{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T14:07:31Z","timestamp":1790690851459,"version":"4.1.0"},"reference-count":70,"publisher":"American Chemical Society (ACS)","issue":"38","license":[{"start":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T00:00:00Z","timestamp":1789430400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T00:00:00Z","timestamp":1789430400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T00:00:00Z","timestamp":1789430400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22072055"],"award-info":[{"award-number":["22072055"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,29]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Surface-assisted laser desorption\/ionization mass spectrometry (SALDI-MS) is a powerful technique for small-molecule analysis but is often limited by inefficient laser-energy utilization and weak interfacial interactions. Herein, we report a three-dimensional hierarchical plasmonic\u2013semiconductor heterostructure that enables the efficient capture, localization, and conversion of laser energy, thereby enhancing laser desorption\/ionization efficiency. Vertically aligned CuO nanorods provide a high-surface-area photothermal architecture, while discretely distributed Ag nanoparticles generate localized electromagnetic hotspots, form Ag\/CuO Schottky interfaces, and increase nanoscale roughness. Photothermal measurements, transient photovoltage analysis, finite-difference time-domain simulations, photoluminescence spectroscopy, and density functional theory calculations reveal a synergistic enhancement mechanism. Enhanced photon harvesting and plasmonic electromagnetic confinement promote nonradiative energy conversion, generating a transient thermal field that drives analyte desorption. Ion formation is likely facilitated by surface-assisted protonation\/deprotonation processes and possible interfacial charge-transfer processes associated with charge separation at the Ag\/CuO interface. Roughness-induced hydrophobicity and moderately strengthened analyte\u2013substrate interactions further facilitate analyte enrichment while maintaining efficient desorption. As a result, the developed substrate exhibits a wide linear dynamic range (10\u20137\u201310\u20133 M, R2 &amp;gt; 0.99) and low detection limits of 0.4\u20130.8 nM for carbendazim, imidacloprid, and thiabendazole. It also demonstrates high reproducibility, spatial uniformity, and long-term stability. Reliable quantitative analysis is achieved in complex matrices, with results consistent with those obtained by UV\u2013vis spectroscopy, demonstrating its potential for rapid and sensitive pesticide detection. This work provides a rational design strategy for high-performance plasmonic\u2013semiconductor SALDI-MS substrates by integrating efficient laser-energy utilization and controlled interfacial carrier dynamics.<\/jats:p>","DOI":"10.1021\/acs.analchem.6c02935","type":"journal-article","created":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T19:01:46Z","timestamp":1789498906000},"page":"28065-28077","source":"Crossref","is-referenced-by-count":0,"title":["Three-Dimensional\nHierarchical Plasmonic\u2013Semiconductor\nHeterostructure for High-Performance SALDI-MS Detection"],"prefix":"10.1021","volume":"98","author":[{"given":"Yan","family":"Wang","sequence":"first","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaxin","family":"Lu","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingtong","family":"Zhai","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2988-6963","authenticated-orcid":true,"given":"Nan","family":"Lu","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,15]]},"reference":[{"key":"2026092909102268900_cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2025.466548","article-title":"Ethanol\/ethyl Acetate\nAzeotropic Mixture Gas-Phase Separation Using MOF-801-Modified Monolithic\nColumns","volume":"1766","author":"Shuqayr","year":"2026","journal-title":"J. Chromatogr. A"},{"issue":"2","key":"2026092909102268900_cit2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2025.115698","article-title":"Development of Chemical\nAnalysis Protocols on the Leaching Compounds of Forest- and Agricultural\nWastes in Cementitious Environment: A Case Study of Coir Fibres","volume":"13","author":"Wang","year":"2025","journal-title":"J. Environ. Chem. Eng."