{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T05:39:57Z","timestamp":1773034797992,"version":"3.50.1"},"reference-count":35,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[1992,10,1]],"date-time":"1992-10-01T00:00:00Z","timestamp":717897600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[1992,10,1]],"date-time":"1992-10-01T00:00:00Z","timestamp":717897600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/legal\/tdmrep-license"}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Molecular Structure: THEOCHEM"],"published-print":{"date-parts":[[1992,10]]},"DOI":"10.1016\/0166-1280(92)85101-p","type":"journal-article","created":{"date-parts":[[2002,7,25]],"date-time":"2002-07-25T04:45:24Z","timestamp":1027572324000},"page":"87-103","update-policy":"https:\/\/doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":7,"special_numbering":"C","title":["Conformational analysis of carbonyl and thiocarbonyl esters: the HC(=X)YXXXCH(CH3)2 (X,Y = O or S) internal rotation"],"prefix":"10.1016","volume":"262","author":[{"given":"J.J.C.","family":"Teixeira-Dias","sequence":"first","affiliation":[]},{"given":"R.","family":"Fausto","sequence":"additional","affiliation":[]},{"given":"L.A.E.Batista","family":"de Carvalho","sequence":"additional","affiliation":[]}],"member":"78","reference":[{"key":"10.1016\/0166-1280(92)85101-P_BIB1","doi-asserted-by":"crossref","first-page":"3163","DOI":"10.1016\/S0021-9258(18)50737-7","volume":"254","author":"Storer","year":"1979","journal-title":"J. Biol. Chem."},{"key":"10.1016\/0166-1280(92)85101-P_BIB2","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1042\/bj0960189","volume":"96","author":"Lowe","year":"1965","journal-title":"J. Biochem."},{"key":"10.1016\/0166-1280(92)85101-P_BIB3","doi-asserted-by":"crossref","first-page":"421","DOI":"10.1016\/0022-2860(91)87152-8","volume":"242","author":"Kim","year":"1991","journal-title":"J. Mol. Struct."},{"key":"10.1016\/0166-1280(92)85101-P_BIB4","unstructured":"M. Kim and P.R. Carey, to be published."},{"key":"10.1016\/0166-1280(92)85101-P_BIB5","doi-asserted-by":"crossref","first-page":"4781","DOI":"10.1021\/bi00289a026","volume":"22","author":"Lee","year":"1983","journal-title":"Biochemistry"},{"key":"10.1016\/0166-1280(92)85101-P_BIB6","doi-asserted-by":"crossref","first-page":"8252","DOI":"10.1021\/ja00338a040","volume":"106","author":"Varughese","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB7","doi-asserted-by":"crossref","first-page":"8258","DOI":"10.1021\/ja00338a041","volume":"106","author":"Carey","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB8","doi-asserted-by":"crossref","first-page":"258","DOI":"10.1021\/bi00401a039","volume":"27","author":"Angus","year":"1988","journal-title":"Biochemistry"},{"key":"10.1016\/0166-1280(92)85101-P_BIB9","unstructured":"P.J. Tonge, A.C. Storer, and P.R. Carey, J. Am. Chem. Soc., submitted for publication."},{"key":"10.1016\/0166-1280(92)85101-P_BIB10","first-page":"1","volume":"7","author":"Carey","year":"1980","journal-title":"Adv. Infrared Raman Spectrosc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB11","doi-asserted-by":"crossref","first-page":"2471","DOI":"10.1021\/ja00007a019","volume":"113","author":"Fausto","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB12","doi-asserted-by":"crossref","first-page":"381","DOI":"10.1016\/0166-1280(87)85034-0","volume":"150","author":"Fausto","year":"1987","journal-title":"J. Mol. Struct. (Theochem.)"},{"key":"10.1016\/0166-1280(92)85101-P_BIB13","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1016\/0166-1280(87)87010-0","volume":"152","author":"Fausto","year":"1987","journal-title":"J. Mol. Struct. (Theochem.)"},{"key":"10.1016\/0166-1280(92)85101-P_BIB14","doi-asserted-by":"crossref","first-page":"1945","DOI":"10.1039\/f29898501945","volume":"85","author":"Fausto","year":"1989","journal-title":"J. Chem. Soc., Faraday Trans. 2"},{"key":"10.1016\/0166-1280(92)85101-P_BIB15","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/0166-1280(90)85155-G","volume":"207","author":"Fausto","year":"1990","journal-title":"J. Mol. Struct., (Theochem.)"},{"key":"10.1016\/0166-1280(92)85101-P_BIB16","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/0166-1280(92)80011-A","volume":"208","author":"de Carvalho","year":"1990","journal-title":"J. Mol. Struct. (Theochem.)"