{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T02:53:30Z","timestamp":1790132010009,"version":"4.0.1"},"reference-count":40,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"},{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-017"},{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-012"},{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-004"}],"funder":[{"DOI":"10.13039\/501100013699","name":"Austrian Federal Ministry of Education Science and Research","doi-asserted-by":"publisher","award":["HR13\/2024"],"award-info":[{"award-number":["HR13\/2024"]}],"id":[{"id":"10.13039\/501100013699","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004488","name":"Croatian Science Foundation","doi-asserted-by":"publisher","award":["IP-2024-05-8924"],"award-info":[{"award-number":["IP-2024-05-8924"]}],"id":[{"id":"10.13039\/501100004488","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100015526","name":"Ministarstvo znanosti i obrazovanja","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100015526","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Talanta"],"published-print":{"date-parts":[[2026,3]]},"DOI":"10.1016\/j.talanta.2025.129103","type":"journal-article","created":{"date-parts":[[2025,11,7]],"date-time":"2025-11-07T16:54:46Z","timestamp":1762534486000},"page":"129103","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":2,"special_numbering":"C","title":["Matrix effects in MeV SIMS for modern pigment\u2013binder systems: The influence of binder composition on SOP secondary molecular ion yield"],"prefix":"10.1016","volume":"299","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5118-217X","authenticated-orcid":false,"given":"Matea","family":"Krmpoti\u0107","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dubravka","family":"Jembrih-Simb\u00fcrger","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-0215-1784","authenticated-orcid":false,"given":"Teodora","family":"Raicu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4100-736X","authenticated-orcid":false,"given":"Iva","family":"Bogdanovi\u0107 Radovi\u0107","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2216-8643","authenticated-orcid":false,"given":"Matija","family":"Matijevi\u0107","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7358-8090","authenticated-orcid":false,"given":"Zdravko","family":"Siketi\u0107","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.talanta.2025.129103_bib1","series-title":"Analysis of Modern Paints","author":"Learner","year":"2004"},{"key":"10.1016\/j.talanta.2025.129103_bib2","doi-asserted-by":"crossref","DOI":"10.1016\/j.microc.2020.104919","article-title":"A simple multi-analytical approach for the detection of oxidative and biological degradation of polymers in contemporary artworks","volume":"157","author":"Macro","year":"2020","journal-title":"Microchem. J."},{"key":"10.1016\/j.talanta.2025.129103_bib3","doi-asserted-by":"crossref","first-page":"1499","DOI":"10.1039\/C4AY02365J","article-title":"Study of modern artistic materials using combined spectroscopic and chromatographic techniques. Case study: painting with the signature \u201cpicasso\u201d","volume":"7","author":"L\u00f3pez-Ram\u00edrez","year":"2015","journal-title":"Anal. Methods"},{"key":"10.1016\/j.talanta.2025.129103_bib4","doi-asserted-by":"crossref","first-page":"155","DOI":"10.1016\/j.microc.2018.02.029","article-title":"Spectroscopic methods for the identification and photostability study of red synthetic organic pigments in alkyd and acrylic paints","volume":"139","author":"Anghelone","year":"2018","journal-title":"Microchem. J."},{"key":"10.1016\/j.talanta.2025.129103_bib5","doi-asserted-by":"crossref","DOI":"10.1016\/j.microc.2021.106708","article-title":"Analytical approaches for the characterization of early synthetic organic pigments for artists' paints","volume":"170","author":"Sundberg","year":"2021","journal-title":"Microchem. J."},{"key":"10.1016\/j.talanta.2025.129103_bib6","doi-asserted-by":"crossref","first-page":"1415","DOI":"10.1007\/s00216-014-8370-y","article-title":"Py-GC\/MS applied to the analysis of synthetic organic pigments: characterization and identification in paint samples","volume":"407","author":"Ghelardi","year":"2015","journal-title":"Anal. Bioanal. Chem."