{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T02:41:56Z","timestamp":1792204916860,"version":"4.4.0"},"reference-count":63,"publisher":"American Chemical Society (ACS)","issue":"1","license":[{"start":{"date-parts":[[2024,12,25]],"date-time":"2024-12-25T00:00:00Z","timestamp":1735084800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["788009-IRMIDYN-ERC-2017-ADG"],"award-info":[{"award-number":["788009-IRMIDYN-ERC-2017-ADG"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2025,1,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Coastal sediments are a key contributor to oceanic phosphorus (P) removal, impacting P bioavailability and primary productivity. Vivianite, an Fe\u00ad(II)-phosphate mineral, can be a major P sink in nonsulfidic, reducing coastal sediments. Despite its importance, vivianite formation processes in sediments remain poorly understood. Here, we applied a novel approach to detect and quantify in situ vivianite formation in three intertidal flats. We conducted 7-week long incubations of mesh-bags filled with sediments mixed with (1) 57Fe-ferrihydrite, (2) 57Fe-ferrihydrite with adsorbed phosphate, and (3) 57Fe-ferrihydrite with adsorbed phosphate and some vivianite (natural Fe isotope abundance), which could serve as crystal growth sites. Synthesizing the ferrihydrite from 57Fe (96.1%) enabled us to detect transformation products using 57Fe-Mo\u0308ssbauer spectroscopy. Vivianite formed only in treatments containing adsorbed phosphate and only at the two sites where vivianite formation was thermodynamically feasible based on porewater chemistry. These results demonstrate vivianite formation within weeks when locally favorable Fe:P ratios exist. Although vivianite comprised a minor fraction of Fe (up to 15%), it represented a significant P pool (up to 72%), emphasizing its role in coastal P burial. Additionally, our results may apply to other environmental systems like limnic sediments.<\/jats:p>","DOI":"10.1021\/acs.est.4c10710","type":"journal-article","created":{"date-parts":[[2024,12,25]],"date-time":"2024-12-25T02:14:28Z","timestamp":1735092868000},"page":"523-532","source":"Crossref","is-referenced-by-count":23,"title":["In Situ Vivianite\nFormation in Intertidal Sediments:\nFerrihydrite-Adsorbed P Triggers Vivianite Formation"],"prefix":"10.1021","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1894-6809","authenticated-orcid":true,"given":"L. Joe\u0308lle","family":"Kubeneck","sequence":"first","affiliation":[{"name":"Soil Chemistry Group, Institute of Biogeochemistry and Pollutant Dynamics, CHN, ETH Zu\u0308rich , ,","place":["Zu\u0308rich, Switzerland, 8092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5379-122X","authenticated-orcid":true,"given":"Katherine A.","family":"Rothwell","sequence":"additional","affiliation":[{"name":"Soil Chemistry Group, Institute of Biogeochemistry and Pollutant Dynamics, CHN, ETH Zu\u0308rich , ,","place":["Zu\u0308rich, Switzerland, 8092"]},{"name":"University of Bristol , , ,","place":["Bristol, U.K., BS8 1RJ"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2972-6588","authenticated-orcid":true,"given":"Luiza","family":"Notini","sequence":"additional","affiliation":[{"name":"Soil Chemistry Group, Institute of Biogeochemistry and Pollutant Dynamics, CHN, ETH Zu\u0308rich , ,","place":["Zu\u0308rich, Switzerland, 8092"]},{"name":"University of Delaware , , , ,","place":["Newark, Delaware, United States, 19716"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6758-3760","authenticated-orcid":true,"given":"Laurel K.","family":"ThomasArrigo","sequence":"additional","affiliation":[{"name":"Soil Chemistry Group, Institute of Biogeochemistry and Pollutant Dynamics, CHN, ETH Zu\u0308rich , ,","place":["Zu\u0308rich, Switzerland, 8092"]},{"name":"University of Neucha\u0302tel , , ,","place":["Neucha\u0302tel, Switzerland, 2000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9608-0882","authenticated-orcid":true,"given":"Katrin","family":"Schulz","sequence":"additional","affiliation":[{"name":"Soil Chemistry Group, Institute of Biogeochemistry and Pollutant Dynamics, CHN, ETH Zu\u0308rich , ,","place":["Zu\u0308rich, Switzerland, 8092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Giulia","family":"Fantappie\u0300","sequence":"additional","affiliation":[{"name":"Soil Chemistry Group, Institute of Biogeochemistry and Pollutant Dynamics, CHN, ETH Zu\u0308rich , ,","place":["Zu\u0308rich, Switzerland, 8092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5954-0309","authenticated-orcid":true,"given":"Prachi","family":"Joshi","sequence":"additional","affiliation":[{"name":"University of Tu\u0308bingen , , ,","place":["Tu\u0308bingen, Germany, 72076"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas","family":"Huthwelker","sequence":"additional","affiliation":[{"name":"Paul Scherrer Institut , ,","place":["Villigen, Switzerland, 5232"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2587-2430","authenticated-orcid":true,"given":"Ruben","family":"Kretzschmar","sequence":"additional","affiliation":[{"name":"Soil Chemistry Group, Institute of Biogeochemistry and Pollutant Dynamics, CHN, ETH Zu\u0308rich , ,","place":["Zu\u0308rich, Switzerland, 8092"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2024,12,25]]},"reference":[{"key":"2026081210102471200_cit1","doi-asserted-by":"publisher","first-page":"2441","DOI":"10.5194\/bg-13-2441-2016","article-title":"Global riverine N and P transport to ocean increased\nduring the 20th century despite increased retention along the aquatic\ncontinuum","volume":"13","author":"Beusen","year":"2016","journal-title":"Biogeosciences"},{"key":"2026081210102471200_cit2","doi-asserted-by":"publisher","first-page":"926","DOI":"10.1126\/science.1156401","article-title":"Spreading\ndead zones and consequences for marine ecosystems","volume":"321","author":"Diaz","year":"2008","journal-title":"Science"},{"key":"2026081210102471200_cit3","doi-asserted-by":"publisher","first-page":"682","DOI":"10.1016\/B0-08-043751-6\/08153-6","article-title":"The Global\nPhosphorus Cycle","volume":"8","author":"Ruttenberg","year":"2003","journal-title":"Treatise Geochem."},{"key":"2026081210102471200_cit4","doi-asserted-by":"publisher","first-page":"217","DOI":"10.1016\/j.gca.2015.09.012","article-title":"Vivianite\nis a major sink for phosphorus in methanogenic coastal surface sediments","volume":"169","author":"Egger","year":"2015","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026081210102471200_cit5","doi-asserted-by":"publisher","first-page":"118","DOI":"10.1016\/j.margeo.2008.05.013","article-title":"Diagenetic\nchanges of magnetic and geochemical signals by anaerobic methane oxidation\nin sediments of the Zambezi deep-sea fan (SW Indian Ocean)","volume":"255","author":"Ma\u0308rz","year":"2008","journal-title":"Mar. Geol."},{"key":"2026081210102471200_cit6","doi-asserted-by":"publisher","first-page":"203","DOI":"10.1021\/es504648d","article-title":"Characterizing phosphorus speciation of Chesapeake\nBay sediments using chemical extraction, 31P NMR, and X-ray\nabsorption fine structure spectroscopy","volume":"49","author":"Li","year":"2015","journal-title":"Environ.\nSci. Technol."},{"key":"2026081210102471200_cit7","doi-asserted-by":"publisher","first-page":"51","DOI":"10.1016\/j.earscirev.2016.04.008","article-title":"The occurrence,\nidentification and\nenvironmental relevance of vivianite in waterlogged soils and aquatic\nsediments","volume":"158","author":"Rothe","year":"2016","journal-title":"Earth-Sci. Rev."