{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T15:45:57Z","timestamp":1792165557675,"version":"4.4.0"},"reference-count":68,"publisher":"American Chemical Society (ACS)","issue":"34","license":[{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Phosphorus (P) associated with goethitic iron ores remains a major challenge for iron ore beneficiation because much of the P is hosted within Fe-associated mineral domains that are poorly accessible to conventional extraction methods. Here, we investigate Fe(II)-catalyzed recrystallization as a low-temperature mineralogical conditioning strategy for selectively restructuring natural goethitic iron ores and enhancing P accessibility. Two goethite-rich Pilbara ores with contrasting crystallinity, Al\u2013Si-substitution, and structural complexity were reacted with aqueous 57Fe-enriched Fe(II) under circumneutral anoxic conditions. Fe(II) rapidly transferred from solution to the solid phase, driving Fe atom exchange and structural reorganization without formation of new bulk crystalline Fe phases. Isotope tracing revealed substantially greater Fe atom exchange in the Fe-rich, well-crystalline ore (GOL, \u223c15%) than in the Al\u2013Si-rich, structurally heterogeneous ore (GOV, \u223c7%), demonstrating that natural mineralogical complexity strongly controls Fe(II)-catalyzed recrystallization. Fe(II) treatment generated a transient pulse of dissolved P followed by rapid resequestration into the solid phase, accompanied by a marked increase in operationally defined NaOH-extractable P demonstrating that recrystallization enhances P accessibility rather than removing P directly from the ore. NaOH-extractable P increased to \u223c75%\u201380% of the initial bulk P content in GOL but only \u223c35%\u201340% in GOV, whereas Al remained largely immobile (&amp;lt;10%) and Si exhibited minimal changes in both aqueous and NaOH-extractable pools, confirming that Fe(II)-catalyzed recrystallization selectively restructures Fe-bearing P-hosting domains while largely preserving aluminosilicate and silica-rich components. Collectively, these results establish Fe(II)-catalyzed recrystallization as a mineralogical conditioning step that redistributes Fe-associated phosphorus into more alkali-accessible pools prior to alkaline extraction. The efficiency of this process is governed by crystallinity, Al\u2013Si-substitution, and structural heterogeneity, providing new mechanistic insight into low-temperature mineralogical conditioning strategy for enhanced P extractability of natural goethitic iron ores.<\/jats:p>","DOI":"10.1021\/acs.est.6c06627","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T18:41:08Z","timestamp":1787424068000},"page":"24067-24080","source":"Crossref","is-referenced-by-count":1,"title":["Mineralogical Controls\non Phosphorus Accessibility\nDuring Fe(II)-Catalyzed Recrystallization of Natural Goethitic Iron\nOres"],"prefix":"10.1021","volume":"60","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8444-6610","authenticated-orcid":true,"given":"Niloofar","family":"Karimian","sequence":"first","affiliation":[{"name":"CSIRO Mineral Resources , Private Bag 10 , , ,","place":["Clayton South, VIC, Australia, 3169"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mark I.","family":"Pownceby","sequence":"additional","affiliation":[{"name":"CSIRO Mineral Resources , Private Bag 10 , , ,","place":["Clayton South, VIC, Australia, 3169"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9628-089X","authenticated-orcid":true,"given":"Edward D.","family":"Burton","sequence":"additional","affiliation":[{"name":"Southern Cross University , , , ,","place":["Lismore, NSW, Australia, 2480"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nathan A.S.","family":"Webster","sequence":"additional","affiliation":[{"name":"CSIRO Mineral