{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T13:48:35Z","timestamp":1785937715927,"version":"3.56.0"},"reference-count":66,"publisher":"American Chemical Society (ACS)","issue":"15","license":[{"start":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T00:00:00Z","timestamp":1783641600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"publisher","award":["TARISTU24-TK16"],"award-info":[{"award-number":["TARISTU24-TK16"]}],"id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"publisher","award":["TEM-TA25"],"award-info":[{"award-number":["TEM-TA25"]}],"id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002301","name":"Eesti Teadusagentuur","doi-asserted-by":"publisher","award":["PRG1702"],"award-info":[{"award-number":["PRG1702"]}],"id":[{"id":"10.13039\/501100002301","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005982","name":"Politechnika Wroclawska","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100005982","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","award":["TK133"],"award-info":[{"award-number":["TK133"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","award":["TK134"],"award-info":[{"award-number":["TK134"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Copper(II) coordination compounds are prospective building blocks of magnetic materials for future technologies and biologically active compounds. Their magnetic properties are greatly influenced by coordinating ligands, counterions, cocrystallization partners, and crystal arrangements. The self-organization of crystal structures containing [Cu(Arg)(B)]2+ cationic complexes is largely determined by the type of counteranions. Using NO3\u2013 ions resulted in the formation of a new copper(II) l\u2013arginato 1D polymeric complex, with the following formula: {[Cu(l\u2013Arg)(phen)(\u03bc-NO3)](NO3)\u00b7H2O}n. The results demonstrate the importance of interactions between NO3\u2013 and the [Cu(l\u2013Arg)(phen)]2+ coordination units in constructing the unit cell, stabilizing the structure and the spectroscopic and magnetic properties. The [Cu(l\u2013Arg)(phen)]2+ cations are linked by NO3\u2013 axial\u2013axial bridges with Cu\u00b7\u00b7\u00b7Cu distance of 7.071 \u00c5, which induced weak antiferromagnetic interactions between copper(II) ions with S = 1\/2. The O\u00b7\u00b7\u00b7H intermolecular interactions mostly control the molecular packing. The EPR (g\u22a5 = 2.056, g|| = 2.230) and vis (16970 cm\u20131) parameters confirm the elongated octahedral geometry (T = 0.76) and SOMO oriented in the xy plane N3O coordination sphere. Solid-state 13C NMR spectroscopy is used to characterize the distribution of spin density in organic ligands, with relativistic two-component (SO-ZORA) DFT calculations used to interpret experimental 13C NMR data. Our current N3O coordination polymer belongs to an interesting class of weakly coupled antiferromagnetic compounds.<\/jats:p>","DOI":"10.1021\/acs.cgd.6c00298","type":"journal-article","created":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T21:06:02Z","timestamp":1783717562000},"page":"5895-5904","source":"Crossref","is-referenced-by-count":1,"title":["Solid-State Arrangement\nand Magnetic Properties of\nHybrid Copper(II)-L-Arginine 1D Coordination Polymer Based on Nitrate\nBridges"],"prefix":"10.1021","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0854-7882","authenticated-orcid":true,"given":"Agnieszka","family":"Wojciechowska","sequence":"first","affiliation":[{"name":"Wroclaw University of Science and Technology , , Wyb. Wyspian\u0301skiego 27 , ,","place":["Wroclaw, Poland, 50\u2212370"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6094-0748","authenticated-orcid":true,"given":"Waldemar","family":"Maniukiewicz","sequence":"additional","affiliation":[{"name":"\u0141o\u0301dz\u0301 University of Technology , , Z\u0307eromskiego 116 , ,","place":["\u0141o\u0301dz\u0301, Poland, 90\u2212924"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7797-0262","authenticated-orcid":true,"given":"Les\u0142aw","family":"Sieron\u0301","sequence":"additional","affiliation":[{"name":"\u0141o\u0301dz\u0301 