{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T18:29:24Z","timestamp":1791138564002,"version":"4.1.0"},"reference-count":50,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2015,3,1]],"date-time":"2015-03-01T00:00:00Z","timestamp":1425168000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"}],"funder":[{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche (France)","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Water Research"],"published-print":{"date-parts":[[2015,3]]},"DOI":"10.1016\/j.watres.2014.12.007","type":"journal-article","created":{"date-parts":[[2014,12,12]],"date-time":"2014-12-12T03:50:00Z","timestamp":1418356200000},"page":"266-278","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":27,"special_numbering":"C","title":["Pseudo-first-order reaction of chemically and biologically formed green rusts with HgII and C15H15N3O2: Effects of pH and stabilizing agents (phosphate, silicate, polyacrylic acid, and bacterial cells)"],"prefix":"10.1016","volume":"70","author":[{"given":"P.-Ph.","family":"Remy","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M.","family":"Etique","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A.A.","family":"Hazotte","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A.-S.","family":"Sergent","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"N.","family":"Estrade","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"C.","family":"Cloquet","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"K.","family":"Hanna","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0853-4299","authenticated-orcid":false,"given":"F.P.A.","family":"Jorand","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"78","reference":[{"key":"10.1016\/j.watres.2014.12.007_bib1","doi-asserted-by":"crossref","first-page":"466","DOI":"10.1016\/j.jhazmat.2011.03.074","article-title":"Laboratory studies using naturally occurring \u201cgreen rust\u201d to aid metal mine water remediation","volume":"190","author":"Bearcock","year":"2011","journal-title":"J. Hazard. Mater."},{"key":"10.1016\/j.watres.2014.12.007_bib2","doi-asserted-by":"crossref","first-page":"1715","DOI":"10.1016\/S0016-7037(01)00556-7","article-title":"Effect of orthophosphate on the oxidation products of Fe(II)\u2013Fe(III) hydroxycarbonate: the transformation of green rust to ferrihydrite","volume":"65","author":"Benali","year":"2001","journal-title":"Geochim. Cosmochim. Ac."},{"issue":"1","key":"10.1016\/j.watres.2014.12.007_bib3","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1016\/j.solidstatesciences.2003.10.004","article-title":"Coprecipitation of Fe(II\u2013III) hydroxycarbonate green rust stabilized by phosphate adsorption","volume":"6","author":"Bocher","year":"2004","journal-title":"Solid State Sci."},{"issue":"57","key":"10.1016\/j.watres.2014.12.007_bib4","first-page":"1","article-title":"Toward a mechanistic understanding of anaerobic nitrate-dependent iron oxidation: balancing electron uptake and detoxification","volume":"3","author":"Carlson","year":"2012","journal-title":"Front. Microbiol."},{"key":"10.1016\/j.watres.2014.12.007_bib5","doi-asserted-by":"crossref","first-page":"303","DOI":"10.1016\/S0009-2541(02)00122-5","article-title":"Natural attenuation of TCE, As, Hg linked to the heterogeneous oxidation of Fe(II): an AFM study","volume":"190","author":"Charlet","year":"2002","journal-title":"Chem. Geol."},{"key":"10.1016\/j.watres.2014.12.007_bib6","doi-asserted-by":"crossref","first-page":"3436","DOI":"10.1021\/es8011047","article-title":"Identification of green rust in groundwater","volume":"43","author":"Christiansen","year":"2009","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib7","doi-asserted-by":"crossref","first-page":"2025","DOI":"10.1016\/0010-938X(95)00096-3","article-title":"The preparation and thermodynamic properties of iron(II)-iron(III) hydroxide-carbonate (green rust); Pourbaix diagram of iron in carbonate-containing aqueous media","volume":"37","author":"Drissi","year":"1995","journal-title":"Corros. Sci."