Resources , Private Bag 10 , , ,","place":["Clayton South, VIC, Australia, 3169"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2687-7252","authenticated-orcid":true,"given":"Andrew J.","family":"Frierdich","sequence":"additional","affiliation":[{"name":"Monash University , , , ,","place":["Clayton, VIC, Australia, 3800"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrew R. C.","family":"Grigg","sequence":"additional","affiliation":[{"name":"Southern Cross University , , , ,","place":["Lismore, NSW, Australia, 2480"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruben","family":"Kretzschmar","sequence":"additional","affiliation":[{"name":"ETH Zurich , , Universita\u0308tstrasse 16, CHN , ,","place":["Zurich, Switzerland, 8092"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,21]]},"reference":[{"issue":"3","key":"2026090307140243700_cit1","doi-asserted-by":"publisher","first-page":"168","DOI":"10.1179\/aes.2000.109.3.168","article-title":"Phosphorus distribution in BIF-derived\niron ores of Hamersley Province, Western Australia","volume":"109","author":"Dukino","year":"2000","journal-title":"Trans. Inst. Min. Metall., Sect. B"},{"issue":"4","key":"2026090307140243700_cit2","doi-asserted-by":"publisher","first-page":"623","DOI":"10.1007\/s11663-007-9063-0","article-title":"Phosphorus\nPartition Between Liquid\nSteel and CaO-SiO2-FeOX-P2O5-MgO Slag Containing 15 to 25 PCT FeO","volume":"38","author":"Basu","year":"2007","journal-title":"Metall.\nMater. Trans. B"},{"key":"2026090307140243700_cit3","doi-asserted-by":"publisher","first-page":"106022","DOI":"10.1016\/j.mineng.2019.106022","article-title":"Characterisation\nof phosphorus and other impurities in goethite-rich iron ores \u2013\nPossible P incorporation mechanisms","volume":"143","author":"Pownceby","year":"2019","journal-title":"Miner.\nEng."},{"key":"2026090307140243700_cit4","doi-asserted-by":"publisher","first-page":"181114","DOI":"10.1016\/j.scitotenv.2025.181114","article-title":"Phosphorus\u2013goethite\ninteractions: A review of mechanisms, environmental implications,\nand industrial relevance","volume":"1012","author":"Karimian","year":"2026","journal-title":"Sci. Total Environ."},{"issue":"5","key":"2026090307140243700_cit5","doi-asserted-by":"publisher","first-page":"797","DOI":"10.2355\/isijinternational.52.797","article-title":"Phosphorus\nremoval from goethitic\niron ore with a low temperature heat treatment and a caustic leach","volume":"52","author":"Fisher-White","year":"2012","journal-title":"ISIJ Int."},{"issue":"3","key":"2026090307140243700_cit6","doi-asserted-by":"publisher","first-page":"325","DOI":"10.1111\/j.1751-3928.2008.00065.x","article-title":"Goethite Morphology\nand Composition in Banded Iron Formation, Orissa, India","volume":"58","author":"Mohapatra","year":"2008","journal-title":"Resour. Geol."},{"key":"2026090307140243700_cit7","first-page":"321","volume-title":"Discovery, Geologic Setting,\nand Controls on Iron Mineralization","author":"Knight","year":"2018"},{"issue":"8","key":"2026090307140243700_cit8","first-page":"325","article-title":"Studies\non Characterisation of Phosphorous in Haematite Iron Ore","volume":"52","author":"Singh","year":"2025","journal-title":"Ironmak. Steelmak. Process. Prod. Appl."},{"issue":"42","key":"2026090307140243700_cit9","doi-asserted-by":"publisher","first-page":"19016","DOI":"10.1021\/acs.est.4c03574","article-title":"Fe(II)-Catalyzed\nRecrystallization Drives Phosphorus and Aluminum Release from Goethite","volume":"58","author":"Karimian","year":"2024","journal-title":"Environ. Sci. Technol."},{"issue":"18","key":"2026090307140243700_cit10","doi-asserted-by":"publisher","first-page":"4782","DOI":"10.1021\/es049373g","article-title":"Spectroscopic evidence for Fe (II)\u2013 Fe (III)\nelectron transfer at the iron oxide\u2013 water interface","volume":"38","author":"Williams","year":"2004","journal-title":"Environ. Sci. Technol."