{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:56:42Z","timestamp":1785851802867,"version":"3.56.0"},"reference-count":68,"publisher":"American Chemical Society (ACS)","issue":"30","license":[{"start":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T00:00:00Z","timestamp":1784678400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T00:00:00Z","timestamp":1784678400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T00:00:00Z","timestamp":1784678400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22306086"],"award-info":[{"award-number":["22306086"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22506077"],"award-info":[{"award-number":["22506077"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52460014"],"award-info":[{"award-number":["52460014"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20232BAB213028"],"award-info":[{"award-number":["20232BAB213028"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20232BCJ22003"],"award-info":[{"award-number":["20232BCJ22003"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20252BAC200597"],"award-info":[{"award-number":["20252BAC200597"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005230","name":"Natural Science Foundation of Chongqing Municipality","doi-asserted-by":"publisher","award":["CSTB2023NSCQ-MSX0950"],"award-info":[{"award-number":["CSTB2023NSCQ-MSX0950"]}],"id":[{"id":"10.13039\/501100005230","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFB3810802"],"award-info":[{"award-number":["2023YFB3810802"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013064","name":"Key Research and Development Program of Jiangxi Province","doi-asserted-by":"publisher","award":["20243BBH81032"],"award-info":[{"award-number":["20243BBH81032"]}],"id":[{"id":"10.13039\/501100013064","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013064","name":"Key Research and Development Program of Jiangxi Province","doi-asserted-by":"publisher","award":["20252BCF320025"],"award-info":[{"award-number":["20252BCF320025"]}],"id":[{"id":"10.13039\/501100013064","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Water-induced deactivation of Pd-based catalysts for light alkane combustion remains a significant challenge. Herein, S-1 zeolite-encapsulated Pd\u2013Pt bimetallic oxide nanoclusters were prepared for catalytic propane oxidation. The optimized Pd0.8Pt0.2@S-1 catalyst exhibits exceptional water resistance with the propane oxidation reaction temperature (T90) shifting by a mere 9 \u00b0C in the presence of 5% H2O and fully recovering once the water feed is terminated, superior activity, and thermal stability. Combined experimental and theoretical insights reveal that the introduction of Pt induces the formation of Pt\u2013O\u2013Pd bonds, modulating the electronic structure of Pd to enhance surface hydrophobicity, optimize oxygen and propane adsorption, and promote propane activation. In situ DRIFTS studies further confirm that propane oxidation over Pd0.8Pt0.2@S-1 proceeds via a Mars\u2013van Krevelen mechanism. This work sheds new light on confined bimetallic synergistic effects for the rational design of catalysts with superior performance.<\/jats:p>","DOI":"10.1021\/acs.est.6c05476","type":"journal-article","created":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T06:44:18Z","timestamp":1784702658000},"page":"21168-21179","source":"Crossref","is-referenced-by-count":0,"title":["Silicalite-1-Confined\nSynergistic Effects of Bimetallic\nOxide Nanoclusters toward High Water Resistance for Complete Propane\nOxidation"],"prefix":"10.1021","volume":"60","author":[{"given":"Zhiqiang","family":"Chen","sequence":"first","affiliation":[{"name":"Nanchang University , , 999 Xuefu Road , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoqiang","family":"Xie","sequence":"additional","affiliation":[{"name":"Nanchang University , , 999 Xuefu Road , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xincheng","family":"Zhou","sequence":"additional","affiliation":[{"name":"Nanchang University , , 999 Xuefu Road , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiang","family":"Tu","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Institute