{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T17:26:54Z","timestamp":1787074014302,"version":"build-2736575974"},"reference-count":60,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T00:00:00Z","timestamp":1785628800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T00:00:00Z","timestamp":1785628800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T00:00:00Z","timestamp":1785628800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100003399","name":"Science and Technology Commission of Shanghai Municipality","doi-asserted-by":"publisher","award":["24142201500"],"award-info":[{"award-number":["24142201500"]}],"id":[{"id":"10.13039\/501100003399","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22373066"],"award-info":[{"award-number":["22373066"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52376119"],"award-info":[{"award-number":["52376119"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Lipid oxidation driven by intermolecular interactions plays a pivotal role in human aging and indoor environmental quality, yet the underlying interaction mechanisms remain largely elusive. Here, we uncover a coupled autoxidation network in the heterogeneous co-ozonolysis of model skin lipids (cholesterol and fatty acids), using online atmospheric pressure photoionization coupled with an ultrahigh-resolution mass spectrometer. Individual cholesterol exhibited extremely low heterogeneous reactivity (determined as effective uptake coefficient, \u03b3eff,\u00a0Chol = 2.94 \u00d7 10\u20136). However, upon co-ozonolysis with fatty acids (oleic or linoleic acid), its reactivity was enhanced by 31-fold (\u03b3eff,\u00a0Chol = 9.11 \u00d7 10\u20135 when mixed with linoleic acid), and elevated relative humidity further amplified this effect by an additional 3-fold. The identification of \u03b1-alkoxyalkyl hydroperoxides, \u03b1-acyloxyalkyl hydroperoxides, hydroxyalkyl hydroperoxides, and secondary ozonides provides direct molecular evidence that Criegee intermediates (CIs) drive the co-ozonolysis interaction network. Furthermore, the detection of highly oxygenated molecules reveals that \u2022OH reactions are triggered by CIs and hydroperoxide decomposition, establishing a free-radical chain propagation pathway that further accelerates autoxidation. We propose a novel interactive lipid autoxidation mechanism: initiated by lipids\u2019 co-ozonolysis, propagated via CI-driven interactions, and amplified by \u2022OH-mediated radical chemistry. These findings unveil a coupling mechanism of CIs and \u2022OH pathways in governing the heterogeneous reactivity of naturally coexisting lipids, providing fundamental insights into their impacts on biological aging and environmental evolution.<\/jats:p>","DOI":"10.1021\/acs.est.6c08123","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T14:33:08Z","timestamp":1785853988000},"page":"22813-22822","source":"Crossref","is-referenced-by-count":0,"title":["Evidence for Coupled\nAutoxidation of Coexisting Lipids\nin Aerosols Driven by Criegee Intermediates and OH Radicals"],"prefix":"10.1021","volume":"60","author":[{"given":"Jigang","family":"Gao","sequence":"first","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, P.R. China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9334-7991","authenticated-orcid":true,"given":"Peiqi","family":"Liu","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, P.R. China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yukai","family":"Huang","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, P.R. China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yulong","family":"Hu","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, P.R. China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5576-1400","authenticated-orcid":true,"given":"Zhongyue","family":"Zhou","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, P.R. China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1102-9752","authenticated-orcid":true,"given":"Wenhao","family":"Yuan","sequence":"additional","affiliation":[{"name":"East China University of Science and Technology , , ,","place":["Shanghai, P.R. China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3902-7430","authenticated-orcid":true,"given":"Meirong","family":"Zeng","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, P.R. China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,2]]},"reference":[{"issue":"9","key":"2026081810411046100_cit1","doi-asserted-by":"publisher","first-page":"4486","DOI":"10.1073\/pnas.1920765117","article-title":"Evidence that Criegee intermediates\ndrive autoxidation in unsaturated lipids","volume":"117","author":"Zeng","year":"2020","journal-title":"Proc.