},{"key":"2026081210102471200_cit8","doi-asserted-by":"publisher","first-page":"58","DOI":"10.1016\/j.chemgeo.2016.05.025","article-title":"Vivianite is a key sink\nfor phosphorus in sediments of the Landsort Deep, an intermittently\nanoxic deep basin in the Baltic Sea","volume":"438","author":"Dijkstra","year":"2016","journal-title":"Chem. Geol."},{"key":"2026081210102471200_cit9","doi-asserted-by":"publisher","first-page":"6979","DOI":"10.5194\/bg-15-6979-2018","article-title":"Large variations\nin iron input to\nan oligotrophic Baltic Sea estuary: Impact on sedimentary phosphorus\nburial","volume":"15","author":"Lenstra","year":"2018","journal-title":"Biogeosciences"},{"key":"2026081210102471200_cit10","doi-asserted-by":"publisher","DOI":"10.1016\/j.marchem.2021.103948","article-title":"Phosphorus\nburial in vivianite-type minerals in methane-rich coastal sediments","volume":"231","author":"Kubeneck","year":"2021","journal-title":"Mar. Chem."},{"key":"2026081210102471200_cit11","doi-asserted-by":"publisher","first-page":"165","DOI":"10.1306\/212F817F-2B24-11D7-8648000102C1865D","article-title":"Authigenic\nvivianite in Potomac River\nsediments; control by ferric oxy-hydroxides","volume":"53","author":"Hearn","year":"1983","journal-title":"J. Sediment. Res."},{"key":"2026081210102471200_cit12","doi-asserted-by":"publisher","first-page":"321","DOI":"10.1016\/S1571-9197(07)07012-7","article-title":"Phosphate interactions\nwith iron\u00ad(hydr)\u00adoxides: Mineralization\npathways and phosphorus retention upon bioreduction","volume":"7","author":"Borch","year":"2007","journal-title":"Developments in Earth and Environmental Sciences"},{"key":"2026081210102471200_cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2020.116609","article-title":"Transformation of redox-sensitive\nto redox-stable iron-bound phosphorus in anoxic lake sediments under\nlaboratory conditions","volume":"189","author":"Heinrich","year":"2021","journal-title":"Water Res."},{"key":"2026081210102471200_cit14","doi-asserted-by":"publisher","first-page":"731","DOI":"10.1007\/BF00026261","article-title":"Iron: phosphorus ratio\nin surface sediment as an indicator of phosphate release from aerobic\nsediments in shallow lakes","volume":"235","author":"Jensen","year":"1992","journal-title":"Hydrobiologia"},{"key":"2026081210102471200_cit15","doi-asserted-by":"publisher","first-page":"140","DOI":"10.1016\/j.gca.2017.01.042","article-title":"Phosphorus burial\nin sediments of the sulfidic deep Black Sea: Key roles for adsorption\nby calcium carbonate and apatite authigenesis","volume":"204","author":"Kraal","year":"2017","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026081210102471200_cit16","doi-asserted-by":"publisher","first-page":"12795","DOI":"10.1021\/acs.est.0c02352","article-title":"Coprecipitation\nof\nphosphate and silicate affects environmental iron (oxyhydr)\u00adoxide transformations:\nA gel-based diffusive sampler approach","volume":"54","author":"Kraal","year":"2020","journal-title":"Environ.\nSci. Technol."},{"key":"2026081210102471200_cit17","doi-asserted-by":"publisher","first-page":"57","DOI":"10.2113\/0540057","article-title":"Principles of Crystal Nucleation\nand Growth","volume":"54","author":"De\nYoreo","year":"2003","journal-title":"Rev. Mineral. Geochem."