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However, native wood limits phase-change material (PCM) uptake, whereas extensive delignification removes lignin\u2019s intrinsic light-harvesting capacity. We developed a cell\u2212wall nano-engineering approach using aqueous p-toluenesulfonic acid to partially remove hemicellulose and redistribute retained lignin. This treatment increased cell-wall accessibility while preserving the wood's photothermal function. After impregnation with poly(ethylene glycol) impregnation, the resulting composite achieved a melting enthalpy of 154.9 J g\u22121 and an encapsulation efficiency of 78.5%. It showed no visible leakage at 80 \u00b0C and maintained stable thermal-storage performance over 100 heating\u2212cooling cycles (differential scanning calorimetry). Lignin redistribution and reassembly within the cell wall also improved water repellency and moisture resistance. Compared with native- and delignified-wood controls, the composite showed stronger broadband absorption and an apparent photothermal conversion efficiency of 83.2% under two-sun irradiation. This lignin-retaining strategy integrates physical PCM confinement, thermal storage, and intrinsic photothermal conversion without requiring additional light absorbers.<\/jats:p>","DOI":"10.1021\/acs.biomac.6c01239","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T07:02:39Z","timestamp":1788764559000},"page":"6636-6645","source":"Crossref","is-referenced-by-count":0,"title":["Lignin-Enabled Cell Wall Engineering of Wood for Integrated Photothermal Conversion and Phase Change Energy Storage"],"prefix":"10.1021","volume":"27","author":[{"given":"Xuetong","family":"Shi","sequence":"first","affiliation":[{"name":"The University of British Columbia , , 2360 East Mall , , ,","place":["Vancouver, British Columbia, Canada, V6T 1Z3"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2371-7368","authenticated-orcid":true,"given":"Yi","family":"Lu","sequence":"additional","affiliation":[{"name":"The University of British Columbia , , 2360 East Mall , , ,","place":["Vancouver, British Columbia, Canada, V6T 1Z3"]},{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, P. 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China, 100190"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Hu","sequence":"additional","affiliation":[{"name":"The University of British Columbia , , 2360 East Mall , , ,","place":["Vancouver, British Columbia, Canada, V6T 1Z3"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-8482-4578","authenticated-orcid":true,"given":"Ran","family":"Bi","sequence":"additional","affiliation":[{"name":"The University of British Columbia , , 2360 East Mall , , ,","place":["Vancouver, British Columbia, Canada, V6T 1Z3"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peipei","family":"Wang","sequence":"additional","affiliation":[{"name":"The University of British Columbia , , 2360 East Mall , , ,","place":["Vancouver, British Columbia, Canada, V6T 1Z3"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4036-4020","authenticated-orcid":true,"given":"Orlando J.","family":"Rojas","sequence":"additional","affiliation":[{"name":"The University of British Columbia , , 2360 East Mall , , ,","place":["Vancouver, British Columbia, Canada, V6T 1Z3"]},{"name":"University of British Columbia , , 2036 Main Mall , , ,","place":["Vancouver, British Columbia, Canada, V6T 1Z1"]},{"name":"The University of British Columbia , , 2424 Main Mall , , ,","place":["Vancouver, British Columbia, Canada, V6T 1Z4"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,7]]},"reference":[{"key":"2026101210522711900_cit1","doi-asserted-by":"publisher","first-page":"111443","DOI":"10.1016\/j.enbuild.2021.111443","article-title":"Inorganic phase change materials in thermal energy storage: A review on perspectives and technological advances in building applications","volume":"252","author":"Junaid","year":"2021","journal-title":"Energy Build."},{"key":"2026101210522711900_cit2","doi-asserted-by":"publisher","first-page":"274","DOI":"10.1016\/j.enbuild.2016.08.007","article-title":"Energy savings due to the use of PCM for relocatable lightweight buildings passive heating and cooling in different weather conditions","volume":"129","author":"Marin","year":"2016","journal-title":"Energy Build."},{"key":"2026101210522711900_cit3","doi-asserted-by":"publisher","first-page":"115960","DOI":"10.1016\/j.applthermaleng.2020.115960","article-title":"Thermal properties of composite organic phase change materials (PCMs): A critical review on their engineering chemistry","volume":"181","author":"Atinafu","year":"2020","journal-title":"Appl. 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