},{"key":"10.1016\/j.watres.2014.12.007_bib8","doi-asserted-by":"crossref","first-page":"799","DOI":"10.1021\/es0345569","article-title":"Reactivity of Fe(II)-bearing minerals toward reductive transformation of organic contaminants","volume":"38","author":"Elsner","year":"2004","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib9","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1021\/es980221t","article-title":"Reductive dechlorination of carbon tetrachloride using iron(II) iron(III) hydroxide sulfate (green rust)","volume":"33","author":"Erbs","year":"1999","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib10","doi-asserted-by":"crossref","first-page":"3742","DOI":"10.1021\/es403358v","article-title":"Abiotic process for Fe(II) oxidation and green rust mineralization driven by a heterotrophic nitrate reducing bacteria (Klebsiella mobilis)","volume":"48","author":"Etique","year":"2014","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib11","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1016\/j.watres.2014.05.028","article-title":"Nitrate reduction by mixed iron(II-III) hydroxycarbonate green rust in the presence of phosphate anions: the key parameters influencing the ammonium selectivity","volume":"62","author":"Etique","year":"2014","journal-title":"Water Res."},{"key":"10.1016\/j.watres.2014.12.007_bib12","doi-asserted-by":"crossref","first-page":"3239","DOI":"10.1016\/S0016-7037(98)00243-9","article-title":"Biogenic iron mineralization accompanying the dissimilatory reduction of hydrous ferric oxide by a groundwater bacterium","volume":"62","author":"Fredrickson","year":"1998","journal-title":"Geochim. Cosmochim. Ac."},{"key":"10.1016\/j.watres.2014.12.007_bib13","doi-asserted-by":"crossref","first-page":"402","DOI":"10.1016\/j.crte.2006.04.005","article-title":"Speciation of iron; characterisation and structure of green rusts and FeII-III oxyhydroxycarbonate fougerite","volume":"338","author":"G\u00e9nin","year":"2006","journal-title":"C. R. Geosci."},{"key":"10.1016\/j.watres.2014.12.007_bib14","doi-asserted-by":"crossref","first-page":"1058","DOI":"10.1021\/es970547m","article-title":"Thermodynamic equilibria in aqueous suspensions of synthetic and natural Fe(II)\u2013Fe(III) green rusts: occurrences of the mineral in hydromorphic soils","volume":"32","author":"G\u00e9nin","year":"1998","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib15","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1016\/j.gca.2013.01.017","article-title":"Surface charge and growth of sulphate and carbonate green rust in aqueous media","volume":"108","author":"Guilbaud","year":"2013","journal-title":"Geochim. Cosmochim. Ac."},{"key":"10.1016\/j.watres.2014.12.007_bib16","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1016\/S0169-1317(00)00029-6","article-title":"Kinetics of nitrate reduction by green rusts effects of interlayer anion and Fe(II):Fe(III) ratio","volume":"18","author":"Hansen","year":"2001","journal-title":"Appl. Clay Sci."},{"key":"10.1016\/j.watres.2014.12.007_bib17","first-page":"187","article-title":"Chapter 5.3 Five-membered Ring Systems: Furans and Benzofurans","author":"Hou","year":"2007"},{"key":"10.1016\/j.watres.2014.12.007_bib18","doi-asserted-by":"crossref","first-page":"600","DOI":"10.1080\/01490451.2012.746403","article-title":"Contribution of anionic vs neutral polymers to the formation of green rust 1 from \u03b3-FeOOH bioreduction","volume":"30","author":"Jorand","year":"2013","journal-title":"Geomicrobiol. J."},{"key":"10.1016\/j.watres.2014.12.007_bib19","doi-asserted-by":"crossref","first-page":"1053","DOI":"10.1007\/s00253-008-1498-y","article-title":"Decolorization of azo dyes by Shewanella sp. under saline conditions","volume":"79","author":"Khalid","year":"2008","journal-title":"Appl. Microbiol. Biotechnol."},{"key":"10.1016\/j.watres.2014.12.007_bib20","doi-asserted-by":"crossref","first-page":"212","DOI":"10.1016\/j.chemosphere.2008.12.002","article-title":"Reductive transformation and mineralization of an azo dye by hydroxysulphate green rust preceding oxidation using H2O2 at neutral pH","volume":"75","author":"Kone","year":"2009","journal-title":"Chemosphere"},{"key":"10.1016\/j.watres.2014.12.007_bib21","doi-asserted-by":"crossref","first-page":"5348","DOI":"10.1021\/es0258374","article-title":"Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 2. Green rust","volume":"36","author":"Lee","year":"2002","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib22","doi-asserted-by":"crossref","first-page":"438","DOI":"10.1021\/es9903779","article-title":"Trapping of Cr by formation of ferrihydrite during the reduction of chromate ions by Fe(II)-Fe(III) hydroxysalt green rusts","volume":"34","author":"Loyaux-Lawniczak","year":"2000","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib23","doi-asserted-by":"crossref","first-page":"1289","DOI":"10.1180\/minmag.2012.076.5.10","article-title":"Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides","volume":"76","author":"Mills","year":"2012","journal-title":"Mineral. Mag."