{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T09:45:04Z","timestamp":1790675104892,"version":"4.1.0"},"reference-count":98,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2025,10,3]],"date-time":"2025-10-03T00:00:00Z","timestamp":1759449600000},"content-version":"am","delay-in-days":641,"URL":"http:\/\/www.elsevier.com\/open-access\/userlicense\/1.0\/"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2024,1,1]],"date-time":"2024-01-01T00:00:00Z","timestamp":1704067200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100011605","name":"National Science Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100011605","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["EAR-2012850"],"award-info":[{"award-number":["EAR-2012850"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011027","name":"Centre for Ecology and Hydrology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100011027","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Science of The Total Environment"],"published-print":{"date-parts":[[2024,1]]},"DOI":"10.1016\/j.scitotenv.2023.167379","type":"journal-article","created":{"date-parts":[[2023,9,28]],"date-time":"2023-09-28T04:58:34Z","timestamp":1695877114000},"page":"167379","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":19,"special_numbering":"C","title":["Sampling frequency, load estimation and the disproportionate effect of storms on solute mass flux in rivers"],"prefix":"10.1016","volume":"906","author":[{"given":"Jinyu","family":"Wang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julien","family":"Bouchez","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antoine","family":"Dolant","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paul","family":"Floury","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrew J.","family":"Stumpf","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Erin","family":"Bauer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laura","family":"Keefer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00e9r\u00f4me","family":"Gaillardet","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Praveen","family":"Kumar","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jennifer L.","family":"Druhan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"issue":"3","key":"10.1016\/j.scitotenv.2023.167379_bb0005","doi-asserted-by":"crossref","first-page":"807","DOI":"10.2136\/sssaj1990.03615995005400030031x","article-title":"Soil property relationships with SPOT satellite digital data in east Central Illinois","volume":"54","author":"Agbu","year":"1990","journal-title":"Soil Sci. Soc. Am. J."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0010","doi-asserted-by":"crossref","first-page":"407","DOI":"10.1002\/2017WR021578","article-title":"Concentration-discharge responses to storm events in coastal California watersheds","volume":"54","author":"Aguilera","year":"2018","journal-title":"Water Resour. Res."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0015","author":"Angel"},{"issue":"23","key":"10.1016\/j.scitotenv.2023.167379_bb0020","doi-asserted-by":"crossref","DOI":"10.1029\/2010GL045168","article-title":"Nutrient loads exported from managed catchments reveal emergent biogeochemical stationarity","volume":"37","author":"Basu","year":"2010","journal-title":"Geophys. Res. Lett."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0025","series-title":"The Soil Hydrology of the Plynlimon Catchments","author":"Bell","year":"2005"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0030","doi-asserted-by":"crossref","first-page":"333","DOI":"10.1016\/j.jhydrol.2015.02.036","article-title":"Seasonal variation in phosphorus concentration\u2013discharge hysteresis inferred from high-frequency in situ monitoring","volume":"524","author":"Bieroza","year":"2015","journal-title":"J. Hydrol."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0035","doi-asserted-by":"crossref","first-page":"738","DOI":"10.1016\/j.scitotenv.2018.02.256","article-title":"The concentration-discharge slope as a tool for water quality management","volume":"630","author":"Bieroza","year":"2018","journal-title":"Sci. Total Environ."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0040","first-page":"19","article-title":"N, P and Si retention along the aquatic continuum from land to ocean","volume":"1","author":"Billen","year":"1991","journal-title":"Ocean Margin Process. Glob. Chang."