},{"key":"10.1016\/0166-1280(92)85101-P_BIB17","author":"Fausto","year":"1987"},{"key":"10.1016\/0166-1280(92)85101-P_BIB18","doi-asserted-by":"crossref","first-page":"1047","DOI":"10.1002\/jcc.540120902","volume":"12","author":"Teixeira-Dias","year":"1991","journal-title":"J. Comput. Chem."},{"key":"10.1016\/0166-1280(92)85101-P_BIB19","unstructured":"R. Fausto, L.A.E. Batista de Carvalho and J.J.C. Teixeira-Dias, submitted for publication."},{"key":"10.1016\/0166-1280(92)85101-P_BIB20","doi-asserted-by":"crossref","first-page":"61","DOI":"10.1016\/0022-2860(89)85068-9","volume":"212","author":"Fausto","year":"1989","journal-title":"J. Mol. Struct."},{"key":"10.1016\/0166-1280(92)85101-P_BIB21","doi-asserted-by":"crossref","first-page":"5817","DOI":"10.1021\/ja00279a025","volume":"108","author":"Wiberg","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB22_1","author":"Peterson","year":"1986"},{"key":"10.1016\/0166-1280(92)85101-P_BIB22_2","article-title":"gaussian 80\/82","author":"Binkley","year":"1982"},{"key":"10.1016\/0166-1280(92)85101-P_BIB23","doi-asserted-by":"crossref","first-page":"939","DOI":"10.1021\/ja00523a008","volume":"102","author":"Binkley","year":"1980","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB24","doi-asserted-by":"crossref","first-page":"2797","DOI":"10.1021\/ja00374a017","volume":"104","author":"Gordon","year":"1982","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB25","author":"Schlegel","year":"1975"},{"key":"10.1016\/0166-1280(92)85101-P_BIB26","author":"de Carvalho","year":"1988"},{"key":"10.1016\/0166-1280(92)85101-P_BIB27","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1016\/0022-2860(77)85049-7","volume":"36","author":"True","year":"1977","journal-title":"J. Mol. Struct."},{"key":"10.1016\/0166-1280(92)85101-P_BIB28","doi-asserted-by":"crossref","first-page":"175","DOI":"10.1002\/jcc.540050208","volume":"5","author":"Klimkowski","year":"1984","journal-title":"J. Comput. Chem."},{"key":"10.1016\/0166-1280(92)85101-P_BIB29","doi-asserted-by":"crossref","first-page":"5035","DOI":"10.1021\/ja00304a002","volume":"107","author":"Wiberg","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB30","doi-asserted-by":"crossref","first-page":"2253","DOI":"10.1021\/ja00527a019","volume":"102","author":"Prose","year":"1980","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB31","doi-asserted-by":"crossref","first-page":"5935","DOI":"10.1021\/ja00254a006","volume":"109","author":"Wiberg","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB32","doi-asserted-by":"crossref","first-page":"2521","DOI":"10.1246\/bcsj.52.2521","volume":"52","author":"Matsushita","year":"1979","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"10.1016\/0166-1280(92)85101-P_BIB33","doi-asserted-by":"crossref","first-page":"5592","DOI":"10.1021\/ja00771a011","volume":"94","author":"Sweigart","year":"1972","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/0166-1280(92)85101-P_BIB34","doi-asserted-by":"crossref","first-page":"365","DOI":"10.1016\/0009-2614(75)85146-3","volume":"32","author":"Flamini","year":"1975","journal-title":"Chem. Phys. Lett."}],"container-title":["Journal of Molecular Structure: THEOCHEM"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:016612809285101P?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:016612809285101P?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2025,9,9]],"date-time":"2025-09-09T20:48:39Z","timestamp":1757450919000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/016612809285101P"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1992,10]]},"references-count":35,"alternative-id":["016612809285101P"],"URL":"https:\/\/doi.org\/10.1016\/0166-1280(92)85101-p","relation":{},"ISSN":["0166-1280"],"issn-type":[{"value":"0166-1280","type":"print"}],"subject":[],"published":{"date-parts":[[1992,10]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"Conformational analysis of carbonyl and thiocarbonyl esters: the HC(=X)YXXXCH(CH3)2 (X,Y = O or S) internal rotation","name":"articletitle","label":"Article Title"},{"value":"Journal of Molecular Structure: THEOCHEM","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/0166-1280(92)85101-P","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"converted-article","name":"content_type","label":"Content Type"},{"value":"Copyright \u00a9 1992 Published by Elsevier B.V.","name":"copyright","label":"Copyright"}]}}