\nNatl. Acad. Sci. U. S. A."},{"issue":"10","key":"2026081810411046100_cit2","doi-asserted-by":"publisher","first-page":"5944","DOI":"10.1021\/cr200084z","article-title":"Free Radical\nLipid Peroxidation: Mechanisms and Analysis","volume":"111","author":"Yin","year":"2011","journal-title":"Chem. Rev."},{"issue":"23","key":"2026081810411046100_cit3","doi-asserted-by":"publisher","first-page":"12757","DOI":"10.1021\/acs.chemrev.0c00761","article-title":"Connecting\nthe \u201cDots\u201d: From Free Radical Lipid Autoxidation to\nCell Pathology and Disease","volume":"120","author":"Foret","year":"2020","journal-title":"Chem. Rev."},{"issue":"5","key":"2026081810411046100_cit4","doi-asserted-by":"publisher","first-page":"1237","DOI":"10.5194\/acp-7-1237-2007","article-title":"The oleic acid-ozone heterogeneous reaction system:\nProducts, kinetics, secondary chemistry, and atmospheric implications\nof a model system \u2013 a review","volume":"7","author":"Zahardis","year":"2007","journal-title":"Atmos.\nChem. Phys."},{"issue":"32","key":"2026081810411046100_cit5","doi-asserted-by":"publisher","first-page":"6686","DOI":"10.1021\/jp049759d","article-title":"Products\nand Mechanisms of Ozone Reactions with Oleic Acid for Aerosol Particles\nHaving Core\u2013Shell Morphologies","volume":"108","author":"Katrib","year":"2004","journal-title":"J. Phys.\nChem. A"},{"issue":"35","key":"2026081810411046100_cit6","doi-asserted-by":"publisher","first-page":"8085","DOI":"10.1021\/jp020527t","article-title":"Reactive\nUptake of Ozone by Oleic Acid Aerosol Particles: Application of Single-Particle\nMass Spectrometry to Heterogeneous Reaction Kinetics","volume":"106","author":"Smith","year":"2002","journal-title":"J. Phys. Chem. A"},{"issue":"32","key":"2026081810411046100_cit7","doi-asserted-by":"publisher","first-page":"6176","DOI":"10.1021\/jp0346007","article-title":"Reaction of Criegee\nIntermediates with Water VaporAn\nAdditional Source of OH Radicals in Alkene Ozonolysis?","volume":"107","author":"Hasson","year":"2003","journal-title":"J. Phys. Chem. A"},{"issue":"11","key":"2026081810411046100_cit8","doi-asserted-by":"publisher","first-page":"745","DOI":"10.1002\/anie.197507451","article-title":"Mechanism\nof ozonolysis","volume":"14","author":"Criegee","year":"1975","journal-title":"Angew. Chem., Int. Ed."},{"issue":"44","key":"2026081810411046100_cit9","doi-asserted-by":"publisher","first-page":"27086","DOI":"10.1039\/D2CP03289A","article-title":"Electrodynamic balance\u2013mass\nspectrometry reveals impact of oxidant concentration on product composition\nin the ozonolysis of oleic acid","volume":"24","author":"Mu\u0308ller","year":"2022","journal-title":"Phys. Chem.\nChem. Phys."},{"issue":"5","key":"2026081810411046100_cit10","doi-asserted-by":"publisher","first-page":"2089","DOI":"10.1002\/anie.201914637","article-title":"On the\nProducts of Cholesterol Autoxidation in Phospholipid Bilayers and\nthe Formation of Secosterols Derived Therefrom","volume":"59","author":"Schaefer","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"issue":"28","key":"2026081810411046100_cit11","doi-asserted-by":"publisher","first-page":"6242","DOI":"10.1021\/jp050606f","article-title":"Cholesterol\nOzonolysis: Kinetics, Mechanism, and Oligomer Products","volume":"109","author":"Dreyfus","year":"2005","journal-title":"J. Phys. Chem. A"},{"issue":"10","key":"2026081810411046100_cit12","doi-asserted-by":"publisher","first-page":"2586","DOI":"10.1016\/j.cell.2025.02.034","article-title":"Cell\nmembranes sustain phospholipid imbalance\nvia cholesterol asymmetry","volume":"188","author":"Doktorova","year":"2025","journal-title":"Cell"},{"issue":"12","key":"2026081810411046100_cit13","doi-asserted-by":"publisher","first-page":"1858","DOI":"10.1038\/s41565-024-01785-0","article-title":"Direct\ncytosolic delivery of siRNA via cell membrane fusion using cholesterol-enriched\nexosomes","volume":"19","author":"Zhuo","year":"2024","journal-title":"Nat. Nanotechnol."