of Eco-Environmental Science Research and Planning , , ,","place":["Nanchang, Jiangxi, China, 330039"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengqing","family":"Zhuo","sequence":"additional","affiliation":[{"name":"Beijing Capital Air Environmental Science & Technology Co., Ltd. , ,","place":["Beijing, China, 100176"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Ji","sequence":"additional","affiliation":[{"name":"Nanchang University , , 999 Xuefu Road , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengbo","family":"Yu","sequence":"additional","affiliation":[{"name":"Nanchang University , , 999 Xuefu Road , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guobo","family":"Li","sequence":"additional","affiliation":[{"name":"Nanchang University , , 999 Xuefu Road , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenming","family":"Liu","sequence":"additional","affiliation":[{"name":"Nanchang University , , 999 Xuefu Road , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4314-8323","authenticated-orcid":true,"given":"Lu","family":"Wei","sequence":"additional","affiliation":[{"name":"Beijing University of Technology , , ,","place":["Beijing, China, 100124"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7768-3688","authenticated-orcid":true,"given":"Jiguang","family":"Deng","sequence":"additional","affiliation":[{"name":"Beijing University of Technology , , ,","place":["Beijing, China, 100124"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weili","family":"Dai","sequence":"additional","affiliation":[{"name":"Nanchang Hangkong University , , , ,","place":["Nanchang, Jiangxi, China, 330063"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9133-5727","authenticated-orcid":true,"given":"Honggen","family":"Peng","sequence":"additional","affiliation":[{"name":"Nanchang University , , 999 Xuefu Road , , ,","place":["Nanchang, Jiangxi, China, 330031"]},{"name":"Nanchang University , , 999 Xuefu Road , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,22]]},"reference":[{"key":"2026080409313145000_cit1","doi-asserted-by":"publisher","first-page":"4299","DOI":"10.1039\/D0CS01262A","article-title":"C-H bond activation\nin light alkanes: A theoretical perspective","volume":"50","author":"Wang","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"2026080409313145000_cit2","doi-asserted-by":"publisher","first-page":"587","DOI":"10.1038\/s41586-018-0871-y","article-title":"Secondary organic aerosol reduced\nby mixture of atmospheric vapours","volume":"565","author":"McFiggans","year":"2019","journal-title":"Nature"},{"key":"2026080409313145000_cit3","doi-asserted-by":"publisher","first-page":"20","DOI":"10.1038\/s41561-023-01334-9","article-title":"Ozone pollution mitigation strategy informed by long-term\ntrends of atmospheric oxidation capacity","volume":"17","author":"Wang","year":"2024","journal-title":"Nat.\nGeosci."},{"key":"2026080409313145000_cit4","doi-asserted-by":"publisher","first-page":"4471","DOI":"10.1021\/acs.chemrev.8b00408","article-title":"Recent advances in the catalytic\noxidation of volatile organic compounds: A review based on pollutant\nsorts and sources","volume":"119","author":"He","year":"2019","journal-title":"Chem. Rev."},{"key":"2026080409313145000_cit5","doi-asserted-by":"publisher","first-page":"747","DOI":"10.1039\/d3ta07590g","article-title":"Recent advances\nand future challenges in the catalytic combustion of light hydrocarbon\nVOCs","volume":"12","author":"He","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"2026080409313145000_cit6","doi-asserted-by":"publisher","first-page":"2265","DOI":"10.1021\/acscatal.5b02617","article-title":"Effect of\nceria crystal plane on the physicochemical and catalytic properties\nof Pd\/ceria for CO and propane oxidation","volume":"6","author":"Hu","year":"2016","journal-title":"ACS\nCatal."