{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:44:53Z","timestamp":1792784693053,"version":"4.5.0"},"reference-count":66,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T00:00:00Z","timestamp":1785283200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T00:00:00Z","timestamp":1785283200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T00:00:00Z","timestamp":1785283200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"name":"Innovative Research Group Project of Hubei Provincial Natural Science Foundation","award":["2023AFA009"],"award-info":[{"award-number":["2023AFA009"]}]},{"name":"National Key Research and Development Program","award":["2023YFD1702800"],"award-info":[{"award-number":["2023YFD1702800"]}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["42577345"],"award-info":[{"award-number":["42577345"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Modern Agricultural Industry Technology System of China","award":["CARS26"],"award-info":[{"award-number":["CARS26"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The environmental persistence of glyphosate and its transformation into aminomethylphosphonic acid (AMPA) necessitate a mechanistic understanding of its abiotic degradation in natural environments. Manganese (Mn) oxides are ubiquitous redox-active minerals capable of oxidizing glyphosate; however, how Mn oxide mineralogy and pH regulate degradation kinetics, pathway selectivity, and interfacial redox processes remains unclear. Here, we investigated glyphosate oxidation by three representative Mn oxides, layered birnessite, disordered-layered vernadite, and tunnel-structured cryptomelane, across pH 3\u20137. Vernadite exhibited the highest and most sustained oxidative reactivity, cryptomelane showed rapid but strongly pH-dependent oxidation, and birnessite displayed slower yet persistent reactivity. Mineral structure controlled product selectivity: under near-neutral conditions, layered Mn oxides favored glycine formation through C\u2013N bond cleavage adjacent to the phosphonate group, whereas tunnel-structured cryptomelane promoted AMPA accumulation through cleavage near the carboxyl group. Acidic conditions (pH 3 and 5) enhanced AMPA accumulation across all Mn oxides, suggesting increased persistence risks. Spectroscopic and kinetic analyses demonstrated that glyphosate oxidation involved surface complexation with Mn(IV), interfacial electron transfer, and propagation through transient, labile Mn(III) intermediates. These findings reveal that Mn oxide mineralogy and pH jointly govern bond-selective glyphosate oxidation and AMPA accumulation, advancing mechanistic predictions of glyphosate fate in soil and aquatic environments.<\/jats:p>","DOI":"10.1021\/acs.est.6c00923","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:15:59Z","timestamp":1785849359000},"page":"25686-25700","source":"Crossref","is-referenced-by-count":0,"title":["Structure-Dependent\nOxidation Mechanisms of Glyphosate\nby Manganese Oxides: Role of Mineralogy and pH"],"prefix":"10.1021","volume":"60","author":[{"given":"Zhe","family":"Liu","sequence":"first","affiliation":[{"name":"Huazhong Agricultural University , , ,","place":["Wuhan, China, 430070"]},{"name":"South China University of Technology , , ,","place":["Guangzhou, China, 510006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengqi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Huazhong Agricultural University , , ,","place":["Wuhan, China, 430070"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyang","family":"Zhou","sequence":"additional","affiliation":[{"name":"Huazhong Agricultural University , , ,","place":["Wuhan, China, 430070"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyu","family":"Liu","sequence":"additional","affiliation":[{"name":"Huazhong Agricultural University , , ,","place":["Wuhan, China, 