},{"issue":"8","key":"10.1016\/j.scitotenv.2023.167379_bb0045","doi-asserted-by":"crossref","DOI":"10.1029\/2019WR026695","article-title":"Depth of solute generation is a dominant control on concentration-discharge relations","volume":"56","author":"Botter","year":"2020","journal-title":"Water Resour. Res."},{"issue":"3","key":"10.1016\/j.scitotenv.2023.167379_bb0050","doi-asserted-by":"crossref","first-page":"345","DOI":"10.5194\/hess-8-345-2004","article-title":"Anatomy of a catchment: the relation of physical attributes of the Plynlimon catchments to variations in hydrology and water status","volume":"8","author":"Brandt","year":"2004","journal-title":"Hydrol. Earth Syst. Sci."},{"issue":"2","key":"10.1016\/j.scitotenv.2023.167379_bb0055","doi-asserted-by":"crossref","DOI":"10.1029\/2021WR030507","article-title":"Antecedent conditions control thresholds of tile-runoff generation and nitrogen export in intensively managed landscapes","volume":"58","author":"Cain","year":"2022","journal-title":"Water Resour. Res."},{"issue":"11","key":"10.1016\/j.scitotenv.2023.167379_bb0060","doi-asserted-by":"crossref","first-page":"2477","DOI":"10.1002\/hyp.13742","article-title":"Sensitivity of nitrate concentration-discharge patterns to soil nitrate distribution and drainage properties in the vertical dimension","volume":"34","author":"Chen","year":"2020","journal-title":"Hydrol. Process."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0065","author":"Cochran"},{"issue":"8","key":"10.1016\/j.scitotenv.2023.167379_bb0070","doi-asserted-by":"crossref","DOI":"10.1002\/eap.2447","article-title":"Concentration-discharge relationships derived from a larger regional dataset as a tool for watershed management","volume":"31","author":"D\u2019Amario","year":"2021","journal-title":"Ecol. Appl."},{"issue":"G1","key":"10.1016\/j.scitotenv.2023.167379_bb0075","doi-asserted-by":"crossref","DOI":"10.1029\/2011JG001782","article-title":"Phosphorus export across an urban to rural gradient in the Chesapeake Bay watershed","volume":"117","author":"Duan","year":"2012","journal-title":"J. Geophys. Res. Biogeo."},{"issue":"2","key":"10.1016\/j.scitotenv.2023.167379_bb0080","doi-asserted-by":"crossref","DOI":"10.1371\/journal.pone.0188889","article-title":"Identification of long-term trends and seasonality in high-frequency water quality data from the Yangtze River basin, China","volume":"13","author":"Duan","year":"2018","journal-title":"PloS One"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0085","series-title":"Managing Soil pH and Crop Nutrients","author":"Fern\u00e1ndez","year":"2009"},{"issue":"5","key":"10.1016\/j.scitotenv.2023.167379_bb0090","doi-asserted-by":"crossref","DOI":"10.1029\/2021JG006660","article-title":"Resiliency of silica export signatures when low order streams are subject to storm events","volume":"127","author":"Fernandez","year":"2022","journal-title":"J. Geophys. Res. Biogeosci."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0095","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/j.scitotenv.2006.12.016","article-title":"Modeling nitrate fluxes at the catchment scale using the integrated tool CAWAQS","volume":"375","author":"Flipo","year":"2007","journal-title":"Sci. Total Environ."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0100","doi-asserted-by":"crossref","first-page":"241","DOI":"10.1016\/j.envpol.2006.03.056","article-title":"Assessment of nitrate pollution in the Grand Morin aquifers (France): combined use of geostatistics and physically based modeling","volume":"146","author":"Flipo","year":"2007","journal-title":"Environ. Pollut."},{"issue":"12","key":"10.1016\/j.scitotenv.2023.167379_bb0105","doi-asserted-by":"crossref","first-page":"6153","DOI":"10.5194\/hess-21-6153-2017","article-title":"The potamochemical symphony: new progress in the high-frequency acquisition of stream chemical data","volume":"21","author":"Floury","year":"2017","journal-title":"Hydrol. Earth Syst. Sci."},{"issue":"2","key":"10.1016\/j.scitotenv.2023.167379_bb0110","doi-asserted-by":"crossref","first-page":"195","DOI":"10.1002\/hyp.13340","article-title":"Chemical weathering and CO2 consumption rate in a multilayered-aquifer dominated watershed under intensive farming: the Orgeval critical zone observatory, France","volume":"33","author":"Floury","year":"2018","journal-title":"Hydrol. Process."