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In parallel with well-established precious metal catalysts, increasing research efforts have shifted toward the use of earth-abundant 3d transition metals, driven by their distinctive intrinsic properties and reactivity profiles. This review summarizes the rapid progress in 3d metal-catalyzed enantioselective C\u2013H functionalization up to March 2025, encompassing both inner-sphere and outer-sphere mechanisms. Emphasis is placed on the underlying challenges and core strategic solutions that have enabled these developments. To provide a comprehensive perspective, the advancements are categorized based on distinct metal\/ligand catalytic systems and subcategorized according to the type of C\u2013H functionalization reactions. Key aspects such as ligand design, reaction development, mechanistic insights, synthetic applications, and current limitations are discussed in detail where appropriate.<\/jats:p>","DOI":"10.1021\/acs.chemrev.6c00255","type":"journal-article","created":{"date-parts":[[2026,7,16]],"date-time":"2026-07-16T13:16:08Z","timestamp":1784207768000},"page":"8768-8852","source":"Crossref","is-referenced-by-count":5,"title":["Earth-Abundant\n3d Transition Metal-Catalyzed Enantioselective\nC\u2013H Functionalization"],"prefix":"10.1021","volume":"126","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2065-3669","authenticated-orcid":true,"given":"Pu-Fan","family":"Qian","sequence":"first","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia-Heng","family":"Hu","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan-Xuan","family":"Wu","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Xu","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2767-6556","authenticated-orcid":true,"given":"Keary M.","family":"Engle","sequence":"additional","affiliation":[{"name":"The Scripps Research Institute , , 10550 N. Torrey Pines Road , , ,","place":["La Jolla, California, United States, 92037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0375-955X","authenticated-orcid":true,"given":"Bing-Feng","family":"Shi","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,16]]},"reference":[{"key":"2026081208065068300_cit1","doi-asserted-by":"publisher","first-page":"112","DOI":"10.1016\/0165-6147(86)90276-2","article-title":"Chirality of Bioactive Agents in\nProtein Binding Storage and Transport Processes","volume":"7","author":"Simonyi","year":"1986","journal-title":"Trends Pharmacol. Sci."},{"key":"2026081208065068300_cit2","volume-title":"Chirality and the Biological\nActivity of Drugs","author":"Crossley","year":"1995"},{"key":"2026081208065068300_cit3a","doi-asserted-by":"publisher","first-page":"187","DOI":"10.1039\/cs9891800187","article-title":"Chemical Multiplication\nof Chirality: Science and Applications","volume":"18","author":"Noyori","year":"1989","journal-title":"Chem.\nSoc. Rev."},{"key":"2026081208065068300_cit3b","doi-asserted-by":"publisher","first-page":"1691","DOI":"10.1126\/science.1083622","article-title":"Privileged Chiral\nCatalysts","volume":"299","author":"Yoon","year":"2003","journal-title":"Science"},{"key":"2026081208065068300_cit3c","doi-asserted-by":"publisher","first-page":"3561","DOI":"10.1021\/cr0505324","article-title":"C\n            2-Symmetric Chiral Bis(Oxazoline)\nLigands in Asymmetric Catalysis","volume":"106","author":"Desimoni","year":"2006","journal-title":"Chem. 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Chem.\nSoc."},{"key":"2026081208065068300_cit38","doi-asserted-by":"publisher","first-page":"20462","DOI":"10.1021\/jacs.1c10743","article-title":"Modular Access\nto Spiro-dihydroquinolines via Scandium-Catalyzed\nDearomative Annulation of Quinolines with Alkynes","volume":"143","author":"Lou","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit39","doi-asserted-by":"publisher","first-page":"1416","DOI":"10.1021\/jacs.4c15046","article-title":"Synthesis of Rigid\nStepladder Polymers via Scandium-Catalyzed Polyspiroannulation\nof Quinoline with Alkyne","volume":"147","author":"Shao","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit40","doi-asserted-by":"publisher","first-page":"2470","DOI":"10.1021\/jacs.0c13166","article-title":"Enantioselective\nC\u2013H Alkenylation of Ferrocenes with Alkynes by Half-Sandwich\nScandium Catalyst","volume":"143","author":"Lou","year":"2021","journal-title":"J. Am. Chem. 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Soc."},{"key":"2026081208065068300_cit68","doi-asserted-by":"publisher","first-page":"1411","DOI":"10.1021\/cr00014a008","article-title":"Metalloporphyrins\nas Versatile Catalysts for Oxidation Reactions and Oxidative DNA Cleavage","volume":"92","author":"Meunier","year":"1992","journal-title":"Chem. Rev."},{"key":"2026081208065068300_cit69a","doi-asserted-by":"publisher","first-page":"6375","DOI":"10.1021\/ja00540a050","article-title":"Hydrocarbon\nOxidations with Oxometalloporphinates. Isolation and Reactions of\na (Porphinato)manganese(V) Complex","volume":"102","author":"Groves","year":"1980","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026081208065068300_cit69b","doi-asserted-by":"publisher","first-page":"6269","DOI":"10.1021\/ja962605u","article-title":"Detection\nand Characterization of an Oxomanganese(V) Porphyrin Complex by Rapid-Mixing\nStopped-Flow Spectrophotometry","volume":"119","author":"Groves","year":"1997","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026081208065068300_cit69c","doi-asserted-by":"publisher","first-page":"12416","DOI":"10.1021\/ja0761737","article-title":"Trans-dioxo Manganese(V) Porphyrins","volume":"129","author":"Jin","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit70","doi-asserted-by":"publisher","first-page":"5850","DOI":"10.1021\/ic300457z","article-title":"Enantioselective Manganese-Porphyrin-Catalyzed\nEpoxidation and C\u2013H Hydroxylation with Hydrogen Peroxide in\nWater\/Methanol Solutions","volume":"51","author":"Srour","year":"2012","journal-title":"Inorg. Chem."