University of Technology , , Z\u0307eromskiego 116 , ,","place":["\u0141o\u0301dz\u0301, Poland, 90\u2212924"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Saied M.","family":"Soliman","sequence":"additional","affiliation":[{"name":"Faculty of Science Alexandria University , , P.O. Box 426, Ibrahimia, 8, ,","place":["Alexandria, Egypt, 21321"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria","family":"Jerzykiewicz","sequence":"additional","affiliation":[{"name":"University of Wroc\u0142aw , , Joliot\u2212Curie 14 , ,","place":["Wroc\u0142aw, Poland, 50-383"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria","family":"Korabik","sequence":"additional","affiliation":[{"name":"University of Wroc\u0142aw , , Joliot\u2212Curie 14 , ,","place":["Wroc\u0142aw, Poland, 50-383"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ivo","family":"Heinmaa","sequence":"additional","affiliation":[{"name":"National Institute of Chemical Physics and Biophysics , , Akadeemia tee 23 , ,","place":["Tallinn, Estonia, EE\u221212618"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joosep","family":"Link","sequence":"additional","affiliation":[{"name":"National Institute of Chemical Physics and Biophysics , , Akadeemia tee 23 , ,","place":["Tallinn, Estonia, EE\u221212618"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Raivo","family":"Stern","sequence":"additional","affiliation":[{"name":"National Institute of Chemical Physics and Biophysics , , Akadeemia tee 23 , ,","place":["Tallinn, Estonia, EE\u221212618"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1203-9549","authenticated-orcid":true,"given":"Jan","family":"Novotny\u0301","sequence":"additional","affiliation":[{"name":"Masaryk University , , ,","place":["Brno, Czechia, CZ\u221262500"]},{"name":"Masaryk University , , ,","place":["Brno, Czechia, CZ\u221262500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3668-3523","authenticated-orcid":true,"given":"Radek","family":"Marek","sequence":"additional","affiliation":[{"name":"Masaryk University , , ,","place":["Brno, Czechia, CZ\u221262500"]},{"name":"Masaryk University , , ,","place":["Brno, Czechia, CZ\u221262500"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,10]]},"reference":[{"key":"2026080509103225700_cit1","volume-title":"Coordination Polymers:\nDesign, Analysis and Application","author":"Batten","year":"2008","edition":"1"},{"key":"2026080509103225700_cit2","doi-asserted-by":"crossref","DOI":"10.1002\/9780470467336","volume-title":"Design and Construction\nof Coordination Polymers","author":"Hong","year":"2009","edition":"1"},{"key":"2026080509103225700_cit3","doi-asserted-by":"publisher","first-page":"3393","DOI":"10.1021\/acs.inorgchem.5b02749","article-title":"Hybrid Organic\u2013Inorganic\nCoordination Complexes as Tunable Optical Response Materials","volume":"55","author":"Travis","year":"2016","journal-title":"Inorg. Chem."},{"key":"2026080509103225700_cit4","doi-asserted-by":"publisher","first-page":"2713","DOI":"10.1039\/b407169g","article-title":"Magnetic nanoporous\ncoordination\npolymers","volume":"14","author":"Maspoch","year":"2004","journal-title":"J. Mater. Chem."},{"key":"2026080509103225700_cit5","doi-asserted-by":"publisher","first-page":"5408","DOI":"10.1039\/C6CS00395H","article-title":"Metal\u2013organic\nframeworks as competitive materials\nfor non-linear optics","volume":"45","author":"Mingabudinova","year":"2016","journal-title":"Chem. Soc. Rev."