},{"key":"10.1016\/j.watres.2014.12.007_bib24","doi-asserted-by":"crossref","first-page":"9597","DOI":"10.1021\/es201820c","article-title":"Binding of HgII to high-affinity sites on bacteria inhibits reduction to Hg0 by Mixed FeII\/III phases","volume":"45","author":"Mishra","year":"2011","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib25","doi-asserted-by":"crossref","first-page":"942","DOI":"10.1016\/j.chemosphere.2007.07.021","article-title":"Abiotic reduction of antimony (V) by green rust (Fe4(II)Fe2(III)(OH)12SO4. 3H2O)","volume":"70","author":"Mitsunobu","year":"2008","journal-title":"Chemosphere"},{"key":"10.1016\/j.watres.2014.12.007_bib26","doi-asserted-by":"crossref","first-page":"1106","DOI":"10.1126\/science.278.5340.1106","article-title":"Abiotic Se redox chemistry in the presence of Fe(II, III)-oxides","volume":"278","author":"Myneni","year":"1997","journal-title":"Science"},{"key":"10.1016\/j.watres.2014.12.007_bib27","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1897\/03-45","article-title":"Reduction of halogenated ethanes by green rust","volume":"23","author":"O'Loughlin","year":"2004","journal-title":"Environ. Toxicol. Chem."},{"key":"10.1016\/j.watres.2014.12.007_bib28","doi-asserted-by":"crossref","first-page":"437","DOI":"10.1016\/S0045-6535(03)00545-9","article-title":"Reduction of AgI, AuIII, CuII, and HgII by FeII\/FeIII hydroxysulfate green rust","volume":"53","author":"O'Loughlin","year":"2003","journal-title":"Chemosphere"},{"key":"10.1016\/j.watres.2014.12.007_bib29","doi-asserted-by":"crossref","first-page":"4570","DOI":"10.1021\/es100294w","article-title":"Effects of oxyanions, natural organic matter, and bacterial cell numbers on the bioreduction of lepidocrocite (\u03b3-FeOOH) and the formation of secondary mineralization products","volume":"44","author":"O'Loughlin","year":"2010","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib30","doi-asserted-by":"crossref","first-page":"16","DOI":"10.1021\/es0020456","article-title":"Iron (II, III) hydroxycarbonate green rust formation and stabilization from lepidocrocite bioreduction","volume":"36","author":"Ona-Nguema","year":"2002","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib31","doi-asserted-by":"crossref","first-page":"6987","DOI":"10.1021\/es304761u","article-title":"Influence of chloride and Fe(II) content on the reduction of Hg(II) by magnetite","volume":"47","author":"Pasakarnis","year":"2013","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib32","series-title":"Atlas d\u2019\u00e9quilibres \u00e9lectrochimiques","first-page":"422","author":"Pourbaix","year":"1963"},{"key":"10.1016\/j.watres.2014.12.007_bib33","doi-asserted-by":"crossref","first-page":"833","DOI":"10.1016\/S0010-938X(02)00184-1","article-title":"Formation of the Fe(II)\u2013Fe(III) hydroxysulphate green rust during marine corrosion of steel","volume":"45","author":"Refait","year":"2003","journal-title":"Corros. Sci."},{"key":"10.1016\/j.watres.2014.12.007_bib34","doi-asserted-by":"crossref","first-page":"476","DOI":"10.1016\/j.crte.2006.04.012","article-title":"Green rusts in electrochemical and microbially influenced corrosion of steel","volume":"338","author":"Refait","year":"2006","journal-title":"C. R. Geosci."},{"key":"10.1016\/j.watres.2014.12.007_bib35","doi-asserted-by":"crossref","first-page":"1055","DOI":"10.1016\/S1293-2558(03)00121-3","article-title":"Coprecipitation of Fe(II) and Fe(III) cations in sulphated aqueous medium and formation of hydroxysulphate green rust","volume":"5","author":"Ruby","year":"2003","journal-title":"Solid State Sci."},{"key":"10.1016\/j.watres.2014.12.007_bib36","doi-asserted-by":"crossref","first-page":"803","DOI":"10.1007\/s10751-006-9361-y","article-title":"Chemical stability of hydroxysulphate green rust synthesized in the presence of foreign anions: carbonate, phosphate and silicate","volume":"167","author":"Ruby","year":"2006","journal-title":"Hyperfine Interact."},{"key":"10.1016\/j.watres.2014.12.007_bib37","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1180\/claymin.1994.029.1.10","article-title":"The formation of green rust and its transformation to lepidocrocite","volume":"29","author":"Schwertmann","year":"1994","journal-title":"Clay Miner."},{"key":"10.1016\/j.watres.2014.12.007_bib38","doi-asserted-by":"crossref","first-page":"86","DOI":"10.1016\/j.chemgeo.2011.07.016","article-title":"Effects of Si-bearing minerals on the nature of secondary iron mineral products from lepidocrocite bioreduction","volume":"289","author":"Sergent","year":"2011","journal-title":"Chem. Geol."},{"key":"10.1016\/j.watres.2014.12.007_bib39","doi-asserted-by":"crossref","first-page":"327","DOI":"10.1016\/S1293-2558(02)00019-5","article-title":"Structure of the Fe(II-III) layered double hydroxysulphate green rust two from Rietveld analysis","volume":"5","author":"Simon","year":"2003","journal-title":"Solid State Sci."