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Herein, we engineer an inverse CuO@CeO2 catalyst to realize the intimate coupling of CeO2 nanoislands with an inverse Ce\u2013O\u2013Cu interfacial architecture. Experimental and theoretical calculations unveil that this specific geometric configuration integrates spatially adjacent vacancies and dual oxygen sites. Unlike conventional Cu\u2013O\u2013Ce interfaces that yield the dominant CH4 by exposing CHx groups to the gas phase, our inverse Ce\u2013O\u2013Cu interface fundamentally manipulates intermediate orientations to synchronously drive multistep tandem reactions. Following initial CH3SSCH3 formation at Ce-adjacent oxygen\/vacancies, strong Cu\u2013S binding anchors CH3S* via Cu-adjacent oxygen vacancies, which geometrically force the terminal CHx group to face the adjacent interfacial oxygen. Such spatial proximity drastically lowers the energy barrier for the key C\u2013S cleavage and C\u2013O coupling to generate CH3SCH3 and CO2. Subsequent deep oxidation of CH3SCH3 with CuO bulk lattice oxygen results in the formation of COx, while sulfur is immobilized as a CuxS reservoir. Consequently, the inverse catalyst achieves complete CH3SH conversion at 180 \u00b0C, outperforming state-of-the-art non-noble metal alternatives with zero emission of hazardous H2S. Critically, moisture is exploited to generate surface hydroxyls, providing the dual functions of active-site protection and oxygen compensation to boost sulfur tolerance. This work establishes a robust nanoisland-mediated inverse interfacial strategy for low-temperature S-VOCs purification without ozone assistance.<\/jats:p>","DOI":"10.1021\/acs.est.6c01807","type":"journal-article","created":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T10:05:15Z","timestamp":1784023515000},"page":"20660-20676","source":"Crossref","is-referenced-by-count":2,"title":["Engineering Inverse\nCuO@CeO\n                    <b>2<\/b>\n                    Interfaces with Tandem Active Sites\nto Boost Low-Temperature Catalytic\nDegradation of Malodorous Methyl Mercaptan"],"prefix":"10.1021","volume":"60","author":[{"given":"Zhizhi","family":"Xu","sequence":"first","affiliation":[{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P. R. China, 650500"]},{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Feng","sequence":"additional","affiliation":[{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P.R. China, 650050"]},{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueying","family":"Yang","sequence":"additional","affiliation":[{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P.R. China, 650050"]},{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junyu","family":"Lai","sequence":"additional","affiliation":[{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P.R. China, 650050"]},{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuxuan","family":"He","sequence":"additional","affiliation":[{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P. R. China, 650500"]},{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dingkai","family":"Chen","sequence":"additional","affiliation":[{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P. R. China, 650500"]},{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sufang","family":"He","sequence":"additional","affiliation":[{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9602-831X","authenticated-orcid":true,"given":"Wenjie","family":"Zhu","sequence":"additional","affiliation":[{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P.R. China, 650050"]},{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jichang","family":"Lu","sequence":"additional","affiliation":[{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P.R. China, 650050"]},{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]},{"name":"Southwest United Graduate School , ,","place":["Kunming, P. R. China, 