},{"key":"2026080509103225700_cit6","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/B978-0-12-816984-1.00005-6","volume-title":"Metal-Organic Frameworks\nfor Biomedical Applications","author":"Barbosa","year":"2020"},{"key":"2026080509103225700_cit7","doi-asserted-by":"publisher","first-page":"506","DOI":"10.1039\/C9CE01309A","article-title":"Tuning\nthe interpenetration of metal\u2013organic frameworks through changing\nligand functionality: effect on gas adsorption properties","volume":"22","author":"Li","year":"2020","journal-title":"CrystEngComm"},{"key":"2026080509103225700_cit8","doi-asserted-by":"publisher","first-page":"3563","DOI":"10.1007\/s11164-023-04957-0","article-title":"Copper(II) coordination polymer based\non L-arginine as a supramolecular hybrid inorganic\u2013organic\nmaterial: synthesis, structural, spectroscopic and magnetic properties","volume":"49","author":"Musio\u0142","year":"2023","journal-title":"Res. Chem. Intermed."},{"key":"2026080509103225700_cit9","doi-asserted-by":"publisher","first-page":"1533","DOI":"10.1016\/j.jpcs.2007.03.032","article-title":"Magnetic properties\nand EPR spectra\nof [Cu(L-arginine)2](NO3)2\u00b73H2O","volume":"68","author":"Gerard","year":"2007","journal-title":"J. Phys. Chem. Solids"},{"key":"2026080509103225700_cit10","doi-asserted-by":"publisher","first-page":"1265","DOI":"10.1080\/00958970701572386","article-title":"K. Syntheses\nand crystal structures\nof cis- and trans-copper(II) complexes\nof L-arginine","volume":"61","author":"Hu","year":"2008","journal-title":"J. Coord. Chem."},{"key":"2026080509103225700_cit11","doi-asserted-by":"publisher","first-page":"1111","DOI":"10.1021\/ic00059a015","article-title":"Structures\nand Stabilities of Ternary Copper(II) Complexes Containingan Acidic\nand a Basic Amino Acid. Evidence for Arginine Side Chain Involvement\nin Intermolecular Interactions and Its Biological Implication","volume":"32","author":"Masuda","year":"1993","journal-title":"Inorg. Chem."},{"key":"2026080509103225700_cit12","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2024.139226","article-title":"New 1D Cd(II) coordination\npolymer based on L\u2013arginine\nligand; Synthesis, X\u2013ray structure, Hirshfeld analysis, DFT\nstudies, and biological activity","volume":"1318","author":"Altowyan","year":"2024","journal-title":"J. Mol. Struct."},{"key":"2026080509103225700_cit13","doi-asserted-by":"publisher","first-page":"1467","DOI":"10.1021\/cg500019g","article-title":"Novel One\u2013Dimensional\nOrganic\u2013Inorganic Polyoxometalate Hybrids Constructed from\nHeteropolymolybdate Units and Copper\u2013Aminoacid Complexes","volume":"14","author":"Zhao","year":"2014","journal-title":"Cryst. Growth Des."},{"key":"2026080509103225700_cit14","doi-asserted-by":"publisher","first-page":"844","DOI":"10.1016\/j.poly.2012.07.031","article-title":"Synthesis,\nstructure and antimicrobial activity of L\u2013argininesilver(I)\nnitrate","volume":"52","author":"Takayama","year":"2013","journal-title":"Polyhedron"},{"key":"2026080509103225700_cit15","doi-asserted-by":"publisher","first-page":"1653","DOI":"10.1134\/S0022476615080302","article-title":"Structural\ncharacterization and antimicrobial\nactivity of a silver(I) complex of arginine","volume":"56","author":"Ahmad","year":"2015","journal-title":"J. Struct. Chem."},{"key":"2026080509103225700_cit16","doi-asserted-by":"publisher","first-page":"185","DOI":"10.1016\/j.ica.2011.08.015","article-title":"The preparation and crystal structure\nof acetatobis(L-arginine)zinc(II) acetate trihydrate, the first reported\nX\u2013ray structure of a zinc(II) \u2013 arginine complex","volume":"377","author":"Alagha","year":"2011","journal-title":"Inorg. Chim. Acta"},{"key":"2026080509103225700_cit17","doi-asserted-by":"publisher","first-page":"1358","DOI":"10.1080\/00958972.2019.1597065","article-title":"Isothiocyanate controlled architecture,\nspectroscopic,\nand magnetic behavior of copper(II) L\u2013arginine complexes","volume":"72","author":"Wojciechowska","year":"2019","journal-title":"J. Coord. Chem."},{"key":"2026080509103225700_cit18","doi-asserted-by":"publisher","first-page":"1250","DOI":"10.1016\/j.jinorgbio.2005.01.006","article-title":"Structural and spectroscopic characterization of aqua-diargininate-copper(II)-carbonate\nmonohydrate","volume":"99","author":"Viera","year":"2005","journal-title":"J. Inorg. Biochem."