{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,30]],"date-time":"2026-03-30T15:11:41Z","timestamp":1774883501544,"version":"3.50.1"},"reference-count":55,"publisher":"Elsevier BV","issue":"1-2","license":[{"start":{"date-parts":[[1996,8,1]],"date-time":"1996-08-01T00:00:00Z","timestamp":838857600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Fluid Phase Equilibria"],"published-print":{"date-parts":[[1996,8]]},"DOI":"10.1016\/s0378-3812(96)90013-8","type":"journal-article","created":{"date-parts":[[2011,12,11]],"date-time":"2011-12-11T10:42:14Z","timestamp":1323600134000},"page":"71-95","source":"Crossref","is-referenced-by-count":83,"title":["Thermodynamic properties of sugars in aqueous solutions: correlation and prediction using a modified UNIQUAC model"],"prefix":"10.1016","volume":"123","author":[{"given":"Ant\u00f3nio M.","family":"Peres","sequence":"first","affiliation":[]},{"given":"Eug\u00e9nia A.","family":"Macedo","sequence":"additional","affiliation":[]}],"member":"78","reference":[{"key":"10.1016\/S0378-3812(96)90013-8_BIB1","doi-asserted-by":"crossref","first-page":"337","DOI":"10.1016\/0378-3812(94)87017-9","article-title":"Measurement and modeling of atmospheric pressure vapor-liquid equilibrium data for binary, ternary and quaternary mixtures of sucrose, glucose, fructose and water components","volume":"93","author":"Abderafi","year":"1994","journal-title":"Fluid Phase Equilibria"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB2","doi-asserted-by":"crossref","first-page":"175","DOI":"10.1016\/0378-3812(92)85047-C","article-title":"Measurement of liquid-solid phase equilibrium in ternary systems of water-sucrose-glucose and water-sucrose-fructose, and predictions with UNIFAC","volume":"73","author":"Abed","year":"1992","journal-title":"Fluid Phase Equilibria"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB3","doi-asserted-by":"crossref","first-page":"116","DOI":"10.1002\/aic.690210115","article-title":"Statistical thermodynamics of liquid mixtures: a new expression of the excess Gibbs energy of partly or completely miscible systems","volume":"21","author":"Abrams","year":"1975","journal-title":"AIChE J."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB4","first-page":"93","article-title":"Pr\u00e9diction de l'activit\u00e9 de l'\u00e9au, des temp\u00e9ratures d'\u00e9bullition et de cong\u00e9lation de solutions aqueuses de sucres par un mod\u00e8le UNIFAC","volume":"109","author":"Achard","year":"1992","journal-title":"Cahier Scientifique"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB5","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/S0008-6215(00)86023-1","article-title":"Excess enthalpies of aqueous solutions of mono- and oligosaccharides at 25\u00b0C","volume":"91","author":"Barone","year":"1981","journal-title":"Carbohydr. Res."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB6","doi-asserted-by":"crossref","first-page":"325","DOI":"10.1021\/je60027a007","article-title":"Osmotic and activity coefficients of some nonelectrolytes","volume":"10","author":"Bonner","year":"1965","journal-title":"J. Chem. Eng. Data"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB7","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/0378-3812(94)80086-3","article-title":"Excess properties and solid-liquid equilibria for aqueous solutions of sugars using a UNIQUAC model","volume":"96","author":"Catt\u00e9","year":"1994","journal-title":"Fluid Phase Equilibria"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB8","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/0378-3812(94)02604-Y","article-title":"A physical chemical UNIFAC model for aqueous solutions of sugars","volume":"105","author":"Catt\u00e9","year":"1995","journal-title":"Fluid Phase Equilibria"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB9","series-title":"Communication to 13th European Seminar on Applied Thermodynamics","article-title":"Salt Solubility in Mixed Solvents","author":"Chiavone-Filho","year":"1993"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB10","doi-asserted-by":"crossref","first-page":"518","DOI":"10.1063\/1.555730","article-title":"Thermodynamic Functions for Aqueous Sodium Chloride","volume":"14","author":"Clarke","year":"1985","journal-title":"J. Phys. Chem. Ref. Data"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB11","series-title":"Communication to CHEMPOR'93","article-title":"Prediction of Water Activity in Non-Electrolyte Solutions by ASOG Group Contribution