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0115","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1016\/S0009-2541(99)00031-5","article-title":"Global silicate weathering and CO2 consumption rates deduced from the chemistry of large rivers","volume":"159","author":"Gaillardet","year":"1999","journal-title":"Chem. Geol."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0120","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1016\/j.jenvman.2014.04.030","article-title":"Curative vs. preventive management of nitrogen transfers in rural areas: lessons from the case of the Orgeval watershed (Seine River basin, France)","volume":"144","author":"Garnier","year":"2014","journal-title":"J. Environ. Manage."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0125","doi-asserted-by":"crossref","first-page":"76","DOI":"10.1016\/j.envsci.2016.04.019","article-title":"Reconnecting crop and cattle farming to reduce nitrogen losses to river water of an intensive agricultural catchment (seine basin, France): past, present and future","volume":"63","author":"Garnier","year":"2016","journal-title":"Environ. Sci. Policy"},{"issue":"13","key":"10.1016\/j.scitotenv.2023.167379_bb0130","doi-asserted-by":"crossref","first-page":"1844","DOI":"10.1002\/hyp.7315","article-title":"Concentration\u2013discharge relationships reflect chemostatic characteristics of US catchments","volume":"23","author":"Godsey","year":"2009","journal-title":"Hydrol. Process."},{"issue":"24","key":"10.1016\/j.scitotenv.2023.167379_bb0135","doi-asserted-by":"crossref","first-page":"3056","DOI":"10.1002\/hyp.13554","article-title":"Catchment chemostasis revisited: water quality responds differently to variations in weather and climate","volume":"33","author":"Godsey","year":"2019","journal-title":"Hydrol. Process."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0140","doi-asserted-by":"crossref","DOI":"10.1016\/j.epsl.2022.117773","article-title":"Subsurface weathering signatures in stream chemistry during an intense storm","volume":"595","author":"Golla","year":"2022","journal-title":"Earth Planet. Sci. Lett."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0145","series-title":"1967\u20132016\u2014Celebrating 50 Years of Geoscience in the Mid-Continent. Guidebook for the 50th Annual Meeting of the Geological Society of America\u2013North-Central Section, April 18\u201319, 2016: Illinois State Geological Survey, Guidebook","first-page":"55","article-title":"Quaternary geology of the Upper Sangamon River Basin: glacial, postglacial, and postsettlement history","volume":"43","author":"Grimley","year":"2016"},{"issue":"12","key":"10.1016\/j.scitotenv.2023.167379_bb0150","doi-asserted-by":"crossref","first-page":"8013","DOI":"10.5194\/bg-10-8013-2013","article-title":"Upland streamwater nitrate dynamics across decadal to sub-daily timescales: a case study of Plynlimon, Wales","volume":"10","author":"Halliday","year":"2013","journal-title":"Biogeosciences"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0155","doi-asserted-by":"crossref","first-page":"23","DOI":"10.1016\/j.proeps.2014.08.005","article-title":"A brief overview of the Global River chemistry database, GLORICH","volume":"10","author":"Hartmann","year":"2014","journal-title":"Procedia Earth Planet. Sci."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0160","doi-asserted-by":"crossref","first-page":"88","DOI":"10.5194\/hess-8-88-2004","article-title":"Temporal variability in phosphorus transfers: classifying concentration\u2013discharge event dynamics","volume":"8","author":"Haygarth","year":"2004","journal-title":"Hydrol. Earth Syst. Sci."},{"issue":"9","key":"10.1016\/j.scitotenv.2023.167379_bb0165","doi-asserted-by":"crossref","DOI":"10.1002\/hyp.14700","article-title":"Pulses within pulses: concentration-discharge relationships across temporal scales in a snowmelt-dominated Rocky Mountain catchment","volume":"36","author":"Hensley","year":"2022","journal-title":"Hydrol. Process."