},{"issue":"6","key":"2026080509103225700_cit19","doi-asserted-by":"publisher","DOI":"10.3390\/ijms24065180","article-title":"Mechanochemical\nPreparation, Solid-State Characterization, and Antimicrobial Performance\nof Copper and Silver Nitrate Coordination Polymers with L- and DL-Arginine\nand Histidine","volume":"24","author":"Fiore","year":"2023","journal-title":"Int. J. Mol. Sci."},{"key":"2026080509103225700_cit20","doi-asserted-by":"publisher","first-page":"401","DOI":"10.1080\/00958970410001689832","article-title":"Synthesis and crystal\nstructures of one-dimensional ClO4\u2013 bridged\ncoordination polymers: {[Cu(Bpy)2(\u03bc2-ClO4)]\u00b7ClO4}n and {[Cu2(L-arg)2(Bpy)2(\u03bc2-ClO4)2]\u00b72ClO4\u00b74H2O}n","volume":"57","author":"Zhou","year":"2004","journal-title":"J. Coord. Chem."},{"key":"2026080509103225700_cit21","doi-asserted-by":"publisher","first-page":"37","DOI":"10.1016\/S0020-1693(98)00375-2","article-title":"Aromatic carboxylate-controlled\nself-organization\nof copper(II)\u2013l-arginine complexes","volume":"286","author":"Ohata","year":"1999","journal-title":"Inorg.\nChim. Acta"},{"key":"2026080509103225700_cit22","doi-asserted-by":"publisher","first-page":"749","DOI":"10.1016\/S0020-1693(00)00013-X","article-title":"Dianion-controlled supramolecular\nassembly of copper(II)-arginine complex ion","volume":"300-302","author":"Ohata","year":"2000","journal-title":"Inorg. Chim. Acta"},{"key":"2026080509103225700_cit23","doi-asserted-by":"publisher","first-page":"1533","DOI":"10.1016\/j.jpcs.2007.03.032","article-title":"Magnetic properties\nand EPR spectra\nof [Cu(L-arginine)2](NO3)2 3H2O","volume":"68","author":"Gerard","year":"2007","journal-title":"J. Phys. Chem. Solids"},{"key":"2026080509103225700_cit24","doi-asserted-by":"publisher","first-page":"41","DOI":"10.1016\/S0020-1693(00)82083-6","article-title":"The preparation\nand crystal structure analysis of bis(L-Arginine)Cu(II)(acetate)2trihydrate","volume":"124","author":"Duarte","year":"1986","journal-title":"Inorg. Chim. Acta"},{"key":"2026080509103225700_cit25","doi-asserted-by":"publisher","first-page":"472","DOI":"10.1016\/j.matchemphys.2016.07.059","article-title":"Supramolecular\nassemblies in [Cu(L-Arg)2(H2O)]C2O4\u00b76H2O complex \u2013 Structural, spectroscopic,\nmagnetic and thermal\nbehaviour","volume":"182","author":"Wojciechowska","year":"2016","journal-title":"Mater. Chem. Phys."},{"key":"2026080509103225700_cit26","doi-asserted-by":"publisher","first-page":"531","DOI":"10.1002\/anie.199605311","article-title":"Programmed\nSelf-Assembly of Copper(II)-L-\nand -D-Arginine Complexes with Aromatic Dicarboxylates to Form Chiral\nDouble-Helical Structures","volume":"35","author":"Ohata","year":"1996","journal-title":"Angew, Chem. Int.\nEd."},{"key":"2026080509103225700_cit27","doi-asserted-by":"publisher","first-page":"58","DOI":"10.1007\/s10947-008-0107-3","article-title":"Crystal structure of bis(L\u2013arginine)copper(II)\nhexachlorodimercurate, [Cu(L\u2013Arg)2]Hg2Cl6","volume":"49","author":"Zabel","year":"2008","journal-title":"J. Struct. Chem."},{"key":"2026080509103225700_cit28","doi-asserted-by":"publisher","first-page":"2932","DOI":"10.1021\/ic8017425","article-title":"Copper(II) Complexes of l\u2013Arginine as Netropsin\nMimics Showing DNA Cleavage Activity in Red Light","volume":"48","author":"Patra","year":"2009","journal-title":"Inorg. Chem."},{"key":"2026080509103225700_cit29","doi-asserted-by":"publisher","first-page":"9030","DOI":"10.1021\/ic701326z","article-title":"Metal-Based\nNetropsin Mimics Showing AT-Selective DNA Binding and DNA Cleavage\nActivity at Red Light","volume":"46","author":"Patra","year":"2007","journal-title":"Inorg. Chem."},{"key":"2026080509103225700_cit30","doi-asserted-by":"publisher","first-page":"847","DOI":"10.1080\/00958970701476943","article-title":"Syntheses,\ncharacterizations and\nSOD-like activities of ternary copper(II) complexes with 1,10-phenanthroline\nand L- \u03b1 -amino acids","volume":"61","author":"Liao","year":"2008","journal-title":"J. Coord. Chem."