},{"key":"2026092909102268900_cit3","doi-asserted-by":"publisher","first-page":"2840","DOI":"10.1021\/acs.analchem.3c03599","article-title":"Ultrahigh-Performance\nSupercritical Fluid Chromatography-Multimodal Ionization-Tandem Mass\nSpectrometry as a Universal Tool for the Analysis of Small Molecules\nin Complex Plant Extracts","volume":"96","author":"Plachka\u0301","year":"2024","journal-title":"Anal. Chem."},{"key":"2026092909102268900_cit4","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2022.340711","article-title":"From Fundamentals in\nCalibration to Modern Methodologies: A Tutorial for Small Molecules\nQuantification in Liquid Chromatography-Mass Spectrometry Bioanalysis","volume":"1240","author":"Visconti","year":"2023","journal-title":"Anal. Chim. Acta"},{"issue":"5","key":"2026092909102268900_cit5","doi-asserted-by":"publisher","first-page":"337","DOI":"10.1002\/(SICI)1098-2787(1998)17:5&lt;337::AID-MAS2&gt;3.0.CO;2-S","article-title":"Ion Formation in MALDI Mass Spectrometry","volume":"17","author":"Zenobi","year":"1998","journal-title":"Mass Spectrom. Rev."},{"key":"2026092909102268900_cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2025.127536","article-title":"1,4-Dioxo-1,2,3,4-tetrahydrophthalazine-6-carboxylic\nAcid as a Novel MALDI Matrix for Enhanced Analysis of Metabolites\nInduced by Imidacloprid Exposure","volume":"286","author":"Yan","year":"2025","journal-title":"Talanta"},{"issue":"9","key":"2026092909102268900_cit7","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202513988","article-title":"Mesoporous\nHigh-Entropy Oxides Nanoplatform\nDecodes Paired-Plasma Metabolic Fingerprinting of Pancreatic Cancer","volume":"38","author":"Sun","year":"2026","journal-title":"Adv. Mater."},{"issue":"6","key":"2026092909102268900_cit8","doi-asserted-by":"publisher","first-page":"1766","DOI":"10.1039\/D3AN02201C","article-title":"Advancing Carbohydrate\nQuantification in MALDI Mass Spectrometry by the Rapidly Freeze-Drying\nDroplet (RFDD) Method","volume":"149","author":"Wu","year":"2024","journal-title":"Analyst"},{"key":"2026092909102268900_cit9","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2020.121172","article-title":"Eliminating Sweet Spot\nin MALDI-MS with Hydrophobic Ordered Structure as Target for Quantifying\nBiomolecules","volume":"218","author":"Li","year":"2020","journal-title":"Talanta"},{"issue":"23","key":"2026092909102268900_cit10","doi-asserted-by":"publisher","first-page":"4335","DOI":"10.1021\/ac00119a021","article-title":"Graphite\nSurface-Assisted Laser Ddesorption\/Ionization\nTime-of-Flight Mass Spectrometry of Peptides and Proteins from Liquid\nSolutions","volume":"67","author":"Sunner","year":"1995","journal-title":"Anal. Chem."},{"issue":"20","key":"2026092909102268900_cit11","doi-asserted-by":"publisher","first-page":"21822","DOI":"10.1021\/acsomega.3c08648","article-title":"Surface-Assisted Laser\nDesorption\/Ionization Mass Spectrometry\nwith a Two-Dimensional Au Nanoparticle Array for Soft Ionization","volume":"9","author":"Shibamoto","year":"2024","journal-title":"ACS Omega"},{"issue":"11","key":"2026092909102268900_cit12","doi-asserted-by":"publisher","first-page":"5988","DOI":"10.1021\/acs.analchem.6b01021","article-title":"On-Tissue\nDerivatization via Electrospray Deposition for Matrix-Assisted Laser\nDesorption\/Ionization Mass Spectrometry Imaging of Endogenous Fatty\nAcids in Rat Brain Tissues","volume":"88","author":"Wu","year":"2016","journal-title":"Anal. Chem."},{"issue":"2","key":"2026092909102268900_cit13","doi-asserted-by":"publisher","first-page":"952","DOI":"10.1021\/acs.analchem.1c03764","article-title":"Monolithic Gold Nanoparticles\/Thiol-\u03b2-cyclodextrin-Functionalized\nTiO2 Nanowires for Enhanced SALDI MS Detection and Imaging\nof Natural Products","volume":"94","author":"Wang","year":"2022","journal-title":"Anal. Chem."