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0170","doi-asserted-by":"crossref","DOI":"10.5400\/jts.2012.v17i1.85-95","article-title":"Relationship between concentration and discharge on storm events: case study at Cakardipa catchment, Cisukabirus subwatershed, upper Ciliwung watershed, Bogor, West Java","volume":"17","author":"Heryani","year":"2020","journal-title":"J. Trop. Soils"},{"issue":"5","key":"10.1016\/j.scitotenv.2023.167379_bb0175","doi-asserted-by":"crossref","first-page":"857","DOI":"10.1111\/j.1752-1688.2010.00482.x","article-title":"Weighted regressions on time, discharge, and season (WRTDS), with an application to Chesapeake Bay river inputs 1","volume":"46","author":"Hirsch","year":"2010","journal-title":"J. Am. Water Resour. Assoc."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0180","series-title":"Assessment of Water Quality and Discharge in the Herring River, Wellfleet, Massachusetts, November 2015 to September 2017","first-page":"59","article-title":"Assessment of water quality and discharge in the Herring River, Wellfleet, Massachusetts, November 2015 to September 2017","volume":"Vols. 2020\u20135120","author":"Huntington","year":"2021"},{"issue":"G2","key":"10.1016\/j.scitotenv.2023.167379_bb0185","doi-asserted-by":"crossref","DOI":"10.1029\/2006JG000309","article-title":"Storm event exports of dissolved organic nitrogen (DON) across multiple catchments in a glaciated forested watershed","volume":"112","author":"Inamdar","year":"2007","journal-title":"J. Geophys. Res. Biogeo."},{"issue":"16","key":"10.1016\/j.scitotenv.2023.167379_bb0190","doi-asserted-by":"crossref","first-page":"3423","DOI":"10.1002\/hyp.6141","article-title":"The impact of storm events on solute exports from a glaciated forested watershed in western New York, USA","volume":"20","author":"Inamdar","year":"2006","journal-title":"Hydrol. Process."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0195","author":"Keefer"},{"issue":"5","key":"10.1016\/j.scitotenv.2023.167379_bb0200","doi-asserted-by":"crossref","first-page":"661","DOI":"10.1016\/j.apgeochem.2010.01.020","article-title":"Using chloride and other ions to trace sewage and road salt in the Illinois waterway","volume":"25","author":"Kelly","year":"2010","journal-title":"Appl. Geochem."},{"issue":"2","key":"10.1016\/j.scitotenv.2023.167379_bb0205","doi-asserted-by":"crossref","first-page":"1424","DOI":"10.1002\/2016WR019722","article-title":"Controls on solute concentration-discharge relationships revealed by simultaneous hydrochemistry observations of hillslope runoff and stream flow: the importance of critical zone structure","volume":"53","author":"Kim","year":"2017","journal-title":"Water Resour. Res."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0210","series-title":"Plynlimon Research: The First Two Decades","author":"Kirby","year":"1991"},{"issue":"30","key":"10.1016\/j.scitotenv.2023.167379_bb0215","doi-asserted-by":"crossref","first-page":"12213","DOI":"10.1073\/pnas.1304328110","article-title":"Universal fractal scaling in stream chemistry and its implications for solute transport and water quality trend detection","volume":"110","author":"Kirchner","year":"2013","journal-title":"Proc. Natl. Acad. Sci."},{"issue":"7","key":"10.1016\/j.scitotenv.2023.167379_bb0220","doi-asserted-by":"crossref","first-page":"1353","DOI":"10.1002\/hyp.5537","article-title":"The fine structure of water-quality dynamics: the (high-frequency) wave of the future","volume":"18","author":"Kirchner","year":"2004","journal-title":"Hydrol. Process."},{"issue":"5","key":"10.1016\/j.scitotenv.2023.167379_bb0225","doi-asserted-by":"crossref","first-page":"2561","DOI":"10.5194\/hess-24-2561-2020","article-title":"Concentration\u2013discharge relationships vary among hydrological events, reflecting differences in event characteristics","volume":"24","author":"Knapp","year":"2020","journal-title":"Hydrol. Earth Syst. Sci."},{"issue":"7","key":"10.1016\/j.scitotenv.2023.167379_bb0230","doi-asserted-by":"crossref","first-page":"2377","DOI":"10.5194\/hess-15-2377-2011","article-title":"Stream recession curves and storage variability in small watersheds","volume":"15","author":"Krakauer","year":"2011","journal-title":"Hydrol. Earth Syst. Sci."