},{"key":"2026081210102471200_cit18","doi-asserted-by":"publisher","DOI":"10.1371\/journal.pone.0143737","article-title":"Sedimentary sulphur: iron ratio indicates vivianite\noccurrence: A study from two contrasting freshwater systems","volume":"10","author":"Rothe","year":"2015","journal-title":"PLoS One"},{"key":"2026081210102471200_cit19","doi-asserted-by":"publisher","first-page":"5169","DOI":"10.5194\/bg-11-5169-2014","article-title":"Evidence for\nvivianite formation and its contribution to long-term phosphorus retention\nin a recent lake sediment: A novel analytical approach","volume":"11","author":"Rothe","year":"2014","journal-title":"Biogeosciences"},{"key":"2026081210102471200_cit20","doi-asserted-by":"publisher","first-page":"10008","DOI":"10.1021\/acs.est.3c00434","article-title":"A new approach\nfor investigating iron mineral transformations in soils and sediments\nusing 57Fe-labeled minerals and 57Fe Mo\u0308ssbauer\nspectroscopy","volume":"57","author":"Notini","year":"2023","journal-title":"Environ. Sci. Technol."},{"key":"2026081210102471200_cit21","doi-asserted-by":"publisher","first-page":"683","DOI":"10.1351\/pac200375060683","article-title":"Atomic weights\nof the elements. Review 2000 (IUPAC Technical Report)","volume":"75","author":"De Laeter","year":"2003","journal-title":"Pure and applied chemistry"},{"key":"2026081210102471200_cit22","doi-asserted-by":"publisher","first-page":"148","DOI":"10.1016\/j.jmarsys.2009.12.014","article-title":"Predicting\nthe consequences\nof nutrient reduction on the eutrophication status of the North Sea","volume":"81","author":"Lenhart","year":"2010","journal-title":"J. Mar. Syst."},{"key":"2026081210102471200_cit23","doi-asserted-by":"publisher","first-page":"231","DOI":"10.1016\/j.gca.2023.01.029","article-title":"Competitive\nincorporation of Mn and Mg in vivianite at varying salinity and effects\non crystal structure and morphology","volume":"346","author":"Kubeneck","year":"2023","journal-title":"Geochim.\nCosmochim. Acta"},{"key":"2026081210102471200_cit24","volume-title":"Field Measurement of\nOxidation-Reduction Potential (ORP)","author":"Striggow","year":"2017"},{"key":"2026081210102471200_cit25","doi-asserted-by":"publisher","first-page":"454","DOI":"10.4319\/lo.1969.14.3.0454","article-title":"Spectrophotometric\ndetermination of hydrogen sulfide in natural waters 1","volume":"14","author":"Cline","year":"1969","journal-title":"Limnol. Oceanogr."},{"key":"2026081210102471200_cit26","doi-asserted-by":"publisher","first-page":"85","DOI":"10.1016\/0168-583X(91)95681-3","article-title":"Voigt-based methods for arbitrary-shape\nstatic hyperfine parameter\ndistributions in Mo\u0308ssbauer spectroscopy","volume":"58","author":"Rancourt","year":"1991","journal-title":"Nucl. Instrum. Methods Phys. Res."},{"key":"2026081210102471200_cit27","doi-asserted-by":"publisher","first-page":"537","DOI":"10.1107\/S0909049505012719","article-title":"ATHENA, ARTEMIS, HEPHAESTUS: Data\nanalysis for X-ray\nabsorption spectroscopy using IFEFFIT","volume":"12","author":"Ravel","year":"2005","journal-title":"J. Synchrotron\nRad."},{"key":"2026081210102471200_cit28","doi-asserted-by":"publisher","first-page":"277","DOI":"10.1021\/es503663z","article-title":"Iron-mediated anaerobic oxidation of methane\nin brackish coastal sediments","volume":"49","author":"Egger","year":"2015","journal-title":"Environ. Sci.\nTechnol."},{"key":"2026081210102471200_cit29","doi-asserted-by":"publisher","first-page":"7","DOI":"10.1007\/s10751-008-9862-y","article-title":"Mo\u0308ssbauer study\nof magnetism in FeII-III (oxy-)\nhydroxycarbonate green rusts; ferrimagnetism of FeII- III hydroxycarbonate","volume":"187","author":"Rusch","year":"2008","journal-title":"Hyperfine Interact."},{"key":"2026081210102471200_cit30","doi-asserted-by":"publisher","first-page":"669","DOI":"10.1016\/S1474-7065(03)00121-9","article-title":"Towards\nthe identification\nof siderite, rhodochrosite, and vivianite in sediments by their low-temperature\nmagnetic properties","volume":"28","author":"Frederichs","year":"2003","journal-title":"Phys. Chem. Earth"},{"key":"2026081210102471200_cit31","doi-asserted-by":"publisher","first-page":"12316","DOI":"10.1021\/acs.est.8b03206","article-title":"Impact of\norganic matter on iron (II)-catalyzed mineral transformations in ferrihydrite\u2013organic\nmatter coprecipitates","volume":"52","author":"ThomasArrigo","year":"2018","journal-title":"Environ. Sci. Technol."