},{"issue":"3","key":"2026081810411046100_cit14","doi-asserted-by":"publisher","first-page":"295","DOI":"10.1210\/edrv-9-3-295","article-title":"Molecular\nBiology of Steroid Hormone Synthesis","volume":"9","author":"Miller","year":"1988","journal-title":"Endocr.\nRev."},{"issue":"7","key":"2026081810411046100_cit15","doi-asserted-by":"publisher","first-page":"479","DOI":"10.3390\/membranes11070479","article-title":"Polyunsaturated Fatty\nAcids Mediated Regulation of Membrane Biochemistry and Tumor Cell\nMembrane Integrity","volume":"11","author":"Mukerjee","year":"2021","journal-title":"Membranes"},{"issue":"6","key":"2026081810411046100_cit16","doi-asserted-by":"publisher","first-page":"451","DOI":"10.1016\/j.phrs.2008.05.002","article-title":"Polyunsaturated\nfatty acids as antioxidants","volume":"57","author":"Richard","year":"2008","journal-title":"Pharmacol. Res."},{"issue":"1","key":"2026081810411046100_cit17","doi-asserted-by":"publisher","first-page":"24","DOI":"10.1016\/j.bbamem.2008.10.011","article-title":"Polyunsaturated fatty acid\u2013cholesterol interactions:\nDomain formation in membranes","volume":"1788","author":"Wassall","year":"2009","journal-title":"Biochim. Biophys.\nActa"},{"issue":"4","key":"2026081810411046100_cit18","doi-asserted-by":"publisher","first-page":"529","DOI":"10.1093\/jn\/119.4.529","article-title":"Monounsaturated\nFatty Acids and Cholesterol Metabolism: Implications for Dietary Recommendations","volume":"119","author":"Grundy","year":"1989","journal-title":"J. Nutr."},{"issue":"3","key":"2026081810411046100_cit19","doi-asserted-by":"publisher","first-page":"647","DOI":"10.1093\/advances\/nmab013","article-title":"Perspective:\nThe Saturated Fat\u2013Unsaturated Oil Dilemma: Relations of Dietary\nFatty Acids and Serum Cholesterol, Atherosclerosis, Inflammation,\nCancer, and All-Cause Mortality","volume":"12","author":"Lawrence","year":"2021","journal-title":"Adv. Nutr."},{"issue":"28","key":"2026081810411046100_cit20","doi-asserted-by":"publisher","first-page":"6285","DOI":"10.1021\/jp071812l","article-title":"Heterogeneous\nReactions of Linoleic Acid and Linolenic\nAcid Particles with Ozone: Reaction Pathways and Changes in Particle\nMass, Hygroscopicity, and Morphology","volume":"111","author":"Lee","year":"2007","journal-title":"J. Phys.\nChem. A"},{"issue":"5","key":"2026081810411046100_cit21","doi-asserted-by":"publisher","first-page":"779","DOI":"10.1021\/acsearthspacechem.9b00002","article-title":"Effect of Ozone Concentration and Relative Humidity\non the Heterogeneous Oxidation of Linoleic Acid Particles by Ozone:\nAn Insight into the Interchangeability of Ozone Concentration and\nTime","volume":"3","author":"Chu","year":"2019","journal-title":"ACS Earth Space Chem."},{"issue":"49","key":"2026081810411046100_cit22","doi-asserted-by":"publisher","first-page":"19576","DOI":"10.1021\/acs.analchem.4c04404","article-title":"Investigating\nthe Kinetics of Heterogeneous Lipid Ozonolysis by an\nOnline Photoionization High-Resolution Mass Spectrometry Technique","volume":"96","author":"Liu","year":"2024","journal-title":"Anal. Chem."},{"issue":"24","key":"2026081810411046100_cit23","doi-asserted-by":"publisher","first-page":"3662","DOI":"10.1016\/j.atmosenv.2009.04.047","article-title":"Product study of oleic\nacid ozonolysis as function of humidity","volume":"43","author":"Vesna","year":"2009","journal-title":"Atmos.\nEnviron."},{"issue":"1","key":"2026081810411046100_cit24","doi-asserted-by":"publisher","first-page":"85","DOI":"10.1039\/D2EA00127F","article-title":"Oxidation pathways of linoleic acid\nrevisited with electrodynamic balance\u2013mass spectrometry","volume":"3","author":"Mu\u0308ller","year":"2023","journal-title":"Environ. Sci.: Atmos."