},{"key":"2026080509103225700_cit31","doi-asserted-by":"publisher","first-page":"3829","DOI":"10.1080\/00958970802150090","article-title":"Synthesis,\ncharacterization and SOD-like activity of a ternary copper(II) complex\nwith 1,10-phenanthroline and L\u2013arginine","volume":"61","author":"Ma","year":"2008","journal-title":"J. Coord. Chem."},{"key":"2026080509103225700_cit32","doi-asserted-by":"publisher","first-page":"272","DOI":"10.1016\/j.matchemphys.2019.02.037","article-title":"Copper(II) complex\nwith L-arginine\n\u2013 Crystal structure, DFT calculations, spectroscopic, thermal\nand magnetic properties","volume":"228","author":"Wojciechowska","year":"2019","journal-title":"Mater. Chem. Phys."},{"key":"2026080509103225700_cit33","doi-asserted-by":"publisher","first-page":"36295","DOI":"10.1039\/C5RA02790J","article-title":"Metal\u2013organic\nframework in\nan L-arginine copper(II) ion polymer: structure, properties, theoretical\nstudies and microbiological activity","volume":"5","author":"Wojciechowska","year":"2015","journal-title":"RSC Adv."},{"key":"2026080509103225700_cit34","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2022.134776","article-title":"The influence of ancillary NCS\u2013 ions\non structural, spectroscopic, magnetic and biological\nproperties of copper(II) L -argininato complex","volume":"1276","author":"Wojciechowska","year":"2023","journal-title":"J. Mol. Struct."},{"key":"2026080509103225700_cit35","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2023.121698","article-title":"The supramolecular hybrid inorganic\u2013organic\nL-argininato-based copper(II) materials \u2013 preparation, structural,\nspectroscopic and thermal properties","volume":"557","author":"Wojciechowska","year":"2023","journal-title":"Inorg.\nChim. Acta"},{"key":"2026080509103225700_cit36","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2024.138094","article-title":"New heteroleptic L-argininato copper(II) complex with\nbromide and N, N\u2019\u2013 heterocyclic ligands \u2013 synthesis,\nsupramolecular, spectroscopic, magnetic and theoretical investigations","volume":"1308","author":"Walkowiak","year":"2024","journal-title":"J. Mol. Struct."},{"key":"2026080509103225700_cit37","doi-asserted-by":"publisher","first-page":"886","DOI":"10.1080\/00958972.2016.1147561","article-title":"1\u2013D\nFramework L-arginine zinc(II)\nunits bridged by oxalate: synthesis, structure, properties, and theoretical\nstudies","volume":"69","author":"Wojciechowska","year":"2016","journal-title":"J. Coord. Chem."},{"key":"2026080509103225700_cit38","doi-asserted-by":"publisher","first-page":"591","DOI":"10.1016\/S0020-1693(00)91863-2","article-title":"The Structure of (+)-dinitrobis-(L-arginato)cobalt(III)\nNitrate Dihydrate","volume":"6","author":"Watson","year":"1972","journal-title":"Inorg. Chim. Acta"},{"key":"2026080509103225700_cit39","doi-asserted-by":"publisher","first-page":"414","DOI":"10.1016\/j.msec.2018.05.065","article-title":"Synthesis,\ncharacterization, DNA\/HSA interactions and in vitro cytotoxic activities\nof two novel water-soluble copper(II) complexes with 1,3,5- triazine\nderivative ligand and amino acids","volume":"91","author":"Zhang","year":"2018","journal-title":"Mater. Sci.\nEng., C"},{"key":"2026080509103225700_cit40","doi-asserted-by":"publisher","first-page":"7652","DOI":"10.1021\/jp801418h","article-title":"Effect of metal ions (Li+, Na+, K+, Mg2+, Ca2+, Ni2+, Cu2+, and Zn2+) and water\ncoordination on the structure and properties of L-arginine and zwitterionic\nL-arginine","volume":"112","author":"Remko","year":"2008","journal-title":"J. Phys. Chem. A"},{"key":"2026080509103225700_cit41","volume-title":"CrysAlis PRO","author":"Rigaku","year":"2019"},{"key":"2026080509103225700_cit42","doi-asserted-by":"publisher","first-page":"3","DOI":"10.1107\/S2053273314026370","article-title":"SHELXT\n- integrated space-group and crystal-structure determination","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr., Sect. A:Found. Adv."