},{"key":"2026080409313145000_cit7","doi-asserted-by":"publisher","first-page":"1518","DOI":"10.1126\/science.abj5291","article-title":"Steam-created grain boundaries for methane C\u2013H activation\nin palladium catalysts","volume":"373","author":"Huang","year":"2021","journal-title":"Science"},{"key":"2026080409313145000_cit8","doi-asserted-by":"publisher","first-page":"830","DOI":"10.1038\/s41929-021-00680-4","article-title":"Engineering catalyst supports to stabilize\nPdOx two-dimensional rafts for water-tolerant methane oxidation","volume":"4","author":"Xiong","year":"2021","journal-title":"Nat. Catal."},{"key":"2026080409313145000_cit9","doi-asserted-by":"publisher","first-page":"68","DOI":"10.1149\/1.2426509","article-title":"The free\nenergy of formation of palladium oxide","volume":"114","author":"Warner","year":"1967","journal-title":"J. Electrochem.\nSoc."},{"key":"2026080409313145000_cit10","doi-asserted-by":"publisher","first-page":"5783","DOI":"10.1021\/acscatal.0c01069","article-title":"Role of water on the structure of\npalladium for complete\noxidation of methane","volume":"10","author":"Li","year":"2020","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit11","doi-asserted-by":"publisher","first-page":"13457","DOI":"10.1021\/acscatal.2c03321","article-title":"Catalytic combustion\nof methane: From mechanism and\nmaterials properties to catalytic performance","volume":"12","author":"Tang","year":"2022","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit12","doi-asserted-by":"publisher","first-page":"1472","DOI":"10.1021\/acscatal.8b03666","article-title":"Highly active Pt\/BN catalysts for propane combustion: The roles of\nsupport and reactant-induced evolution of active sites","volume":"9","author":"Liu","year":"2019","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit13","doi-asserted-by":"publisher","first-page":"89","DOI":"10.1016\/j.jcat.2021.06.018","article-title":"Insights and\ncomparison of structure-property relationships in propane and propene\ncatalytic combustion on Pd- and Pt-based catalysts","volume":"401","author":"Yang","year":"2021","journal-title":"J. Catal."},{"key":"2026080409313145000_cit14","doi-asserted-by":"publisher","first-page":"195404","DOI":"10.1103\/PhysRevB.69.195404","article-title":"Water adsorption on\nmetal surfaces:\nA general picture from density functional theory studies","volume":"69","author":"Meng","year":"2004","journal-title":"Phys. Rev. B"},{"key":"2026080409313145000_cit15","doi-asserted-by":"publisher","first-page":"381","DOI":"10.1016\/j.surfrep.2009.07.001","article-title":"Water adsorption and the wetting of metal surfaces, Surf","volume":"64","author":"Hodgson","year":"2009","journal-title":"Sci. Rep."},{"key":"2026080409313145000_cit16","doi-asserted-by":"publisher","first-page":"4372","DOI":"10.1021\/acscatal.7b00393","article-title":"Uniform Pt\/Pd\nbimetallic nanocrystals demonstrate platinum\neffect on palladium methane combustion activity and stability","volume":"7","author":"Goodman","year":"2017","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit17","doi-asserted-by":"publisher","first-page":"281","DOI":"10.1016\/S0926-860X(01)00914-0","article-title":"Effect\nof water\nvapor on the activity of Pt-Pd\/Al2O3 catalysts\nfor methane combustion, Appl","volume":"226","author":"Pieck","year":"2002","journal-title":"Catal. A Gen."},{"key":"2026080409313145000_cit18","doi-asserted-by":"publisher","first-page":"244","DOI":"10.1038\/s41578-020-00250-3","article-title":"Confining isolated\natoms and clusters in crystalline porous materials\nfor catalysis","volume":"6","author":"Liu","year":"2021","journal-title":"Nat. Rev. Mater."},{"key":"2026080409313145000_cit19","doi-asserted-by":"publisher","first-page":"2894","DOI":"10.1021\/acs.accounts.1c00274","article-title":"Confinement in a zeolite\nand zeolite catalysis","volume":"54","author":"Chai","year":"2021","journal-title":"Acc. Chem. Res."},{"key":"2026080409313145000_cit20","doi-asserted-by":"publisher","first-page":"2579","DOI":"10.1021\/acs.accounts.1c00074","article-title":"Zeolite Fixed\nmetal nanoparticles: New perspective in catalysis","volume":"54","author":"Wang","year":"2021","journal-title":"Acc. Chem. Res."},{"key":"2026080409313145000_cit21","doi-asserted-by":"publisher","first-page":"6039","DOI":"10.1021\/acs.chemrev.2c00315","article-title":"Metal sites in zeolites:\nSynthesis, characterization,\nand catalysis","volume":"123","author":"Zhang","year":"2023","journal-title":"Chem. Rev."