{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,19]],"date-time":"2026-10-19T20:49:42Z","timestamp":1792442982111,"version":"4.5.0"},"reference-count":39,"publisher":"American Chemical Society (ACS)","issue":"9","license":[{"start":{"date-parts":[[2019,2,7]],"date-time":"2019-02-07T00:00:00Z","timestamp":1549497600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2019,2,7]],"date-time":"2019-02-07T00:00:00Z","timestamp":1549497600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2019,2,7]],"date-time":"2019-02-07T00:00:00Z","timestamp":1549497600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["GM 116894"],"award-info":[{"award-number":["GM 116894"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Biochemistry"],"published-print":{"date-parts":[[2019,3,5]]},"DOI":"10.1021\/acs.biochem.9b00041","type":"journal-article","created":{"date-parts":[[2019,2,7]],"date-time":"2019-02-07T19:57:10Z","timestamp":1549569430000},"page":"1246-1259","source":"Crossref","is-referenced-by-count":19,"title":["Transition State Analysis of the Reaction Catalyzed by the Phosphotriesterase from <i>Sphingobium<\/i> sp. TCM1"],"prefix":"10.1021","volume":"58","author":[{"given":"Andrew N.","family":"Bigley","sequence":"first","affiliation":[{"name":"Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dao Feng","family":"Xiang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tamari","family":"Narindoshvili","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Charlie W.","family":"Burgert","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Utah State University, Logan, Utah 84322, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5696-2087","authenticated-orcid":true,"given":"Alvan C.","family":"Hengge","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Utah State University, Logan, Utah 84322, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5918-3089","authenticated-orcid":true,"given":"Frank M.","family":"Raushel","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2019,2,7]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1128\/AEM.01845-14"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biochem.5b01144"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1007\/s00204-006-0120-2"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2012.03.067"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1016\/j.taap.2011.01.005"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.aquatox.2015.02.009"},{"key":"ref7\/cit7","volume-title":"Environmental Health Criteria 209, Flame Retardants: Tris(chloropropyl) Phosphate and Tris(2-chloroethyl) Phosphate","author":"World Health Organization","year":"1998"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2008.07.002"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biochem.6b00364"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b12739"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/bi00244a010"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/bi00437a021"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/bi047440d"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/bi960663m"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biochem.8b00145"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1016\/S0968-0896(01)00306-6"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/ja01055a001"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/ar000143q"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/bi00244a011"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/9780470143476.ch2"},{"key":"ref21\/cit21","first-page":"915","volume-title":"Isotope Effects in Chemistry and Biology","author":"Cleland W. W.","year":"2006"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1039\/C4RA01507J"},{"key":"ref23\/cit23","volume-title":"Ionisation Constants of Organic Acids in Aqueous Solution","author":"International Union on Pure and Applied Chemsitry","year":"1979"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/ja00176a067"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/bi0506270"},{"key":"ref26\/cit26","volume-title":"Structure and Mechanism in Protein Science: a Guide to Enzyme Catalysis and Protein Folding","author":"Fersht A.","year":"1999"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/ja01012a030"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/ja00176a067"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/ja072196+"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1021\/ja011025g"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/ja00091a003"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/bi960325l"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/bi0497805"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1016\/j.bbapap.2005.06.008"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1042\/BJ20101054"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1021\/bi010682i"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1038\/nsmb767"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/bi002661e"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1021\/bi300811t"}],"container-title":["Biochemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.biochem.9b00041","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,24]],"date-time":"2023-04-24T01:32:15Z","timestamp":1682299935000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.biochem.9b00041"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,2,7]]},"references-count":39,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2019,3,5]]}},"alternative-id":["10.1021\/acs.biochem.9b00041"],"URL":"https:\/\/doi.org\/10.1021\/acs.biochem.9b00041","relation":{},"ISSN":["0006-2960","1520-4995"],"issn-type":[{"value":"0006-2960","type":"print"},{"value":"1520-4995","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,2,7]]}}}