},{"key":"2026081208065068300_cit71","doi-asserted-by":"publisher","first-page":"5253","DOI":"10.1021\/jo00018a008","article-title":"Catalytic Asymmetric\nEpoxidation of Unfunctionalized\nAlkenes Using the First D4-Symmetric Metallotetraphenylporphyrin","volume":"56","author":"Halterman","year":"1991","journal-title":"J. Org. Chem."},{"key":"2026081208065068300_cit72","doi-asserted-by":"publisher","first-page":"5793","DOI":"10.1016\/j.tetlet.2008.07.133","article-title":"Synthesis of Chiral Water-Soluble\nMetalloporphyrins (Fe, Ru): New Catalysts for Asymmetric Carbene Transfer\nin Water","volume":"49","author":"Nicolas","year":"2008","journal-title":"Tetrahedron Lett."},{"key":"2026081208065068300_cit73a","doi-asserted-by":"publisher","first-page":"4268","DOI":"10.1021\/ic060306s","article-title":"Electronic Structure and Reactivity of Isomeric Oxo-Mn(V)\nPorphyrins: Effects of Spin-State Crossing and pKa Modulation","volume":"45","author":"De Angelis","year":"2006","journal-title":"Inorg. Chem."},{"key":"2026081208065068300_cit73b","doi-asserted-by":"publisher","first-page":"11516","DOI":"10.1021\/ic1015274","article-title":"A \u201cPush-Pull\u201d\nMechanism for Heterolytic O\u2013O Bond Cleavage in Hydroperoxo\nManganese Porphyrins","volume":"49","author":"Jin","year":"2010","journal-title":"Inorg. 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Sci."},{"key":"2026081208065068300_cit82","doi-asserted-by":"publisher","first-page":"5323","DOI":"10.1002\/cctc.201801476","article-title":"Enantioselective\nBenzylic Hydroxylation of Arylalkanes with H2O2 in Fluorinated Alcohols in the Presence of Chiral Mn Aminopyridine\nComplexes","volume":"10","author":"Ottenbacher","year":"2018","journal-title":"ChemCatChem."},{"key":"2026081208065068300_cit83","doi-asserted-by":"publisher","first-page":"170","DOI":"10.1016\/j.jcat.2020.08.005","article-title":"Highly\nEnantioselective Undirected\nCatalytic Hydroxylation of Benzylic CH2 groups with H2O2","volume":"390","author":"Ottenbacher","year":"2020","journal-title":"J. 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Sci."},{"key":"2026081208065068300_cit102","doi-asserted-by":"publisher","first-page":"6243","DOI":"10.1021\/ja00358a009","article-title":"Aliphatic Hydroxylation\nCatalyzed\nby Iron Porphyrin Complexes","volume":"105","author":"Groves","year":"1983","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit103a","doi-asserted-by":"publisher","first-page":"8537","DOI":"10.1021\/ja00204a047","article-title":"Asymmetric Hydroxylation\nby a Chiral Iron Porphyrin","volume":"111","author":"Groves","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit103b","doi-asserted-by":"publisher","first-page":"3628","DOI":"10.1021\/jo00298a046","article-title":"Asymmetric Hydroxylation, Epoxidation,\nand Sulfoxidation Catalyzed by Vaulted Binaphthyl Metalloporphyrins","volume":"55","author":"Groves","year":"1990","journal-title":"J. Org. 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Lett."},{"key":"2026081208065068300_cit105","doi-asserted-by":"publisher","first-page":"5824","DOI":"10.1016\/j.tet.2012.05.014","article-title":"Enantioselective\nWater-Soluble Iron-Porphyrin-Catalyzed Epoxidation with Aqueous Hydrogen\nPeroxide and Hydroxylation with Iodobenzene Diacetate","volume":"68","author":"Le Maux","year":"2012","journal-title":"Tetrahedron"},{"key":"2026081208065068300_cit106","doi-asserted-by":"publisher","first-page":"16211","DOI":"10.1021\/jacs.0c07810","article-title":"Iron-Catalyzed\nAmination of Strong Aliphatic C(sp3)\u2013H Bonds","volume":"142","author":"Das","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit107","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218577","article-title":"Chiral\nIron Porphyrins Catalyze Enantioselective Intramolecular C(sp3)\u2013H Bond Amination Upon Visible-Light Irradiation","volume":"62","author":"Wang","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081208065068300_cit108","doi-asserted-by":"publisher","first-page":"6318","DOI":"10.1021\/jacs.9b00615","article-title":"Iron-Catalyzed Aerobic\nDehydrogenative Kinetic Resolution of Cyclic Secondary Amines","volume":"141","author":"Lu","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit109a","doi-asserted-by":"publisher","first-page":"2274","DOI":"10.1002\/zaac.200300222","article-title":"Synthesis,\nStructure, and Spectroscopic Properties of a Dinuclear FeIII(\u03bc2-O)FeIII Complex\nUsing a Strongly Electron-Donating Ligand: Implications for the Generation\nof New High-Valent Species","volume":"629","author":"Glaser","year":"2003","journal-title":"Z. Anorg. Allg.\nChem."},{"key":"2026081208065068300_cit109b","doi-asserted-by":"publisher","first-page":"6804","DOI":"10.1021\/ic800335t","article-title":"Molecular and Electronic\nStructures of Mononuclear Iron Complexes Using Strongly Electron-Donating\nLigands and their Oxidized Forms","volume":"47","author":"Strautmann","year":"2008","journal-title":"Inorg. Chem."},{"key":"2026081208065068300_cit110a","doi-asserted-by":"publisher","first-page":"6082","DOI":"10.1021\/ja901391u","article-title":"Iron-catalyzed Asymmetric\nAerobic Oxidation: Oxidative Coupling of 2-Naphthols","volume":"131","author":"Egami","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit110b","doi-asserted-by":"publisher","first-page":"13633","DOI":"10.1021\/ja105442m","article-title":"Enantioenriched\nSynthesis of C1-Symmetric BINOLs: Iron-Catalyzed\nCross-Coupling of 2-Naphthols and Some Mechanistic Insight","volume":"132","author":"Egami","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit110c","doi-asserted-by":"publisher","first-page":"5823","DOI":"10.1039\/c2cc18090a","article-title":"What Factors Influence\nthe Catalytic Activity of Iron-Salan Complexes for Aerobic Oxidative\nCoupling of 2-Naphthols?","volume":"48","author":"Matsumoto","year":"2012","journal-title":"Chem. Commun."