{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,26]],"date-time":"2026-06-26T04:34:26Z","timestamp":1782448466648,"version":"3.54.5"},"reference-count":42,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2024,3,1]],"date-time":"2024-03-01T00:00:00Z","timestamp":1709251200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2024,3,1]],"date-time":"2024-03-01T00:00:00Z","timestamp":1709251200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2024,3,1]],"date-time":"2024-03-01T00:00:00Z","timestamp":1709251200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2024,3,1]],"date-time":"2024-03-01T00:00:00Z","timestamp":1709251200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2024,3,1]],"date-time":"2024-03-01T00:00:00Z","timestamp":1709251200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2024,3,1]],"date-time":"2024-03-01T00:00:00Z","timestamp":1709251200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2024,3,1]],"date-time":"2024-03-01T00:00:00Z","timestamp":1709251200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100002322","name":"CAPES","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","doi-asserted-by":"publisher","award":["PQ1C 304018\/2020-1"],"award-info":[{"award-number":["PQ1C 304018\/2020-1"]}],"id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Separation and Purification Technology"],"published-print":{"date-parts":[[2024,3]]},"DOI":"10.1016\/j.seppur.2023.125757","type":"journal-article","created":{"date-parts":[[2023,11,20]],"date-time":"2023-11-20T15:34:42Z","timestamp":1700494482000},"page":"125757","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":21,"special_numbering":"C","title":["Selective solvent extraction of nickel and cobalt from a Ni lateritic sulfuric solution using synergism caused by LIX860N-IC and Versatic 10"],"prefix":"10.1016","volume":"332","author":[{"given":"Alexandre Silva","family":"Guimar\u00e3es","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Georgio Patr\u00edcio","family":"de Souza Resende","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Iranildes Daniel","family":"dos Santos","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcelo Borges","family":"Mansur","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.seppur.2023.125757_b0005","series-title":"Standard potentials in aqueous solution","author":"Bard","year":"1985"},{"issue":"3\u20134","key":"10.1016\/j.seppur.2023.125757_b0010","doi-asserted-by":"crossref","first-page":"245","DOI":"10.1016\/j.hydromet.2011.07.010","article-title":"The effect of temperature on hydroxyoxime stability in the LIX 63-Versatic 10-tributyl phosphate synergistic solvent extraction system under synthetic nickel laterite conditions","volume":"109","author":"Barnard","year":"2011","journal-title":"Hydrometall."},{"key":"10.1016\/j.seppur.2023.125757_b0015","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.mineng.2015.01.015","article-title":"Recovery of nickel and cobalt from leach solutions of nickel laterites using a synergistic system consisting of Versatic 10 and Acorga CLX 50","volume":"77","author":"Cheng","year":"2015","journal-title":"Miner. Eng."},{"issue":"1","key":"10.1016\/j.seppur.2023.125757_b0020","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1016\/j.hydromet.2010.04.009","article-title":"Recovery of nickel and cobalt from laterite leach solutions using direct solvent extraction: Part 1 - selection of a synergistic SX system","volume":"104","author":"Cheng","year":"2010","journal-title":"Hydrometall."},{"issue":"1\u20132","key":"10.1016\/j.seppur.2023.125757_b0025","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/j.hydromet.2006.05.002","article-title":"Solvent extraction of nickel and cobalt with synergistic systems consisting of carboxylic acid and aliphatic hydroxyoxime","volume":"84","author":"Cheng","year":"2006","journal-title":"Hydrometall."},{"issue":"12","key":"10.1016\/j.seppur.2023.125757_b0030","doi-asserted-by":"crossref","first-page":"1234","DOI":"10.1016\/j.mineng.2006.03.003","article-title":"Direct solvent extraction of nickel at Bulong operations","volume":"19","author":"Donegan","year":"2006","journal-title":"Miner. Eng."