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0235","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/j.ancene.2018.04.002","article-title":"Critical transition in critical zone of intensively managed landscapes","volume":"22","author":"Kumar","year":"2018","journal-title":"Anthropocene"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0240","series-title":"Computational Intelligence","first-page":"265","article-title":"Hydraulic head interpolation in an aquifer unit using ANFIS and ordinary kriging","author":"Kurtulus","year":"2011"},{"issue":"1\u20132","key":"10.1016\/j.scitotenv.2023.167379_bb0245","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1080\/04353676.1993.11880379","article-title":"A rainfall intensity-duration threshold for landslides in a humid-tropical environment, Puerto Rico","volume":"75","author":"Larsen","year":"1993","journal-title":"Geogr. Ann. Ser. B"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0250","series-title":"An Evaluation of Methods for Computing Annual Water-quality Loads","first-page":"1","author":"Lee","year":"2019"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0255","doi-asserted-by":"crossref","first-page":"879","DOI":"10.1016\/j.ecolind.2018.11.057","article-title":"Evaluation of concentration-discharge dynamics and nitrogen export on anthropogenic inputs and stormflow across alternative time-scales","volume":"98","author":"Li","year":"2019","journal-title":"Ecol. Indic."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0260","doi-asserted-by":"crossref","DOI":"10.1016\/j.geoderma.2020.114239","article-title":"A new dynamic wetness index (DWI) predicts soil moisture persistence and correlates with key indicators of surface soil geochemistry","volume":"368","author":"Li","year":"2020","journal-title":"Geoderma"},{"issue":"3","key":"10.1016\/j.scitotenv.2023.167379_bb0265","doi-asserted-by":"crossref","DOI":"10.3390\/w12030862","article-title":"Climatic variabilities control the solute dynamics of monsoon Karstic River: approaches from C-Q relationship, isotopes, and model analysis in the Liujiang River","volume":"12","author":"Liu","year":"2020","journal-title":"Water"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0270","doi-asserted-by":"crossref","first-page":"388","DOI":"10.1016\/j.scitotenv.2015.11.028","article-title":"Using hysteresis analysis of high-resolution water quality monitoring data, including uncertainty, to infer controls on nutrient and sediment transfer in catchments","volume":"543","author":"Lloyd","year":"2016","journal-title":"Sci. Total Environ."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0275","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/j.jhydrol.2010.05.034","article-title":"Influence of antecedent hydrologic conditions on patterns of hydrochemical export from a first-order agricultural watershed in southern Ontario, Canada","volume":"389","author":"Macrae","year":"2010","journal-title":"J. Hydrol."},{"issue":"16","key":"10.1016\/j.scitotenv.2023.167379_bb0280","doi-asserted-by":"crossref","DOI":"10.1029\/2020GL087051","article-title":"Is the river a chemostat?: Scale versus land use controls on nitrate concentration-discharge dynamics in the Upper Mississippi River Basin","volume":"47","author":"Marinos","year":"2020","journal-title":"Geophys. Res. Lett."},{"issue":"5","key":"10.1016\/j.scitotenv.2023.167379_bb0285","doi-asserted-by":"crossref","first-page":"1155","DOI":"10.1007\/s10457-016-0053-6","article-title":"Identifying barriers and motivators for adoption of multifunctional perennial cropping systems by landowners in the Upper Sangamon River Watershed, Illinois","volume":"92","author":"Mattia","year":"2018","journal-title":"Agrofor. Syst."},{"issue":"4","key":"10.1016\/j.scitotenv.2023.167379_bb0290","doi-asserted-by":"crossref","first-page":"301","DOI":"10.1007\/s10021-003-0161-9","article-title":"Biogeochemical hot spots and hot moments at the interface of terrestrial and aquatic ecosystems","volume":"6","author":"McClain","year":"2003","journal-title":"Ecosystems"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0295","series-title":"Nitrate and Total Phosphorus Loads in Illinois Rivers: Update Through the 2017 Water Year","author":"McIsaac","year":"2019"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0300","series-title":"Hydrog\u00e9ologie de la Beauce (France). Bulletin: Hydrog\u00e9ologie, g\u00e9ologie de l'ing\u00e9nieur. Section III","first-page":"191","author":"M\u00e9gnien","year":"1973"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0305","series-title":"Atmospheric Inputs and River Transport of Dissolved Substances","author":"Meybeck","year":"1983"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0310","doi-asserted-by":"crossref","DOI":"10.1016\/j.advwatres.2019.103379","article-title":"Seasonal and event-based concentration-discharge relationships to identify catchment controls on nutrient export regimes","volume":"131","author":"Minaudo","year":"2019","journal-title":"Adv. Water Resour."