},{"key":"2026081208065068300_cit111a","doi-asserted-by":"publisher","first-page":"3653","DOI":"10.1021\/ja00324a041","article-title":"Assembly and Characterization\nof\nan Accurate Model for the Diiron Center in Hemerythrin","volume":"106","author":"Armstrong","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit111b","doi-asserted-by":"publisher","first-page":"12356","DOI":"10.1021\/ja00154a047","article-title":"Biomimetic Oxidation Studies. 9.\nMechanistic Aspects of the Oxidation of Alcohols with Functional,\nActive Site Methane Monooxygenase Enzyme Models in Aqueous Solution","volume":"117","author":"Rabion","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit111c","doi-asserted-by":"publisher","first-page":"2607","DOI":"10.1021\/cr960039f","article-title":"Dioxygen Activation\nby Enzymes with Mononuclear Non-Heme Iron Active Sites","volume":"96","author":"Que","year":"1996","journal-title":"Chem. Rev."},{"key":"2026081208065068300_cit111d","doi-asserted-by":"publisher","first-page":"8566","DOI":"10.1021\/ja971503g","article-title":"C\u2013H Bond Activation by a Ferric Methoxide Complex:\nA Model for the Rate-Determining Step in the Mechanism of Lipoxygenase","volume":"119","author":"Jonas","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit111e","doi-asserted-by":"publisher","first-page":"2760","DOI":"10.1021\/ic990251c","article-title":"Hydrogen Transfer Reactivity of a Ferric Bi-imidazoline\nComplex that Models the Activity of Lipoxygenase Enzymes","volume":"38","author":"Roth","year":"1999","journal-title":"Inorg. Chem."},{"key":"2026081208065068300_cit112","doi-asserted-by":"publisher","first-page":"85","DOI":"10.1016\/S1381-1169(99)00402-1","article-title":"Hydroxylation\nof Alkanes Catalysed\nby a Chiral \u03bc-Oxo Diferric Complex: A Metal-Based\nMechanism","volume":"156","author":"Mekmouche","year":"2000","journal-title":"J. Mol. Catal. A: Chem."},{"key":"2026081208065068300_cit113a","doi-asserted-by":"publisher","first-page":"100","DOI":"10.1038\/nature13892","article-title":"Asymmetric Photoredox\nTransition-Metal Catalysis Activated by Visible Light","volume":"515","author":"Huo","year":"2014","journal-title":"Nature"},{"key":"2026081208065068300_cit113b","doi-asserted-by":"publisher","first-page":"320","DOI":"10.1021\/acs.accounts.6b00586","article-title":"Steering Asymmetric Lewis Acid Catalysis\nExclusively with Octahedral Metal-Centered Chirality","volume":"50","author":"Zhang","year":"2017","journal-title":"Acc. Chem. Res."},{"key":"2026081208065068300_cit114a","doi-asserted-by":"publisher","first-page":"4322","DOI":"10.1021\/jacs.7b01098","article-title":"Octahedral\nRuthenium Complex with Exclusive Metal-Centered Chirality for Highly\nEffective Asymmetric Catalysis","volume":"139","author":"Zheng","year":"2017","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026081208065068300_cit114b","doi-asserted-by":"publisher","first-page":"1088","DOI":"10.1002\/anie.201811927","article-title":"Catalytic Enantioselective Intramolecular C(sp3)\u2013H Amination of 2-Azidoacetamides","volume":"58","author":"Zhou","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081208065068300_cit114c","doi-asserted-by":"publisher","first-page":"3202","DOI":"10.1039\/C9SC00054B","article-title":"Enantioselective\nIntramolecular C\u2013H Amination of Aliphatic Azides by Dual Ruthenium\nand Phosphine Catalysis","volume":"10","author":"Qin","year":"2019","journal-title":"Chem. Sci."},{"key":"2026081208065068300_cit115","doi-asserted-by":"publisher","first-page":"566","DOI":"10.1038\/s41557-022-00895-3","article-title":"Stereocontrolled\n1,3-Nitrogen Migration to Access Chiral \u03b1-Amino\nAcids","volume":"14","author":"Ye","year":"2022","journal-title":"Nat. Chem."},{"key":"2026081208065068300_cit116","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202300296","article-title":"N-Boc-Protected \u03b1-Amino Acids by 1,3-Migratory\nNitrene C(sp3)\u2013H Insertion","volume":"26","author":"Zhou","year":"2023","journal-title":"Eur. J. Org. Chem."},{"key":"2026081208065068300_cit117","doi-asserted-by":"publisher","first-page":"2065","DOI":"10.1002\/cjoc.202300162","article-title":"Enantioselective\nand Enantioconvergent Iron-Catalyzed C(sp3)\u2013H Aminations\nto Chiral 2-Imidazolidinones","volume":"41","author":"Cui","year":"2023","journal-title":"Chin. J. Chem."},{"key":"2026081208065068300_cit118","doi-asserted-by":"publisher","first-page":"524","DOI":"10.14135\/j.cnki.1006-3080.20230523001","article-title":"Chiral Phenanthroline\nLigand-Promoted Iron-Catalyzed Enantioselective Intramolecular C(sp3)\u2013H Amination","volume":"50","author":"Li","year":"2024","journal-title":"J. East China\nUniv. Sci. Technol."},{"key":"2026081208065068300_cit119","doi-asserted-by":"publisher","first-page":"3789","DOI":"10.1021\/acscatal.5c00222","article-title":"Mechanistic\nand Computational Insights into Asymmetric Intramolecular Iron-Catalyzed\nNitrene Transfer into Benzylic C\u2013H Bonds","volume":"15","author":"Seo","year":"2025","journal-title":"ACS Catal."},{"key":"2026081208065068300_cit120","doi-asserted-by":"publisher","first-page":"645","DOI":"10.1038\/s44160-023-00267-w","article-title":"Expedited\nSynthesis of \u03b1-Amino Acids by Single-Step Enantioselective \u03b1-Amination of Carboxylic Acids","volume":"2","author":"Ye","year":"2023","journal-title":"Nat. Synth."},{"key":"2026081208065068300_cit121","doi-asserted-by":"publisher","first-page":"1484","DOI":"10.1002\/anie.201509603","article-title":"Expedient\nIron-Catalyzed C\u2013H Allylation\/Alkylation by Triazole Assistance\nwith Ample Scope","volume":"55","author":"Cera","year":"2016","journal-title":"Angew. Chem., Int. 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Lett."},{"key":"2026081208065068300_cit126","doi-asserted-by":"publisher","first-page":"5135","DOI":"10.1039\/C9DT00705A","article-title":"Mo\u0308ssbauer and Mass Spectrometry\nSupport for\nIron(II) Catalysts in Enantioselective C\u2013H Activation","volume":"48","author":"Loup","year":"2019","journal-title":"Dalton Trans."},{"key":"2026081208065068300_cit127a","doi-asserted-by":"publisher","first-page":"1300","DOI":"10.1021\/om2005673","article-title":"Hydrofluoroarylation of Alkynes with Ni Catalysts.