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Volatile methylsiloxanes (VMS) are an important class of VCPs and high-production chemicals. Using quantum chemical calculations and kinetics modeling, we investigated the reaction mechanism of peroxy radicals of VMS, which are key intermediates in determining the atmospheric chemistry of VMS. L2-RSiCH2O2\u2022 and D3-RSiCH2O2\u2022 derived from hexamethyldisiloxane and hexamethylcyclotrisiloxane, respectively, were selected as representative model systems. The results indicated that L2-RSiCH2O2\u2022 and D3-RSiCH2O2\u2022 follow a novel Si\u2013C\u2013O rearrangement-driven autoxidation mechanism, leading to the formation of low volatile silanols and high yield of formaldehyde at low NO\/HO2\u2022 conditions. At high NO\/HO2\u2022 conditions, L2-RSiCH2O2\u2022 and D3-RSiCH2O2\u2022 react with NO\/HO2\u2022 to form organic nitrate, hydroperoxide, and active alkoxy radicals. The alkoxy radicals further follow a Si\u2013C\u2013O rearrangement step to finally form formate esters. The novel Si\u2013C\u2013O rearrangement mechanism of both peroxy and alkoxy radicals are supported by available experimental studies on the oxidation of VMS. Notably, the high yield of formaldehyde is estimated to significantly contribute to formaldehyde pollution in the indoor environment, especially during indoor cleaning.<\/jats:p>","DOI":"10.1021\/acs.est.0c01090","type":"journal-article","created":{"date-parts":[[2020,5,13]],"date-time":"2020-05-13T10:56:12Z","timestamp":1589367372000},"page":"7136-7145","source":"Crossref","is-referenced-by-count":50,"title":["Formation\nof Low-Volatile Products and Unexpected\nHigh Formaldehyde Yield from the Atmospheric Oxidation of Methylsiloxanes"],"prefix":"10.1021","volume":"54","author":[{"given":"Zihao","family":"Fu","sequence":"first","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9119-9785","authenticated-orcid":true,"given":"Hong-Bin","family":"Xie","sequence":"additional","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3736-4329","authenticated-orcid":true,"given":"Jonas","family":"Elm","sequence":"additional","affiliation":[{"name":"Aarhus University , , Langelandsgade 140 , ,","place":["Aarhus C, Denmark, DK-8000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xirui","family":"Guo","sequence":"additional","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqiang","family":"Fu","sequence":"additional","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]},{"name":"University of Alberta , , , ,","place":["Edmonton, Alberta, Canada, T6G2R3"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5756-3336","authenticated-orcid":true,"given":"Jingwen","family":"Chen","sequence":"additional","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,5,13]]},"reference":[{"key":"2026081717175515000_cit1","doi-asserted-by":"publisher","first-page":"1186","DOI":"10.1073\/pnas.1714715115","article-title":"Urban flux\nmeasurements reveal a large pool of oxygenated volatile organic compound\nemissions","volume":"115","author":"Karl","year":"2018","journal-title":"Proc. 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Chem.\nPhys."},{"key":"2026081717175515000_cit40","doi-asserted-by":"publisher","first-page":"8442","DOI":"10.1021\/acs.est.7b02374","article-title":"Formation of highly\noxidized radicals and multifunctional products from the atmospheric\noxidation of alkylbenzenes","volume":"51","author":"Wang","year":"2017","journal-title":"Environ. Sci. Technol."},{"key":"2026081717175515000_cit41","doi-asserted-by":"publisher","first-page":"12255","DOI":"10.1021\/acs.est.8b02783","article-title":"Primary formation\nof highly oxidized multifunctional products in the OH-Initiated oxidation\nof isoprene: a combined theoretical and experimental study","volume":"52","author":"Wang","year":"2018","journal-title":"Environ. Sci. 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Sci.\nTechnol."},{"key":"2026081717175515000_cit57","doi-asserted-by":"publisher","first-page":"1164","DOI":"10.1016\/j.atmosenv.2006.09.038","article-title":"A new detailed\nchemical model for indoor air pollution","volume":"41","author":"Carslaw","year":"2007","journal-title":"Atmos.\nEnviron."