},{"issue":"1","key":"2026090307140243700_cit11","doi-asserted-by":"publisher","first-page":"61","DOI":"10.1021\/es901882a","article-title":"Connecting Observations of Hematite (\u03b1-Fe2O3) Growth Catalyzed by Fe(II)","volume":"44","author":"Rosso","year":"2010","journal-title":"Environ. Sci. Technol."},{"issue":"16","key":"2026090307140243700_cit12","doi-asserted-by":"publisher","first-page":"3967","DOI":"10.1016\/j.gca.2005.03.016","article-title":"Fast transformation\nof iron oxyhydroxides by the catalytic action of aqueous Fe(II)","volume":"69","author":"Pedersen","year":"2005","journal-title":"Geochim. Cosmochim. Acta"},{"issue":"3","key":"2026090307140243700_cit13","doi-asserted-by":"publisher","first-page":"1519","DOI":"10.1021\/es203272z","article-title":"Controls on Fe(II)-Activated Trace\nElement Release\nfrom Goethite and Hematite","volume":"46","author":"Frierdich","year":"2012","journal-title":"Environ. Sci. Technol."},{"issue":"22","key":"2026090307140243700_cit14","doi-asserted-by":"publisher","first-page":"14518","DOI":"10.1039\/C5CP00921A","article-title":"Ab Initio Modeling\nof Fe(II) Adsorption and Interfacial\nElectron Transfer at Goethite (\u0391-FeOOH) Surfaces","volume":"17","author":"Alexandrov","year":"2015","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026090307140243700_cit15","doi-asserted-by":"publisher","first-page":"62","DOI":"10.1016\/j.gca.2015.05.032","article-title":"Effect of Phosphate and Sulfate on Ni Repartitioning\nDuring Fe(II)-Catalyzed Fe(III) Oxide Mineral Recrystallization","volume":"165","author":"Hinkle","year":"2015","journal-title":"Geochim. Cosmochim. Acta"},{"issue":"19","key":"2026090307140243700_cit16","doi-asserted-by":"publisher","first-page":"11302","DOI":"10.1021\/es503084u","article-title":"Fe (II)-catalyzed recrystallization\nof goethite\nrevisited","volume":"48","author":"Handler","year":"2014","journal-title":"Environ. Sci. Technol."},{"issue":"19","key":"2026090307140243700_cit17","doi-asserted-by":"publisher","first-page":"10614","DOI":"10.1021\/es302094a","article-title":"Fe Electron\nTransfer and Atom Exchange\nin Goethite: Influence of Al-Substitution and Anion Sorption","volume":"46","author":"Latta","year":"2012","journal-title":"Environ. Sci. Technol."},{"issue":"12","key":"2026090307140243700_cit18","doi-asserted-by":"publisher","first-page":"1271","DOI":"10.1021\/acsearthspacechem.8b00100","article-title":"Changes\nin Crystallinity and Tracer-Isotope Distribution of Goethite during\nFe(II)-Accelerated Recrystallization","volume":"2","author":"Southall","year":"2018","journal-title":"ACS Earth\nSpace Chem."},{"issue":"5","key":"2026090307140243700_cit19","doi-asserted-by":"publisher","first-page":"2751","DOI":"10.1021\/acs.est.7b05772","article-title":"The Role of Defects\nin Fe(II)\u2013Goethite Electron Transfer","volume":"52","author":"Notini","year":"2018","journal-title":"Environ. Sci. Technol."},{"issue":"5","key":"2026090307140243700_cit20","doi-asserted-by":"publisher","first-page":"450","DOI":"10.1007\/s12594-011-0049-9","article-title":"Microstructure-Compositional Variation\nin Iron Oxy-Hydroxide Minerals Formed With Manganese Mineralization,\nEastern Ghats Supergroup, Orissa","volume":"77","author":"Mohapatra","year":"2011","journal-title":"J. Geol. Soc.\nIndia"},{"issue":"6","key":"2026090307140243700_cit21","doi-asserted-by":"publisher","first-page":"673","DOI":"10.1007\/s11771-006-0003-y","article-title":"Removal of Phosphorus From Iron Ores\nby Chemical Leaching","volume":"13","author":"Yong-shi","year":"2006","journal-title":"J. Central South Univ.\nTechnol."