},{"issue":"3","key":"10.1016\/j.seppur.2023.125757_b0035","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1021\/ar50111a005","article-title":"Chemical kinetics and mechanisms in solvent extraction of copper chelates","volume":"10","author":"Flett","year":"1977","journal-title":"Acc. Chem. Res."},{"key":"10.1016\/j.seppur.2023.125757_b0040","doi-asserted-by":"crossref","unstructured":"A.S. Guimar\u00e3es, G.P.S. Resende, I.D. Santos, Y.M. Vera, M.B. Mansur, Evaluating cationic extractant systems containing Versatic 10 on the solvent extraction of metals from a Ni lateritic sulfuric solution. Sep. Purif. Technol., 328 (2024) 125060. 10.1016j.seppur.2023.125060.","DOI":"10.1016\/j.seppur.2023.125060"},{"key":"10.1016\/j.seppur.2023.125757_b0045","unstructured":"A.S. Guimar\u00e3es, G.P.S. Resende, I.D. Santos, M.B. Mansur, Development of a conceptual direct solvent extraction route to produce purified concentrated cobalt and nickel solutions from a Ni lateritic sulfuric solution, Hydrometallurgy, submitted for publication."},{"key":"10.1016\/j.seppur.2023.125757_b0050","doi-asserted-by":"crossref","DOI":"10.1016\/j.mineng.2022.107684","article-title":"Removal of Mg and Ca from Ni-rich sulphate solutions by solvent extraction using cationic and neutral extractants","volume":"185","author":"Guimar\u00e3es","year":"2022","journal-title":"Miner. Eng."},{"key":"10.1016\/j.seppur.2023.125757_b0055","doi-asserted-by":"crossref","DOI":"10.1016\/j.seppur.2020.116570","article-title":"Purification of concentrated nickel sulfuric liquors via synergistic solvent extraction of calcium and magnesium using mixtures of D2EHPA and Cyanex 272","volume":"239","author":"Guimar\u00e3es","year":"2020","journal-title":"Sep. Purif. Technol."},{"key":"10.1016\/j.seppur.2023.125757_b0060","doi-asserted-by":"crossref","first-page":"250","DOI":"10.1016\/j.hydromet.2017.12.001","article-title":"Selection of a synergistic solvent extraction system to selectively remove calcium and magnesium from concentrate nickel sulfate solutions","volume":"175","author":"Guimar\u00e3es","year":"2018","journal-title":"Hydrometall."},{"key":"10.1016\/j.seppur.2023.125757_b0065","doi-asserted-by":"crossref","first-page":"91","DOI":"10.1016\/j.hydromet.2017.08.005","article-title":"Solvent extraction of calcium and magnesium from concentrate nickel sulfate solutions using D2EHPA and Cyanex 272 extractants","volume":"173","author":"Guimar\u00e3es","year":"2017","journal-title":"Hydrometall."},{"key":"10.1016\/j.seppur.2023.125757_b0070","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1016\/j.hydromet.2014.10.005","article-title":"Purification of nickel from multicomponent aqueous sulfuric solutions by synergistic solvent extraction using Cyanex 272 and Versatic 10","volume":"150","author":"Guimar\u00e3es","year":"2014","journal-title":"Hydrometall."},{"key":"10.1016\/j.seppur.2023.125757_b0075","doi-asserted-by":"crossref","first-page":"222","DOI":"10.1016\/j.hydromet.2010.10.003","article-title":"Selective precipitation of mixed nickel-cobalt hydroxide","volume":"105","author":"Harvey","year":"2011","journal-title":"Hydrometall."},{"key":"10.1016\/j.seppur.2023.125757_b0080","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1016\/j.mineng.2015.02.010","article-title":"Reagent selection for recovery of nickel and cobalt from nitric acid nickel laterite leach solutions by solvent extraction","volume":"77","author":"Hutton-Ashkenny","year":"2015","journal-title":"Miner. Eng."},{"key":"10.1016\/j.seppur.2023.125757_b0085","unstructured":"G.L. Hubred, R.N. Kust, D.L. Natwig, J.P. Pemsler, Cobalt stripping process, US patent n\u00b0 4083915, 1978. https:\/\/patentimages.storage.googleapis.com\/bc\/ef\/39\/b4f0e5d5fcc3a0\/US4083915.pdf."},{"key":"10.1016\/j.seppur.2023.125757_b0090","series-title":"Vogel\u2019s textbook of quantitative chemical analysis","author":"Jeffrery","year":"1989"},{"key":"10.1016\/j.seppur.2023.125757_b0095","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1016\/j.hydromet.2015.10.012","article-title":"Selective extraction and separation of nickel from cobalt, manganese and lithium in pre-treated leach liquors of ternary cathode material of spent lithium-ion batteries using synergism caused by Versatic 10 and LIX 84-I","volume":"159","author":"Joo","year":"2016","journal-title":"Hydrometall."