{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:44:52Z","timestamp":1792784692081,"version":"4.5.0"},"reference-count":48,"publisher":"American Chemical Society (ACS)","issue":"39","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"name":"National Natural Science Foundation of China (NSFC)","award":["52221004"],"award-info":[{"award-number":["52221004"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["52225002"],"award-info":[{"award-number":["52225002"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["U24A20190"],"award-info":[{"award-number":["U24A20190"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Catalysis under nanoscale confinement is widely pursued, but practical systems remain limited by a persistent contradiction: maximizing confinement-enhanced reactivity usually increases the residence time and accelerates pore failure. Here we present a ceramic nanofiltration platform that resolves this trade-off by coupling subnanometer confinement with transient, flow-through ion dehydration. The membrane is constructed by atomic layer deposition on a hierarchical \u03b1-Al2O3\/\u03b3-Al2O3 scaffold, yielding a robust, ultrathin Al2O3 active layer with tunable nanochannels and minimized transport distance to the reaction interface. During transmembrane permeation, Fe2+ ions are partially dehydrated, exposing vacant coordination sites that immediately react with H2O2 upon emergence to degrade organic micropollutants (e.g., tetracycline). This synergistic process yields a kinetic enhancement ratio of 90.5% for the dehydration group relative to the corresponding rehydration group. The kinetic enhancement ratio obtained with the commercial polyamide nanofiltration membrane NF270 under the same comparison framework was substantially lower. Beyond activity, the inorganic architecture sustains 30 d of continuous backwashing with &amp;lt;3% fluctuation in pure-water permeability and exhibits a kinetic enhancement ratio of 89.6% after backwashing. Importantly, the reverse-mode configuration reduces reliance on prolonged reactant residence within nanopores, thereby lowering the risk of pore blockage. These results establish a membrane-enabled strategy for capturing nonequilibrium ionic states and thereby translate nanoconfinement chemistry into an operationally durable format, with broad implications for water treatment, electrochemical conversion, and selective resource recovery.<\/jats:p>","DOI":"10.1021\/acs.est.6c07607","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T17:01:34Z","timestamp":1790096494000},"page":"28120-28130","source":"Crossref","is-referenced-by-count":0,"title":["Controlled Ion Dehydration-Driven\nCatalysis Enabled\nby Reverse-Mode Nanofiltration"],"prefix":"10.1021","volume":"60","author":[{"given":"Wenkai","family":"An","sequence":"first","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7038-2604","authenticated-orcid":true,"given":"Lie","family":"Liu","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingxin","family":"Liu","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Congyu","family":"Hou","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6117-095X","authenticated-orcid":true,"given":"Gong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]},{"name":"Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences , , ,","place":["Beijing, China, 100085"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0855-0202","authenticated-orcid":true,"given":"Huijuan","family":"Liu","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5444-895X","authenticated-orcid":true,"given":"Qinghua","family":"Ji","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]},{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7578-5629","authenticated-orcid":true,"given":"Jiuhui","family":"Qu","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]},{"name":"Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences , , ,","place":["Beijing, China, 100085"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,22]]},"reference":[{"issue":"8038","key":"2026100609065324500_cit1","doi-asserted-by":"publisher","first-page":"353","DOI":"10.1038\/s41586-024-08140-2","article-title":"Selective ion transport through hydrated\nmicropores in polymer membranes","volume":"635","author":"Wang","year":"2024","journal-title":"Nature"},{"issue":"4","key":"2026100609065324500_cit2","doi-asserted-by":"publisher","first-page":"256","DOI":"10.1038\/s41565-020-0652-2","article-title":"Chemical reactivity under nanoconfinement","volume":"15","author":"Grommet","year":"2020","journal-title":"Nat. Nanotechnol."