},{"key":"2026090307140243700_cit22","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1016\/B978-0-444-42497-6.50006-0","article-title":"Genesis of iron ore\nin banded iron-formation by supergene and supergene-metamorphic\nprocesses\u2500a conceptual model","volume":"13","author":"Morris","year":"1985","journal-title":"Handb.\nStrata-Bound Stratiform Ore Deposits"},{"key":"2026090307140243700_cit23","first-page":"567","article-title":"Goethite classification,\ndistribution and properties with reference\nto Australian iron deposits","author":"Manuel","year":"2017","journal-title":"Proc. Iron Ore"},{"issue":"1\u20132","key":"2026090307140243700_cit24","first-page":"123","article-title":"Refinement of the\nhematite structure","volume":"51","author":"Blake","year":"1966","journal-title":"Am. Mineralogist: Journal\nof Earth and Planetary Materials"},{"issue":"null","key":"2026090307140243700_cit25","first-page":"25","volume":"19","author":"Hazemann","year":"1991","journal-title":"Phys. Chem. Miner."},{"issue":"null","key":"2026090307140243700_cit26","doi-asserted-by":"publisher","first-page":"6288","DOI":"10.1128\/AEM.00246-06","volume":"72","author":"Brodie","year":"2006","journal-title":"Appl. Environ.\nMicrobiol."},{"issue":"8","key":"2026090307140243700_cit27","doi-asserted-by":"publisher","first-page":"1334","DOI":"10.2355\/isijinternational.53.1334","article-title":"In situ\nX-ray diffraction investigation\nof the formation mechanisms of silico-ferrite of calcium and aluminium-I-type\n(SFCA-I-type) complex calcium ferrites","volume":"53","author":"Webster","year":"2013","journal-title":"ISIJ\nInt."},{"key":"2026090307140243700_cit28","doi-asserted-by":"publisher","first-page":"537","DOI":"10.1107\/S0909049505012719","article-title":"ATHENA, ARTEMIS, HEPHAESTUS:\nHEPHAESTUS: data analysis\nfor X-ray absorption spectroscopy using IFEFFIT","volume":"12","author":"Ravel","year":"2005","journal-title":"J. Synchrotron Radiat."},{"issue":"1","key":"2026090307140243700_cit29","doi-asserted-by":"publisher","first-page":"85","DOI":"10.1016\/0168-583X(91)95681-3","article-title":"Voigt-based methods\nfor arbitrary-shape static hyperfine\nparameter distributions in Mo\u0308ssbauer spectroscopy","volume":"58","author":"Rancourt","year":"1991","journal-title":"Nucl. Instrum. Methods Phys. Res. B: Beam Interact. Mater.\nAt."},{"issue":"10","key":"2026090307140243700_cit30","doi-asserted-by":"publisher","first-page":"1867","DOI":"10.1039\/D2EM00290F","article-title":"Ferrihydrite\ntransformations in flooded\npaddy soils: rates, pathways, and product spatial distributions","volume":"24","author":"Grigg","year":"2022","journal-title":"Environ. Sci.:Processes Impacts"},{"issue":"2","key":"2026090307140243700_cit31","doi-asserted-by":"publisher","first-page":"333","DOI":"10.1111\/j.1365-2389.1983.tb01039.x","article-title":"The Influence\nof Iron Oxides on Phosphate Adsorption by Soil","volume":"34","author":"Borggaard","year":"1983","journal-title":"J. Soil Sci."},{"issue":"4","key":"2026090307140243700_cit32","doi-asserted-by":"publisher","first-page":"729","DOI":"10.1111\/j.1365-2389.1992.tb00172.x","article-title":"Comparison\nof Different Models for Phosphate Sorption as a Function of the Iron\nand Aluminium Oxides of Soils","volume":"43","author":"Freese","year":"1992","journal-title":"J. Soil Sci."},{"issue":"1\u20133","key":"2026090307140243700_cit33","first-page":"11","article-title":"The Third\nInternational Workshop on Phosphorus in Sediments","volume":"253","author":"Boers","year":"1993","journal-title":"Hydrobiologia"},{"issue":"1","key":"2026090307140243700_cit34","doi-asserted-by":"publisher","first-page":"43","DOI":"10.1007\/BF00033500","article-title":"The Role\nof the Ironhydroxide-Phosphate-Sulphide System in the Phosphate Exchange\nBetween Sediments and Overlying Water","volume":"297","author":"Golterman","year":"1995","journal-title":"Hydrobiologia"},{"issue":"7","key":"2026090307140243700_cit35","doi-asserted-by":"publisher","first-page":"779","DOI":"10.1021\/ac60289a016","article-title":"Ferrozine---a\nnew spectrophotometric reagent for iron","volume":"42","author":"Stookey","year":"1970","journal-title":"Anal.