},{"issue":"12","key":"10.1016\/j.seppur.2023.125757_b0100","doi-asserted-by":"crossref","first-page":"2593","DOI":"10.1351\/pac198254122593","article-title":"Critical evaluation of some equilibrium constants involving acidic organophosphorous extractants","volume":"54","author":"Kolarik","year":"1982","journal-title":"Pure Appl. Chem."},{"key":"10.1016\/j.seppur.2023.125757_b0105","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1016\/j.hydromet.2017.01.001","article-title":"Solvent extraction process for the recovery of nickel and cobalt from Caldag laterite leach solution: The first bench scale study","volume":"169","author":"Kursunoglu","year":"2017","journal-title":"Hydrometall."},{"key":"10.1016\/j.seppur.2023.125757_b0110","doi-asserted-by":"crossref","first-page":"1220","DOI":"10.1016\/j.mineng.2006.01.003","article-title":"The recovery of nickel from high-pressure acid leach solutions using mixed hydroxide product \u2500 LIX84INS technology","volume":"19","author":"Mackenzie","year":"2006","journal-title":"Miner. Eng."},{"issue":"17","key":"10.1016\/j.seppur.2023.125757_b0115","doi-asserted-by":"crossref","first-page":"4068","DOI":"10.1021\/ie020883y","article-title":"Reactive extraction of zinc sulfate with bis(2-ethylhexyl)phosphoric acid in a short K\u00fchni column used in batch mode","volume":"42","author":"Mansur","year":"2003","journal-title":"Ind. Eng. Chem. Res."},{"key":"10.1016\/j.seppur.2023.125757_b0120","first-page":"124","article-title":"The development of a novel hydrometallurgical process for nickel and cobalt recovery from Goro laterite ore","volume":"93","author":"Mihaylov","year":"2000","journal-title":"Conference on Mining Millennium"},{"key":"10.1016\/j.seppur.2023.125757_b0125","unstructured":"J. Narbutt, Effects of hydration and solvation of metal complexes on separations of metal ions by solvent extraction, in: Proc. of International Solvent Extraction Conference (ISEC 2008), volume II, 1035-1042, 2008. http:\/\/www.solventextract.org\/documents\/2008\/ISEC-2008-Proceedings.pdf."},{"key":"10.1016\/j.seppur.2023.125757_b0130","doi-asserted-by":"crossref","first-page":"1235","DOI":"10.1016\/0022-1902(75)80475-1","article-title":"Alpha-substituted oxime extractants \u2014 I. Extraction of Cu(II), Ni(II), Co(II) and Fe(III) by aliphatic alphahydroxyoximes","volume":"37","author":"Preston","year":"1975","journal-title":"J. Inorg. Nucl. Chem."},{"key":"10.1016\/j.seppur.2023.125757_b0135","doi-asserted-by":"crossref","first-page":"2187","DOI":"10.1016\/0022-1902(75)80475-1","article-title":"\u03b1-substituted oxime extractants \u2014 II. Extraction of Cu(II), Ni(II), Co(II) and Fe(III) by aliphatic \u03b1-hydroxyoximes and \u03b1-dioximes","volume":"37","author":"Preston","year":"1975","journal-title":"J. Inorg. Nucl. Chem."},{"key":"10.1016\/j.seppur.2023.125757_b0140","doi-asserted-by":"crossref","first-page":"1739","DOI":"10.1007\/s11663-021-02141-6","article-title":"Roasting and leaching behavior of nickel laterite ore","volume":"52","author":"Ribeiro","year":"2021","journal-title":"Metallurgical and Materials Transaction B"},{"key":"10.1016\/j.seppur.2023.125757_b0145","series-title":"Solvent extraction - Principles and applications to process metallurgy","author":"Ritcey","year":"2006"},{"key":"10.1016\/j.seppur.2023.125757_b0150","doi-asserted-by":"crossref","first-page":"259","DOI":"10.1016\/j.hydromet.2015.06.010","article-title":"Selective removal of calcium from sulfate solutions containing magnesium and nickel using aqueous two-phase systems (ATPS)","volume":"156","author":"Santos","year":"2015","journal-title":"Hydrometall."},{"issue":"1","key":"10.1016\/j.seppur.2023.125757_b0155","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1080\/08827508.2020.1809392","article-title":"Iron precipitation strategies from nickel laterite ore sulfuric acid leach liquor","volume":"43","author":"Silva","year":"2022","journal-title":"Mineral Processes and Extractive Metallurgy Review"},{"key":"10.1016\/j.seppur.2023.125757_b0160","article-title":"Nickel hydroxide precipitation from aqueous sulfate media","volume":"42\u201346","author":"Sist","year":"2003","journal-title":"Journal of Minerals, Metals & Materials Society"},{"key":"10.1016\/j.seppur.2023.125757_b0165","unstructured":"K. Sole, P. Cole, Purification of nickel by solvent extraction, in: Y. Marcus, A.K. Sengupta, J.A. Marinsky (eds.) Ion Exchange and Solvent Extraction, vol. 15, Marcel Dekker, Inc., 2003, 2002, 143-195. ISBN: 0-8247-0601-3."