650092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9930-261X","authenticated-orcid":true,"given":"Yongming","family":"Luo","sequence":"additional","affiliation":[{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P.R. China, 650050"]},{"name":"Kunming University of Science and Technology , , ,","place":["Kunming, P. R. China, 650500"]},{"name":"The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, the Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province , , ,","place":["Kunming, P. R. China, 650500"]},{"name":"Southwest United Graduate School , ,","place":["Kunming, P. R. China, 650092"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,14]]},"reference":[{"key":"2026072809095218500_cit1","doi-asserted-by":"publisher","first-page":"109718","DOI":"10.1016\/j.vacuum.2020.109718","article-title":"Catalytic\noxidation\/photocatalytic degradation of ethyl mercaptan on \u03b1-MnO2@H4Nb6O17-NS nanocomposite","volume":"182","author":"Guo","year":"2020","journal-title":"Vacuum"},{"issue":"D04304","key":"2026072809095218500_cit2","doi-asserted-by":"publisher","DOI":"10.1029\/2011JD016360","article-title":"Hydrocarbon\nemissions characterization in the Colorado Front Range: A pilot study","volume":"117","author":"Pe\u0301tron","year":"2012","journal-title":"J. Geophys. 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Technol."},{"issue":"12","key":"2026072809095218500_cit5","doi-asserted-by":"publisher","first-page":"2777","DOI":"10.1021\/es011416v","article-title":"Adsorption\nof Methyl Mercaptan on\nActivated Carbons","volume":"36","author":"Bashkova","year":"2002","journal-title":"Environ. Sci. Technol."},{"key":"2026072809095218500_cit6","doi-asserted-by":"publisher","first-page":"134901","DOI":"10.1016\/j.chemosphere.2022.134901","article-title":"Study on adsorption\nof low-concentration\nmethyl mercaptan by starch-based activated carbon","volume":"302","author":"Yao","year":"2022","journal-title":"Chemosphere"},{"key":"2026072809095218500_cit7","doi-asserted-by":"publisher","first-page":"124680","DOI":"10.1016\/j.cej.2020.124680","article-title":"Adsorption\/oxidation\nof ethyl mercaptan on Fe-N-modified active carbon catalyst","volume":"393","author":"Lyu","year":"2020","journal-title":"Chem. Eng. J."},{"key":"2026072809095218500_cit8","doi-asserted-by":"publisher","first-page":"122578","DOI":"10.1016\/j.apcatb.2023.122578","article-title":"Interstitial\ncarbon-platinum electronic metal-support interaction structure boost\nsynergistic removal of O3 and CH3SH via surface\natomic oxygen","volume":"329","author":"Ma","year":"2023","journal-title":"Appl. Catal., B"},{"issue":"16","key":"2026072809095218500_cit9","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2319119121","article-title":"Precisely constructing\norbital coupling-modulated iron dinuclear site for enhanced catalytic\nozonation performance","volume":"121","author":"Qu","year":"2024","journal-title":"Proc. Natl. Acad. Sci.\nU. S. A."},{"key":"2026072809095218500_cit10","doi-asserted-by":"publisher","first-page":"185","DOI":"10.1016\/j.apcatb.2018.05.063","article-title":"The investigation\nof the role of basic lanthanum (La) species on the improvement of\ncatalytic activity and stability of HZSM-5 material for eliminating\nmethanethiol-(CH3SH)","volume":"237","author":"Lu","year":"2018","journal-title":"Appl. Catal.,\nB"},{"key":"2026072809095218500_cit11","doi-asserted-by":"publisher","first-page":"121289","DOI":"10.1016\/j.jhazmat.2019.121289","article-title":"The identification\nof active chromium species to enhance catalytic\nbehaviors of alumina-based catalysts for sulfur-containing VOC abatement","volume":"384","author":"Lu","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"2026072809095218500_cit12","doi-asserted-by":"publisher","first-page":"676","DOI":"10.1016\/j.jes.2025.09.029","article-title":"Recent advances\nin the catalytic removal of gaseous methyl mercaptan","volume":"164","author":"Liu","year":"2026","journal-title":"J. Environ. Sci."