\nChem."},{"issue":"12","key":"2026090307140243700_cit36","doi-asserted-by":"publisher","first-page":"6556","DOI":"10.1021\/es2046266","article-title":"Potential Function of Added Minerals\nas Nucleation\nSites and Effect of Humic Substances on Mineral Formation by the Nitrate-Reducing\nFe(II)-Oxidizer Acidovorax Sp. BoFeN1","volume":"46","author":"Dippon","year":"2012","journal-title":"Environ. Sci. Technol."},{"issue":"20","key":"2026090307140243700_cit37","doi-asserted-by":"publisher","first-page":"11681","DOI":"10.1021\/acs.est.7b02603","article-title":"Susceptibility of\nGoethite to Fe2+-Catalyzed Recrystallization Over Time","volume":"51","author":"Joshi","year":"2017","journal-title":"Environ. Sci. Technol."},{"issue":"2","key":"2026090307140243700_cit38","doi-asserted-by":"publisher","first-page":"471","DOI":"10.1021\/es0617035","article-title":"Fe(II) Sorption on Hematite: New Insights Based on\nSpectroscopic Measurements","volume":"41","author":"Larese-Casanova","year":"2007","journal-title":"Environ. Sci. Technol."},{"issue":"1","key":"2026090307140243700_cit39","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1111\/j.1365-2389.1992.tb00121.x","article-title":"Properties and Distribution\nof Iron Oxides and Their\nAssociation With Minor Elements in the Soils of South-western Australia","volume":"43","author":"Singh","year":"1992","journal-title":"J. Soil Sci."},{"issue":"1","key":"2026090307140243700_cit40","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1007\/s00269-017-0897-y","article-title":"Spectral and Morphological Characteristics\nof Synthetic Nanophase Iron (Oxyhydr)oxides","volume":"45","author":"Sklute","year":"2018","journal-title":"Phys. Chem. Miner."},{"issue":"14","key":"2026090307140243700_cit41","doi-asserted-by":"publisher","first-page":"3090","DOI":"10.1021\/es010295w","article-title":"Adsorption of Glyphosate on Goethite:\nMolecular Characterization of Surface Complexes","volume":"36","author":"Sheals","year":"2002","journal-title":"Environ. Sci. Technol."},{"issue":"9","key":"2026090307140243700_cit42","doi-asserted-by":"publisher","first-page":"367","DOI":"10.3390\/min8090367","article-title":"Cr Release From Cr-Substituted\nGoethite During Aqueous Fe(II)-Induced Recrystallization","volume":"8","author":"Hua","year":"2018","journal-title":"Minerals"},{"issue":"3","key":"2026090307140243700_cit43","doi-asserted-by":"publisher","first-page":"308","DOI":"10.1007\/s00027-003-0654-9","article-title":"Reductive\nDissolution of Goethite and the Subsequent Transformation of 4-Cyanonitrobenzene:\nRole of Ascorbic Acid and pH","volume":"65","author":"Smolen","year":"2003","journal-title":"Aquat. Sci."},{"issue":"13","key":"2026090307140243700_cit44","doi-asserted-by":"publisher","first-page":"3721","DOI":"10.1016\/j.gca.2010.03.037","article-title":"Biomineralization of lepidocrocite\nand goethite by nitrate-reducing Fe(II)-oxidizing bacteria: Effect\nof pH, bicarbonate, phosphate, and humic acids","volume":"74","author":"Larese-Casanova","year":"2010","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2026090307140243700_cit45","doi-asserted-by":"publisher","first-page":"328","DOI":"10.1016\/j.jssc.2012.05.022","article-title":"FeII Induced Mineralogical Transformations\nof Ferric Oxyhydroxides Into Magnetite of Variable Stoichiometry and\nMorphology","volume":"194","author":"Usman","year":"2012","journal-title":"J. Solid State Chem."