},{"key":"2026080409313145000_cit22","doi-asserted-by":"publisher","first-page":"666","DOI":"10.1038\/s41929-024-01155-y","article-title":"Regioselective\nhydroformylation\nwith subnanometre Rh clusters in MFI zeolite","volume":"7","author":"Dou","year":"2024","journal-title":"Nat. Catal."},{"key":"2026080409313145000_cit23","doi-asserted-by":"publisher","first-page":"497","DOI":"10.1126\/science.adu6907","article-title":"A self-regenerating\nPt\/Ge-MFI zeolite for propane dehydrogenation with high endurance","volume":"388","author":"Hong","year":"2025","journal-title":"Science"},{"key":"2026080409313145000_cit24","doi-asserted-by":"publisher","first-page":"27600","DOI":"10.1021\/jacs.4c08813","article-title":"Zeolite-encaged isolated palladium\nredox centers toward sustainable Wacker-type oxidations","volume":"146","author":"Li","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026080409313145000_cit25","doi-asserted-by":"publisher","first-page":"20898","DOI":"10.1021\/jacs.1c09535","article-title":"Zeolite-encaged isolated\nplatinum ions enable heterolytic dihydrogen activation and selective\nhydrogenations","volume":"143","author":"Deng","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"2026080409313145000_cit26","doi-asserted-by":"publisher","first-page":"124752","DOI":"10.1016\/j.apcatb.2024.124752","article-title":"Tailored engineering\nof intracrystalline mesopores for boosting multicomponent volatile\norganic compounds simultaneous deep oxidation, Appl","volume":"362","author":"He","year":"2025","journal-title":"Catal. B: Environ. Energy"},{"key":"2026080409313145000_cit27","doi-asserted-by":"publisher","first-page":"124717","DOI":"10.1016\/j.cej.2020.124717","article-title":"Hierarchical zeolite\nenveloping Pd-CeO2 nanowires: An efficient adsorption\/catalysis\nbifunctional catalyst for low temperature propane total degradation","volume":"393","author":"Dong","year":"2020","journal-title":"Chem. Eng. J."},{"key":"2026080409313145000_cit28","doi-asserted-by":"publisher","first-page":"201","DOI":"10.1016\/j.jcat.2022.06.031","article-title":"Boosting the\ndeep oxidation of propane over zeolite encapsulated Rh-Mn bimetallic\nnanoclusters: Elucidating the role of confinement and synergy effects","volume":"413","author":"Liu","year":"2022","journal-title":"J. Catal."},{"key":"2026080409313145000_cit29","doi-asserted-by":"publisher","first-page":"295","DOI":"10.1038\/s41467-021-27828-x","article-title":"Intra-crystalline mesoporous\nzeolite encapsulation-derived thermally\nrobust metal nanocatalyst in deep oxidation of light alkanes","volume":"13","author":"Peng","year":"2022","journal-title":"Nat. Commun."},{"key":"2026080409313145000_cit30","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417618","article-title":"Elucidating confinement\nand microenvironment of ru clusters stably\nconfined in mfi zeolite for efficient propane oxidation","volume":"64","author":"Wang","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026080409313145000_cit31","doi-asserted-by":"publisher","first-page":"302","DOI":"10.1080\/01614940.2021.1948301","article-title":"Interaction of water\nwith zeolites: A review","volume":"63","author":"Resasco","year":"2021","journal-title":"Catal. Rev."},{"key":"2026080409313145000_cit32","doi-asserted-by":"publisher","first-page":"2303","DOI":"10.1021\/acscatal.8b04486","article-title":"Design\nof stable palladium-based zeolite catalysts for complete methane oxidation\nby postsynthesis zeolite modification","volume":"9","author":"Petrov","year":"2019","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit33","doi-asserted-by":"publisher","first-page":"7371","DOI":"10.1021\/acscatal.0c04868","article-title":"Stable\npalladium oxide clusters encapsulated in silicalite-1 for complete\nmethane oxidation","volume":"11","author":"Li","year":"2021","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit34","doi-asserted-by":"publisher","first-page":"6121","DOI":"10.1021\/acs.iecr.4c00464","article-title":"Rapid and facile synthesis\nof nanosized silicalite-1 zeolites from solid silica in a semisolid-like\nsystem via a two-step crystallization method, Ind","volume":"63","author":"Zheng","year":"2024","journal-title":"Eng. Chem. Res."