},{"issue":"2","key":"10.1016\/j.scitotenv.2023.167379_bb0315","doi-asserted-by":"crossref","first-page":"1270","DOI":"10.1002\/2016WR019635","article-title":"Elemental properties, hydrology, and biology interact to shape concentration-discharge curves for carbon, nutrients, sediment, and major ions","volume":"53","author":"Moatar","year":"2017","journal-title":"Water Resour. Res."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0320","doi-asserted-by":"crossref","DOI":"10.3389\/fevo.2019.00516","article-title":"Stream solutes and particulates export regimes: a new framework to optimize their monitoring","volume":"7","author":"Moatar","year":"2020","journal-title":"Front. Ecol. Evol."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0325","series-title":"Caract\u00e9risation de la g\u00e9ochimie des interfaces nappe-rivi\u00e8re du bassin des Avenelles in Fonctionnement hydrog\u00e9ophysique des interfaces nappe-rivi\u00e8re et cons\u00e9quences sur la ressource en eau","author":"Mouchel","year":"2016"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0330","doi-asserted-by":"crossref","first-page":"194","DOI":"10.1016\/j.jhydrol.2013.09.036","article-title":"Designing a multi-scale sampling system of stream\u2013aquifer interfaces in a sedimentary basin","volume":"504","author":"Mouhri","year":"2013","journal-title":"J. Hydrol."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0335","doi-asserted-by":"crossref","first-page":"133","DOI":"10.1016\/j.advwatres.2015.09.026","article-title":"Catchment controls on solute export","volume":"86","author":"Musolff","year":"2015","journal-title":"Adv. Water Resour."},{"issue":"10","key":"10.1016\/j.scitotenv.2023.167379_bb0340","doi-asserted-by":"crossref","DOI":"10.1029\/2020WR029442","article-title":"Spatial and temporal variability in concentration-discharge relationships at the event scale","volume":"57","author":"Musolff","year":"2021","journal-title":"Water Resour. Res."},{"issue":"2","key":"10.1016\/j.scitotenv.2023.167379_bb0345","doi-asserted-by":"crossref","first-page":"295","DOI":"10.5194\/hess-4-295-2000","article-title":"Sodium and chloride levels in rainfall, mist, streamwater and groundwater at the Plynlimon catchments, mid-Wales: inferences on hydrological and chemical controls","volume":"4","author":"Neal","year":"2000","journal-title":"Hydrol. Earth Syst. Sci."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0350","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1016\/0022-1694(90)90226-N","article-title":"Acid neutralization capacity variations for the Hafren forest stream, mid-Wales: inferences for hydrological processes","volume":"121","author":"Neal","year":"1990","journal-title":"J. Hydrol."},{"issue":"3","key":"10.1016\/j.scitotenv.2023.167379_bb0355","doi-asserted-by":"crossref","first-page":"583","DOI":"10.5194\/hess-1-583-1997","article-title":"The hydrochemistry of the headwaters of the River Severn, Plynlimon","volume":"1","author":"Neal","year":"1997","journal-title":"Hydrol. Earth Syst. Sci."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0360","doi-asserted-by":"crossref","first-page":"174","DOI":"10.1016\/j.jhydrol.2008.06.027","article-title":"Sources and fate of nitrate in the Illinois River Basin, Illinois","volume":"359","author":"Panno","year":"2008","journal-title":"J. Hydrol."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0365","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1007\/s10533-010-9416-7","article-title":"Event controlled DOC export from forested watersheds","volume":"100","author":"Raymond","year":"2010","journal-title":"Biogeochemistry"},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0370","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1007\/BF00279585","article-title":"Impact of afforestation on the soil solution chemistry of stagnopodzols in mid-Wales","volume":"38","author":"Reynolds","year":"1988","journal-title":"Water Air Soil Pollut."},{"issue":"12","key":"10.1016\/j.scitotenv.2023.167379_bb0375","doi-asserted-by":"crossref","DOI":"10.1002\/hyp.14455","article-title":"Stormflow concentration\u2013discharge dynamics of suspended sediment and dissolved phosphorus in an agricultural watershed","volume":"35","author":"Rose","year":"2021","journal-title":"Hydrol. Process."