},{"issue":"38","key":"2026092909102268900_cit14","doi-asserted-by":"publisher","first-page":"42567","DOI":"10.1021\/acsami.0c12949","article-title":"Porous TiO2 Film Immobilized with Gold Nanoparticles\nfor Dual-Polarity SALDI MS Detection and Imaging","volume":"12","author":"Wang","year":"2020","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026092909102268900_cit15","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2024.142301","article-title":"Enrichment and Characterization\nof Foodborne Fungal\nSpores by Ferric Ion-Based Surface-Assisted Laser Desorption\/Ionization\nMass Spectrometry","volume":"467","author":"Yang","year":"2025","journal-title":"Food Chem."},{"issue":"9","key":"2026092909102268900_cit16","doi-asserted-by":"publisher","first-page":"1902","DOI":"10.1021\/jasms.5c00136","article-title":"Integrating\nElectrostatic Adsorption-Laser Desorption\/Ionization-MS with a Derivative\nFull-Spectrum Internal Standard Approach for Acylcarnitine Quantification\nin Clinical Samples","volume":"36","author":"Cao","year":"2025","journal-title":"J. Am. Soc. Mass Spectrom."},{"key":"2026092909102268900_cit17","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2024.135560","article-title":"Improving Performance of SALDI-MS\nby Regulating Density of Plasmonic Nanoparticles","volume":"409","author":"Zhai","year":"2024","journal-title":"Sens. Actuators B: Chem."},{"key":"2026092909102268900_cit18","doi-asserted-by":"publisher","first-page":"285","DOI":"10.1016\/j.jcis.2021.12.105","article-title":"Yolk-Shell\nNi\/NiO Anchored on N-Doped Graphene Synthesized as Dual-Ion MALDI\nMatrix for Detecting and Imaging Bioactive Small Molecules","volume":"613","author":"Zhao","year":"2022","journal-title":"J. Colloid Interface Sci."},{"key":"2026092909102268900_cit19","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2022.107381","article-title":"Magnetic Carbon Nanoparticles Derived\nfrom Candle Soot for SALDI MS Analyses of Drugs and Heavy Metals in\nLatent Fingermarks","volume":"178","author":"Amin","year":"2022","journal-title":"Microchem. J."},{"issue":"20","key":"2026092909102268900_cit20","doi-asserted-by":"publisher","first-page":"4815","DOI":"10.1007\/s00216-018-1119-2","article-title":"Metal Oxide\nNanoparticles for Latent\nFingerprint Visualization and Analysis of Small Drug Molecules Using\nSurface-Assisted Laser Desorption\/Ionization Mass Spectrometry","volume":"410","author":"Amin","year":"2018","journal-title":"Anal. Bioanal. Chem."},{"key":"2026092909102268900_cit21","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2024.118102","article-title":"Advances in Nanomaterials for Surface-Assisted\nLaser Desorption Ionization Mass Spectrometry: Applications in Small\nMolecule Analysis Over the Past Five Years","volume":"183","author":"Jin","year":"2025","journal-title":"TrAC, Trends Anal. Chem."},{"issue":"3","key":"2026092909102268900_cit22","doi-asserted-by":"publisher","first-page":"217","DOI":"10.1007\/s41664-022-00211-5","article-title":"Recent Advances\nin Surface-Assisted\nLaser Desorption\/Ionization Mass Spectrometry and Its Imaging for\nSmall Molecules","volume":"6","author":"Huang","year":"2022","journal-title":"J. Anal. Test."},{"key":"2026092909102268900_cit23","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2022.116902","article-title":"High Spatial Resolution\nMass Spectrometry Imaging for Spatial Metabolomics:\nAdvances, Challenges, and Future Perspectives","volume":"159","author":"Ma","year":"2023","journal-title":"TrAC, Trends Anal. Chem."