degradation of tetrachloroethene during the application of carbo-iron at a contaminated field site","volume":"628\u2013629","author":"Vogel","year":"2018","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0215","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1016\/0304-5102(83)80110-2","article-title":"Catalyzed reduction of organofunctional groups with sodium borohydride","volume":"18","author":"Wade","year":"1983","journal-title":"J. Mol. Catal."},{"key":"10.1016\/j.scitotenv.2021.152065_bb0220","doi-asserted-by":"crossref","first-page":"815","DOI":"10.1016\/j.jhazmat.2008.04.027","article-title":"Dechlorination of chlorinated methanes by Pd\/Fe bimetallic nanoparticles","volume":"161","author":"Wang","year":"2009","journal-title":"J. Hazard. Mater."}],"container-title":["Science of The Total Environment"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0048969721071412?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0048969721071412?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,1,21]],"date-time":"2026-01-21T22:01:08Z","timestamp":1769032868000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0048969721071412"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,3]]},"references-count":40,"alternative-id":["S0048969721071412"],"URL":"https:\/\/doi.org\/10.1016\/j.scitotenv.2021.152065","relation":{},"ISSN":["0048-9697"],"issn-type":[{"value":"0048-9697","type":"print"}],"subject":[],"published":{"date-parts":[[2022,3]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Borohydride and metallic copper as a robust dehalogenation system: Selectivity assessment and system optimization","name":"articletitle","label":"Article Title"},{"value":"Science of The Total Environment","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.scitotenv.2021.152065","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2021 Elsevier B.V. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"152065"}}