},{"key":"10.1016\/j.watres.2014.12.007_bib40","doi-asserted-by":"crossref","first-page":"5224","DOI":"10.1021\/es0495462","article-title":"Significance of iron(II,III) hydroxycarbonate green rust in arsenic remediation using zerovalent iron in laboratory column tests","volume":"38","author":"Su","year":"2004","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib41","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1180\/claymin.1985.020.1.11","article-title":"A rapid method for the formation of Fe(II)-Fe(III) hydroxycarbonate","volume":"20","author":"Taylor","year":"1985","journal-title":"Clay Miner."},{"key":"10.1016\/j.watres.2014.12.007_bib42","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1016\/S0883-2927(99)00097-9","article-title":"The ferrozine method revisited: Fe(II)\/Fe(III) determination in natural waters","volume":"15","author":"Viollier","year":"2000","journal-title":"Appl. Geochem."},{"key":"10.1016\/j.watres.2014.12.007_bib43","doi-asserted-by":"crossref","first-page":"5307","DOI":"10.1021\/es9003608","article-title":"Reduction of Hg(II) to Hg(0) by magnetite","volume":"43","author":"Wiatrowski","year":"2009","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib44","doi-asserted-by":"crossref","first-page":"6690","DOI":"10.1021\/es061046g","article-title":"Novel reduction of mercury(II) by mercury-sensitive dissimilatory metal reducing bacteria","volume":"40","author":"Wiatrowski","year":"2006","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib45","doi-asserted-by":"crossref","first-page":"3488","DOI":"10.1021\/es010579g","article-title":"Kinetics of Cr(VI) reduction by carbonate green rust","volume":"35","author":"Williams","year":"2001","journal-title":"Environ. Sci. Technol."},{"key":"10.1016\/j.watres.2014.12.007_bib46","doi-asserted-by":"crossref","first-page":"599","DOI":"10.1130\/G32959.1","article-title":"Green rust formation controls nutrient availability in a ferruginous water column","volume":"40","author":"Zegeye","year":"2012","journal-title":"Geology"},{"key":"10.1016\/j.watres.2014.12.007_bib47","doi-asserted-by":"crossref","first-page":"5978","DOI":"10.1021\/jp500462r","article-title":"Origin of the differential nanoscale reactivity of biologically and chemically formed green rusts crystals investigated by chemical force spectroscopy","volume":"118","author":"Zegeye","year":"2014","journal-title":"J. Phys. Chem. C"},{"key":"10.1016\/j.watres.2014.12.007_bib48","doi-asserted-by":"crossref","first-page":"209","DOI":"10.1111\/j.1472-4669.2010.00238.x","article-title":"Bacterial and iron oxide aggregates mediate secondary iron mineral formation: green-rust vs magnetite","volume":"8","author":"Zegeye","year":"2010","journal-title":"Geobiology"},{"key":"10.1016\/j.watres.2014.12.007_bib49","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1080\/01490450500248960","article-title":"Formation of hydroxysulphate green rust 2 as a single iron(II\u2013III) mineral in microbial culture","volume":"22","author":"Zegeye","year":"2005","journal-title":"Geomicrobiol. J."},{"key":"10.1016\/j.watres.2014.12.007_bib50","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1080\/01490450601134325","article-title":"Kinetic and thermodynamic analysis during dissimilatory \u03b3-FeOOH reduction: formation of green rust 1 and magnetite","volume":"24","author":"Zegeye","year":"2007","journal-title":"Geomicrobiol. J."}],"container-title":["Water Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0043135414008392?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0043135414008392?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2018,9,26]],"date-time":"2018-09-26T22:22:18Z","timestamp":1538000538000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0043135414008392"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,3]]},"references-count":50,"alternative-id":["S0043135414008392"],"URL":"https:\/\/doi.org\/10.1016\/j.watres.2014.12.007","relation":{},"ISSN":["0043-1354"],"issn-type":[{"value":"0043-1354","type":"print"}],"subject":[],"published":{"date-parts":[[2015,3]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Pseudo-first-order reaction of chemically and biologically formed green rusts with HgII and C15H15N3O2: Effects of pH and stabilizing agents (phosphate, silicate, polyacrylic acid, and bacterial cells)","name":"articletitle","label":"Article Title"},{"value":"Water Research","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.watres.2014.12.007","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"Copyright \u00a9 2014 Elsevier Ltd. All rights reserved.","name":"copyright","label":"Copyright"}]}}