430070"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1187-3221","authenticated-orcid":true,"given":"Bruno","family":"Lanson","sequence":"additional","affiliation":[{"name":"University Grenoble Alpes, CNRS, University Savoie Mont Blanc, IRD, University Gustave Eiffel, ISTerre , ,","place":["Grenoble, France, F-38000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wantong","family":"Zhao","sequence":"additional","affiliation":[{"name":"Huazhong Agricultural University , , ,","place":["Wuhan, China, 430070"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5499-7174","authenticated-orcid":true,"given":"Xionghan","family":"Feng","sequence":"additional","affiliation":[{"name":"Huazhong Agricultural University , , ,","place":["Wuhan, China, 430070"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenfeng","family":"Tan","sequence":"additional","affiliation":[{"name":"Huazhong Agricultural University , , ,","place":["Wuhan, China, 430070"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guining","family":"Lu","sequence":"additional","affiliation":[{"name":"South China University of Technology , , ,","place":["Guangzhou, China, 510006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5484-3922","authenticated-orcid":true,"given":"Xiaoming","family":"Wang","sequence":"additional","affiliation":[{"name":"Huazhong Agricultural University , , ,","place":["Wuhan, China, 430070"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,29]]},"reference":[{"key":"2026091511113723200_cit1","doi-asserted-by":"publisher","first-page":"144","DOI":"10.1016\/j.eja.2009.04.004","article-title":"Glyphosate effects on diseases of plants","volume":"31","author":"Johal","year":"2009","journal-title":"Eur. J. Agron."},{"key":"2026091511113723200_cit2","doi-asserted-by":"publisher","first-page":"117477","DOI":"10.1016\/j.envres.2023.117477","article-title":"Recent technologies for glyphosate removal from aqueous environment:\na critical review","volume":"240","author":"Yaah","year":"2024","journal-title":"Environ. Res."},{"key":"2026091511113723200_cit3","doi-asserted-by":"publisher","first-page":"3","DOI":"10.1186\/s12302-016-0070-0","article-title":"Trends\nin glyphosate herbicide use in the United States and globally","volume":"28","author":"Benbrook","year":"2016","journal-title":"Environ. Sci. Eur."},{"key":"2026091511113723200_cit4","doi-asserted-by":"publisher","first-page":"154","DOI":"10.1016\/j.colsurfa.2013.01.022","article-title":"Degradation\nof glyphosate and AMPA (amino methylphosphonic\nacid) solutions by thin films of birnessite electrodeposited: A new\ndesign of material for remediation processes?","volume":"435","author":"Ndjeri","year":"2013","journal-title":"Colloids Surf., A"},{"key":"2026091511113723200_cit5","doi-asserted-by":"publisher","first-page":"1866","DOI":"10.1016\/j.chemosphere.2013.06.041","article-title":"Environmental fate of glyphosate and aminomethylphosphonic\nacid in surface waters and soil of agricultural basins","volume":"93","author":"Aparicio","year":"2013","journal-title":"Chemosphere"},{"key":"2026091511113723200_cit6","doi-asserted-by":"publisher","first-page":"1027","DOI":"10.1002\/ps.4652","article-title":"The history\nand current status of glyphosate","volume":"74","author":"Duke","year":"2018","journal-title":"Pest Manage.\nSci."},{"key":"2026091511113723200_cit7","doi-asserted-by":"publisher","first-page":"8789","DOI":"10.3390\/app12178789","article-title":"Review\nof glyphosate-based herbicide and aminomethylphosphonic acid (AMPA):\nEnvironmental and health impacts","volume":"12","author":"Ojelade","year":"2022","journal-title":"Appl. Sci."},{"key":"2026091511113723200_cit8","doi-asserted-by":"publisher","first-page":"255","DOI":"10.1016\/j.scitotenv.2017.10.309","article-title":"Environmental and\nhealth effects of the herbicide glyphosate","volume":"616\u2013617","author":"Van Bruggen","year":"2018","journal-title":"Sci. Total Environ."