},{"key":"2026080409313145000_cit35","doi-asserted-by":"publisher","first-page":"142885","DOI":"10.1016\/j.cplett.2026.142885","article-title":"Synthesis of core-shell\nstructured CoOx\/TS-1@S-1 zeolite and its catalytic performance\nin the oxidation of ethylbenzene","volume":"896","author":"Fang","year":"2026","journal-title":"Chem. Phys.\nLett."},{"key":"2026080409313145000_cit36","doi-asserted-by":"publisher","first-page":"124221","DOI":"10.1016\/j.apcatb.2024.124221","article-title":"Palladium\nnanoparticles anchored on silanol nests of\nzeolite showed superior stability for methane combustion, Appl","volume":"356","author":"Wang","year":"2024","journal-title":"Catal. B: Environ. Energy"},{"key":"2026080409313145000_cit37","doi-asserted-by":"publisher","first-page":"119142","DOI":"10.1016\/j.apcatb.2020.119142","article-title":"In-situ confinement\nof ultrasmall palladium nanoparticles in silicalite-1 for methane\ncombustion with excellent activity and hydrothermal stability, Appl","volume":"276","author":"Wang","year":"2020","journal-title":"Catal. B: Environ."},{"key":"2026080409313145000_cit38","doi-asserted-by":"publisher","DOI":"10.3390\/catal11121446","article-title":"Atomic structure of Pd-, Pt-, and PdPt-based catalysts\nof total oxidation of methane: In situ EXAFS study","volume":"11","author":"Saraev","year":"2021","journal-title":"Catalysts"},{"key":"2026080409313145000_cit39","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201803966","article-title":"Ultrasmall\nMetal Nanoparticles Confined within crystalline\nnanoporous materials: A fascinating class of nanocatalysts","volume":"31","author":"Wang","year":"2019","journal-title":"Adv. Mater."},{"key":"2026080409313145000_cit40","doi-asserted-by":"publisher","first-page":"28009","DOI":"10.1021\/acs.jpcc.6b09223","article-title":"Characterization of Surface Structure and Oxidation\/Reduction\nBehavior of Pd\u2013Pt\/Al2O3 Model Catalysts","volume":"120","author":"Martin","year":"2016","journal-title":"J. Phys. Chem. C"},{"key":"2026080409313145000_cit41","doi-asserted-by":"publisher","first-page":"5456","DOI":"10.1021\/acscatal.3c00360","article-title":"Biphasic janus particles explain\nself-healing in Pt-Pd diesel oxidation catalysts","volume":"13","author":"Porter","year":"2023","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit42","doi-asserted-by":"publisher","first-page":"3403","DOI":"10.1039\/D3CY00430A","article-title":"Ultra-stable\nPd ions at Al T1\/T2 sites on a dealuminated Pd\/beta\npassive NOx adsorber, Catal","volume":"13","author":"Zhu","year":"2023","journal-title":"Sci.\nTechnol."},{"key":"2026080409313145000_cit43","doi-asserted-by":"publisher","first-page":"138937","DOI":"10.1016\/j.cej.2022.138937","article-title":"Reaction gas-induced\npartial exsolution of Pd from PdCeMnO for methane\ncombustion","volume":"451","author":"Zhao","year":"2023","journal-title":"Chem. Eng. J."},{"key":"2026080409313145000_cit44","doi-asserted-by":"publisher","first-page":"2522","DOI":"10.1021\/acscatal.3c05968","article-title":"The role of adsorbed\nspecies in 1-butene isomerization:\nParahydrogen-induced polarization nmr of Pd-Au catalyzed butadiene\nhydrogenation","volume":"14","author":"Wang","year":"2024","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit45","doi-asserted-by":"publisher","first-page":"3637","DOI":"10.1021\/acsanm.2c05378","article-title":"Size-controlled palladium\nnanoparticles encapsulated in silicalite-1 for methane catalytic combustion","volume":"6","author":"Liu","year":"2023","journal-title":"ACS Appl. Nano Mater."