\nC\u2013H Activation via Ligand-to-Ligand Hydrogen\nTransfer, an Alternative to Oxidative Addition","volume":"31","author":"Guihaume\u0301","year":"2012","journal-title":"Organometallics"},{"key":"2026081208065068300_cit127b","doi-asserted-by":"publisher","first-page":"13098","DOI":"10.1021\/ja505579f","article-title":"Linear-Selective Hydroarylation of Unactivated Terminal\nand Internal Olefins with Trifuoromethyl-Substituted Arenes","volume":"136","author":"Bair","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit127c","doi-asserted-by":"publisher","first-page":"2957","DOI":"10.1021\/jacs.6b00024","article-title":"Nickel-Catalyzed Hydroacylation of\nStyrenes with Simple Aldehydes: Reaction Development and Mechanistic\nInsights","volume":"138","author":"Xiao","year":"2016","journal-title":"J. Am. Chem. 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Chem.\nSoc."},{"key":"2026081208065068300_cit131b","doi-asserted-by":"publisher","first-page":"4816","DOI":"10.1021\/ja01599a079","article-title":"The Reaction of Azobenzene\nand Carbon Monoxide","volume":"78","author":"Murahashi","year":"1956","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit132a","doi-asserted-by":"publisher","first-page":"1208","DOI":"10.1021\/ar400270x","article-title":"Low-Valent Cobalt Catalysis:\nNew Opportunities for C\u2013H Functionalization","volume":"47","author":"Gao","year":"2014","journal-title":"Acc. Chem. Res."},{"key":"2026081208065068300_cit132b","doi-asserted-by":"publisher","first-page":"2756","DOI":"10.1039\/C4CY00053F","article-title":"Cobalt Mediated C\u2013H Bond Functionalization:\nEmerging Tools for Organic Synthesis","volume":"4","author":"Tilly","year":"2014","journal-title":"Catal.\nSci. 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Rev."},{"key":"2026081208065068300_cit169","doi-asserted-by":"publisher","first-page":"6455","DOI":"10.1021\/acscatal.1c01351","article-title":"Chiral Carboxylic\nAcid Assisted Enantioselective\nC\u2013H Activation with Achiral CpxMIII (M\n= Co, Rh, Ir) Catalysts","volume":"11","author":"Yoshino","year":"2021","journal-title":"ACS Catal."},{"key":"2026081208065068300_cit170","doi-asserted-by":"publisher","first-page":"15425","DOI":"10.1002\/anie.201808595","article-title":"Enantioselective\nCobalt(III)-Catalyzed\nC\u2013H Activation Enabled by Chiral Carboxylic Acid Cooperation","volume":"57","author":"Pesciaioli","year":"2018","journal-title":"Angew. Chem., Int. 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Ber."},{"key":"2026081208065068300_cit191b","doi-asserted-by":"publisher","first-page":"717","DOI":"10.1002\/hlca.19910740405","article-title":"Syntheses\nand Crystal Structures of 4,5-Dihydro-2-(2\u2019-hydroxyphenyl)oxazole-Containing\nMetal Complexes","volume":"74","author":"Bolm","year":"1991","journal-title":"Helv. Chim. 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Soc."},{"key":"2026081208065068300_cit250a","doi-asserted-by":"publisher","first-page":"410","DOI":"10.1246\/cl.150024","article-title":"Nickel Catalysts\/N,N\u2019-Bidentate Directing Groups:\nAn Excellent Partnership in Directed C\u2013H Activation Reactions","volume":"44","author":"Castro","year":"2015","journal-title":"Chem. Lett."},{"key":"2026081208065068300_cit250b","doi-asserted-by":"publisher","first-page":"55","DOI":"10.1007\/s41061-016-0053-z","article-title":"Nickel-Catalyzed Aromatic C\u2013H\nFunctionalization","volume":"374","author":"Yamaguchi","year":"2016","journal-title":"Top. Curr. 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Rev."},{"key":"2026081208065068300_cit266","doi-asserted-by":"publisher","first-page":"858","DOI":"10.1021\/acscatal.0c04585","article-title":"Selective C(sp3)\u2013H\nCleavage of Enamides for Synthesis of 2-Pyridones via Ligand-Enabled Ni\u2013Al Bimetallic Catalysis","volume":"11","author":"Wang","year":"2021","journal-title":"ACS Catal."},{"key":"2026081208065068300_cit267","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202209625","article-title":"Enantioselective Nickel-Catalyzed\nC(sp3)\u2013H Activation of Formamides","volume":"61","author":"Wang","year":"2022","journal-title":"Angew. Chem., Int. 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Ed."},{"key":"2026081208065068300_cit271a","doi-asserted-by":"publisher","first-page":"7341","DOI":"10.1021\/jo2012434","article-title":"Design and Synthesis\nof C2-Symmetric N-Heterocyclic\nCarbene Precursors and Metal Carbenoids","volume":"76","author":"Albright","year":"2011","journal-title":"J.\nOrg. Chem."},{"key":"2026081208065068300_cit271b","doi-asserted-by":"publisher","first-page":"19680","DOI":"10.1021\/ja209187a","article-title":"Application of a C2-Symmetric Copper Carbenoid in the Enantioselective\nHydrosilylation of Dialkyl and Aryl\u2013Alkyl Ketones","volume":"133","author":"Albright","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit272","doi-asserted-by":"publisher","first-page":"4573","DOI":"10.1021\/ja00301a048","article-title":"Methylaluminum Bis(2,6-di-tert-butyl-4-alkylphenoxide).\nA New Reagent for Obtaining Unusual Equatorial and Anti-Cram Selectivity\nin Carbonyl Alkylation","volume":"107","author":"Maruoka","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit273","doi-asserted-by":"publisher","first-page":"4489","DOI":"10.1021\/jacs.8b01181","article-title":"Nickel-Catalyzed Enantioselective\nPyridone C\u2013H Functionalizations Enabled by a Bulky N-Heterocyclic Carbene Ligand","volume":"140","author":"Diesel","year":"2018","journal-title":"J.\nAm. Chem. Soc."},{"key":"2026081208065068300_cit274","doi-asserted-by":"publisher","first-page":"1125","DOI":"10.1002\/adsc.201901582","article-title":"Nickel\/NHC\u2013Catalyzed Enantioselective Cyclization of Pyridones\nand Pyrimidones with Tethered Alkenes","volume":"362","author":"Shen","year":"2020","journal-title":"Adv.\nSynth. Catal."