},{"key":"2026092909102268900_cit24","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2019.120531","article-title":"Exfoliated\nMXene as a Mediator for Efficient Laser Desorption\/Ionization Mass\nSpectrometry Analysis of Various Analytes","volume":"209","author":"Chae","year":"2020","journal-title":"Talanta"},{"issue":"2","key":"2026092909102268900_cit25","doi-asserted-by":"publisher","first-page":"288","DOI":"10.3390\/nano11020288","article-title":"Graphene\nOxide Derivatives and Their\nNanohybrid Structures for Laser Desorption\/Ionization Time-of-Flight\nMass Spectrometry Analysis of Small Molecules","volume":"11","author":"Kim","year":"2021","journal-title":"Nanomaterials"},{"key":"2026092909102268900_cit26","doi-asserted-by":"publisher","first-page":"650","DOI":"10.1021\/acs.analchem.2c01878","article-title":"Titania Nanosheet as\na Matrix for Surface-Assisted Laser Desorption\/Ionization Mass Spectrometry\nAnalysis and Imaging","author":"Gao","year":"2022","journal-title":"Anal. Chem."},{"key":"2026092909102268900_cit27","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.aca.2018.12.057","article-title":"Plasmonic Metal\nNanoparticles as Efficient Mass Tags for Ion Signal\nAmplification and Ultrasensitive Detection of Protein Markers","volume":"1055","author":"Cheng","year":"2019","journal-title":"Anal. Chim. Acta"},{"issue":"11","key":"2026092909102268900_cit28","doi-asserted-by":"publisher","first-page":"2288","DOI":"10.1039\/D5AN00317B","article-title":"Donor\u2013Acceptor Covalent Organic Framework Nanofilm-Based Laser\nDesorption\/Ionization Mass Spectrometry for Rapid and Sensitive Determination\nof Creatinine in Human Serum","volume":"150","author":"Su","year":"2025","journal-title":"Analyst"},{"issue":"16","key":"2026092909102268900_cit29","doi-asserted-by":"publisher","first-page":"3751","DOI":"10.1007\/s00216-024-05297-7","article-title":"Matrix- and\nSurface-Assisted Laser Desorption\/Ionization\u2013Mass\nSpectrometry Analysis of Fingermark Components for Forensic Studies:\nCurrent Trends and Future Prospects","volume":"416","author":"Amin","year":"2024","journal-title":"Anal. Bioanal.\nChem."},{"issue":"5","key":"2026092909102268900_cit30","doi-asserted-by":"publisher","first-page":"1008","DOI":"10.1021\/jasms.4c00462","article-title":"A Practical\nApproach for Internal Energy Tuning in LDI-MS: Porous Silicon Substrates\nas a Case Study","volume":"36","author":"Whyte Ferreira","year":"2025","journal-title":"J. Am. Soc. Mass Spectrom."},{"issue":"1","key":"2026092909102268900_cit31","doi-asserted-by":"publisher","first-page":"25","DOI":"10.3390\/nano14010025","article-title":"Efficient\nAnalysis of Small Molecules\nvia Laser Desorption\/Ionization Time-of-Flight Mass Spectrometry (LDI-TOF\nMS) Using Gold Nanoshells with Nanogaps","volume":"14","author":"Kim","year":"2024","journal-title":"Nanomaterials"},{"issue":"36","key":"2026092909102268900_cit32","doi-asserted-by":"publisher","first-page":"20368","DOI":"10.1021\/acs.jpcc.6b06261","article-title":"Nanosecond UV Laser\nAblation of Gold Nanoparticles: Enhancement of Ion Desorption by Thermal-Driven\nDesorption, Vaporization, or Phase Explosion","volume":"120","author":"Lai","year":"2016","journal-title":"J. Phys. Chem. C"},{"issue":"31","key":"2026092909102268900_cit33","doi-asserted-by":"publisher","first-page":"11119","DOI":"10.1039\/C7NR04098A","article-title":"Highly\nOriented Langmuir\u2013Blodgett Film of Silver\nCuboctahedra as an Effective Matrix-Free Sample Plate for Surface-Assisted\nLaser Desorption\/Ionization Mass Spectrometry","volume":"9","author":"Kuo","year":"2017","journal-title":"Nanoscale"},{"issue":"51","key":"2026092909102268900_cit34","doi-asserted-by":"publisher","first-page":"44751","DOI":"10.1021\/acsami.8b17051","article-title":"Monodispersed Ag Nanoparticle\nin Layered Double Hydroxides as Matrix for Laser Desorption\/Ionization\nMass Spectrometry","volume":"10","author":"Xu","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"31","key":"2026092909102268900_cit35","doi-asserted-by":"publisher","first-page":"20795","DOI":"10.1039\/C7CP04033D","article-title":"Silver-Gold Alloy\nNanoparticles as Tunable Substrates for Systematic Control of Ion-Desorption\nEfficiency and Heat Transfer in Surface-Assisted Laser Desorption\/Ionization","volume":"19","author":"Lai","year":"2017","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"22","key":"2026092909102268900_cit36","doi-asserted-by":"publisher","first-page":"20509","DOI":"10.1021\/acsami.9b03386","article-title":"Synergistic Effect\nof the Heterostructure of Au Nanoislands\non TiO2 Nanowires for Efficient Ionization in Laser Desorption\/Ionization\nMass Spectrometry","volume":"11","author":"Kim","year":"2019","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026092909102268900_cit37","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2021.129709","article-title":"Au Nanoparticles\/ZnO\nNanorods as SALDI-MS Substrate for on-Plate\nEnrichment and Detection of Glutathione in Real Samples","volume":"335","author":"Dou","year":"2021","journal-title":"Sens. Actuators B: Chem."