},{"key":"2026091511113723200_cit9","doi-asserted-by":"publisher","first-page":"5550","DOI":"10.3390\/molecules25235550","article-title":"Technologies employed\nin the treatment of water contaminated\nwith glyphosate: A review","volume":"25","author":"Espinoza-Montero","year":"2020","journal-title":"Molecules"},{"key":"2026091511113723200_cit10","doi-asserted-by":"publisher","first-page":"188","DOI":"10.1134\/S0003683815020209","article-title":"Microbial degradation of glyphosate herbicides (Review)","volume":"51","author":"Sviridov","year":"2015","journal-title":"Appl. Biochem. Microbiol."},{"key":"2026091511113723200_cit11","doi-asserted-by":"publisher","first-page":"187","DOI":"10.1016\/j.watres.2017.03.055","article-title":"AminoMethylPhosphonic\nacid (AMPA)\nin natural waters: Its sources, behavior and environmental fate","volume":"117","author":"Grandcoin","year":"2017","journal-title":"Water Res."},{"key":"2026091511113723200_cit12","doi-asserted-by":"publisher","first-page":"815","DOI":"10.2136\/sssaj2014.10.0394","article-title":"Birnessite-catalyzed\ndegradation\nof glyphosate: A mechanistic study aided by kinetics batch studies\nand NMR spectroscopy","volume":"79","author":"Paudel","year":"2015","journal-title":"Soil Sci. Soc. Am. J."},{"key":"2026091511113723200_cit13","doi-asserted-by":"publisher","first-page":"3447","DOI":"10.1073\/pnas.96.7.3447","article-title":"Manganese\noxide minerals: Crystal structures and economic and environmental\nsignificance","volume":"96","author":"Post","year":"1999","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2026091511113723200_cit14","doi-asserted-by":"publisher","first-page":"120345","DOI":"10.1016\/j.watres.2023.120345","article-title":"Solutions for an efficient arsenite\noxidation and removal from groundwater containing ferrous iron","volume":"243","author":"Ying","year":"2023","journal-title":"Water Res."},{"key":"2026091511113723200_cit15","doi-asserted-by":"publisher","first-page":"89","DOI":"10.1016\/j.eehl.2024.01.002","article-title":"Understanding the role of manganese\noxides in retaining harmful metals: Insights into oxidation and adsorption\nmechanisms at microstructure level","volume":"3","author":"Li","year":"2024","journal-title":"Eco-Environ.\nHealth"},{"key":"2026091511113723200_cit16","doi-asserted-by":"publisher","first-page":"395","DOI":"10.1080\/26395940.2022.2123047","article-title":"Catalytic degradation of organic pollutants by manganese\noxides: a comprehensive review","volume":"34","author":"Li","year":"2022","journal-title":"Environ. Pollut.\nBioavailab."},{"key":"2026091511113723200_cit17","doi-asserted-by":"publisher","first-page":"10978","DOI":"10.1021\/acs.est.6b02673","article-title":"Spectroscopic investigation of interfacial\ninteraction of manganese oxide with triclosan, aniline, and phenol","volume":"50","author":"Shaikh","year":"2016","journal-title":"Environ. Sci. Technol."},{"key":"2026091511113723200_cit18","doi-asserted-by":"publisher","first-page":"200","DOI":"10.1016\/j.watres.2019.01.011","article-title":"Enhanced transformation\nof sulfonamide antibiotics by manganese(IV) oxide in the presence\nof model humic constituents","volume":"153","author":"Song","year":"2019","journal-title":"Water Res."},{"key":"2026091511113723200_cit19","doi-asserted-by":"publisher","first-page":"124432","DOI":"10.1016\/j.envpol.2024.124432","article-title":"Comparing\nthe abiotic removal of glyphosate by \u03b2-MnO2 and \u03b4-MnO2\ncolloids: Insights into kinetics and mechanisms","volume":"357","author":"Xiong","year":"2024","journal-title":"Environ. Pollut."},{"key":"2026091511113723200_cit20","doi-asserted-by":"publisher","first-page":"9223","DOI":"10.1021\/es051342d","article-title":"Oxidative degradation\nof glyphosate and aminomethylphosphonate\nby manganese oxide","volume":"39","author":"Barrett","year":"2005","journal-title":"Environ. Sci. Technol."