},{"issue":"50","key":"2026090307140243700_cit46","doi-asserted-by":"publisher","first-page":"48130","DOI":"10.1021\/acsomega.3c07014","article-title":"Screening\nof Metal Oxides and Hydroxides for Arsenic Removal From Water Using\nMolecular Dynamics Simulations","volume":"8","author":"Hira","year":"2023","journal-title":"ACS Omega"},{"issue":"8","key":"2026090307140243700_cit47","doi-asserted-by":"publisher","first-page":"1956","DOI":"10.1111\/j.1462-2920.2007.01312.x","article-title":"Phylogenetic and Physiological Diversity of Dissimilatory\nFerric Iron Reducers in Sediments of the Polluted Scheldt Estuary,\nNorthwest Europe","volume":"9","author":"Lin","year":"2007","journal-title":"Environ. Microbiol."},{"key":"2026090307140243700_cit48","doi-asserted-by":"publisher","first-page":"115080","DOI":"10.1016\/j.geoderma.2021.115080","article-title":"Distribution\nand chemical species of phosphorus across density fractions in Andisols\nof contrasting mineralogy","volume":"395","author":"Takamoto","year":"2021","journal-title":"Geoderma"},{"issue":"3","key":"2026090307140243700_cit49","doi-asserted-by":"publisher","first-page":"636","DOI":"10.1107\/S0909049599000370","article-title":"XAFS study of adsorbed and mineral\nforms of phosphate","volume":"6","author":"Hesterberg","year":"1999","journal-title":"J. Synchrotron Radiat."},{"issue":"20","key":"2026090307140243700_cit50","doi-asserted-by":"publisher","first-page":"4253","DOI":"10.1021\/es025660d","article-title":"Solid-state\nspeciation of natural\nand alum-amended poultry litter using XANES spectroscopy","volume":"36","author":"Peak","year":"2002","journal-title":"Environ. Sci. Technol."},{"issue":"19","key":"2026090307140243700_cit51","doi-asserted-by":"publisher","first-page":"7485","DOI":"10.1021\/es0503130","article-title":"Phosphorus speciation in manure and manure-amended\nsoils using XANES spectroscopy","volume":"39","author":"Sato","year":"2005","journal-title":"Environ. Sci.\nTechnol."},{"issue":"6","key":"2026090307140243700_cit52","doi-asserted-by":"publisher","first-page":"1736","DOI":"10.1107\/S1600577518013334","article-title":"Phosphorus K-Edge XANES\nSpectroscopy Has Probably Often\nUnderestimated Iron Oxyhydroxide-Bound P in Soils","volume":"25","author":"Prietzel","year":"2018","journal-title":"J. Synchrotron Radiat."},{"issue":"27","key":"2026090307140243700_cit53","doi-asserted-by":"publisher","first-page":"6297","DOI":"10.1021\/ja964352a","article-title":"A Multiplet Analysis of Fe K-Edge\n1s f 3d Pre-Edge Features of Iron Complexes","volume":"119","author":"Westre","year":"1997","journal-title":"J.\nAm. Chem. Soc."},{"issue":"10","key":"2026090307140243700_cit54","doi-asserted-by":"publisher","first-page":"104207","DOI":"10.1088\/0953-8984\/21\/10\/104207","article-title":"The 1s X-Ray Absorption Pre-Edge\nStructures in Transition Metal Oxides","volume":"21","author":"Frank","year":"2009","journal-title":"J. Phys.:\nCondens. Matter"},{"issue":"10","key":"2026090307140243700_cit55","doi-asserted-by":"publisher","first-page":"1908","DOI":"10.1021\/jp111520r","article-title":"Investigation\nof the Fe K-edge XANES\nspectra from Fe(1-x)Ga(x)SbO4: local versus nonlocal excitations","volume":"115","author":"Sigrist","year":"2011","journal-title":"J. Phys. Chem. A"},{"issue":"24","key":"2026090307140243700_cit56","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1103\/PhysRevB.94.245115","article-title":"Calculation of optical\nand K pre-edge absorption spectra for ferrous iron of distorted sites\nin oxide crystals","volume":"94","author":"Vercamer","year":"2016","journal-title":"Phys. Rev. B"},{"issue":"17","key":"2026090307140243700_cit57","doi-asserted-by":"publisher","first-page":"6698","DOI":"10.1021\/es0505346","article-title":"Coupled Fe(II)\u2013Fe(III)\nElectron and Atom Exchange as a Mechanism for Fe Isotope Fractionation\nDuring Dissimilatory Iron Oxide Reduction","volume":"39","author":"Crosby","year":"2005","journal-title":"Environ.\nSci. 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