},{"key":"2026080509103225700_cit43","doi-asserted-by":"publisher","first-page":"3","DOI":"10.1107\/S2053229614024218","article-title":"Crystal\nstructure refinement with SHELXL","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr.,\nSect. C:Struct. Chem."},{"key":"2026080509103225700_cit44","volume-title":"Crystal Explorer","author":"Turner","year":"2017"},{"key":"2026080509103225700_cit45","doi-asserted-by":"publisher","first-page":"532","DOI":"10.1021\/ed085p532","article-title":"Diamagnetic Corrections\nand Pascal\u2019s Constants","volume":"85","author":"Bain","year":"2008","journal-title":"J. Chem. Educ."},{"key":"2026080509103225700_cit46","doi-asserted-by":"publisher","first-page":"325","DOI":"10.1002\/3527601678.ch20","article-title":"First-Principles\nCalculations of Paramagnetic NMR Shifts","volume-title":"Calculation of NMR and EPR Parameters: Theory and Applications.","author":"Moon","year":"2004"},{"key":"2026080509103225700_cit47","doi-asserted-by":"publisher","first-page":"8432","DOI":"10.1021\/jacs.6b02749","article-title":"Interpreting the Paramagnetic NMR\nSpectra of Potential Ru(III) Metallodrugs:\nSynergy between Experiment and Relativistic DFT Calculations","volume":"138","author":"Novotny\u0301","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"2026080509103225700_cit48","doi-asserted-by":"publisher","first-page":"1467","DOI":"10.1021\/acs.accounts.3c00786","article-title":"Paramagnetic Effects in NMR Spectroscopy\nof Transition-Metal Complexes: Principles and Chemical Concepts","volume":"57","author":"Novotny\u0301","year":"2024","journal-title":"Acc. Chem. Res."},{"issue":"2","key":"2026080509103225700_cit49","doi-asserted-by":"publisher","first-page":"357","DOI":"10.1039\/B509070A","article-title":"Structural\nsystematics of the [Cu(chelate)3][Y]2 series.\nAn interesting crystallographic structural insight involving vibronic\ncoupling and the Jahn\u2013Teller effect (JTE). The syntheses and\nlow temperature crystal structures of tris(2,2\u2032bipyridyl)copper(ii)\ntetraphenylborate and tris(2,2\u2032bipyridyl)zinc(ii) tetraphenylborate","author":"Murphy","year":"2006","journal-title":"Dalton Trans."},{"key":"2026080509103225700_cit50","doi-asserted-by":"publisher","DOI":"10.1039\/9781847559456","volume-title":"Metal-Ligand Bonding","author":"Moore","year":"2004"},{"key":"2026080509103225700_cit51","doi-asserted-by":"publisher","first-page":"245","DOI":"10.1016\/j.jcat.2020.06.015","article-title":"Infrared\nspectra of surface nitrates: Revision of the current opinions based\non the case study of ceria","volume":"394","author":"Mihaylov","year":"2021","journal-title":"J. Catal."},{"key":"2026080509103225700_cit52","doi-asserted-by":"publisher","first-page":"264","DOI":"10.1016\/j.molstruc.2013.01.003","article-title":"Extremely\ndifferent structures and vibrational spectra\nof tetramethylpyrazine nitrate dihydrate in solid and solutions","volume":"1037","author":"Sobczyk","year":"2013","journal-title":"J. Mol. Struct."},{"key":"2026080509103225700_cit53","doi-asserted-by":"publisher","first-page":"7584","DOI":"10.1021\/jp9017103","article-title":"Infrared Spectroscopy\nof the Microhydrated Nitrate\nIons NO3\u2013(H2O)1\u20136","volume":"113","author":"Goebbert","year":"2009","journal-title":"J. Phys. Chem. A"},{"key":"2026080509103225700_cit54","doi-asserted-by":"publisher","first-page":"C64","DOI":"10.1088\/0031-8949\/73\/1\/N12","article-title":"New insights into the\nJahn\u2013Teller effect in NO3 via the dark A\u0303 2E\u2019\u2019 state","volume":"73","author":"Okumura","year":"2006","journal-title":"Phys. Scr."},{"key":"2026080509103225700_cit55","doi-asserted-by":"publisher","first-page":"6760","DOI":"10.1063\/1.1310615","article-title":"Far-ultraviolet\nresonance Raman spectroscopy of nitrate\nion in solution","volume":"113","author":"Waterland","year":"2000","journal-title":"J. Chem. Phys."},{"key":"2026080509103225700_cit56","volume-title":"Molecular Magnetism","author":"Kahn","year":"1993"},{"key":"2026080509103225700_cit57","doi-asserted-by":"publisher","first-page":"1164","DOI":"10.1002\/jcc.23234","article-title":"PHI: a\npowerful new program for the analysis of anisotropic monomeric and\nexchange-coupled polynuclear d- and f-block complexes","volume":"34","author":"Chilton","year":"2013","journal-title":"J. Comput. Chem."