},{"key":"2026081208065068300_cit275","doi-asserted-by":"publisher","first-page":"5628","DOI":"10.1021\/jacs.9b00931","article-title":"Regio- and Enantioselective C\u2013H Cyclization\nof Pyridines with Alkenes Enabled by a Nickel\/N-Heterocyclic\nCarbene Catalysis","volume":"141","author":"Zhang","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit276","doi-asserted-by":"publisher","first-page":"11044","DOI":"10.1002\/anie.201904774","article-title":"A Bulky Chiral\nN-Heterocyclic Carbene Nickel Catalyst Enables Enantioselective C\u2013H\nFunctionalizations of Indoles and Pyrroles","volume":"58","author":"Diesel","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081208065068300_cit277","doi-asserted-by":"publisher","first-page":"13433","DOI":"10.1002\/anie.201907387","article-title":"Nickel\/NHC\u2013Catalyzed\nAsymmetric C\u2013H Alkylation of Fluoroarenes with Alkenes: Synthesis\nof Enantioenriched Fluorotetralins","volume":"58","author":"Cai","year":"2019","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026081208065068300_cit278","doi-asserted-by":"publisher","first-page":"3242","DOI":"10.1021\/acs.orglett.6b01492","article-title":"Chiral N-Heterocyclic\nCarbene Ligand Enabled Nickel(0)-Catalyzed Enantioselective Three-Component\nCouplings as Direct Access to Silylated Indanols","volume":"18","author":"Ahlin","year":"2016","journal-title":"Org. Lett."},{"key":"2026081208065068300_cit279","doi-asserted-by":"publisher","first-page":"5896","DOI":"10.1002\/anie.201101468","article-title":"Nickel-Catalyzed\nThree-Component Coupling between Aryl Aldehydes, Norbornenes, and\nSilanes Leading to Indanols through Aromatic C\u2013H Bond Activation\nof Aryl Aldehydes","volume":"50","author":"Ogata","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081208065068300_cit280","doi-asserted-by":"publisher","first-page":"3225","DOI":"10.1021\/ol0165692","article-title":"Enantioselective\nRuthenium-Catalyzed Ring-Closing Metathesis","volume":"3","author":"Seiders","year":"2001","journal-title":"Org. Lett."},{"key":"2026081208065068300_cit281","doi-asserted-by":"publisher","first-page":"7135","DOI":"10.1038\/s41467-024-51409-3","article-title":"Nickel(II)\/BINOL-Catalyzed\nEnantioselective C\u2013H Activation via Desymmetrization\nand Kinetic Resolution","volume":"15","author":"Yao","year":"2024","journal-title":"Nat. Commun."},{"key":"2026081208065068300_cit282a","doi-asserted-by":"publisher","first-page":"9909","DOI":"10.1021\/jacs.7b03548","article-title":"Computational Study\nof Ni-Catalyzed C\u2013H Functionalization: Factors that Control\nthe Competition of Oxidative Addition and Radical Pathways","volume":"139","author":"Omer","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit282b","doi-asserted-by":"publisher","first-page":"1144","DOI":"10.1039\/C7SC04604A","article-title":"The Mechanism of\nDirected Ni(II)-Catalyzed C\u2013H Iodination with Molecular Iodine","volume":"9","author":"Haines","year":"2018","journal-title":"Chem. Sci."},{"key":"2026081208065068300_cit282c","doi-asserted-by":"publisher","first-page":"12602","DOI":"10.1021\/jacs.8b07708","article-title":"Understanding Ni(II)-Mediated C(sp3)\u2013H\nActivation: Tertiary Ureas as Model Substrates","volume":"140","author":"Beattie","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit282d","doi-asserted-by":"publisher","first-page":"17382","DOI":"10.1021\/jacs.9b09109","article-title":"Catalytically Relevant\nIntermediates in the Ni-Catalyzed C(sp2)-H and C(sp3)\u2013H Functionalization of Aminoquinoline Substrates","volume":"141","author":"Roy","year":"2019","journal-title":"J. Am. Chem. 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Rev.\nChem."},{"key":"2026081208065068300_cit308","doi-asserted-by":"crossref","DOI":"10.1002\/3527600086","volume-title":"Modern Organocopper Chemistry","author":"Krause","year":"2002"},{"key":"2026081208065068300_cit309","doi-asserted-by":"publisher","first-page":"2174","DOI":"10.1002\/cber.190103402141","article-title":"Ueber Synthesen in der Biphenylreihe","volume":"34","author":"Ullmann","year":"1901","journal-title":"Ber. Dtsch. Chem. Ges."},{"key":"2026081208065068300_cit310","doi-asserted-by":"publisher","first-page":"1691","DOI":"10.1002\/cber.19060390298","article-title":"Ueber Phenylirungen bei Gegenwart von Kupfer als Katalysator","volume":"39","author":"Goldberg","year":"1906","journal-title":"Ber. Dtsch. Chem. Ges."},{"key":"2026081208065068300_cit311a","doi-asserted-by":"publisher","first-page":"613","DOI":"10.1021\/cr60232a002","article-title":"The Ullmann Synthesis of Biaryls,\n1945\u20131963","volume":"64","author":"Fanta","year":"1964","journal-title":"Chem. 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Rev."},{"key":"2026081208065068300_cit311e","doi-asserted-by":"publisher","first-page":"2339","DOI":"10.1021\/cr200241f","article-title":"Mechanisms of Nucleophilic Organocopper(I)\nReactions","volume":"112","author":"Yoshikai","year":"2012","journal-title":"Chem. Rev."},{"key":"2026081208065068300_cit311f","doi-asserted-by":"publisher","first-page":"3464","DOI":"10.1039\/c2cs15323h","article-title":"Recent Advances in\nCopper-Catalyzed Dehydrogenative Functionalization via a Single Electron Transfer (SET) Process","volume":"41","author":"Zhang","year":"2012","journal-title":"Chem. Soc. Rev."},{"key":"2026081208065068300_cit311g","doi-asserted-by":"publisher","first-page":"6234","DOI":"10.1021\/cr300527g","article-title":"Aerobic Copper-Catalyzed Organic Reactions","volume":"113","author":"Allen","year":"2013","journal-title":"Chem. Rev."