},{"key":"2026091511113723200_cit21","doi-asserted-by":"publisher","first-page":"132467","DOI":"10.1016\/j.jhazmat.2023.132467","article-title":"Effect\nof temperature on the degradation of glyphosate by Mn-oxide: Products\nand pathways of degradation","volume":"461","author":"Moller","year":"2024","journal-title":"J. Hazard. Mater"},{"key":"2026091511113723200_cit22","doi-asserted-by":"publisher","first-page":"19513","DOI":"10.1021\/acs.est.5c09711","article-title":"Chemical choreography at the Mn oxide\ninterface: Protein\nassociation modulates glyphosate bonding configurations and favors\nthe AMPA oxidation pathway","volume":"59","author":"Azimzadeh","year":"2025","journal-title":"Environ. Sci. Technol."},{"key":"2026091511113723200_cit23","doi-asserted-by":"publisher","first-page":"8474","DOI":"10.1021\/acs.jafc.6b02608","article-title":"Mechanisms of bond cleavage during manganese oxide\nand UV degradation of glyphosate: results from phosphate oxygen isotopes\nand molecular simulations","volume":"64","author":"Jaisi","year":"2016","journal-title":"J. Agric. Food Chem."},{"key":"2026091511113723200_cit24","doi-asserted-by":"publisher","first-page":"122198","DOI":"10.1016\/j.watres.2024.122198","article-title":"Trivalent manganese\nin dissolved forms: Occurrence,\nspeciation, reactivity and environmental geochemical impact","volume":"263","author":"Wang","year":"2024","journal-title":"Water Res."},{"key":"2026091511113723200_cit25","doi-asserted-by":"publisher","first-page":"92","DOI":"10.1016\/j.gca.2020.04.034","article-title":"Classical mechanical simulations of layer- and tunnel-structured\nmanganese oxide minerals","volume":"291","author":"Newton","year":"2020","journal-title":"Geochim. Cosmochim.\nActa"},{"key":"2026091511113723200_cit26","doi-asserted-by":"publisher","first-page":"591","DOI":"10.1107\/S2052520619006528","article-title":"The structure and crystal chemistry\nof vernadite in ferromanganese crusts","volume":"75","author":"Lee","year":"2019","journal-title":"Acta\nCrystallogr."},{"key":"2026091511113723200_cit27","doi-asserted-by":"publisher","first-page":"9741","DOI":"10.1073\/pnas.1902473116","article-title":"Photoelectric conversion on Earth\u2019s surface\nvia widespread Fe- and Mn-mineral coatings","volume":"116","author":"Lu","year":"2019","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2026091511113723200_cit28","doi-asserted-by":"publisher","first-page":"2506","DOI":"10.1021\/jacs.9b12266","article-title":"Redox cycling\ndriven transformation of layered manganese oxides to tunnel structures","volume":"142","author":"Jung","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026091511113723200_cit29","doi-asserted-by":"publisher","first-page":"238","DOI":"10.1039\/C9EN01000A","article-title":"Coupled morphological and structural evolution of \u03b4-MnO2 to \u03b1-MnO2 through multistage oriented assembly\nprocesses: the role of Mn(III)","volume":"7","author":"Liang","year":"2020","journal-title":"Environ. Sci.:\nNano"},{"key":"2026091511113723200_cit30","doi-asserted-by":"publisher","first-page":"122082","DOI":"10.1016\/j.watres.2024.122082","article-title":"Structure\nand molecular-level transformation for oxidation of effluent organic\nmatters by manganese oxides","volume":"262","author":"Liu","year":"2024","journal-title":"Water Res."},{"key":"2026091511113723200_cit31","doi-asserted-by":"publisher","first-page":"493","DOI":"10.1180\/minmag.1971.038.296.12","article-title":"The synthesis\nof birnessite, cryptomelane, and some other oxides and hydroxides\nof manganese","volume":"38","author":"McKenzie","year":"1971","journal-title":"Mineral Mag."},{"key":"2026091511113723200_cit32","doi-asserted-by":"publisher","first-page":"220","DOI":"10.1016\/j.gca.2016.07.035","article-title":"Structural\nresponse of phyllomanganates\nto wet aging and aqueous Mn(II)","volume":"192","author":"Hinkle","year":"2016","journal-title":"Geochim. Cosmochim.