},{"key":"2026080409313145000_cit46","doi-asserted-by":"publisher","first-page":"15132","DOI":"10.1021\/jacs.2c04871","article-title":"Dynamical\nstudy of adsorbate-induced restructuring kinetics in bimetallic catalysts\nusing the PdAu(111) model system","volume":"144","author":"Zhou","year":"2022","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026080409313145000_cit47","doi-asserted-by":"publisher","first-page":"7534","DOI":"10.1039\/D0AN01303J","article-title":"Pd nanoparticle growth monitored by DRIFT spectroscopy\nof adsorbed CO","volume":"145","author":"Tereshchenko","year":"2020","journal-title":"Analyst"},{"key":"2026080409313145000_cit48","doi-asserted-by":"publisher","DOI":"10.1038\/srep42172","article-title":"Photodeposited Pd nanoparticles\nwith disordered structure for phenylacetylene\nsemihydrogenation","volume":"7","author":"Fan","year":"2017","journal-title":"Sci. Rep."},{"key":"2026080409313145000_cit49","doi-asserted-by":"publisher","first-page":"112738","DOI":"10.1016\/j.mcat.2022.112738","article-title":"Catalytic oxidation of propane over\nPt-Pd bimetallic nanoparticles supported on TiO2","volume":"532","author":"Camposeco","year":"2022","journal-title":"Mol. Catal."},{"key":"2026080409313145000_cit50","doi-asserted-by":"publisher","first-page":"21246","DOI":"10.1021\/acsami.5c00598","article-title":"Construction of electron-enriched\nPt\u03b4+ with reactive oxygen species for enhanced propane\ncatalytic combustion","volume":"17","author":"Yu","year":"2025","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026080409313145000_cit51","doi-asserted-by":"publisher","first-page":"6494","DOI":"10.1038\/s41467-024-50216-0","article-title":"Anchoring\nPdOx clusters on defective alumina for improved catalytic\nmethane oxidation","volume":"15","author":"Yu","year":"2024","journal-title":"Nat. Commun."},{"key":"2026080409313145000_cit52","doi-asserted-by":"publisher","first-page":"112086","DOI":"10.1016\/j.micromeso.2022.112086","article-title":"Promotion effect of\nthe S-1 zeolite\nmicroenvironment on confined Pd nanoparticles for the selective hydrogenation\nof nitrile, Micropor","volume":"341","author":"Lu","year":"2022","journal-title":"Mesopor. Mater."},{"key":"2026080409313145000_cit53","doi-asserted-by":"publisher","first-page":"3041","DOI":"10.1021\/acs.est.3c08380","article-title":"Role of the\nin-situ-formed surface (Pt-S-O)-Ti active structure in SO2-promoted C3H8 combustion over a Pt\/TiO2 catalyst","volume":"58","author":"Chen","year":"2024","journal-title":"Environ. Sci. Technol."},{"key":"2026080409313145000_cit54","doi-asserted-by":"publisher","first-page":"11910","DOI":"10.1039\/D0RA10773E","article-title":"Yttrium stabilization and Pt addition\nto Pd\/ZrO2 catalyst for the oxidation of methane in the\npresence of ethylene and water","volume":"11","author":"Khan","year":"2021","journal-title":"RSC Adv."},{"key":"2026080409313145000_cit55","doi-asserted-by":"publisher","first-page":"6044","DOI":"10.1021\/acscatal.3c00816","article-title":"Recent progress\nin metal-molecular sieve catalysts for propane dehydrogenation","volume":"13","author":"Song","year":"2023","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit56","doi-asserted-by":"publisher","first-page":"1310","DOI":"10.1021\/acscatal.1c04092","article-title":"Boosting propane\ndehydrogenation\nover PtZn encapsulated in an epitaxial high-crystallized zeolite with\na low surface barrier","volume":"12","author":"Zhang","year":"2022","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit57","doi-asserted-by":"publisher","first-page":"10376","DOI":"10.1021\/acscatal.4c02599","article-title":"Mass-transfer enhancement\nin the CO2 oxidative\ndehydrogenation of propane over GaN supported on zeolite nanosheets\nwith a short b-axis and hierarchical pores","volume":"14","author":"Zhu","year":"2024","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit58","doi-asserted-by":"publisher","first-page":"3356","DOI":"10.1021\/acscatal.2c05704","article-title":"Effect of diffusion constraints and\nZnOx speciation on nonoxidative dehydrogenation of propane\nand isobutane over ZnO-containing catalysts","volume":"13","author":"Zhao","year":"2023","journal-title":"ACS Catal."},{"key":"2026080409313145000_cit59","doi-asserted-by":"publisher","first-page":"20370","DOI":"10.1021\/acs.est.3c05634","article-title":"In situ synthesis\nof encapsulated Pd@silicalite-2 for highly stable methane catalytic\ncombustion","volume":"57","author":"Sun","year":"2023","journal-title":"Environ. Sci. Technol."