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Sci."],"published-print":{"date-parts":[[1999,1,25]]},"DOI":"10.1021\/ci9800357","type":"journal-article","created":{"date-parts":[[2002,7,26]],"date-time":"2002-07-26T05:38:39Z","timestamp":1027661919000},"page":"68-76","source":"Crossref","is-referenced-by-count":0,"title":["Time-Resolved Profiles in Modulated Polarization Spectroscopy"],"prefix":"10.1021","volume":"39","author":[{"given":"A.","family":"Vrancic","sequence":"first","affiliation":[{"name":"Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, and The Rugjer Boskovic Institute, 10000 Zagreb, Croatia"}]},{"given":"K.","family":"Rupnik","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, and The Rugjer Boskovic Institute, 10000 Zagreb, Croatia"}]},{"given":"L.","family":"Klasinc","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, and The Rugjer Boskovic Institute, 10000 Zagreb, Croatia"}]},{"given":"S. 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D.","year":"1975"},{"key":"ci9800357b00008\/ci9800357b00008_1","unstructured":"Vrancic,A.A Selective Digital IntegratorThe New Device for ModulatedPolarization Spectroscopy. Ph.D. Dissertation, Louisiana State University, Baton Rouge, May 1998."},{"key":"ci9800357b00009\/ci9800357b00009_1","first-page":"399","volume":"9","author":"Stokes G. G","year":"1852","journal-title":"Trans. Camb. Philos. Soc"},{"key":"ci9800357b00010\/ci9800357b00010_1","volume-title":"Polarized Light","author":"Shurcliff W. A.","year":"1964"},{"key":"ci9800357b00011\/ci9800357b00011_1","doi-asserted-by":"crossref","first-page":"471","DOI":"10.1080\/00387017708065502","volume":"10","author":"Jensen","year":"1977","journal-title":"Spectrosc. Lett"},{"key":"ci9800357b00013\/ci9800357b00013_1","first-page":"1941","volume":"31","author":"Jones R. C","year":"1941","journal-title":"J. Opt. Soc. Am"},{"key":"ci9800357b00014\/ci9800357b00014_1","doi-asserted-by":"crossref","first-page":"493","DOI":"10.1364\/JOSA.31.000493","volume":"31","author":"Hurwitz H.","year":"1941","journal-title":"J. Opt. Soc. Am"},{"key":"ci9800357b00016\/ci9800357b00016_1","volume-title":"Spectra of Atoms and Molecules","author":"Bernath P. F.","year":"1995"},{"key":"ci9800357b00017\/ci9800357b00017_1","volume-title":"Modern Quantum Mechanics","author":"Sakurai J. J.","year":"1985"},{"key":"ci9800357b00021\/ci9800357b00021_1","unstructured":"The equation for polarization as a function oft, namely,\u03a0(1.018t+ 2 \u00d7 10-6), is determined by the apparatus. The factor 1.018 arises because PEM modulation was 1.8% faster than the averaging frequency of the SDI. This frequency mismatch combined with the instrumental averaging procedure also produces a small phase shift of 2 \u00d7 10-6. For example,Iavg(\u03a0(t)) att= 5 \u03bcs actually represents the absorbance of the polarization that exists att= 1.018 \u00d7 5 + 2 \u03bcs. The origins of the frequency mismatch and phase shift (and their use for gauging the small changes of the PEM frequency, \u223c2%, produced by the alterations of retardation voltage required at different wavelengths of light) are discussed elsewhere.8"},{"key":"ci9800357b00022\/ci9800357b00022_1","doi-asserted-by":"crossref","unstructured":"Snyder, P. A.; Schatz, P. N.; Rowe, E. M. InApplications of CircularlyPolarized Radiation Using Synchrotron and Ordinary Sources; Allen, F., Bustamante, C., Eds.; Plenum:\u2009 New York, 1985; p 43.","DOI":"10.1007\/978-1-4757-9229-4_5"},{"key":"ci9800357b00023\/ci9800357b00023_1","volume-title":"Baton Rouge","author":"Vrancic A. 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