},{"issue":"1","key":"2026081810411046100_cit25","doi-asserted-by":"publisher","first-page":"84","DOI":"10.1039\/b310149e","article-title":"Heterogeneous\nreaction of ozone with liquid unsaturated\nfatty acids: Detailed kinetics and gas-phase product studies","volume":"6","author":"Thornberry","year":"2004","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"7","key":"2026081810411046100_cit26","doi-asserted-by":"publisher","first-page":"1972","DOI":"10.1021\/ja00345a052","article-title":"Ozonization of cholesterol","volume":"105","author":"Gumulka","year":"1983","journal-title":"J.\nAm. Chem. Soc."},{"issue":"22","key":"2026081810411046100_cit27","doi-asserted-by":"publisher","first-page":"6932","DOI":"10.1021\/jacs.6b03344","article-title":"Cholesterol Autoxidation\nRevisited: Debunking the Dogma\nAssociated with the Most Vilified of Lipids","volume":"138","author":"Zielinski","year":"2016","journal-title":"J. Am. Chem. Soc."},{"issue":"13","key":"2026081810411046100_cit28","doi-asserted-by":"publisher","first-page":"3255","DOI":"10.1073\/pnas.1722323115","article-title":"Cholesterol\nprovides nonsacrificial\nprotection of membrane lipids from chemical damage at air\u2013water\ninterface","volume":"115","author":"Zhang","year":"2018","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"issue":"4","key":"2026081810411046100_cit29","doi-asserted-by":"publisher","first-page":"1345","DOI":"10.1021\/bi0516778","article-title":"A Product\nof Ozonolysis of Cholesterol Alters the Biophysical Properties of\nPhosphatidylethanolamine Membranes","volume":"45","author":"Wachtel","year":"2006","journal-title":"Biochemistry"},{"issue":"8","key":"2026081810411046100_cit30","doi-asserted-by":"publisher","first-page":"1428","DOI":"10.1016\/j.bbamem.2019.06.002","article-title":"Interactions\nof cholesterol and 7-ketocholesterol with unsaturated fatty acids\nof different unsaturation degree \u2013 The monolayer study","volume":"1861","author":"Fidalgo Rodri\u0301guez","year":"2019","journal-title":"Biochim. Biophys. Acta"},{"key":"2026081810411046100_cit31","doi-asserted-by":"publisher","first-page":"104968","DOI":"10.1016\/j.chemphyslip.2020.104968","article-title":"How unsaturated\nfatty acids and plant stanols affect sterols plasma level and cellular\nmembranes? Review on model studies involving the Langmuir monolayer\ntechnique","volume":"232","author":"Fidalgo Rodri\u0301guez","year":"2020","journal-title":"Chem. Phys. Lipids"},{"issue":"24","key":"2026081810411046100_cit32","doi-asserted-by":"publisher","first-page":"15561","DOI":"10.5194\/acp-16-15561-2016","article-title":"Size-dependent\nchemical ageing of oleic acid aerosol under dry and humidified conditions","volume":"16","author":"Al-Kindi","year":"2016","journal-title":"Atmos. Chem. Phys."},{"issue":"16","key":"2026081810411046100_cit33","doi-asserted-by":"publisher","first-page":"6580","DOI":"10.1021\/acs.jpclett.0c01823","article-title":"Efficient Coupling\nof Reaction Pathways of Criegee\nIntermediates and Free Radicals in the Heterogeneous Ozonolysis of\nAlkenes","volume":"11","author":"Zeng","year":"2020","journal-title":"J. Phys. Chem. Lett."},{"issue":"18","key":"2026081810411046100_cit34","doi-asserted-by":"publisher","first-page":"9178","DOI":"10.1021\/acs.est.4c13472","article-title":"Coupling of Lipid Peroxidation and Criegee Intermediate\nMediated Autoxidation in the Heterogeneous Oxidation of Linoleic Acid\nAerosols","volume":"59","author":"Zeng","year":"2025","journal-title":"Environ. Sci. Technol."},{"issue":"1","key":"2026081810411046100_cit35","doi-asserted-by":"publisher","first-page":"147","DOI":"10.1111\/j.1751-1097.1979.tb07127.x","article-title":"The oxidation of cholesterol by hydroxyl radical","volume":"30","author":"Ansari","year":"1979","journal-title":"Photochem. Photobiol."},{"issue":"6","key":"2026081810411046100_cit36","doi-asserted-by":"publisher","first-page":"528","DOI":"10.1021\/acs.estlett.3c00290","article-title":"Ozone-Initiated\nYield of Reactive\nOxygen Species in a Model Indoor Surface Film","volume":"10","author":"Morrison","year":"2023","journal-title":"Environ. Sci. Technol. Lett."