},{"key":"2026081208065068300_cit311h","doi-asserted-by":"publisher","first-page":"3525","DOI":"10.1039\/C3CS60289C","article-title":"Copper Catalysed\nUllmann Type Chemistry: from Mechanistic Aspects to Modern Development","volume":"43","author":"Sambiagio","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"2026081208065068300_cit311i","doi-asserted-by":"publisher","first-page":"8824","DOI":"10.1002\/anie.201403110","article-title":"Practical Aerobic Oxidations of Alcohols\nand Amines with Homogeneous Copper\/TEMPO and Related Catalyst Systems","volume":"53","author":"Ryland","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081208065068300_cit311j","doi-asserted-by":"publisher","first-page":"1756","DOI":"10.1021\/acs.accounts.5b00060","article-title":"Copper-Catalyzed Aerobic Oxidations\nof Organic Molecules: Pathways for Two-Electron Oxidation with a Four-Electron\nOxidant and a One-Electron Redox-Active Catalyst","volume":"48","author":"McCann","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"2026081208065068300_cit311k","volume-title":"Copper-Mediated Cross-Coupling\nReactions","author":"Evano","year":"2014"},{"key":"2026081208065068300_cit311l","doi-asserted-by":"publisher","first-page":"4504","DOI":"10.1039\/C5CS00882D","article-title":"Copper-Catalyzed Oxidative Carbon\u2013Heteroatom\nBond Formation: A Recent Update","volume":"45","author":"Zhu","year":"2016","journal-title":"Chem. Soc.\nRev."},{"key":"2026081208065068300_cit311m","doi-asserted-by":"publisher","first-page":"48","DOI":"10.1002\/anie.201507594","article-title":"Copper\nHydride Catalyzed Hydroamination of Alkenes and Alkynes","volume":"55","author":"Pirnot","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081208065068300_cit312a","doi-asserted-by":"publisher","first-page":"325","DOI":"10.1021\/ar960062n","article-title":"Chiral Bis(oxazoline)\nCopper(II) Complexes: Versatile Catalysts for Enantioselective Cycloaddition,\nAldol, Michael, and Carbonyl Ene Reactions","volume":"33","author":"Johnson","year":"2000","journal-title":"Acc. Chem. Res."},{"key":"2026081208065068300_cit312b","doi-asserted-by":"publisher","first-page":"3561","DOI":"10.1021\/cr0505324","article-title":"C\n            2-Symmetric\nChiral Bis(Oxazoline) Ligands in Asymmetric Catalysis","volume":"106","author":"Desimoni","year":"2006","journal-title":"Chem. 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Res."},{"key":"2026081208065068300_cit315b","doi-asserted-by":"publisher","first-page":"1640","DOI":"10.1039\/D1CS00727K","article-title":"Copper-Catalyzed Radical\nRelay in C(sp3)\u2013H Functionalization","volume":"51","author":"Zhang","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"2026081208065068300_cit315c","doi-asserted-by":"publisher","first-page":"107","DOI":"10.1038\/s44160-021-00016-x","article-title":"Copper-Catalysed Asymmetric\nRadical Cyanation","volume":"1","author":"Wang","year":"2022","journal-title":"Nat. Synth."},{"key":"2026081208065068300_cit316","doi-asserted-by":"publisher","first-page":"1408","DOI":"10.3762\/bjoc.19.102","article-title":"Application\nof N-Heterocyclic Carbene-Cu(I) Complexes as Catalysts\nin Organic\nSynthesis: A Review","volume":"19","author":"Beig","year":"2023","journal-title":"Beilstein J. Org. 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Soc."},{"key":"2026081208065068300_cit328a","doi-asserted-by":"publisher","first-page":"756","DOI":"10.1021\/ja01536a062","article-title":"The Reactions\nof t-Butyl Perbenzoate and Olefins-a Stereospecific\nReaction","volume":"80","author":"Kharasch","year":"1958","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit328b","doi-asserted-by":"publisher","first-page":"325","DOI":"10.1021\/jo01096a625","article-title":"Radical Substitution Reactions","volume":"23","author":"Kharasch","year":"1958","journal-title":"J. Org. Chem."},{"key":"2026081208065068300_cit329a","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1055\/s-1972-21818","article-title":"One-Step Substitutive\nAcyloxylation at Carbon. Part I. Reactions Involving Peroxides","volume":"1972","author":"Rawlinson","year":"1972","journal-title":"Synthesis"},{"key":"2026081208065068300_cit329b","doi-asserted-by":"publisher","first-page":"3567","DOI":"10.1002\/1521-3773(20011001)40:19&lt;3567::AID-ANIE3567&gt;3.0.CO;2-C","article-title":"Catalytic Allylic Oxidation of Alkenes\nUsing an Asymmetric Kharasch\u2013Sosnovsky Reaction","volume":"40","author":"Eames","year":"2001","journal-title":"Angew. Chem., Int. 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Sci."},{"key":"2026081208065068300_cit359c","doi-asserted-by":"publisher","first-page":"3","DOI":"10.1016\/S0022-328X(98)01106-1","article-title":"Luminescent Polynuclear\nMetal Acetylides","volume":"578","author":"Yam","year":"1999","journal-title":"J. Organomet. Chem."},{"key":"2026081208065068300_cit360","doi-asserted-by":"publisher","first-page":"10965","DOI":"10.1021\/jacs.8b07436","article-title":"Enantioselective\nTrifluoromethylalkynylation of Alkenes via Copper-Catalyzed\nRadical Relay","volume":"140","author":"Fu","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit361","doi-asserted-by":"publisher","first-page":"12493","DOI":"10.1021\/jacs.0c05373","article-title":"Enantioselective\nCopper-Catalyzed Alkynylation of Benzylic C\u2013H Bonds via Radical Relay","volume":"142","author":"Fu","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit362","doi-asserted-by":"publisher","first-page":"13468","DOI":"10.1021\/jacs.2c06432","article-title":"Enantioselective Radical\nTrifluoromethylation of Benzylic C\u2013H Bonds via Cooperative Photoredox and Copper Catalysis","volume":"144","author":"Xu","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit363","doi-asserted-by":"publisher","first-page":"2407","DOI":"10.1016\/j.chempr.2020.07.003","article-title":"Enantioselective Copper-Catalyzed\nTrifluoromethylation of Benzylic Radicals via Ring\nOpening of Cyclopropanols","volume":"6","author":"Jiang","year":"2020","journal-title":"Chem."},{"key":"2026081208065068300_cit364","doi-asserted-by":"publisher","first-page":"459","DOI":"10.1038\/s41557-020-0436-1","article-title":"The\nMerger of Decatungstate and Copper Catalysis to Enable Aliphatic C(sp3)\u2013H Trifluoromethylation","volume":"12","author":"Sarver","year":"2020","journal-title":"Nat.\nChem."},{"key":"2026081208065068300_cit365","doi-asserted-by":"publisher","first-page":"545","DOI":"10.1016\/j.ccr.2007.08.019","article-title":"High Symmetry Dirhodium(II) Paddlewheel\nComplexes as Chiral Catalysts","volume":"252","author":"Hansen","year":"2008","journal-title":"Coord. Chem.