},{"key":"10.1016\/j.talanta.2025.129103_bib7","doi-asserted-by":"crossref","first-page":"6957","DOI":"10.1007\/s00216-016-9862-8","article-title":"Revealing the composition of organic materials in polychrome works of art: the role of mass spectrometry-based techniques","volume":"408","author":"Calvano","year":"2016","journal-title":"Anal. Bioanal. Chem."},{"key":"10.1016\/j.talanta.2025.129103_bib8","doi-asserted-by":"crossref","first-page":"16","DOI":"10.1186\/s40494-021-00641-x","article-title":"The emergence of Liu Kang's new painting style (1950\u20131958): a multi-analytical approach for the study of the artist's painting materials and technique","volume":"10","author":"Lizun","year":"2022","journal-title":"Herit. Sci."},{"issue":"10","key":"10.1016\/j.talanta.2025.129103_bib9","doi-asserted-by":"crossref","first-page":"1729","DOI":"10.1007\/s13361-011-0171-3","article-title":"Identification of different copper green pigments in Renaissance paintings by Cluster-TOF-SIMS imaging analysis","volume":"22","author":"Richardin","year":"2011","journal-title":"J. Am. Soc. Mass Spectrom."},{"issue":"3","key":"10.1016\/j.talanta.2025.129103_bib10","doi-asserted-by":"crossref","first-page":"753","DOI":"10.1021\/ac1017748","article-title":"Unexpected materials in a rembrandt painting characterized by high spatial resolution Cluster-TOF-SIMS imaging","volume":"83","author":"Sanyova","year":"2011","journal-title":"Anal. Chem."},{"issue":"38","key":"10.1016\/j.talanta.2025.129103_bib11","first-page":"39573","article-title":"Beyond artists' colors: a spectral reference database for the identification of \u03b2-Naphthol and triarylcarbonium colorants by MeV SIMS","volume":"9","author":"Raicu","year":"2024","journal-title":"ACS Omega"},{"issue":"13","key":"10.1016\/j.talanta.2025.129103_bib12","doi-asserted-by":"crossref","first-page":"9287","DOI":"10.1021\/acs.analchem.0c01630","article-title":"Identification of synthetic organic pigments (SOPs) used in modern artist's paints with secondary ion mass spectrometry with MeV ions","volume":"92","author":"Krmpoti\u0107","year":"2020","journal-title":"Anal. Chem."},{"key":"10.1016\/j.talanta.2025.129103_bib13","doi-asserted-by":"crossref","DOI":"10.1016\/j.polymdegradstab.2021.109769","article-title":"Study of UV ageing effects in modern artists' paints with MeV-SIMS","volume":"195","author":"Krmpoti\u0107","year":"2022","journal-title":"Polym. Degrad. Stabil."},{"issue":"20","key":"10.1016\/j.talanta.2025.129103_bib14","doi-asserted-by":"crossref","first-page":"12997","DOI":"10.1021\/acs.analchem.9b03058","article-title":"Determination of deposition order of toners, inkjet inks, and blue ballpoint pen combining MeV-Secondary ion mass spectrometry and particle induced X-ray emission","volume":"91","author":"Moore","year":"2019","journal-title":"Anal. Chem."},{"key":"10.1016\/j.talanta.2025.129103_bib15","doi-asserted-by":"crossref","DOI":"10.1016\/j.ijms.2022.116983","article-title":"Cationization of organic molecules under keV and MeV primary ion bombardment","volume":"484","author":"Jen\u010di\u010d","year":"2023","journal-title":"Int. J. Mass Spectrom."},{"key":"10.1016\/j.talanta.2025.129103_bib16","series-title":"Pigment Handbook, Volume 3: Characterization and Physical Relationships","year":"1973"},{"key":"10.1016\/j.talanta.2025.129103_bib17","doi-asserted-by":"crossref","first-page":"832","DOI":"10.1063\/1.90546","article-title":"Mechanism of the SIMS matrix effect","volume":"33","author":"Deline","year":"1978","journal-title":"Appl. Phys. Lett."},{"key":"10.1016\/j.talanta.2025.129103_bib18","doi-asserted-by":"crossref","first-page":"1156","DOI":"10.1039\/C9JA00428A","article-title":"The matrix effect in TOF-SIMS analysis of two-element inorganic thin films","volume":"35","author":"Priebe","year":"2020","journal-title":"J. Anal. At. Spectrom."},{"key":"10.1016\/j.talanta.2025.129103_bib19","doi-asserted-by":"crossref","first-page":"599","DOI":"10.1016\/j.ijms.2014.06.027","article-title":"The matrix effect in organic secondary ion mass spectrometry","volume":"377","author":"Shard","year":"2015","journal-title":"Int. J. Mass Spectrom."