Method","author":"Correa","year":"1993"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB12","doi-asserted-by":"crossref","first-page":"922","DOI":"10.1111\/j.1365-2621.1976.tb00753_41_4.x","article-title":"Predicting the water activity of multicomponent systems from water sorption isotherms of individual components","volume":"41","author":"Chuang","year":"1976","journal-title":"J. Food Science"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB13","doi-asserted-by":"crossref","first-page":"2553","DOI":"10.1039\/f19888402553","article-title":"Excess enthalpy and excess volume in ternary aqueous solutions with sucrose-glucose, sucrose-glycerol and glucose-glycerol at 298.15 K","volume":"84","author":"Daldrup","year":"1988","journal-title":"J. Chem. Soc., Faraday Trans. I"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB14","series-title":"DIPPR Tables of Physical and Thermodynamic Properties of Pure Compounds","year":"1984"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB15","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1111\/j.1365-2621.1981.tb00992.x","article-title":"The evaluation of water activity in aqueous solutions from freezing point depression","volume":"16","author":"Fontan","year":"1981","journal-title":"J. Food Technol."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB16","series-title":"Vapor-Liquid Equilibria using UNIFAC","author":"Fredenslund","year":"1977"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB17","series-title":"Communication to European Symposium on Computer Aided Process Engineering - ESCAPE 2","article-title":"Modelling of Liquid-Solid Phase Equilibria with UNIFAC. Application to Sugar Systems","author":"Gabas","year":"1992"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB18","doi-asserted-by":"crossref","first-page":"1245","DOI":"10.1016\/S0022-0248(07)80130-8","article-title":"Predictions with UNIFAC of liquid-solid phase diagrams: application to water-sucrose-glucose, water-sucrose-fructose and water-xylose-mannose","volume":"128","author":"Gabas","year":"1993","journal-title":"J. Crystal Growth"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB19","article-title":"Vapor-Liquid Equilibrium Data Collection","author":"Gmehling","year":"1977","journal-title":"DECHEMA Chemistry Data Series"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB20","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1021\/i200016a021","article-title":"Vapor-liquid equilibria by UNIFAC group contribution. Revision and extension 2","volume":"21","author":"Gmehling","year":"1982","journal-title":"Ind. Eng. Chem. Process Des. Dev."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB21","doi-asserted-by":"crossref","first-page":"809","DOI":"10.1063\/1.555831","article-title":"Thermodynamic and transport properties of carbohydrates and their monophosphates: the pentoses and hexoses","volume":"18","author":"Goldberg","year":"1989","journal-title":"J. Phys. Chem. Ref. Data"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB22","doi-asserted-by":"crossref","first-page":"459","DOI":"10.1021\/ja01871a068","article-title":"A new micro-calorimeter: the heats of dilution of aqueous solutions of sucrose at 20 and 30\u00b0C and their heat capacities at 25\u00b0C","volume":"61","author":"Gucker","year":"1939","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB23","doi-asserted-by":"crossref","first-page":"1047","DOI":"10.1063\/1.3253108","article-title":"Osmotic coefficients and mean activity coefficients of uni-univalent electrolytes in water at 25\u00b0C","volume":"1","author":"Hamer","year":"1972","journal-title":"J. Phys. Chem. Ref. Data"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB24","doi-asserted-by":"crossref","first-page":"2352","DOI":"10.1021\/ie00058a017","article-title":"Vapor-liquid equilibria by UNIFAC group contribution. Revision and extension 5","volume":"30","author":"Hansen","year":"1991","journal-title":"Ind. Eng. Chem. Res."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB25","first-page":"588","volume":"20","author":"Jackson","year":"1926","journal-title":"Sci. Papers Bur. Standards"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB26","first-page":"73","article-title":"\u00dcber die Verd\u00fcnnungsw\u00e4rmen einiger Nichtelektrolyte in w\u00e4briger L\u00f6sung bis in das Gebiet grober Verd\u00fcnnung","volume":"54","author":"Lange","year":"1950","journal-title":"Z. Electrochem."