\nRev."},{"key":"2026081208065068300_cit366","doi-asserted-by":"publisher","first-page":"2456","DOI":"10.1002\/anie.199724561","article-title":"Insertion of Carbenoids into Cp-H\nBonds of Ferrocenes: An Enantioselective-Catalytic Entry to Planar-Chiral\nFertocenes","volume":"36","author":"Siegel","year":"1997","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"2026081208065068300_cit367","doi-asserted-by":"publisher","first-page":"731","DOI":"10.1021\/ol070092y","article-title":"Simple and\nEfficient Heterogeneous Copper Catalysts for Enantioselective C\u2013H\nCarbene Insertion","volume":"9","author":"Fraile","year":"2007","journal-title":"Org. Lett."},{"key":"2026081208065068300_cit368a","doi-asserted-by":"publisher","first-page":"6075","DOI":"10.1039\/c1ob05499f","article-title":"Enantioselective\nC\u2013H Carbene Insertions with Homogeneous and Immobilized Copper\nComplexes","volume":"9","author":"Fraile","year":"2011","journal-title":"Org. Biomol. Chem."},{"key":"2026081208065068300_cit368b","doi-asserted-by":"publisher","first-page":"6763","DOI":"10.1016\/j.tetlet.2011.10.026","article-title":"Desymmetrization\nof meso [3.2.1]Oxabicyclic Systems Using Metal-Catalysed\nAsymmetric Intramolecular C\u2013H Insertion","volume":"52","author":"Zhang","year":"2011","journal-title":"Tetrahedron Lett."},{"key":"2026081208065068300_cit369","doi-asserted-by":"publisher","first-page":"1184","DOI":"10.1021\/ja909713a","article-title":"Highly\nEnantioselective Intramolecular Copper Catalyzed C\u2013H Insertion\nReactions of \u03b1-Diazosulfones","volume":"132","author":"Flynn","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit370a","doi-asserted-by":"publisher","first-page":"667","DOI":"10.1039\/C0OB00914H","article-title":"Asymmetric Copper-Catalysed\nIntramolecular C\u2013H Insertion Reactions of \u03b1-Diazo-\u03b2-keto Sulfones","volume":"9","author":"Slattery","year":"2011","journal-title":"Org. Biomol. Chem."},{"key":"2026081208065068300_cit370b","doi-asserted-by":"publisher","first-page":"765","DOI":"10.1055\/s-0031-1290598","article-title":"Investigation of\nAdditive Effects in Enantioselective Copper-Catalysed C\u2013H Insertion\nand Aromatic Addition Reactions of \u03b1-Diazocarbonyl\nCompounds","volume":"23","author":"Slattery","year":"2012","journal-title":"Synlett"},{"key":"2026081208065068300_cit370c","doi-asserted-by":"publisher","first-page":"1297","DOI":"10.1016\/j.tet.2012.12.003","article-title":"Catalyst,\nAdditive and Counterion Effects on the Efficiency and Enantioselectivity\nof Copper-Catalysed C\u2013H Insertion Reactions of \u03b1-Diazosulfones","volume":"69","author":"Slattery","year":"2013","journal-title":"Tetrahedron"},{"key":"2026081208065068300_cit370d","doi-asserted-by":"publisher","first-page":"7612","DOI":"10.1039\/C4OB01430H","article-title":"Enantioselective Copper Catalysed\nC\u2013H Insertion Reaction of 2-Sulfonyl-2-diazoacetamides to Form \u03b3-Lactams","volume":"12","author":"Clarke","year":"2014","journal-title":"Org. Biomol. Chem."},{"key":"2026081208065068300_cit370e","doi-asserted-by":"publisher","first-page":"2609","DOI":"10.1039\/C7OB00214A","article-title":"Enantioselective Copper Catalysed\nIntramolecular C\u2013H Insertion Reactions of \u03b1-Diazo-\u03b2-keto Sulfones, \u03b1-Diazo-\u03b2-keto Phosphine Oxides and 2-Diazo-1,3-diketones;\nthe Influence of the Carbene Substituent","volume":"15","author":"Shiely","year":"2017","journal-title":"Org.\nBiomol. Chem."},{"key":"2026081208065068300_cit371a","doi-asserted-by":"publisher","first-page":"1456","DOI":"10.1055\/s-1997-1067","article-title":"Benzylic and\nAllylic Amination","volume":"12","author":"Kohmura","year":"1997","journal-title":"Synlett"},{"key":"2026081208065068300_cit371b","doi-asserted-by":"publisher","first-page":"5175","DOI":"10.1039\/b509678b","article-title":"Tuneable Asymmetric Copper-Catalysed\nAllylic Amination and Oxidation Reactions","author":"Clark","year":"2005","journal-title":"Chem.\nCommun."},{"key":"2026081208065068300_cit372","doi-asserted-by":"publisher","first-page":"697","DOI":"10.1038\/s41557-020-0482-8","article-title":"Enantioselective\nRadical C\u2013H\nAmination for the Synthesis of \u03b2-Amino Alcohols","volume":"12","author":"Nakafuku","year":"2020","journal-title":"Nat. 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Rev."},{"key":"2026081208065068300_cit374","doi-asserted-by":"publisher","first-page":"4896","DOI":"10.1021\/ja513079r","article-title":"Nickel-Catalyzed\nCross-Coupling of Photoredox-Generated\nRadicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed\nCross-Couplings","volume":"137","author":"Gutierrez","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit375","doi-asserted-by":"publisher","first-page":"681","DOI":"10.1126\/science.aad8313","article-title":"Asymmetric Copper-Catalyzed\nC\u2013N Cross-Couplings Induced by Visible Light","volume":"351","author":"Kainz","year":"2016","journal-title":"Science"},{"key":"2026081208065068300_cit376","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217638","article-title":"Enantioselective Intermolecular\nRadical Amidation and Amination of Benzylic C\u2013H Bonds via Dual Copper and Photocatalysis","volume":"62","author":"Chen","year":"2023","journal-title":"Angew. Chem., Int. 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Res."},{"key":"2026081208065068300_cit380b","doi-asserted-by":"publisher","first-page":"580","DOI":"10.1038\/s41570-021-00291-4","article-title":"Nitrene Transfer Catalysts for Enantioselective C\u2013N\nBond Formation","volume":"5","author":"Ju","year":"2021","journal-title":"Nat. Rev. Chem."},{"key":"2026081208065068300_cit380c","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202403437","article-title":"Spin Crossover and Its Application\nin Organometallic Catalysis: Concepts and Recent Progress","volume":"30","author":"He","year":"2024","journal-title":"Chem. - Eur. J."