},{"issue":"12","key":"10.1016\/j.talanta.2025.129103_bib20","doi-asserted-by":"crossref","first-page":"1111","DOI":"10.1002\/sia.2121","article-title":"Reduction of matrix effects in TOF-SIMS analysis by metal-assisted SIMS (MetA-SIMS)","volume":"37","author":"Inoue","year":"2005","journal-title":"Surf. Interface Anal."},{"issue":"10","key":"10.1016\/j.talanta.2025.129103_bib21","doi-asserted-by":"crossref","first-page":"2358","DOI":"10.1021\/jasms.3c00237","article-title":"Gold-assisted molecular imaging of organic tissue by MeV secondary ion mass spectrometry","volume":"34","author":"Jen\u010di\u010d","year":"2023","journal-title":"J. Am. Soc. Mass Spectrom."},{"issue":"8","key":"10.1016\/j.talanta.2025.129103_bib22","doi-asserted-by":"crossref","first-page":"1017","DOI":"10.1002\/rcm.1881","article-title":"Matrix\u2010enhanced secondary ion mass spectrometry: the influence of MALDI matrices on molecular ion yields of thin organic films","volume":"19","author":"Adriaensen","year":"2005","journal-title":"Rapid Commun. Mass Spectrom."},{"issue":"10","key":"10.1016\/j.talanta.2025.129103_bib23","doi-asserted-by":"crossref","first-page":"2211","DOI":"10.1021\/jasms.3c00173","article-title":"Matrix-enhanced SIMS: the influence of primary ion species and cluster size on ion yield and ion yield enhancement of lipids","volume":"34","author":"Adolphs","year":"2023","journal-title":"J. Am. Soc. Mass Spectrom."},{"issue":"21","key":"10.1016\/j.talanta.2025.129103_bib24","doi-asserted-by":"crossref","first-page":"8308","DOI":"10.1021\/ac202222h","article-title":"High-reactivity matrices increase the sensitivity of matrix enhanced secondary ion mass spectrometry","volume":"83","author":"Svara","year":"2011","journal-title":"Anal. Chem."},{"issue":"1\u20132","key":"10.1016\/j.talanta.2025.129103_bib25","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1016\/0042-207X(84)90111-8","article-title":"A comparison of SIMS with other techniques based on ion-beam solid interactions","volume":"34","author":"Werner","year":"1984","journal-title":"Vacuum"},{"issue":"22","key":"10.1016\/j.talanta.2025.129103_bib26","doi-asserted-by":"crossref","first-page":"1962","DOI":"10.1002\/rcm.8265","article-title":"The influence of polyatomic primary ion chemistry on matrix effects in secondary ion mass spectrometry analysis","volume":"32","author":"Alnajeebi","year":"2018","journal-title":"Rapid Commun. Mass Spectrom."},{"issue":"12","key":"10.1016\/j.talanta.2025.129103_bib27","doi-asserted-by":"crossref","first-page":"2014","DOI":"10.1007\/s13361-016-1492-z","article-title":"Reducing the matrix effect in organic cluster SIMS using dynamic reactive ionization","volume":"27","author":"Tian","year":"2016","journal-title":"J. Am. Soc. Mass Spectrom."},{"issue":"12","key":"10.1016\/j.talanta.2025.129103_bib28","doi-asserted-by":"crossref","first-page":"5654","DOI":"10.1021\/ac4013732","article-title":"Enhancing secondary ion yields in time of flight-secondary ion mass spectrometry using water cluster primary beams","volume":"85","author":"Sheraz n\u00e9e Rabbani","year":"2013","journal-title":"Anal. Chem."},{"issue":"36","key":"10.1016\/j.talanta.2025.129103_bib29","doi-asserted-by":"crossref","first-page":"19705","DOI":"10.1021\/acs.jpcc.7b02596","article-title":"Reducing the matrix effect in molecular secondary ion mass spectrometry by laser post-ionization","volume":"121","author":"Breuer","year":"2017","journal-title":"J. Phys. Chem. C"},{"key":"10.1016\/j.talanta.2025.129103_bib30","doi-asserted-by":"crossref","first-page":"234","DOI":"10.1016\/j.nimb.2014.02.068","article-title":"Development of a TOF SIMS setup at the Zagreb heavy ion microbeam facility","volume":"332","author":"Tadi\u0107","year":"2014","journal-title":"Nucl. Instrum. Methods Phys. Res. B"},{"key":"10.1016\/j.talanta.2025.129103_bib31","doi-asserted-by":"crossref","first-page":"122","DOI":"10.1016\/j.nimb.2019.05.047","article-title":"Data acquisition and control system for an evolving nuclear microprobe","volume":"451","author":"Cosic","year":"2019","journal-title":"Nucl. Instrum. Methods Phys. Res. B"},{"issue":"6","key":"10.1016\/j.talanta.2025.129103_bib32","doi-asserted-by":"crossref","first-page":"905","DOI":"10.1002\/rcm.3444","article-title":"mMass data miner: an open source alternative for mass spectrometric data analysis","volume":"22","author":"Strohalm","year":"2008","journal-title":"Rapid Commun. Mass Spectrom."