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB27","doi-asserted-by":"crossref","first-page":"2274","DOI":"10.1021\/ie00071a018","article-title":"A modified group-contribution model for prediction of phase equilibria and heats of mixing","volume":"26","author":"Larsen","year":"1987","journal-title":"Ind. Eng. Chem. Research"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB28","series-title":"Thermodynamics and Vapour-Liquid Equilibria","first-page":"1","article-title":"Physical Chemistry of Foods","author":"Le Maguer","year":"1992"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB29","doi-asserted-by":"crossref","first-page":"1667","DOI":"10.1111\/j.1365-2621.1983.tb05056.x","article-title":"Water activity and freezing point depression of aqueous solutions and liquid foods","volume":"48","author":"Lerici","year":"1983","journal-title":"J. Food Science"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB30","doi-asserted-by":"crossref","first-page":"205","DOI":"10.1002\/btpr.5420030404","article-title":"Techniques for estimating the vapor-liquid equilibrium of sugar solutions","volume":"3","author":"Leschke","year":"1987","journal-title":"Biotechnol. Progr."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB31","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1007\/978-1-4899-0664-9_16","article-title":"The prediction of water activities in multicomponent systems","volume":"302","author":"Lilley","year":"1991","journal-title":"Adv. Exp. Med. Biol."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB32","doi-asserted-by":"crossref","first-page":"676","DOI":"10.1021\/i200023a023","article-title":"Vapor-liquid equilibria by UNIFAC group contribution. Revision and extension 3","volume":"22","author":"Macedo","year":"1983","journal-title":"Ind. Eng. Chem. Process Des. Dev."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB33","doi-asserted-by":"crossref","first-page":"1620","DOI":"10.1246\/bcsj.56.1620","article-title":"Studies on aqueous solutions of sacchardies. I. Activity coefficients of monosaccharides in aqueous solutions at 25\u00b0C","volume":"56","author":"Miyajima","year":"1983","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB34","series-title":"Crystallisation","author":"Mullin","year":"1972"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB35","article-title":"Solid-liquid equilibrium of sugars in mixed solvents","author":"Peres","year":"1996","journal-title":"Entropie"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB36","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1007\/BF02105282","article-title":"Thermal behavior of carbohydrates studied by heat flow calorimetry","volume":"28","author":"Raemy","year":"1983","journal-title":"J. Therm. Anal."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB37","doi-asserted-by":"crossref","first-page":"1830","DOI":"10.1021\/ja01324a003","article-title":"The activity coefficients of the alkali chlorides and of lithium iodide in aqueous solution from vapor pressure measurements","volume":"56","author":"Robinson","year":"1934","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB38","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1039\/tf9423800063","article-title":"The osmotic coefficients of some organic compounds in relation to their chemical constitution","volume":"38","author":"Robinson","year":"1942","journal-title":"Trans. Faraday Soc."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB39","doi-asserted-by":"crossref","first-page":"1954","DOI":"10.1021\/j100828a010","article-title":"Activity coefficients in aqueous solutions of sucrose, mannitol and their mixtures at 25\u00b0C","volume":"65","author":"Robinson","year":"1961","journal-title":"J. Phys. Chem."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB40","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1016\/0008-6215(93)87004-C","article-title":"Melting and glass transitions of low molecular weight carbohydrates","volume":"238","author":"Roos","year":"1993","journal-title":"Carbohydr. Res."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB41","first-page":"1","article-title":"The water activity of honey and related sugar solutions","volume":"14","author":"R\u00fcegg","year":"1981","journal-title":"Lebensm. Wiss. u. - Technol."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB42","doi-asserted-by":"crossref","first-page":"1171","DOI":"10.1016\/0009-2509(86)87090-7","article-title":"Calculation of vapour-liquid equilibria in mixed solvent\/salt systems using an extended UNIQUAC equation","volume":"41","author":"Sander","year":"1986","journal-title":"Chem. Eng. Sci."