},{"issue":"18","key":"10.1016\/j.scitotenv.2023.167379_bb0380","doi-asserted-by":"crossref","first-page":"2829","DOI":"10.1002\/hyp.13235","article-title":"Concentration\u2013discharge relationships describe solute and sediment mobilization, reaction, and transport at event and longer timescales","volume":"32","author":"Rose","year":"2018","journal-title":"Hydrol. Process."},{"issue":"5","key":"10.1016\/j.scitotenv.2023.167379_bb0385","doi-asserted-by":"crossref","first-page":"612","DOI":"10.1016\/j.ecoleng.2008.12.035","article-title":"Nutrient retention function of a stream wetland complex\u2014a high-frequency monitoring approach","volume":"36","author":"R\u00fccker","year":"2010","journal-title":"Ecol. Eng."},{"issue":"7","key":"10.1016\/j.scitotenv.2023.167379_bb0390","doi-asserted-by":"crossref","first-page":"5276","DOI":"10.1002\/2016WR019708","article-title":"Concentration-discharge relationships during an extreme event: contrasting behavior of solutes and changes to chemical quality of dissolved organic material in the Boulder Creek watershed during the September 2013 flood","volume":"53","author":"Rue","year":"2017","journal-title":"Water Resour. Res."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0395","series-title":"Load estimator (LOADEST): A FORTRAN Program for Estimating Constituent Loads in Streams and Rivers","article-title":"Load estimator (LOADEST): a FORTRAN program for estimating constituent loads in streams and rivers","volume":"Vols. 4-A5","author":"Runkel","year":"2004"},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0400","doi-asserted-by":"crossref","DOI":"10.1029\/2021WR029931","article-title":"Streams as mirrors: reading subsurface water chemistry from stream chemistry","volume":"58","author":"Stewart","year":"2022","journal-title":"Water Resour. Res."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0405","author":"Stumpf"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0410","series-title":"Observatoire Oracle (Version 2015) [ASCII]","author":"Tallec","year":"2015"},{"issue":"10","key":"10.1016\/j.scitotenv.2023.167379_bb0415","doi-asserted-by":"crossref","DOI":"10.1029\/2010WR009605","article-title":"Relative dominance of hydrologic versus biogeochemical factors on solute export across impact gradients","volume":"47","author":"Thompson","year":"2011","journal-title":"Water Resour. Res."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0420","series-title":"USGS Water Data for the Nation","author":"U.S. Geological Survey","year":"2017"},{"issue":"7","key":"10.1016\/j.scitotenv.2023.167379_bb0425","doi-asserted-by":"crossref","first-page":"5345","DOI":"10.1002\/2017WR020491","article-title":"High-frequency dissolved organic carbon and nitrate measurements reveal differences in storm hysteresis and loading in relation to land cover and seasonality","volume":"53","author":"Vaughan","year":"2017","journal-title":"Water Resour. Res."},{"issue":"13","key":"10.1016\/j.scitotenv.2023.167379_bb0430","doi-asserted-by":"crossref","first-page":"1821","DOI":"10.1002\/hyp.7627","article-title":"Impact of precipitation characteristics on soil hydrology in tile-drained landscapes","volume":"24","author":"Vidon","year":"2010","journal-title":"Hydrol. Process."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0435","doi-asserted-by":"crossref","first-page":"34","DOI":"10.1016\/j.jhydrol.2009.07.013","article-title":"Seasonal solute dynamics across land uses during storms in glaciated landscape of the US Midwest","volume":"376","author":"Vidon","year":"2009","journal-title":"J. Hydrol."},{"issue":"9","key":"10.1016\/j.scitotenv.2023.167379_bb0440","doi-asserted-by":"crossref","first-page":"1192","DOI":"10.1016\/j.agrformet.2010.05.004","article-title":"Effect of slope position and land use on nitrous oxide (N2O) emissions (Seine Basin, France)","volume":"150","author":"Vilain","year":"2010","journal-title":"Agric. For. Meteorol."