},{"issue":"41","key":"2026092909102268900_cit38","doi-asserted-by":"publisher","first-page":"23708","DOI":"10.1021\/acs.jpcc.5b05957","article-title":"Ion-Desorption\nEfficiency and Internal-Energy Transfer\nin Surface-Assisted Laser Desorption\/Ionization: More Implication(s)\nfor the Thermal-Driven and Phase-Transition-Driven Desorption Process","volume":"119","author":"Ng","year":"2015","journal-title":"J. Phys. Chem. C"},{"key":"2026092909102268900_cit39","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2025.127718","article-title":"Improving\nDetection Sensitivity of SALDI-MS by Constructing Patterned\nComposite Hierarchical Structures","volume":"288","author":"Lu","year":"2025","journal-title":"Talanta"},{"key":"2026092909102268900_cit40","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2025.114324","article-title":"Enhanced SALDI-MS Sensitivity\nVia Schottky and p-n Junction Engineering in Ag\/TiO2\/Si\nNanohybrids: Leveraging Charge Separation and Plasmonic Thermal Effects","volume":"215","author":"Lu","year":"2025","journal-title":"Microchem. J."},{"issue":"16","key":"2026092909102268900_cit41","doi-asserted-by":"publisher","first-page":"10376","DOI":"10.1021\/acs.analchem.9b02623","article-title":"Hepatocarcinoma Discrimination\nby Ratiometric Lipid Profiles Using\nTip-Contact Sampling\/Ionization Mass Spectrometry","volume":"91","author":"Chen","year":"2019","journal-title":"Anal. Chem."},{"issue":"5","key":"2026092909102268900_cit42","doi-asserted-by":"publisher","first-page":"4231","DOI":"10.1021\/acsanm.0c00417","article-title":"Silicon Nanocone\nArrays via Pattern\nTransfer of Mushroomlike SiO2 Nanopillars for Broadband\nAntireflective Surfaces","volume":"3","author":"Yamada","year":"2020","journal-title":"ACS Appl. Nano Mater."},{"key":"2026092909102268900_cit43","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2026.148779","article-title":"A Hierarchical\nThree-Dimensional SERS Substrate for Trace Pesticide Residue Detection","volume":"511","author":"Lu","year":"2026","journal-title":"Food Chem."},{"key":"2026092909102268900_cit44","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2025.143422","article-title":"Hierarchical Structure\nof Pyramid Si-ZnO NRs as Reliable SALDI-MS\nPlatform for Trace Detection of Pesticide","volume":"476","author":"Chen","year":"2025","journal-title":"Food\nChem."},{"issue":"6","key":"2026092909102268900_cit45","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adx8264","article-title":"Interface-Engineered\nPlasmonic Covalent Organic Framework\nNanofilms on TiO2 Nanotubes for Universal Mass Spectrometry\nImaging","volume":"12","author":"Xu","year":"2026","journal-title":"Sci. Adv."},{"issue":"39","key":"2026092909102268900_cit46","doi-asserted-by":"publisher","first-page":"24173","DOI":"10.1039\/D2CP03177A","article-title":"Laser Desorption\/Ionization\non Nanostructured Silicon: Morphology Matters","volume":"24","author":"Dou","year":"2022","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026092909102268900_cit47","doi-asserted-by":"publisher","first-page":"776","DOI":"10.1016\/j.snb.2018.12.086","article-title":"Non-Enzymatic\nand Non-Invasive Glucose Detection Using Au Nanoparticle Decorated\nCuO Nanorods","volume":"283","author":"Chakraborty","year":"2019","journal-title":"Sens. Actuators B: Chem."},{"issue":"16","key":"2026092909102268900_cit48","doi-asserted-by":"publisher","first-page":"1847","DOI":"10.1002\/rcm.1124","article-title":"Thermometer Ions for\nMatrix-Enhanced Laser Desorption\/Ionization Internal Energy Calibration","volume":"17","author":"Greisch","year":"2003","journal-title":"Rapid Commun. Mass Spectrom."