},{"issue":"10","key":"2026100609065324500_cit3","doi-asserted-by":"publisher","first-page":"6668","DOI":"10.1021\/acs.chemrev.2c00728","article-title":"Theory\nand Simulations of Ionic Liquids in Nanoconfinement","volume":"123","author":"Kondrat","year":"2023","journal-title":"Chem. Rev."},{"issue":"1","key":"2026100609065324500_cit4","doi-asserted-by":"publisher","first-page":"4075","DOI":"10.1038\/s41467-023-39533-y","article-title":"Nanoconfinement enabled\nnon-covalently decorated MXene membranes\nfor ion-sieving","volume":"14","author":"Kang","year":"2023","journal-title":"Nat. Commun."},{"issue":"1","key":"2026100609065324500_cit5","doi-asserted-by":"publisher","first-page":"7359","DOI":"10.1038\/s41467-025-62656-3","article-title":"Nanoconfinement promotes CO2 electroreduction to methanol\non a molecular catalyst","volume":"16","author":"Shi","year":"2025","journal-title":"Nat. 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Membr.\nSci."},{"issue":"7","key":"2026100609065324500_cit27","doi-asserted-by":"publisher","first-page":"2670","DOI":"10.1002\/aic.16097","article-title":"Atomic layer deposition\nfabricating of ceramic nanofiltration membranes for efficient separation\nof dyes from water","volume":"64","author":"Chen","year":"2018","journal-title":"AIChE J."},{"issue":"6067","key":"2026100609065324500_cit28","doi-asserted-by":"publisher","first-page":"444","DOI":"10.1126\/science.1212101","article-title":"Ultrafast Viscous Permeation of Organic\nSolvents Through\nDiamond-Like Carbon Nanosheets","volume":"335","author":"Karan","year":"2012","journal-title":"Science"},{"issue":"9","key":"2026100609065324500_cit29","doi-asserted-by":"publisher","first-page":"1643","DOI":"10.1016\/S0925-9635(02)00109-7","article-title":"Effect of film thickness\non the stress and adhesion of diamond-like carbon coatings","volume":"11","author":"Sheeja","year":"2002","journal-title":"Diamond Relat. Mater."},{"key":"2026100609065324500_cit30","doi-asserted-by":"publisher","first-page":"106308","DOI":"10.1016\/j.jwpe.2024.106308","article-title":"Advancements\nand challenges in ceramic membranes incorporating\ntwo-dimensional nanomaterials for semiconductor wastewater treatment:\nA critical review","volume":"68","author":"Kim","year":"2024","journal-title":"J. Water Proc. Eng."},{"issue":"6735","key":"2026100609065324500_cit31","doi-asserted-by":"publisher","first-page":"776","DOI":"10.1126\/science.ado7489","article-title":"Engineering grain boundaries\nin monolayer molybdenum disulfide for efficient water-ion separation","volume":"387","author":"Shen","year":"2025","journal-title":"Science"},{"issue":"1","key":"2026100609065324500_cit32","doi-asserted-by":"publisher","first-page":"8616","DOI":"10.1038\/ncomms9616","article-title":"Water desalination\nwith a single-layer\nMoS2 nanopore","volume":"6","author":"Heiranian","year":"2015","journal-title":"Nat. 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Sci."},{"issue":"4","key":"2026100609065324500_cit36","doi-asserted-by":"publisher","first-page":"639","DOI":"10.1021\/cm0304546","article-title":"Low-Temperature\nAl2O3 Atomic Layer Deposition","volume":"16","author":"Groner","year":"2004","journal-title":"Chem. Mater."},{"issue":"45","key":"2026100609065324500_cit37","doi-asserted-by":"publisher","first-page":"41033","DOI":"10.1021\/acsomega.2c04402","article-title":"Atomic-Layer-Deposited\nAluminum Oxide Thin Films Probedwith X-ray Scattering and Compared\nto Molecular Dynamics andDensity Functional Theory Models","volume":"7","author":"Pugliese","year":"2022","journal-title":"ACS Omega"},{"issue":"8","key":"2026100609065324500_cit38","doi-asserted-by":"publisher","first-page":"725","DOI":"10.1038\/s44221-023-00113-5","article-title":"Shielding\neffect enables fast ion transfer through nanoporous membrane for highly\nenergy-efficient electrodialysis","volume":"1","author":"Lin","year":"2023","journal-title":"Nat. Water"},{"issue":"9","key":"2026100609065324500_cit39","doi-asserted-by":"publisher","first-page":"1381","DOI":"10.1021\/j150579a011","article-title":"Phenomenological\nTheory of Ion Solvation. Effective Radii of Hydrated Ions","volume":"63","author":"Nightingale","year":"1959","journal-title":"J. Phys. Chem."