\nActa"},{"key":"2026091511113723200_cit33","doi-asserted-by":"publisher","first-page":"6045","DOI":"10.1021\/es050276c","article-title":"Siderophore-manganese(III) interactions II. Manganite\ndissolution promoted by desferrioxamine B","volume":"39","author":"Duckworth","year":"2005","journal-title":"Environ.\nSci. Technol."},{"key":"2026091511113723200_cit34","doi-asserted-by":"publisher","first-page":"735","DOI":"10.1016\/j.scitotenv.2018.07.221","article-title":"Assessing\nplant-available\nglyphosate in contrasting soils by diffusive gradient in thin-films\ntechnique (DGT)","volume":"646","author":"Weng","year":"2019","journal-title":"Sci. Total Environ."},{"key":"2026091511113723200_cit35","doi-asserted-by":"publisher","first-page":"1109","DOI":"10.1021\/acs.est.7b03692","article-title":"Degradation\nof glyphosate by Mn-oxide may bypass sarcosine and form glycine directly\nafter C\u2013N bond cleavage","volume":"52","author":"Li","year":"2018","journal-title":"Environ. Sci.\nTechnol."},{"key":"2026091511113723200_cit36","doi-asserted-by":"publisher","first-page":"14384","DOI":"10.1021\/acs.est.3c04727","article-title":"Adsorption\nmechanisms of glyphosate on ferrihydrite: Effects of Al\nsubstitution and aggregation state","volume":"57","author":"Li","year":"2023","journal-title":"Environ.\nSci. Technol."},{"key":"2026091511113723200_cit37","volume-title":"GB\/T 20684\u20132017. Glyphosate\nWater Soluble Powders (Granules)","author":"China Standards Press.","year":"2017"},{"key":"2026091511113723200_cit38","doi-asserted-by":"publisher","first-page":"1362","DOI":"10.1021\/acsearthspacechem.9b00127","article-title":"Competition of sorption\nand degradation reactions during\nglyphosate degradation by ferrihydrite\/\u03b4-manganese oxide composites","volume":"3","author":"Li","year":"2019","journal-title":"ACS Earth Space Chem."},{"key":"2026091511113723200_cit39","doi-asserted-by":"publisher","first-page":"10227","DOI":"10.1021\/acs.est.9b03456","article-title":"Influence of pyrophosphate on the\ngeneration of soluble Mn(III) from reactions involving Mn oxides and\nMn(VII)","volume":"53","author":"Liu","year":"2019","journal-title":"Environ. Sci. Technol."},{"key":"2026091511113723200_cit40","doi-asserted-by":"publisher","first-page":"116420","DOI":"10.1016\/j.watres.2020.116420","article-title":"Highly enhanced oxidation\nof arsenite at the surface of birnessite in the presence of pyrophosphate\nand the underlying reaction mechanisms","volume":"187","author":"Ying","year":"2020","journal-title":"Water\nRes."},{"key":"2026091511113723200_cit41","doi-asserted-by":"publisher","first-page":"117878","DOI":"10.1016\/j.apcatb.2019.117878","article-title":"One-pot synthesis of\natomically dispersed Pt on MnO2 for efficient catalytic\ndecomposition of toluene at low temperatures","volume":"257","author":"Zhang","year":"2019","journal-title":"Appl. Catal., B"},{"key":"2026091511113723200_cit42","doi-asserted-by":"publisher","first-page":"1769","DOI":"10.1021\/acs.est.0c07132","article-title":"Interfacial molecular\nfractionation on ferrihydrite reduces the photochemical reactivity\nof dissolved organic matter","volume":"55","author":"Wang","year":"2021","journal-title":"Environ. Sci. Technol."},{"key":"2026091511113723200_cit43","doi-asserted-by":"publisher","first-page":"305","DOI":"10.2138\/am-1998-3-414","article-title":"Interpretation of XPS\nMn(2p) spectra of Mn oxyhydroxides\nand constraints on the mechanism of MnO2 precipitation","volume":"83","author":"Nesbitt","year":"1998","journal-title":"Am. Mineral."},{"key":"2026091511113723200_cit44","doi-asserted-by":"publisher","first-page":"475","DOI":"10.1016\/j.apsusc.2015.12.159","article-title":"XPS determination\nof Mn oxidation states in Mn (hydr)oxides","volume":"366","author":"Ilton","year":"2016","journal-title":"Appl.\nSurf. Sci."},{"key":"2026091511113723200_cit45","doi-asserted-by":"publisher","first-page":"537","DOI":"10.1107\/S0909049505012719","article-title":"ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray\nabsorption spectroscopy using IFEFFIT","volume":"12","author":"Ravel","year":"2005","journal-title":"J. Synchrotron\nRadiat."