{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,3]],"date-time":"2026-10-03T18:03:32Z","timestamp":1791050612222,"version":"4.1.0"},"reference-count":33,"publisher":"Oxford University Press (OUP)","issue":"1","license":[{"start":{"date-parts":[[2021,11,26]],"date-time":"2021-11-26T00:00:00Z","timestamp":1637884800000},"content-version":"unspecified","delay-in-days":0,"URL":"https:\/\/www.cambridge.org\/core\/terms"}],"content-domain":{"domain":["cambridge.org"],"crossmark-restriction":true},"short-container-title":["Microsc Microanal"],"published-print":{"date-parts":[[2022,2]]},"abstract":"<jats:p>\n                    The nitrogen deficiency in steels measured by atom probe tomography (APT) is considered to arise from the obscurement of singly charged dimer nitrogen ions (N\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    ) by the iron-dominant peak (\n                    <jats:sup>56<\/jats:sup>\n                    Fe\n                    <jats:sup>2+<\/jats:sup>\n                    ) at 28 Da. To verify this by quantifying the amount of N\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    ions,\n                    <jats:italic>\u03b3\u2032<\/jats:italic>\n                    -Fe\n                    <jats:sub>4<\/jats:sub>\n                    N consisting of the\n                    <jats:sup>15<\/jats:sup>\n                    N isotope was prepared on iron substrates by plasma nitriding using a nitrogen isotopic gas (\n                    <jats:sup>15<\/jats:sup>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    ). Although considerable amounts of\n                    <jats:sup>15<\/jats:sup>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    were observed at 30 Da without overlap with any iron peak, the observed nitrogen concentrations of\n                    <jats:italic>\u03b3\u2032<\/jats:italic>\n                    -Fe\n                    <jats:sub>4<\/jats:sub>\n                    N were clearly lower than the stoichiometric composition (19\u201320 at%), using both pulsed voltage and pulsed laser atom probes. The origin of the missing nitrogen, excluding nitrogen obscured by other ion species, was predicted to be the occurrence of neutral nitrogen or nitrogen gas molecules in field evaporation. The generation rate of iron nitride ions (FeN\n                    <jats:sup>2+<\/jats:sup>\n                    ) for\n                    <jats:sup>15<\/jats:sup>\n                    N was significantly lower than that for\n                    <jats:sup>14<\/jats:sup>\n                    N in\n                    <jats:italic>\u03b3\u2032<\/jats:italic>\n                    -Fe\n                    <jats:sub>4<\/jats:sub>\n                    N, which affected the amount of the missing nitrogen. The isotope effect suggests that the isotopic ratio cannot always be determined from only one ion species among the multiple species observed in the APT analysis. We discuss the mechanism of the isotope effect in FeN\n                    <jats:sup>2+<\/jats:sup>\n                    formation by field evaporation.\n                  <\/jats:p>","DOI":"10.1017\/s1431927621013623","type":"journal-article","created":{"date-parts":[[2021,11,25]],"date-time":"2021-11-25T22:34:15Z","timestamp":1637879655000},"page":"42-52","update-policy":"https:\/\/doi.org\/10.1017\/policypage","source":"Crossref","is-referenced-by-count":8,"title":["Quantitative Analysis of Nitrogen by Atom Probe Tomography Using Stoichiometric\n                    <i>\u03b3\u2032<\/i>\n                    -Fe\n                    <sub>4<\/sub>\n                    N Consisting of\n                    <sup>15<\/sup>\n                    N Isotope"],"prefix":"10.1093","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1983-9653","authenticated-orcid":false,"given":"Jun","family":"Takahashi","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kazuto","family":"Kawakami","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Koyo","family":"Miura","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mitsuhiro","family":"Hirano","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Naofumi","family":"Ohtsu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"286","published-online":{"date-parts":[[2021,11,26]]},"reference":[{"key":"S1431927621013623_ref30","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2017.01.015"},{"key":"S1431927621013623_ref7","