},{"issue":"8","key":"10.1016\/j.talanta.2025.129103_bib33","doi-asserted-by":"crossref","first-page":"3045","DOI":"10.1021\/ac7025892","article-title":"Effective path length in attenuated total reflection spectroscopy","volume":"80","author":"Averett","year":"2008","journal-title":"Anal. Chem."},{"key":"10.1016\/j.talanta.2025.129103_bib34","doi-asserted-by":"crossref","first-page":"96","DOI":"10.1080\/01410096.2000.9995156","article-title":"A review of synthetic binding media in twentieth\u2010century paints","volume":"24","author":"Learner","year":"2000","journal-title":"Conservator"},{"key":"10.1016\/j.talanta.2025.129103_bib35","series-title":"Issues in Contemporary Oil Paint","year":"2014"},{"key":"10.1016\/j.talanta.2025.129103_bib36","doi-asserted-by":"crossref","first-page":"100","DOI":"10.1016\/j.saa.2016.04.026","article-title":"Determination of early warning signs for photocatalytic degradation of titanium white oil paints by means of surface analysis","volume":"172","author":"van Driel","year":"2017","journal-title":"Spectrochim. Acta"},{"issue":"11","key":"10.1016\/j.talanta.2025.129103_bib37","doi-asserted-by":"crossref","first-page":"10169","DOI":"10.1021\/acsami.7b00638","article-title":"Investigating the photocatalytic degradation of oil paint using ATR-IR and AFM-IR","volume":"9","author":"Morsch","year":"2017","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"10.1016\/j.talanta.2025.129103_bib38","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1016\/j.polymdegradstab.2016.10.007","article-title":"Influence of phthalocyanine pigments on the photo-degradation of alkyd artists' paints under different conditions of artificial solar radiation","volume":"134","author":"Anghelone","year":"2016","journal-title":"Polym. Degrad. Stabil."},{"key":"10.1016\/j.talanta.2025.129103_bib39","doi-asserted-by":"crossref","first-page":"870","DOI":"10.1016\/j.apsusc.2015.12.162","article-title":"Surface analysis characterisation of gum binders used in modern watercolour paints","volume":"364","author":"Sano","year":"2016","journal-title":"Appl. Surf. Sci."},{"issue":"7","key":"10.1016\/j.talanta.2025.129103_bib40","doi-asserted-by":"crossref","first-page":"1518","DOI":"10.1021\/jasms.0c00080","article-title":"Dependence of megaelectron volt time-of-flight secondary ion mass spectrometry secondary molecular ion yield from phthalocyanine blue on primary ion stopping power","volume":"31","author":"Brajkovi\u0107","year":"2020","journal-title":"J. Am. Soc. Mass Spectrom."}],"container-title":["Talanta"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0039914025015942?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0039914025015942?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2026,3,12]],"date-time":"2026-03-12T13:59:59Z","timestamp":1773323999000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0039914025015942"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,3]]},"references-count":40,"alternative-id":["S0039914025015942"],"URL":"https:\/\/doi.org\/10.1016\/j.talanta.2025.129103","relation":{},"ISSN":["0039-9140"],"issn-type":[{"value":"0039-9140","type":"print"}],"subject":[],"published":{"date-parts":[[2026,3]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Matrix effects in MeV SIMS for modern pigment\u2013binder systems: The influence of binder composition on SOP secondary molecular ion yield","name":"articletitle","label":"Article Title"},{"value":"Talanta","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.talanta.2025.129103","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2025 Elsevier B.V. All rights are reserved, including those for text and data mining, AI training, and similar technologies.","name":"copyright","label":"Copyright"}],"article-number":"129103"}}