},{"key":"2026072809095218500_cit13","doi-asserted-by":"publisher","first-page":"160574","DOI":"10.1016\/j.cej.2025.160574","article-title":"Synergistically\nconstructing dual oxygen\/sulfur vacancies and activating lattice oxygen\nin MoS2\/TiO2 via heterointerface charge transfer\nfor catalytic degradation of sulfur-containing VOCs","volume":"507","author":"Ai","year":"2025","journal-title":"Chem. Eng. J."},{"key":"2026072809095218500_cit14","doi-asserted-by":"publisher","first-page":"122742","DOI":"10.1016\/j.seppur.2022.122742","article-title":"Insights into the different\ncatalytic behavior between Ce and Cr modified MCM-41 catalysts: Cr2S3 as new active species for CH3SH decomposition","volume":"307","author":"Cao","year":"2023","journal-title":"Sep. Purif. Technol."},{"key":"2026072809095218500_cit15","doi-asserted-by":"crossref","first-page":"123114","DOI":"10.1016\/j.apcatb.2023.123114","article-title":"An ultra-long stability\nof lanthanum (La) modified molecular sieve for catalytic degradation\nof typical sulfur-containing VOCs in a near-real environment","volume":"339","author":"Lu","year":"2023","journal-title":"Appl. Catal., B"},{"key":"2026072809095218500_cit16","doi-asserted-by":"publisher","first-page":"547","DOI":"10.1016\/j.apcatb.2013.07.056","article-title":"Conversion\nof methyl mercaptan and methanol to hydrocarbons over solid acid catalysts\n\u2013 A comparative study","volume":"144","author":"Hulea","year":"2014","journal-title":"Appl. Catal.,\nB"},{"key":"2026072809095218500_cit17","doi-asserted-by":"publisher","first-page":"66","DOI":"10.1016\/j.apcata.2017.01.011","article-title":"Effects of rare-earth\n(Nd, Er and Y) doping on catalytic performance of HZSM-5 zeolite catalysts\nfor methyl mercaptan (CH3SH) decomposition","volume":"533","author":"He","year":"2017","journal-title":"Appl. Catal. A Gen"},{"issue":"12","key":"2026072809095218500_cit18","doi-asserted-by":"publisher","first-page":"3735","DOI":"10.1039\/D1EN00744K","article-title":"Atomically dispersed Pd sites on Ti-SBA-15 for efficient\ncatalytic combustion of typical gaseous VOCs","volume":"8","author":"Wen","year":"2021","journal-title":"Environ. Sci.: Nano"},{"key":"2026072809095218500_cit19","doi-asserted-by":"publisher","first-page":"118767","DOI":"10.1016\/j.apcatb.2020.118767","article-title":"Excellent\ncatalytic activity and water resistance of UiO-66-supported highly\ndispersed Pd nanoparticles for toluene catalytic oxidation","volume":"269","author":"Bi","year":"2020","journal-title":"Appl. Catal., B"},{"issue":"3\u20134","key":"2026072809095218500_cit20","doi-asserted-by":"publisher","first-page":"466","DOI":"10.1016\/j.apcatb.2010.03.005","article-title":"Comprehensive\ninvestigation of Pd\/ZSM-5\/MCM-48 composite catalysts with enhanced\nactivity and stability for benzene oxidation","volume":"96","author":"He","year":"2010","journal-title":"Appl. Catal., B"},{"issue":"16","key":"2026072809095218500_cit21","doi-asserted-by":"publisher","first-page":"11657","DOI":"10.1021\/acs.est.2c01798","article-title":"Self-Accelerating\nInterfacial Catalytic Elimination of Gaseous Sulfur-Containing Volatile\nOrganic Compounds as Microbubbles in a Facet-Engineered Three-Dimensional\nBiOCl Sponge Fenton-Like Process","volume":"56","author":"Qu","year":"2022","journal-title":"Environ. Sci.\nTechnol."},{"key":"2026072809095218500_cit22","doi-asserted-by":"publisher","first-page":"125905","DOI":"10.1016\/j.apcatb.2025.125905","article-title":"Tailoring covalency competition of spinel oxides to enhance the reactivity\nof surface atomic oxygen for boosted catalytic ozonation","volume":"381","author":"Xu","year":"2026","journal-title":"Appl. Catal., B"},{"issue":"19","key":"2026072809095218500_cit23","doi-asserted-by":"publisher","first-page":"12771","DOI":"10.1021\/acs.est.0c05235","article-title":"Facet Engineered\n\u03b1-MnO2 for Efficient\nCatalytic Ozonation of Odor CH3SH: Oxygen Vacancy-Induced\nActive Centers and Catalytic Mechanism","volume":"54","author":"He","year":"2020","journal-title":"Environ.