},{"issue":"2","key":"2026092909102268900_cit49","doi-asserted-by":"publisher","first-page":"117","DOI":"10.1002\/oms.1210260215","article-title":"New Basis\nfor a Method for the Estimation\nof Secondary Ion Internal Energy Distribution in \u2018Soft\u2019\nIonization Techniques","volume":"26","author":"Derwa","year":"1991","journal-title":"Org. Mass Spectrom."},{"issue":"8","key":"2026092909102268900_cit50","doi-asserted-by":"publisher","first-page":"5645","DOI":"10.1021\/acs.analchem.0c00036","article-title":"The Hidden Heroes: Holes in Charge-Driven Desorption Mass Spectrometry","volume":"92","author":"Cheng","year":"2020","journal-title":"Anal. Chem."},{"issue":"24","key":"2026092909102268900_cit51","doi-asserted-by":"publisher","first-page":"8570","DOI":"10.1021\/acs.analchem.1c04929","article-title":"Dual-Mechanism-Driven\nStrategy for High-Coverage Detection of Serum\nLipids on a Novel SALDI-MS Target","volume":"94","author":"Qu","year":"2022","journal-title":"Anal. Chem."},{"issue":"77","key":"2026092909102268900_cit52","doi-asserted-by":"publisher","first-page":"10905","DOI":"10.1039\/C8CC05793A","article-title":"Hot Electron Transfer Promotes Ion Production in Plasmonic Metal\nNanostructure Assisted Laser Desorption Ionization Mass Spectrometry","volume":"54","author":"Li","year":"2018","journal-title":"Chem. Commun."},{"key":"2026092909102268900_cit53","doi-asserted-by":"publisher","first-page":"45","DOI":"10.1016\/j.aca.2012.03.057","article-title":"Measurement of Laser Activated Electron\nTunneling from Semiconductor Zinc Oxide to Adsorbed Organic Molecules\nby a Matrix Assisted Laser Desorption Ionization Mass Spectrometer","volume":"729","author":"Zhong","year":"2012","journal-title":"Anal. Chim. Acta"},{"issue":"31","key":"2026092909102268900_cit54","doi-asserted-by":"publisher","first-page":"11028","DOI":"10.1021\/acs.langmuir.3c01313","article-title":"Cassie\u2019s Law\nReformulated:\nComposite Surfaces from Superspreading to Superhydrophobic","volume":"39","author":"McHale","year":"2023","journal-title":"Langmuir"},{"issue":"17","key":"2026092909102268900_cit55","doi-asserted-by":"publisher","first-page":"4322","DOI":"10.3390\/ma17174322","article-title":"Estimation\nof the Structure of Hydrophobic Surfaces Using the Cassie-Baxter Equation","volume":"17","author":"Myronyuk","year":"2024","journal-title":"Materials"},{"issue":"7","key":"2026092909102268900_cit56","doi-asserted-by":"publisher","first-page":"3886","DOI":"10.1039\/D3TA06521A","article-title":"Transition\nfrom the Wenzel to Cassie-Baxter State by PFOTES\/TiO2 Nanoparticles\nLeading to a Mechanically Robust and Damage\/Contamination-Recoverable\nSurface","volume":"12","author":"Heo","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"2026092909102268900_cit57","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2024.159319","article-title":"Defining\nthe Nature of Adventitious\nCarbon and Improving Its Merit as a Charge Correction Reference for\nXPS","volume":"653","author":"Grey","year":"2024","journal-title":"Appl. Surf. Sci."},{"key":"2026092909102268900_cit58","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2021.131097","article-title":"Multifunctional Ag-Coated\nCuO Microbowl Arrays for Highly Efficient,\nUltrasensitive, and Recyclable Surface-Enhanced Raman Scattering","volume":"354","author":"Meng","year":"2022","journal-title":"Sens. Actuators B: Chem."},{"issue":"14","key":"2026092909102268900_cit59","doi-asserted-by":"publisher","DOI":"10.1002\/admi.202200047","article-title":"Superhydrophobic\nAg-Decorated CuO Nanowire Arrays with Analyte-Concentrating and Self-Cleaning\nBinary Functions for Ultrasensitive and Recyclable Surface-Enhanced\nRaman Scattering","volume":"9","author":"Meng","year":"2022","journal-title":"Adv. Mater. Interfaces"},{"issue":"3","key":"2026092909102268900_cit60","doi-asserted-by":"publisher","first-page":"2285","DOI":"10.1039\/D4TA04263H","article-title":"Cu\u2013Ag Interactions in Bimetallic Cu\u2013Ag\nCatalysts Enhance C2+ Product Formation During Electrochemical\nCO Reduction","volume":"13","author":"Rollier","year":"2025","journal-title":"J. Mater. Chem. A"},{"key":"2026092909102268900_cit61","doi-asserted-by":"publisher","DOI":"10.1016\/j.susc.2023.122307","article-title":"Ag-Oxide Signature\nin Ag 3d Photoelectron Spectra:\nA Study on Free Nanoparticles","volume":"733","author":"Tzomos","year":"2023","journal-title":"Surf. Sci."