},{"key":"2026081210102471200_cit32","doi-asserted-by":"publisher","first-page":"5477","DOI":"10.1021\/es4043275","article-title":"Effect\nof solution and solid-phase conditions on the Fe (II)-accelerated\ntransformation of ferrihydrite to lepidocrocite and goethite","volume":"48","author":"Boland","year":"2014","journal-title":"Environ. Sci. Technol."},{"key":"2026081210102471200_cit33","doi-asserted-by":"publisher","first-page":"105","DOI":"10.1016\/j.gca.2019.12.028","article-title":"Labile Fe (III) from sorbed Fe (II) oxidation is the\nkey intermediate in Fe (II)-catalyzed ferrihydrite transformation","volume":"272","author":"Sheng","year":"2020","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026081210102471200_cit34","doi-asserted-by":"publisher","first-page":"2977","DOI":"10.1016\/S0016-7037(03)00276-X","article-title":"Secondary mineralization\npathways\ninduced by dissimilatory iron reduction of ferrihydrite under advective\nflow","volume":"67","author":"Hansel","year":"2003","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026081210102471200_cit35","doi-asserted-by":"publisher","first-page":"166","DOI":"10.1021\/es060695p","article-title":"Phosphate imposed limitations\non biological reduction and alteration of ferrihydrite","volume":"41","author":"Borch","year":"2007","journal-title":"Environ. Sci. Technol."},{"key":"2026081210102471200_cit36","doi-asserted-by":"publisher","first-page":"3239","DOI":"10.1016\/S0016-7037(98)00243-9","article-title":"Biogenic iron mineralization accompanying\nthe dissimilatory reduction of hydrous ferric oxide by a groundwater\nbacterium","volume":"62","author":"Fredrickson","year":"1998","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026081210102471200_cit37","doi-asserted-by":"publisher","first-page":"1058","DOI":"10.1021\/es970547m","article-title":"Thermodynamic\nequilibria in aqueous suspensions of\nsynthetic and natural Fe\u00ad(II)- Fe\u00ad(III) green rusts: Occurrences of\nthe mineral in hydromorphic soils","volume":"32","author":"Ge\u0301nin","year":"1998","journal-title":"Environ.\nSci. Technol."},{"key":"2026081210102471200_cit38","doi-asserted-by":"publisher","first-page":"1426","DOI":"10.2138\/am-1998-11-1232","article-title":"Bacterial\nreduction of crystalline Fe3+ oxides\nin single phase suspensions and subsurface materials","volume":"83","author":"Zachara","year":"1998","journal-title":"Am. Mineral."},{"key":"2026081210102471200_cit39","doi-asserted-by":"publisher","first-page":"1715","DOI":"10.1016\/S0016-7037(01)00556-7","article-title":"Effect\nof orthophosphate on the oxidation products of Fe\u00ad(II)-Fe\u00ad(III) hydroxycarbonate:\nThe transformation of green rust to ferrihydrite","volume":"65","author":"Benali","year":"2001","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026081210102471200_cit40","doi-asserted-by":"publisher","first-page":"2799","DOI":"10.1016\/j.gca.2003.12.024","article-title":"Biotransformation\nof two-line silica-ferrihydrite by a dissimilatory Fe (III)-reducing\nbacterium: Formation of carbonate green rust in the presence of phosphate","volume":"68","author":"Kukkadapu","year":"2004","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026081210102471200_cit41","doi-asserted-by":"publisher","first-page":"117","DOI":"10.1016\/j.solidstatesciences.2003.10.004","article-title":"Coprecipitation of Fe\u00ad(II\u2013III) hydroxycarbonate\ngreen rust stabilised by phosphate adsorption","volume":"6","author":"Bocher","year":"2004","journal-title":"Solid State Sci."