},{"issue":"3","key":"10.1016\/j.scitotenv.2023.167379_bb0445","doi-asserted-by":"crossref","first-page":"1085","DOI":"10.5194\/bg-9-1085-2012","article-title":"Budget of N2O emissions at the watershed scale: role of land cover and topography (the Orgeval basin, France)","volume":"9","author":"Vilain","year":"2012","journal-title":"Biogeosciences"},{"issue":"3","key":"10.1016\/j.scitotenv.2023.167379_bb0450","doi-asserted-by":"crossref","first-page":"1721","DOI":"10.5194\/hess-21-1721-2017","article-title":"A lab in the field: high-frequency analysis of water quality and stable isotopes in stream water and precipitation","volume":"21","author":"von Freyberg","year":"2017","journal-title":"Hydrol. Earth Syst. Sci."},{"issue":"3","key":"10.1016\/j.scitotenv.2023.167379_bb0455","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1016\/j.jhydrol.2008.08.013","article-title":"Stream nitrate and DOC dynamics during three spring storms across land uses in glaciated landscapes of the Midwest","volume":"362","author":"Wagner","year":"2008","journal-title":"J. Hydrol."},{"key":"10.1016\/j.scitotenv.2023.167379_bb0460","doi-asserted-by":"crossref","first-page":"749","DOI":"10.1016\/j.jhydrol.2018.02.079","article-title":"Controls of event-based nutrient transport within nested headwater agricultural watersheds of the western Lake Erie basin","volume":"559","author":"Williams","year":"2018","journal-title":"J. Hydrol."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0465","doi-asserted-by":"crossref","DOI":"10.2136\/vzj2018.04.0088","article-title":"The intensively managed landscape critical zone observatory: a scientific testbed for understanding critical zone processes in agroecosystems","volume":"17","author":"Wilson","year":"2018","journal-title":"Vadose Zone J."},{"issue":"1","key":"10.1016\/j.scitotenv.2023.167379_bb0470","doi-asserted-by":"crossref","DOI":"10.1029\/2020WR027992","article-title":"Disentangling the impact of catchment heterogeneity on nitrate export dynamics from event to long-term time scales","volume":"57","author":"Winter","year":"2021","journal-title":"Water Resour. Res."},{"issue":"18","key":"10.1016\/j.scitotenv.2023.167379_bb0475","doi-asserted-by":"crossref","DOI":"10.1029\/2012GL052785","article-title":"Dissolved organic matter export from a forested watershed during Hurricane Irene","volume":"39","author":"Yoon","year":"2012","journal-title":"Geophys. Res. Lett."},{"issue":"3","key":"10.1016\/j.scitotenv.2023.167379_bb0480","doi-asserted-by":"crossref","first-page":"443","DOI":"10.1007\/s10533-019-00546-9","article-title":"Understanding how estuarine hydrology controls ammonium and other inorganic nitrogen concentrations and fluxes through a subtropical estuary, Southeast China under normal and flood-affected conditions","volume":"142","author":"Yu","year":"2019","journal-title":"Biogeochemistry"},{"key":"10.1016\/j.scitotenv.2023.167379_bb0485","doi-asserted-by":"crossref","first-page":"1268","DOI":"10.1016\/j.scitotenv.2017.09.221","article-title":"Synthesis of nutrient and sediment export patterns in the Chesapeake Bay watershed: complex and non-stationary concentration-discharge relationships","volume":"618","author":"Zhang","year":"2018","journal-title":"Sci. Total Environ."},{"issue":"2","key":"10.1016\/j.scitotenv.2023.167379_bb0490","doi-asserted-by":"crossref","DOI":"10.1029\/2022GL101177","article-title":"Reconstruction of sparse stream flow and concentration time-series through compressed sensing","volume":"50","author":"Zhang","year":"2023","journal-title":"Geophys. Res. Lett."}],"container-title":["Science of The Total Environment"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0048969723060060?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0048969723060060?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T17:30:12Z","timestamp":1790184612000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0048969723060060"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,1]]},"references-count":98,"alternative-id":["S0048969723060060"],"URL":"https:\/\/doi.org\/10.1016\/j.scitotenv.2023.167379","relation":{},"ISSN":["0048-9697"],"issn-type":[{"value":"0048-9697","type":"print"}],"subject":[],"published":{"date-parts":[[2024,1]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Sampling frequency, load estimation and the disproportionate effect of storms on solute mass flux in rivers","name":"articletitle","label":"Article Title"},{"value":"Science of The Total Environment","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.scitotenv.2023.167379","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2023 Elsevier B.V. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"167379"}}