},{"issue":"35","key":"2026100609065324500_cit40","doi-asserted-by":"publisher","first-page":"14242","DOI":"10.1021\/jacs.1c05765","article-title":"In Situ Characterization of Dehydration\nduring Ion Transport in Polymeric\nNanochannels","volume":"143","author":"Lu","year":"2021","journal-title":"J. Am. Chem. Soc."},{"issue":"35","key":"2026100609065324500_cit41","doi-asserted-by":"publisher","first-page":"15874","DOI":"10.1021\/acs.est.4c07510","article-title":"The Hidden Role of the Dielectric\nEffect in Nanofiltration: A Novel Perspective to Unravel New Ion Separation\nMechanisms","volume":"58","author":"Zhai","year":"2024","journal-title":"Environ. Sci. Technol."},{"key":"2026100609065324500_cit42","doi-asserted-by":"publisher","first-page":"124342","DOI":"10.1016\/j.memsci.2025.124342","article-title":"Deciphering the overlooked\nrole of dielectric exclusion in the ion\nselectivity of nanofiltration membranes","volume":"733","author":"Xu","year":"2025","journal-title":"J.\nMembr. Sci."},{"key":"2026100609065324500_cit43","doi-asserted-by":"publisher","first-page":"118117","DOI":"10.1016\/j.memsci.2020.118117","article-title":"Experimental and theoretical characterization\nof commercial nanofiltration membranes for the treatment of ion exchange\nspent regenerant","volume":"606","author":"Micari","year":"2020","journal-title":"J. Membr. Sci."},{"key":"2026100609065324500_cit44","doi-asserted-by":"publisher","first-page":"461","DOI":"10.1016\/j.mssp.2014.07.016","article-title":"Synthesis\nand characterization of\ndiamond-like carbon film on silicon by electrodeposition from solution\nof ethanol and methanol","volume":"27","author":"Ismail","year":"2014","journal-title":"Mater. Sci. Semicond.\nProcess."},{"issue":"2","key":"2026100609065324500_cit45","doi-asserted-by":"publisher","first-page":"227","DOI":"10.1007\/PL00021125","article-title":"Electrodeposition of diamond-like\namorphous carbon films on aluminum from acetonitrile","volume":"71","author":"Cai","year":"2000","journal-title":"Appl. Phys. A: mater. Sci. Process."},{"issue":"9","key":"2026100609065324500_cit46","doi-asserted-by":"publisher","first-page":"3876","DOI":"10.1039\/C2CS35378D","article-title":"Hierarchical\nporous materials: catalytic\napplications","volume":"42","author":"Parlett","year":"2013","journal-title":"Chem. Soc. Rev."},{"issue":"22","key":"2026100609065324500_cit47","doi-asserted-by":"publisher","first-page":"14056","DOI":"10.1021\/acs.chemrev.6b00374","article-title":"Hollow Nano-\nand Microstructures\nas Catalysts","volume":"116","author":"Prieto","year":"2016","journal-title":"Chem. Rev."},{"issue":"12","key":"2026100609065324500_cit48","doi-asserted-by":"publisher","first-page":"915","DOI":"10.1038\/s41570-024-00658-3","article-title":"Understanding the chemistry of mesostructured\nporous nanoreactors","volume":"8","author":"Ma","year":"2024","journal-title":"Nat. Rev. Chem."}],"container-title":["Environmental Science &amp;\nTechnology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.est.6c07607","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/39\/28120\/68605945\/acs.est.6c07607.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/39\/28120\/68605945\/acs.est.6c07607.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T13:49:33Z","timestamp":1791294573000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/esthag\/article\/60\/39\/28120\/5435694\/Controlled-Ion-Dehydration-Driven-Catalysis"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,22]]},"references-count":48,"journal-issue":{"issue":"39","published-online":{"date-parts":[[2026,9,22]]},"published-print":{"date-parts":[[2026,10,6]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.est.6c07607","relation":{},"ISSN":["0013-936X","1520-5851"],"issn-type":[{"value":"0013-936X","type":"print"},{"value":"1520-5851","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,22]]}}}