},{"key":"2026081717175515000_cit58","doi-asserted-by":"publisher","first-page":"1374","DOI":"10.1039\/C9EM00129H","article-title":"Role of location,\nseason, occupant activity, and chemistry in indoor ozone and nitrogen\noxide mixing ratios","volume":"21","author":"Zhou","year":"2019","journal-title":"Environ. Sci.: Processes\nImpacts"},{"key":"2026081717175515000_cit59","doi-asserted-by":"publisher","first-page":"434","DOI":"10.1111\/ina.12316","article-title":"Identification of the major HOx radical\npathways in an indoor air environment","volume":"27","author":"Mendez","year":"2017","journal-title":"Indoor\nair"},{"key":"2026081717175515000_cit60","doi-asserted-by":"publisher","first-page":"3627","DOI":"10.1016\/S1352-2310(03)00460-6","article-title":"HOx concentrations and\nOH reactivity observations in New York\nCity during PMTACS-NY2001","volume":"37","author":"Ren","year":"2003","journal-title":"Atmos. Environ."},{"key":"2026081717175515000_cit61","doi-asserted-by":"publisher","first-page":"595","DOI":"10.1021\/acs.estlett.8b00415","article-title":"Measurement\nof NO3 and\nN2O5 in a residential kitchen","volume":"5","author":"Arata","year":"2018","journal-title":"Environ. Sci. Technol. Lett."},{"key":"2026081717175515000_cit62","doi-asserted-by":"publisher","first-page":"1393","DOI":"10.1039\/C9EM00194H","article-title":"Assessing\nindoor gas phase oxidation capacity through real-time measurements\nof HONO and NOx in Guangzhou, China","volume":"21","author":"Liu","year":"2019","journal-title":"Environ. Sci. Processes Impacts"},{"key":"2026081717175515000_cit63","doi-asserted-by":"publisher","first-page":"8355","DOI":"10.1021\/acs.est.8b01792","article-title":"Time-resolved\nmeasurements of nitric oxide, nitrogen dioxide, and nitrous acid in\nan occupied New York home","volume":"52","author":"Zhou","year":"2018","journal-title":"Environ. Sci. Technol."},{"key":"2026081717175515000_cit64","doi-asserted-by":"publisher","first-page":"4713","DOI":"10.1016\/S1352-2310(01)00090-5","article-title":"OH and HO2 measurements\nin a forested region of north-western Greece","volume":"35","author":"Creasey","year":"2001","journal-title":"Atmos. Environ."},{"key":"2026081717175515000_cit65","doi-asserted-by":"publisher","first-page":"737","DOI":"10.1038\/nature06870","article-title":"Atmospheric oxidation capacity sustained\nby a tropical forest","volume":"452","author":"Lelieveld","year":"2008","journal-title":"Nature"},{"key":"2026081717175515000_cit66","doi-asserted-by":"publisher","first-page":"8468","DOI":"10.1016\/j.atmosenv.2007.07.002","article-title":"Rate constants\nfor the atmospheric reactions of alkoxy radicals: An updated estimation\nmethod","volume":"41","author":"Atkinson","year":"2007","journal-title":"Atmos. Environ."},{"key":"2026081717175515000_cit67","doi-asserted-by":"publisher","first-page":"12608","DOI":"10.1039\/C0CP00387E","article-title":"A structure-activity\nrelationship for the rate coefficient\nof H-migration in substituted alkoxy radicals","volume":"12","author":"Vereecken","year":"2010","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026081717175515000_cit68","doi-asserted-by":"publisher","first-page":"4681","DOI":"10.1021\/cr040179m","article-title":"Organophosphorus\n\u03c0-conjugated materials","volume":"106","author":"Baumgartner","year":"2006","journal-title":"Chem. Rev."},{"key":"2026081717175515000_cit69","doi-asserted-by":"publisher","first-page":"713","DOI":"10.1021\/cr00094a002","article-title":"Arsenic speciation in the environment","volume":"89","author":"Cullen","year":"1989","journal-title":"Chem. Rev."},{"key":"2026081717175515000_cit70","doi-asserted-by":"publisher","first-page":"2419","DOI":"10.1021\/acs.est.7b06387","article-title":"Indoor chemistry","volume":"52","author":"Weschler","year":"2018","journal-title":"Environ. Sci.\nTechnol."},{"key":"2026081717175515000_cit71","doi-asserted-by":"publisher","first-page":"6696","DOI":"10.1016\/j.atmosenv.2006.06.005","article-title":"Indoor\nsecondary pollutants from\ncleaning product and air freshener use in the presence of ozone","volume":"40","author":"Singer","year":"2006","journal-title":"Atmos. Environ."},{"key":"2026081717175515000_cit72","unstructured":"Indoor air quality guideline\n- formaldehyde in the home. 2004. 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Technol."},{"key":"2026081717175515000_cit76","doi-asserted-by":"publisher","first-page":"1730","DOI":"10.1021\/acs.est.9b05767","article-title":"Multiphase chemistry\ncontrols inorganic chlorinated and nitrogenated compounds in indoor\nair during bleach cleaning","volume":"54","author":"Mattila","year":"2020","journal-title":"Environ. Sci. 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