},{"key":"2026092909102268900_cit62","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2025.138353","article-title":"Ag-Modified\nSulfur Vacancy-Rich ZnIn2S4 Ultrathin Nanosheets\nPromote Oxygen Activation for Efficient Photocatalytic Hydrogen Peroxide\nSynthesis","volume":"700","author":"He","year":"2025","journal-title":"J. Colloid Interface Sci."},{"key":"2026092909102268900_cit63","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2025.139158","article-title":"Accelerated\nCharge Transport of Ti and Zr Co-Doped Fe2O3 Photoanodes by a Super-Hydrophilic Metal-Phytate Coating for Efficient\nPhotoelectrochemical Water Oxidation","volume":"703","author":"Jiang","year":"2026","journal-title":"J. Colloid\nInterface Sci."},{"issue":"24","key":"2026092909102268900_cit64","doi-asserted-by":"publisher","first-page":"54145","DOI":"10.1016\/j.ceramint.2024.10.271","article-title":"Construction and Photothermal\nProperties of Ag Nanoparticles\nModified Multilevel Porous CuO Film with Ultra-Wide Infrared Spectrum\nAbsorption","volume":"50","author":"Cheng","year":"2024","journal-title":"Ceram. Int."},{"issue":"12","key":"2026092909102268900_cit65","doi-asserted-by":"publisher","first-page":"4720","DOI":"10.1021\/ac8026367","article-title":"Ion Desorption Efficiency\nand Internal Energy Transfer in Carbon-Based Surface-Assisted Laser\nDesorption\/Ionization Mass Spectrometry: Desorption Mechanism(s) and\nthe Design of SALDI Substrates","volume":"81","author":"Tang","year":"2009","journal-title":"Anal. Chem."},{"issue":"23","key":"2026092909102268900_cit66","doi-asserted-by":"publisher","first-page":"7926","DOI":"10.1039\/C5AN01754H","article-title":"Direct\nDetection of Illicit Drugs from Biological Fluids\nby Desorption\/ionization Mass Spectrometry with Nanoporous Silicon\nMicroparticles","volume":"140","author":"Guinan","year":"2015","journal-title":"Analyst"},{"issue":"1","key":"2026092909102268900_cit67","doi-asserted-by":"publisher","first-page":"25","DOI":"10.1038\/nnano.2014.311","article-title":"Plasmon-Induced\nHot Carrier Science\nand Technology","volume":"10","author":"Brongersma","year":"2015","journal-title":"Nat. Nanotechnol."},{"key":"2026092909102268900_cit68","article-title":"Principles\nof Field Ionization and Field Desorption Mass Spectrometry","author":"Beckey","year":"1977"},{"key":"2026092909102268900_cit69","article-title":"Field Ion Microscopy: Principles and Applications","author":"Mu\u0308ller","year":"1969"},{"key":"2026092909102268900_cit70","article-title":"Field Emission\nand Field Ionization","author":"Gomer","year":"1961"}],"container-title":["Analytical Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.analchem.6c02935","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/ancham\/article-pdf\/98\/38\/28065\/68521401\/acs.analchem.6c02935.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/ancham\/article-pdf\/98\/38\/28065\/68521401\/acs.analchem.6c02935.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T13:33:31Z","timestamp":1790688811000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/ancham\/article\/98\/38\/28065\/5430610\/Three-Dimensional-Hierarchical-Plasmonic"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,15]]},"references-count":70,"journal-issue":{"issue":"38","published-online":{"date-parts":[[2026,9,15]]},"published-print":{"date-parts":[[2026,9,29]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.analchem.6c02935","relation":{},"ISSN":["0003-2700","1520-6882"],"issn-type":[{"value":"0003-2700","type":"print"},{"value":"1520-6882","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,15]]}}}