},{"key":"2026080509103225700_cit58","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.135.A640","article-title":"Linear Magnetic Chains with Anisotroyic Coupling","volume":"135","author":"Bonner","year":"1964","journal-title":"Phys. Rev."},{"key":"2026080509103225700_cit59","doi-asserted-by":"publisher","first-page":"11611","DOI":"10.1021\/ic8011519","article-title":"Rare Example\nof \u03bc-Nitrito-1\u03ba2O, O\u2032:2\u03baO Coordinating\nMode in Copper(II) Nitrite Complexes with Monoanionic Tridentate Schiff\nBase Ligands: Structure, Magnetic, and Electrochemical Properties","volume":"47","author":"Sarkar","year":"2008","journal-title":"Inorg. Chem."},{"key":"2026080509103225700_cit60","doi-asserted-by":"publisher","first-page":"691","DOI":"10.1016\/0003-9861(74)90298-7","article-title":"Structural implications\nderived from the analysis of\nelectron paramagnetic resonance spectra of natural and artificial\ncopper proteins","volume":"165","author":"Peisach","year":"1974","journal-title":"Arch. Biochem. Biophys."},{"key":"2026080509103225700_cit61","doi-asserted-by":"publisher","first-page":"851","DOI":"10.1246\/bcsj.74.851","article-title":"Assignment\nof d\u2013d Transitions\nof Square Planar [CuIIN4] Complexes Containing\nImidate and Amine Ligands by Means of Polarized Crystal Spectra","volume":"74","author":"Akitsu","year":"2001","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"2026080509103225700_cit62","volume-title":"The Principles of Nuclear\nMagnetism","author":"Abragam","year":"1961"},{"key":"2026080509103225700_cit63","doi-asserted-by":"publisher","first-page":"9368","DOI":"10.1021\/acs.inorgchem.1c00204","article-title":"Crystal and\nSubstituent Effects on\nParamagnetic NMR Shifts in Transition-Metal Complexes","volume":"60","author":"Novotny\u0301","year":"2021","journal-title":"Inorg. Chem."},{"key":"2026080509103225700_cit64","doi-asserted-by":"publisher","first-page":"8748","DOI":"10.1021\/acs.inorgchem.8b00073","article-title":"Interplay of Through-Bond Hyperfine and Substituent Effects on the\nNMR Chemical Shifts in Ru(III) Complexes","volume":"57","author":"Jeremias","year":"2018","journal-title":"Inorg.\nChem."},{"key":"2026080509103225700_cit65","doi-asserted-by":"publisher","first-page":"8580","DOI":"10.1021\/acs.inorgchem.3c04425","article-title":"Mechanisms of Ligand Hyperfine Coupling\nin Transition-Metal Complexes: \u03c3 and \u03c0 Transmission Pathways","volume":"63","author":"Novotny\u0301","year":"2024","journal-title":"Inorg. Chem."},{"key":"2026080509103225700_cit66","doi-asserted-by":"publisher","first-page":"9042","DOI":"10.1039\/D5SC09905F","article-title":"Unraveling the coordination\nisomerism by ligand hyperfine NMR shifts","volume":"17","author":"Cidlinska\u0301","year":"2026","journal-title":"Chem.\nSci."}],"container-title":["Crystal Growth &amp; Design"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.cgd.6c00298","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/cgdefu\/article-pdf\/26\/15\/5895\/65879821\/acs.cgd.6c00298.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/cgdefu\/article-pdf\/26\/15\/5895\/65879821\/acs.cgd.6c00298.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T13:21:17Z","timestamp":1785936077000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/cgdefu\/article\/26\/15\/5895\/5206803\/Solid-State-Arrangement-and-Magnetic-Properties-of"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,10]]},"references-count":66,"journal-issue":{"issue":"15","published-online":{"date-parts":[[2026,7,10]]},"published-print":{"date-parts":[[2026,8,5]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.cgd.6c00298","relation":{},"ISSN":["1528-7483","1528-7505"],"issn-type":[{"value":"1528-7483","type":"print"},{"value":"1528-7505","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,10]]}}}