},{"key":"2026081210102471200_cit42","doi-asserted-by":"publisher","first-page":"3405","DOI":"10.1039\/D0EN00398K","article-title":"Organic matter\ninfluences transformation products of ferrihydrite exposed to sulfide","volume":"7","author":"ThomasArrigo","year":"2020","journal-title":"Environ. Sci. Nano"},{"key":"2026081210102471200_cit43","doi-asserted-by":"publisher","first-page":"311","DOI":"10.1016\/j.gca.2021.12.032","article-title":"Phosphate coprecipitation affects\nreactivity of iron (oxyhydr)\u00adoxides towards dissolved iron and sulfide","volume":"321","author":"Kraal","year":"2020","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026081210102471200_cit44","doi-asserted-by":"publisher","first-page":"5929","DOI":"10.1021\/acs.est.1c08789","article-title":"Stabilization\nof ferrihydrite and lepidocrocite by silicate during Fe (II)-catalyzed\nmineral transformation: Impact on particle morphology and silicate\ndistribution","volume":"56","author":"Schulz","year":"2022","journal-title":"Environ. Sci. Technol."},{"key":"2026081210102471200_cit45","doi-asserted-by":"publisher","first-page":"225","DOI":"10.1016\/0009-2541(80)90088-1","article-title":"Formation\nof siderite and vivianite and the pore-water composition of a recent\nbog sediment in Denmark","volume":"31","author":"Postma","year":"1980","journal-title":"Chem. Geol."},{"key":"2026081210102471200_cit46","doi-asserted-by":"publisher","first-page":"316","DOI":"10.1038\/341316a0","article-title":"Evidence\nfor sulphate-controlled\nphosphorus release from sediments of aquatic systems","volume":"341","author":"Caraco","year":"1989","journal-title":"Nature"},{"key":"2026081210102471200_cit47","doi-asserted-by":"publisher","first-page":"1607","DOI":"10.1007\/s12237-017-0233-2","article-title":"Phosphorus sequestration in sediments\nalong the salinity gradients of Chesapeake Bay subestuaries","volume":"40","author":"Hartzell","year":"2017","journal-title":"Estuaries Coast"},{"key":"2026081210102471200_cit48","doi-asserted-by":"publisher","first-page":"139","DOI":"10.1016\/j.gca.2023.04.032","article-title":"Phosphorus\ncontrols on the formation of vivianite versus green rust under anoxic\nconditions","volume":"351","author":"Xiong","year":"2023","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026081210102471200_cit49","doi-asserted-by":"publisher","first-page":"135","DOI":"10.1038\/ngeo2878","article-title":"A key role for green rust in the\nPrecambrian oceans\nand the genesis of iron formations","volume":"10","author":"Halevy","year":"2017","journal-title":"Nat. Geosci."},{"key":"2026081210102471200_cit50","doi-asserted-by":"publisher","DOI":"10.1016\/j.earscirev.2020.103430","article-title":"The biogeochemistry of ferruginous\nlakes and past ferruginous oceans","volume":"211","author":"Swanner","year":"2020","journal-title":"Earth-Sci.\nRev."},{"key":"2026081210102471200_cit51","doi-asserted-by":"publisher","first-page":"173","DOI":"10.1016\/j.gca.2024.01.020","article-title":"Transformation\nof vivianite in intertidal sediments with contrasting sulfide conditions","volume":"370","author":"Kubeneck","year":"2024","journal-title":"Geochim. Cosmochim. 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Technol."},{"key":"2026081210102471200_cit55","doi-asserted-by":"publisher","first-page":"38","DOI":"10.1021\/acs.est.6b03558","article-title":"A new approach\nto sampling intact Fe plaque reveals Si-induced changes in Fe mineral\ncomposition and shoot As in rice","volume":"51","author":"Amaral","year":"2017","journal-title":"Environ. 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