},{"issue":"5","key":"10.1016\/j.seppur.2023.125757_b0170","doi-asserted-by":"crossref","first-page":"783","DOI":"10.1080\/07366299308918186","article-title":"An assessment of the long-term stabilities of Cyanex 302 and Cyanex 301 in sulfuric and nitric acids","volume":"11","author":"Sole","year":"1993","journal-title":"Solvent Extr. Ion Exch."},{"key":"10.1016\/j.seppur.2023.125757_b0175","first-page":"167","article-title":"Laterites - has the time finally come?","volume":"172","author":"Taylor","year":"1995","journal-title":"Min. Mag."},{"key":"10.1016\/j.seppur.2023.125757_b0180","unstructured":"A. Vahed, D.F. Colton, J-P. Duterque, W. Karner, Development of a fluid bed pyrohydrolysis process for Inco's Goro nickel project, in: Conference TMS Annual Meeting, Charlotte, USA, 2004."},{"key":"10.1016\/j.seppur.2023.125757_b0185","doi-asserted-by":"crossref","first-page":"88","DOI":"10.1016\/j.ces.2017.05.003","article-title":"Modeling the phase equilibrium in liquid-liquid extraction of copper over a wide range of copper and hydroxyoximes extractant concentrations","volume":"171","author":"Vasilyev","year":"2017","journal-title":"Chem. Eng. Sci."},{"key":"10.1016\/j.seppur.2023.125757_b0190","doi-asserted-by":"crossref","first-page":"527","DOI":"10.1080\/08827500008914177","article-title":"Pressure acid leaching of nickel laterites: a review","volume":"6","author":"Whittington","year":"2000","journal-title":"Miner. Process. Extr. Metall. Rev."},{"key":"10.1016\/j.seppur.2023.125757_b0195","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1016\/j.hydromet.2013.05.015","article-title":"Selective leaching of nickel from mixed nickel cobalt hydroxide precipitate","volume":"138","author":"Williams","year":"2013","journal-title":"Hydrometall."},{"issue":"1","key":"10.1016\/j.seppur.2023.125757_b0200","doi-asserted-by":"crossref","first-page":"32","DOI":"10.1515\/nbec-2015-0011","article-title":"Selective recovery of copper from solutions after bioleaching electronic waste","volume":"14","author":"Willner","year":"2015","journal-title":"Nova Biotechnol. Et Chim."},{"key":"10.1016\/j.seppur.2023.125757_b0205","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/j.hydromet.2012.02.012","article-title":"Extraction and separation of nickel and cobalt with hydroxamic acids LIX\u00ae1104, LIX\u00ae1104SM and the mixture of LIX\u00ae1104 and Versatic 10","volume":"119\u2013120","author":"Zhang","year":"2012","journal-title":"Hydrometall."},{"key":"10.1016\/j.seppur.2023.125757_b0210","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.hydromet.2012.07.001","article-title":"Separation and recovery of copper, nickel, cobalt and zinc in chloride solutions by synergistic solvent extraction","volume":"127\u2013128","author":"Zhu","year":"2012","journal-title":"Hydrometall."}],"container-title":["Separation and Purification Technology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1383586623026655?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S1383586623026655?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T17:40:24Z","timestamp":1778607624000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S1383586623026655"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,3]]},"references-count":42,"alternative-id":["S1383586623026655"],"URL":"https:\/\/doi.org\/10.1016\/j.seppur.2023.125757","relation":{},"ISSN":["1383-5866"],"issn-type":[{"value":"1383-5866","type":"print"}],"subject":[],"published":{"date-parts":[[2024,3]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Selective solvent extraction of nickel and cobalt from a Ni lateritic sulfuric solution using synergism caused by LIX860N-IC and Versatic 10","name":"articletitle","label":"Article Title"},{"value":"Separation and Purification Technology","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.seppur.2023.125757","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2023 Elsevier B.V. All rights reserved.","name":"copyright","label":"Copyright"}],"article-number":"125757"}}