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Each sample can contain over 500 homologue groups, collectively producing &amp;gt;1000 m\/z ratios that require interference checks. High-resolution mass spectrometry methods vary in ionization signals and data formats and require specialized algorithms for quantification. CPxplorer streamlines data processing through the integration of three modules: (1) CPions generates target ion sets and isotopic thresholds for compound identification into the next module; (2) Skyline performs instrument-independent data integration, interference evaluation, and homologue profiling; and (3) CPquant deconvolves homologues and reports concentrations using reference standards and homologue profiles from Skyline. Evaluation of the workflow with NIST-SRM-2585 dust and ERM-CE100 fish tissue material yielded comparable results across raw data formats from different instruments. Further applications of CPxplorer across diverse matrices, including indoor dust, organic films, silicone wrist bands, and food samples, demonstrated the usefulness in biological and environmental monitoring. Compared to existing tools limited to qualitative detection, CPxplorer enables quantitative outputs, reduces processing time, and expands functionality to PCA-like substances (e.g., BCAs) and PCA degradation products (e.g., OH-PCAs). CPxplorer reduces learning barriers, empowers users to quantify PCAs across various analytical instruments, and contributes to generating comparable results in the field.<\/jats:p>","DOI":"10.1021\/acs.est.5c04928","type":"journal-article","created":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T13:02:35Z","timestamp":1760014955000},"page":"22074-22084","source":"Crossref","is-referenced-by-count":1,"title":["Streamlining Quantification\nand Data Harmonization\nof Polychlorinated Alkanes Using a Platform-Independent Workflow"],"prefix":"10.1021","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-5823-7105","authenticated-orcid":true,"given":"Idoia","family":"Beloki Ezker","sequence":"first","affiliation":[{"name":"Linko\u0308ping University , , ,","place":["Linko\u0308ping, Sweden, 581 83"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2043-8128","authenticated-orcid":true,"given":"Bo","family":"Yuan","sequence":"additional","affiliation":[{"name":"Norwegian University of Science and Technology , , ,","place":["Trondheim, Norway, 7491"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-3479-2362","authenticated-orcid":true,"given":"Anders R\u00f8srud","family":"Borgen","sequence":"additional","affiliation":[{"name":"NILU , , ,","place":["Kjeller, Norway, 2007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7553-3325","authenticated-orcid":true,"given":"Jiyan","family":"Liu","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, China, 100085"]},{"name":"University of Chinese Academy of Sciences , , , ,","place":["Hangzhou, Zhejiang, China, 310000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6115-4076","authenticated-orcid":true,"given":"Yawei","family":"Wang","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, China, 100085"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5729-1908","authenticated-orcid":true,"given":"Thanh","family":"Wang","sequence":"additional","affiliation":[{"name":"Linko\u0308ping University , , ,","place":["Linko\u0308ping, Sweden, 581 83"]},{"name":"Linko\u0308ping University , , ,","place":["Linko\u0308ping, Sweden, 581 83"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,10,9]]},"reference":[{"key":"2026081812160924000_cit1","doi-asserted-by":"publisher","first-page":"117363","DOI":"10.1016\/j.trac.2023.117363","article-title":"Recommended terms and abbreviations for polychlorinated alkanes (PCAs)\nas the predominant component of chlorinated paraffins (CPs)","volume":"169","author":"Fernandes","year":"2023","journal-title":"TrAC - Trends in Analytical Chemistry"},{"key":"2026081812160924000_cit2","doi-asserted-by":"publisher","first-page":"143","DOI":"10.1016\/j.emcon.2020.03.003","article-title":"Chlorinated paraffins\nin the technosphere:\nA review of available information and data gaps demonstrating the\nneed to support the Stockholm Convention implementation","volume":"6","author":"Guida","year":"2020","journal-title":"Emerg. 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