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4614-3436-8"},{"key":"S1431927621013623_ref22","doi-asserted-by":"publisher","DOI":"10.1007\/s11661-015-3133-8"},{"key":"S1431927621013623_ref23","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2017.06.196"},{"key":"S1431927621013623_ref28","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2011.03.024"},{"key":"S1431927621013623_ref1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2011.01.031"},{"key":"S1431927621013623_ref12","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2018.11.293"},{"key":"S1431927621013623_ref19","doi-asserted-by":"publisher","DOI":"10.1088\/0022-3727\/17\/1\/026"},{"key":"S1431927621013623_ref24","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2018.02.001"},{"key":"S1431927621013623_ref20","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4615-4281-0"},{"key":"S1431927621013623_ref13","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(82)90434-4"},{"key":"S1431927621013623_ref3","unstructured":"Cheng, L , Stark, I , Korevaar, BM , Mittemeijer, EJ & Smith, GDM (1988). The initial stage of aging iron-nitrogen martensite. In Proc Int Cof High Nitrogen Steels. pp. 97\u2013101. London: The Institute of Metals."},{"key":"S1431927621013623_ref10","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.44.1520"},{"key":"S1431927621013623_ref15","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2014.06.004"},{"key":"S1431927621013623_ref29","doi-asserted-by":"publisher","DOI":"10.1017\/S1431927620000045"},{"key":"S1431927621013623_ref27","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(92)91055-G"},{"key":"S1431927621013623_ref2","doi-asserted-by":"publisher","DOI":"10.1021\/jo040220l"},{"key":"S1431927621013623_ref11","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2015.02.153"},{"key":"S1431927621013623_ref31","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2007.02.008"},{"key":"S1431927621013623_ref33","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2008.11.017"},{"key":"S1431927621013623_ref16","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2011.01.016"},{"key":"S1431927621013623_ref5","doi-asserted-by":"publisher","DOI":"10.1021\/jz400015h"},{"key":"S1431927621013623_ref18","volume-title":"The Physical Metallurgy of Steels","author":"Leslie","year":"1981"},{"key":"S1431927621013623_ref4","doi-asserted-by":"publisher","DOI":"10.1351\/pac200375060683"},{"key":"S1431927621013623_ref17","doi-asserted-by":"publisher","DOI":"10.1017\/S1431927617000150"},{"key":"S1431927621013623_ref26","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2010.11.021"},{"key":"S1431927621013623_ref8","doi-asserted-by":"publisher","DOI":"10.1088\/1367-2630\/18\/3\/033031"},{"key":"S1431927621013623_ref21","doi-asserted-by":"publisher","DOI":"10.1016\/j.scriptamat.2012.09.007"},{"key":"S1431927621013623_ref6","doi-asserted-by":"publisher","DOI":"10.1063\/1.4830023"},{"key":"S1431927621013623_ref32","doi-asserted-by":"publisher","DOI":"10.1021\/cr50004a004"},{"key":"S1431927621013623_ref25","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2014.09.004"},{"key":"S1431927621013623_ref9","doi-asserted-by":"publisher","DOI":"10.1007\/s11661-016-3731-0"},{"key":"S1431927621013623_ref14","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2015.04.200"}],"container-title":["Microscopy and Microanalysis"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.cambridge.org\/core\/services\/aop-cambridge-core\/content\/view\/S1431927621013623","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,2,14]],"date-time":"2023-02-14T16:32:37Z","timestamp":1676392357000},"score":1,"resource":{"primary":{"URL":"https:\/\/academic.oup.com\/mam\/article\/28\/1\/42\/6889367"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,11,26]]},"references-count":33,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2022,2]]}},"alternative-id":["S1431927621013623"],"URL":"https:\/\/doi.org\/10.1017\/s1431927621013623","relation":{},"ISSN":["1431-9276","1435-8115"],"issn-type":[{"value":"1431-9276","type":"print"},{"value":"1435-8115","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,11,26]]},"assertion":[{"value":"Copyright \u00a9 The Author(s), 2021. Published by Cambridge University Press on behalf of the Microscopy Society of America","name":"copyright","label":"Copyright","group":{"name":"copyright_and_licensing","label":"Copyright and Licensing"}}]}}