},{"key":"2026081208065068300_cit381","doi-asserted-by":"publisher","first-page":"16238","DOI":"10.1021\/jacs.3c05258","article-title":"Regio- and Enantioselective Catalytic \u03b4-C\u2013H\nAmidation of Dioxazolones Enabled by Open-Shell Copper-Nitrenoid Transfer","volume":"145","author":"Kim","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit382a","doi-asserted-by":"publisher","first-page":"1016","DOI":"10.1126\/science.aap7503","article-title":"Selective Formation\nof \u03b3-Lactams via C\u2013H\nAmidation Enabled by Tailored Iridium Catalysts","volume":"359","author":"Hong","year":"2018","journal-title":"Science"},{"key":"2026081208065068300_cit382b","doi-asserted-by":"publisher","first-page":"219","DOI":"10.1038\/s41929-019-0230-x","article-title":"Asymmetric\nFormation of \u03b3-Lactams via C\u2013H Amidation Enabled by Chiral Hydrogen-Bond-Donor Catalysts","volume":"2","author":"Park","year":"2019","journal-title":"Nat. Catal."},{"key":"2026081208065068300_cit382c","doi-asserted-by":"publisher","first-page":"7194","DOI":"10.1021\/jacs.9b02811","article-title":"Iridium-Catalyzed Enantioselective C(sp3)\u2013H Amidation Controlled by Attractive Noncovalent Interactions","volume":"141","author":"Wang","year":"2019","journal-title":"J. Am. Chem. 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Chem.\nSoc."},{"key":"2026081208065068300_cit387","doi-asserted-by":"publisher","first-page":"358","DOI":"10.1038\/s41929-020-0425-1","article-title":"Copper-Catalysed\nBenzylic C\u2013H Coupling with Alcohols via Radical\nRelay Enabled by Redox Buffering","volume":"3","author":"Hu","year":"2020","journal-title":"Nat. Catal."},{"key":"2026081208065068300_cit388","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420613","article-title":"Benzylic C(sp3)\u2013H Phosphonylation via Dual Photo\nand Copper\nCatalysis","volume":"64","author":"Li","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081208065068300_cit389","doi-asserted-by":"publisher","first-page":"58","DOI":"10.1038\/s41929-024-01276-4","article-title":"Site- and Enantioselective\nAllylic and Propargylic C\u2013H Oxidation Enabled by Copper-Based\nBiomimetic Catalysis","volume":"8","author":"Zhang","year":"2025","journal-title":"Nat. Catal."},{"key":"2026081208065068300_cit390a","doi-asserted-by":"publisher","first-page":"177","DOI":"10.1038\/nature03311","article-title":"Crystal\nStructure of a Membrane-Bound Metalloenzyme that Catalyses the Biological\nOxidation of Methane","volume":"434","author":"Lieberman","year":"2005","journal-title":"Nature"},{"key":"2026081208065068300_cit390b","doi-asserted-by":"publisher","first-page":"115","DOI":"10.1038\/nature08992","article-title":"Oxidation\nof Methane by a Biological Dicopper Centre","volume":"465","author":"Balasubramanian","year":"2010","journal-title":"Nature"},{"key":"2026081208065068300_cit391a","doi-asserted-by":"publisher","first-page":"2084","DOI":"10.1021\/ja00897a013","article-title":"The Copper-Catalyzed\nReaction of Peresters with Hydrocarbons","volume":"85","author":"Walling","year":"1963","journal-title":"J.\nAm. Chem. Soc."},{"key":"2026081208065068300_cit391b","doi-asserted-by":"publisher","first-page":"1862","DOI":"10.1021\/jo01017a036","article-title":"Studies on the Mechanism of the Reaction\nof Peroxides and Alkenes with Copper Salts","volume":"30","author":"Kochi","year":"1965","journal-title":"J. Org. Chem."},{"key":"2026081208065068300_cit391c","doi-asserted-by":"publisher","first-page":"8230","DOI":"10.1021\/ja00286a020","article-title":"Allylic Oxidations by Peroxy Esters\nCatalyzed by Copper Salts. The Potential for Stereoselective Syntheses","volume":"108","author":"Beckwith","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit391d","doi-asserted-by":"publisher","first-page":"1747","DOI":"10.1021\/om049052d","article-title":"Catalytic\nAllylic Amination versus Allylic Oxidation: A Mechanistic\nDichotomy","volume":"24","author":"Smith","year":"2005","journal-title":"Organometallics"},{"key":"2026081208065068300_cit392","doi-asserted-by":"publisher","first-page":"27196","DOI":"10.1021\/jacs.4c11145","article-title":"Photoexcited\nCopper-Catalyzed Enantioselective Allylic C(sp3)\u2013H\nAcyloxylation of Acyclic Internal Alkenes","volume":"146","author":"Tang","year":"2024","journal-title":"J.\nAm. Chem. Soc."},{"key":"2026081208065068300_cit393","doi-asserted-by":"publisher","first-page":"627","DOI":"10.1021\/jacs.4c12544","article-title":"Catalytic Asymmetric\nOxidative Coupling between C(sp3)\u2013H Bonds and Carboxylic\nAcids","volume":"147","author":"Liu","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026081208065068300_cit394","doi-asserted-by":"publisher","first-page":"10036","DOI":"10.1021\/acs.orglett.4c03933","article-title":"Enantioselective\nPropargylic\nC(sp3)\u2013H Acyloxylation Enabled by Photoexcited Copper\nCatalysis","volume":"26","author":"Tang","year":"2024","journal-title":"Org. Lett."},{"key":"2026081208065068300_cit395","doi-asserted-by":"publisher","first-page":"1393","DOI":"10.1055\/a-2240-5349","article-title":"Copper-Catalyzed\nEnantioselective\nRadical Esterification of Propargylic C\u2013H Bonds","volume":"56","author":"Xi","year":"2024","journal-title":"Synthesis"},{"key":"2026081208065068300_cit396","doi-asserted-by":"publisher","first-page":"1129","DOI":"10.1002\/anie.201911742","article-title":"Enantioselective\nCopper(I)\/Chiral Phosphoric Acid Catalyzed Intramolecular Amination\nof Allylic and Benzylic C\u2013H Bonds","volume":"59","author":"Ye","year":"2020","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026081208065068300_cit397","doi-asserted-by":"publisher","first-page":"163","DOI":"10.1021\/op034137w","article-title":"Solvent and Temperature Effects in\nthe Free Radical Aerobic Oxidation of Alkyl and Acyl Aromatics Catalysed\nby Transition Metal Salts and N-Hydroxyphthalimide:\nNew Processes for the Synthesis of p-Hydroxybenzoic\nAcid, Diphenols, and Dienes for Liquid Crystals and Cross-Linked Polymers","volume":"8","author":"Minisci","year":"2004","journal-title":"Org. Process Res. 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