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB43","doi-asserted-by":"crossref","first-page":"733","DOI":"10.1007\/BF00643457","article-title":"Enthalpy of dilution of aqueous mixtures of amides, sugars, urea, ethylene glycol, and pentaerythritol at 25\u00b0C: enthalpy of interaction of the hydrocarbon, amide and hydroxyl functional groups in dilute aqueous solutions","volume":"5","author":"Savage","year":"1976","journal-title":"J. Solution Chemistry"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB44","doi-asserted-by":"crossref","first-page":"3061","DOI":"10.1021\/ja01279a066","article-title":"Isotonic solutions. I. The chemical potential of water in aqueous solutions of sodium chloride, potassium chloride, sulfuric acid, sucrose, urea and glycerol at 25\u00b0C","volume":"60","author":"Scatchard","year":"1938","journal-title":"J. Am. Chem. Soc."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB45","doi-asserted-by":"crossref","first-page":"714","DOI":"10.1021\/i260072a024","article-title":"Vapor-liquid equilibria by UNIFAC group contribution. Revision and extension","volume":"18","author":"Skjold-J\u00f8rgensen","year":"1979","journal-title":"Ind. Eng. Chem. Process Des. Dev."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB46","author":"Stephen","year":"1963"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB47","doi-asserted-by":"crossref","first-page":"2126","DOI":"10.1021\/j100879a010","article-title":"Interactions in aqueous nonelectrolyte solutions. I. Solute-solvent equilibria","volume":"70","author":"Stokes","year":"1966","journal-title":"J. Phys. Chem."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB48","doi-asserted-by":"crossref","first-page":"851","DOI":"10.1016\/0021-9614(77)90171-9","article-title":"Excess enthalpies and excess volumes of water\/sucrose\/mannitol at 298.15 K","volume":"9","author":"Stroth","year":"1977","journal-title":"J. Chem. Thermodyn."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB49","doi-asserted-by":"crossref","first-page":"1183","DOI":"10.1039\/tf9555101183","article-title":"The thermodynamic properties of aqueous solutions of glucose","volume":"51","author":"Taylor","year":"1955","journal-title":"Trans. Faraday Soc."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB50","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1021\/ie00061a030","article-title":"Vapor-liquid equilibria by UNIFAC group contribution. 4. Revision and extension","volume":"26","author":"Tiegs","year":"1987","journal-title":"Ind. Eng. Chem. Res."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB51","first-page":"736","article-title":"Solubility of anhydrous \u03b2-D-fructose in water","volume":"21","author":"Vas\u00e1tko","year":"1967","journal-title":"Chem. Zvesti."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB52","year":"1973"},{"key":"10.1016\/S0378-3812(96)90013-8_BIB53","doi-asserted-by":"crossref","first-page":"1334","DOI":"10.1021\/j150474a004","article-title":"Sucrose hydrates: the sucrose-water phase diagram","volume":"53","author":"Young","year":"1949","journal-title":"J. Phys. Chem."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB54","doi-asserted-by":"crossref","first-page":"1093","DOI":"10.1021\/j150501a015","article-title":"D-fructose-water phase diagram","volume":"56","author":"Young","year":"1952","journal-title":"J. Phys. Chem."},{"key":"10.1016\/S0378-3812(96)90013-8_BIB55","doi-asserted-by":"crossref","first-page":"616","DOI":"10.1021\/j150551a023","article-title":"D-glucose-water phase diagram","volume":"61","author":"Young","year":"1957","journal-title":"J. Phys. Chem."}],"container-title":["Fluid Phase Equilibria"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0378381296900138?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S0378381296900138?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2018,11,27]],"date-time":"2018-11-27T18:52:10Z","timestamp":1543344730000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0378381296900138"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1996,8]]},"references-count":55,"aliases":["10.1016\/0378-3812(96)03046-4"],"journal-issue":{"issue":"1-2","published-print":{"date-parts":[[1996,8]]}},"alternative-id":["S0378381296900138"],"URL":"https:\/\/doi.org\/10.1016\/s0378-3812(96)90013-8","relation":{},"ISSN":["0378-3812"],"issn-type":[{"value":"0378-3812","type":"print"}],"subject":[],"published":{"date-parts":[[1996,8]]}}}