\nSci. Technol."},{"key":"2026072809095218500_cit24","doi-asserted-by":"publisher","first-page":"122877","DOI":"10.1016\/j.apcatb.2023.122877","article-title":"Highly\nefficient degradation of sulfur-containing volatile organic compounds\nby amorphous MnO2 at room temperature: Implications for\ncontrolling odor pollutants","volume":"334","author":"Liu","year":"2023","journal-title":"Appl. Catal., B"},{"key":"2026072809095218500_cit25","doi-asserted-by":"publisher","first-page":"132891","DOI":"10.1016\/j.seppur.2025.132891","article-title":"Catalytic autoxidation of methyl\nmercaptan at room temperature over three-dimensionally ordered macroporous\nCu2Ce8O catalyst","volume":"367","author":"Xu","year":"2025","journal-title":"Sep.\nPurif. Technol."},{"key":"2026072809095218500_cit26","doi-asserted-by":"publisher","first-page":"136922","DOI":"10.1016\/j.seppur.2026.136922","article-title":"Oxygen-vacancy\nengineering\nin copper-doped layered MnOx catalysts boosts room-temperature\nautoxidation of methyl mercaptan","volume":"390","author":"Lin","year":"2026","journal-title":"Sep. Purif.\nTechnol."},{"key":"2026072809095218500_cit27","doi-asserted-by":"crossref","first-page":"164197","DOI":"10.1016\/j.apsusc.2025.164197","article-title":"Investigation\ninto the catalytic roles of Mn-doped spherical CeO2 catalysts\nfor CH3SH degradation at room temperature","volume":"695","author":"Tang","year":"2025","journal-title":"Appl. Surf. Sci."},{"key":"2026072809095218500_cit28","doi-asserted-by":"publisher","first-page":"137035","DOI":"10.1016\/j.jhazmat.2024.137035","article-title":"Disentangling activity-stability\ntrade-off in the catalytic degradation of malodorous sulfur-containing\nVOCs driven by active sites\u2019 self-dynamic evolution","volume":"486","author":"Fang","year":"2025","journal-title":"J. Hazard. Mater."},{"issue":"4","key":"2026072809095218500_cit29","doi-asserted-by":"publisher","first-page":"110137","DOI":"10.1016\/j.cclet.2024.110137","article-title":"Design\nof highly active meso-zeolite enveloping Pt\u2013Ni bimetallic catalysts\nfor degradation of toluene","volume":"36","author":"He","year":"2025","journal-title":"Chin. Chem. Lett."},{"issue":"1","key":"2026072809095218500_cit30","doi-asserted-by":"publisher","first-page":"157","DOI":"10.1007\/s40820-025-02010-w","article-title":"Vertical\nInterfacial Engineering in Two-Step-Processed Perovskite\nFilms Enabled by Dual-Interface Modification for High-Efficiency p-i-n\nSolar Cells","volume":"18","author":"Zhou","year":"2026","journal-title":"Nano Micro Lett."},{"issue":"49","key":"2026072809095218500_cit31","doi-asserted-by":"publisher","first-page":"44781","DOI":"10.1021\/jacs.5c09230","article-title":"Promoted\nElectrochemical CO2 Methanation over Ultrastable Cu(II)-V(O)\nPair Sites in Cu-CeO2 Catalyst: Water Activation and Intermediate\nAdsorption Tuning","volume":"147","author":"Wang","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026072809095218500_cit32","doi-asserted-by":"publisher","first-page":"124253","DOI":"10.1016\/j.apcatb.2024.124253","article-title":"Synchronous catalytic\nelimination of malodorous mercaptans based\nVOCs: Controlling byproducts and revealing sites-pathway relationship","volume":"357","author":"Lu","year":"2024","journal-title":"Appl. Catal., B"},{"issue":"16","key":"2026072809095218500_cit33","doi-asserted-by":"publisher","first-page":"9513","DOI":"10.1039\/C6RA26264C","article-title":"Insight into the structure and energy of Mo27SxOy clusters","volume":"7","author":"Liu","year":"2017","journal-title":"RSC Adv."},{"issue":"2","key":"2026072809095218500_cit34","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202519485","article-title":"Inverse NiOx-Ag Interface\nto Decouple Reactant Activation for Ag-Ni\/SiO2-Catalyzed\nEster Hydrogenation","volume":"65","author":"Luo","year":"2026","journal-title":"Angew. Chem., Int. 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