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A fitted CL map reveals the distribution of Ti<jats:sup>4+<\/jats:sup> within the grains and shows subtle growth zoning, together with radiation halos from <jats:sup>238<\/jats:sup>U decay. The sensitivity of the SXE spectrometer to carbon, together with the anisotropic X-ray emission from highly orientated pyrolytic graphite, has enabled the C K\u03b1 peak shape to be used to measure the crystal orientation of individual graphite regions. Mapping has revealed that most grains are predominantly of a single orientation, and a number of graphite grains have been investigated to demonstrate the application of this new SXE technique. A peak fitting approach to analyzing the SXE spectra was developed to project the C K\u03b1 2<jats:italic>p<jats:sub>z<\/jats:sub><\/jats:italic> and 2<jats:italic>p<\/jats:italic><jats:sub>(<jats:italic>x<\/jats:italic>+<jats:italic>y<\/jats:italic>)<\/jats:sub> orbital components of the graphite. The shape of these two end-member components is comparable to those produced by electron density of states calculations. 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