},{"key":"2026080409313145000_cit60","doi-asserted-by":"publisher","first-page":"802","DOI":"10.1016\/j.apsusc.2019.03.134","article-title":"Thin-felt Al-fiber-structured\nPd-Co-MnOx\/Al2O3 catalyst with high\nmoisture resistance for high-throughput\nO3 decomposition, Appl","volume":"481","author":"Tao","year":"2019","journal-title":"Surf. Sci."},{"key":"2026080409313145000_cit61","doi-asserted-by":"publisher","first-page":"2271","DOI":"10.1021\/acs.est.6b03983","article-title":"Efficient removal of methane over cobalt-monoxide-doped AuPd nanocatalysts","volume":"51","author":"Xie","year":"2017","journal-title":"Environ. Sci. Technol."},{"key":"2026080409313145000_cit62","doi-asserted-by":"publisher","first-page":"121623","DOI":"10.1016\/j.apcatb.2022.121623","article-title":"Impact of Pd: Pt ratio of Pd\/Pt bimetallic catalyst\non CH4 oxidation, Appl","volume":"316","author":"Park","year":"2022","journal-title":"Catal. B:\nEnviron."},{"key":"2026080409313145000_cit63","doi-asserted-by":"publisher","first-page":"119177","DOI":"10.1016\/j.apcatb.2020.119177","article-title":"PdPt-TiO2 nanowires: Correlating\ncomposition, electronic effects and O-vacancies with activities towards\nwater splitting and oxygen reduction, Appl","volume":"277","author":"Da Silva","year":"2020","journal-title":"Catal. B: Environ. Energy"},{"key":"2026080409313145000_cit64","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.jcat.2016.12.021","article-title":"A detailed spectroscopic analysis of the growth of\noxy-carbon species on the surface of Pt\/Al2O3 during propane oxidation","volume":"347","author":"O\u2019Brien","year":"2017","journal-title":"J. Catal."},{"key":"2026080409313145000_cit65","doi-asserted-by":"publisher","first-page":"148344","DOI":"10.1016\/j.cej.2023.148344","article-title":"Catalytic oxidation\nof propane over nanorod-like TiO2 supported\nRu catalysts: Structure-activity dependence and mechanistic insights","volume":"481","author":"Wang","year":"2024","journal-title":"Chem. Eng. J."},{"key":"2026080409313145000_cit66","doi-asserted-by":"publisher","first-page":"120171","DOI":"10.1016\/j.apcatb.2021.120171","article-title":"Insights into flower-like Al2O3 spheres with rich unsaturated pentacoordinate\nAl3+ sites stabilizing Ru-CeOx for propane total\noxidation, Appl","volume":"292","author":"Liu","year":"2021","journal-title":"Catal. B: Environ."},{"key":"2026080409313145000_cit67","doi-asserted-by":"publisher","first-page":"179","DOI":"10.1016\/j.jcat.2021.02.014","article-title":"Manipulating\nmorphology and surface engineering of spinel cobalt oxides to attain\nhigh catalytic performance for propane oxidation","volume":"396","author":"Zhu","year":"2021","journal-title":"J. Catal."},{"key":"2026080409313145000_cit68","doi-asserted-by":"publisher","first-page":"122528","DOI":"10.1016\/j.apcatb.2023.122528","article-title":"Cr-doping regulates Mn3O4 spinel structure\nfor efficient total oxidation of propane: Structural effects and reaction\nmechanism determination, Appl","volume":"328","author":"Feng","year":"2023","journal-title":"Catal. B: Environ.\nEnergy"}],"container-title":["Environmental Science &amp;\nTechnology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.est.6c05476","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/30\/21168\/66115685\/acs.est.6c05476.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/30\/21168\/66115685\/acs.est.6c05476.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:31:45Z","timestamp":1785850305000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/esthag\/article\/60\/30\/21168\/5226248\/Silicalite-1-Confined-Synergistic-Effects-of"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,22]]},"references-count":68,"journal-issue":{"issue":"30","published-online":{"date-parts":[[2026,7,22]]},"published-print":{"date-parts":[[2026,8,4]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.est.6c05476","relation":{},"ISSN":["0013-936X","1520-5851"],"issn-type":[{"value":"0013-936X","type":"print"},{"value":"1520-5851","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,22]]}}}