},{"key":"2026091511113723200_cit46","doi-asserted-by":"publisher","first-page":"1098","DOI":"10.1016\/j.jhazmat.2007.11.015","article-title":"The oxidative degradation\nof 2-mercaptobenzothiazole at the interface of \u03b2-MnO2 and water","volume":"154","author":"Li","year":"2008","journal-title":"J. Hazard. Mater."},{"key":"2026091511113723200_cit47","doi-asserted-by":"publisher","first-page":"441","DOI":"10.1002\/ps.1512","article-title":"Fate of glyphosate\nin soil and the possibility of leaching\nto ground and surface waters: a review","volume":"64","author":"Borggaard","year":"2008","journal-title":"Pest\nManage. Sci."},{"key":"2026091511113723200_cit48","doi-asserted-by":"publisher","first-page":"5733","DOI":"10.1007\/s11356-015-5796-5","article-title":"Glyphosate\nand AMPA adsorption in\nsoils: laboratory experiments and pedotransfer rules","volume":"23","author":"Sidoli","year":"2016","journal-title":"Environ. Sci. Pollut. Res."},{"key":"2026091511113723200_cit49","doi-asserted-by":"publisher","first-page":"317","DOI":"10.1006\/jcis.2001.7773","article-title":"ATR\u2013FTIR\nSpectroscopic Investigation on Phosphate\nAdsorption Mechanisms at the Ferrihydrite\u2013Water Interface","volume":"241","author":"Arai","year":"2001","journal-title":"J. Colloid Interface Sci."},{"key":"2026091511113723200_cit50","doi-asserted-by":"publisher","first-page":"10248","DOI":"10.1021\/acs.inorgchem.6b01465","article-title":"Synthesis of birnessite in the presence\nof phosphate, silicate, or\nsulfate","volume":"55","author":"Wang","year":"2016","journal-title":"Inorg. Chem."},{"key":"2026091511113723200_cit51","doi-asserted-by":"publisher","first-page":"532","DOI":"10.1107\/S1600577515023085","article-title":"Reference\nspectra of important adsorbed organic and\ninorganic phosphate binding forms for soil P speciation using synchrotron-based\nK-edge XANES spectroscopy","volume":"23","author":"Prietzel","year":"2016","journal-title":"J. Synchrotron Radiat."},{"key":"2026091511113723200_cit52","doi-asserted-by":"publisher","first-page":"227","DOI":"10.1016\/j.gca.2025.06.030","article-title":"Phytase-mediated\nhydrolysis\nof different soil phytate species: Kinetics and mineral interfacial\nmechanisms","volume":"403","author":"Liu","year":"2025","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026091511113723200_cit53","doi-asserted-by":"publisher","first-page":"24","DOI":"10.1016\/j.chemgeo.2017.03.035","article-title":"In-situ determination of the kinetics\nand mechanisms of nickel adsorption by nanocrystalline vernadite","volume":"459","author":"Grangeon","year":"2017","journal-title":"Chem. Geol."},{"key":"2026091511113723200_cit54","doi-asserted-by":"publisher","first-page":"2791","DOI":"10.1021\/acs.est.4c10882","article-title":"Green glyphosate treatment\nwith ferrihydrite and CaO2 via forming surface ternary\ncomplex","volume":"59","author":"Zhang","year":"2025","journal-title":"Environ. Sci. Technol."},{"key":"2026091511113723200_cit55","doi-asserted-by":"publisher","first-page":"132596","DOI":"10.1016\/j.jhazmat.2023.132596","article-title":"The relative contributions of Mn(III)\nand Mn(IV) in manganese dioxide\npolymorphs to bisphenol A degradation","volume":"461","author":"Yang","year":"2024","journal-title":"J. Hazard.\nMater."},{"key":"2026091511113723200_cit56","doi-asserted-by":"publisher","first-page":"117034","DOI":"10.1016\/j.watres.2021.117034","article-title":"Sustained\nproduction of superoxide radicals by manganese oxides under ambient\ndark conditions","volume":"196","author":"Zhang","year":"2021","journal-title":"Water Res."},{"key":"2026091511113723200_cit57","doi-asserted-by":"publisher","first-page":"3476","DOI":"10.1021\/acs.est.7b05820","article-title":"Diffusion-\nand pH-dependent reactivity of layer-type MnO2: reactions\nat particle edges versus vacancy sites","volume":"52","author":"Wang","year":"2018","journal-title":"Environ.\nSci. Technol."},{"key":"2026091511113723200_cit58","doi-asserted-by":"publisher","first-page":"1750","DOI":"10.1021\/acs.est.5b04436","article-title":"Redox reactions\nbetween Mn(II) and hexagonal birnessite change its layer symmetry","volume":"50","author":"Zhao","year":"2016","journal-title":"Environ. Sci. Technol."},{"key":"2026091511113723200_cit59","doi-asserted-by":"publisher","first-page":"7453","DOI":"10.1021\/acs.est.9b01242","article-title":"Metal adsorption controls stability\nof layered manganese oxides","volume":"53","author":"Yang","year":"2019","journal-title":"Environ. Sci. Technol."},{"key":"2026091511113723200_cit60","doi-asserted-by":"publisher","first-page":"1844","DOI":"10.1021\/acs.est.7b04379","article-title":"Structural\ntransformation of birnessite\nby fulvic acid under anoxic conditions","volume":"52","author":"Wang","year":"2018","journal-title":"Environ.\nSci. Technol."},{"key":"2026091511113723200_cit61","doi-asserted-by":"publisher","first-page":"26583","DOI":"10.1021\/acs.est.5c13738","article-title":"MnO2 structural\npolymorph-mediated interaction with dissolved organic matter: underlying\nprotection and transformation mechanisms","volume":"59","author":"Wang","year":"2025","journal-title":"Environ.\nSci. Technol."},{"key":"2026091511113723200_cit62","doi-asserted-by":"publisher","first-page":"1004","DOI":"10.1016\/j.cej.2018.07.103","article-title":"Oxidation of bisphenol A by nonradical\nactivation of peroxymonosulfate in the presence of amorphous manganese\ndioxide","volume":"352","author":"Wang","year":"2018","journal-title":"Chem. Eng. J."},{"key":"2026091511113723200_cit63","doi-asserted-by":"publisher","first-page":"5548","DOI":"10.1021\/es703143g","article-title":"Kinetic\nmodeling of oxidation of\nantibacterial agents by manganese oxide","volume":"42","author":"Zhang","year":"2008","journal-title":"Environ.\nSci. Technol."},{"key":"2026091511113723200_cit64","doi-asserted-by":"publisher","first-page":"137810","DOI":"10.1016\/j.jhazmat.2025.137810","article-title":"Selective\nglyphosate degradation via oxygen activation using Fe-N-C: Critical\nrole of size exclusion","volume":"490","author":"Chen","year":"2025","journal-title":"J. Hazard. Mater."},{"key":"2026091511113723200_cit65","doi-asserted-by":"publisher","first-page":"5882","DOI":"10.1021\/es400878c","article-title":"Different crystallographic\none-dimensional MnO2 nanomaterials\nand their superior performance in catalytic phenol degradation","volume":"47","author":"Saputra","year":"2013","journal-title":"Environ. Sci. Technol."},{"key":"2026091511113723200_cit66","doi-asserted-by":"publisher","first-page":"12771","DOI":"10.1021\/acs.est.0c05235","article-title":"Facet engineered \u03b1-MnO2 for efficient\ncatalytic ozonation of odor CH3SH: Oxygen vacancy-induced\nactive centers and catalytic mechanism","volume":"54","author":"He","year":"2020","journal-title":"Environ.\nSci. Technol."}],"container-title":["Environmental Science &amp;\nTechnology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.est.6c00923","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/36\/25686\/66324634\/acs.est.6c00923.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/36\/25686\/66324634\/acs.est.6c00923.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T15:43:20Z","timestamp":1789487000000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/esthag\/article\/60\/36\/25686\/5236384\/Structure-Dependent-Oxidation-Mechanisms-of"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,29]]},"references-count":66,"journal-issue":{"issue":"36","published-online":{"date-parts":[[2026,7,29]]},"published-print":{"date-parts":[[2026,9,15]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.est.6c00923","relation":{},"ISSN":["0013-936X","1520-5851"],"issn-type":[{"value":"0013-936X","type":"print"},{"value":"1520-5851","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,29]]}}}