},{"issue":"4","key":"2026081810411046100_cit37","doi-asserted-by":"publisher","first-page":"277","DOI":"10.1002\/kin.20907","article-title":"Infrared\nSpectroscopic Evidence for\na Heterogeneous Reaction between Ozone and Sodium Oleate at the Gas\u2013Aerosol\nInterface: Effect of Relative Humidity","volume":"47","author":"Na\u0301jera","year":"2015","journal-title":"Int.\nJ. Chem. Kinet."},{"key":"2026081810411046100_cit38","doi-asserted-by":"publisher","DOI":"10.1029\/2007JD009754","article-title":"Heterogeneous reactions of methacrolein and methyl\nvinyl ketone: Kinetics and mechanisms of uptake and ozonolysis on\nsilicon dioxide","volume":"113","author":"Chen","year":"2008","journal-title":"J. Geophys. Res.: Atmos."},{"issue":"4","key":"2026081810411046100_cit39","doi-asserted-by":"publisher","first-page":"2087","DOI":"10.1021\/ac302560c","article-title":"Real Time in Situ\nChemical Characterization of Submicrometer Organic Particles Using\nDirect Analysis in Real Time-Mass Spectrometry","volume":"85","author":"Nah","year":"2013","journal-title":"Anal. Chem."},{"issue":"1","key":"2026081810411046100_cit40","doi-asserted-by":"publisher","first-page":"603","DOI":"10.1021\/acs.analchem.9b05200","article-title":"In Situ Atmospheric\nPressure Photoionization Mass Spectrometric Monitoring of Initial\nPyrolysis Products of Biomass in Real Time","volume":"92","author":"Chen","year":"2020","journal-title":"Anal. Chem."},{"issue":"38","key":"2026081810411046100_cit41","doi-asserted-by":"publisher","first-page":"12987","DOI":"10.1021\/acs.analchem.1c02710","article-title":"In Situ Reactor-Integrated\nElectrospray Ionization Mass Spectrometry for Heterogeneous Catalytic\nReactions and Its Application in the Process Analysis of High-Pressure\nLiquid-Phase Lignin Depolymerization","volume":"93","author":"Cui","year":"2021","journal-title":"Anal.\nChem."},{"key":"2026081810411046100_cit42","doi-asserted-by":"publisher","first-page":"100069","DOI":"10.1016\/j.jaecs.2022.100069","article-title":"Online investigation\nof lignin depolymerization\nvia reactor-integrated electrospray ionization high-resolution mass\nspectrometry","volume":"10","author":"Cui","year":"2022","journal-title":"Appl. Energy Combust. Sci."},{"issue":"9","key":"2026081810411046100_cit43","doi-asserted-by":"publisher","first-page":"3209","DOI":"10.5194\/acp-9-3209-2009","article-title":"The heterogeneous\nreaction of hydroxyl radicals with sub-micron squalane particles:\nA model system for understanding the oxidative aging of ambient aerosols","volume":"9","author":"Smith","year":"2009","journal-title":"Atmos. Chem. Phys."},{"issue":"27","key":"2026081810411046100_cit44","doi-asserted-by":"publisher","first-page":"6469","DOI":"10.1021\/jp025597e","article-title":"Reactive Uptake of\nOzone by Aerosol-Associated Unsaturated\nFatty Acids: Kinetics, Mechanism, and Products","volume":"106","author":"Moise","year":"2002","journal-title":"J. Phys. Chem. A"},{"issue":"9","key":"2026081810411046100_cit45","doi-asserted-by":"publisher","first-page":"71","DOI":"10.1029\/2002GL014692","article-title":"Kinetics of\nsubmicron oleic acid aerosols with ozone: A novel aerosol mass spectrometric\ntechnique","volume":"29","author":"Morris","year":"2002","journal-title":"Geophys. Res. Lett."},{"issue":"45","key":"2026081810411046100_cit46","doi-asserted-by":"publisher","first-page":"10019","DOI":"10.1021\/jp0404145","article-title":"Kinetics and Product\nStudies for Ozonolysis Reactions\nof Organic Particles Using Aerosol CIMS","volume":"108","author":"Hearn","year":"2004","journal-title":"J.\nPhys. Chem. A"},{"key":"2026081810411046100_cit47","doi-asserted-by":"publisher","first-page":"469","DOI":"10.1039\/b417502f","article-title":"Aerosol\nproducts, mechanisms, and kinetics of heterogeneous reactions of ozone\nwith oleic acid in pure and mixed particles","volume":"130","author":"Ziemann","year":"2005","journal-title":"Faraday Discuss"},{"issue":"48","key":"2026081810411046100_cit48","doi-asserted-by":"publisher","first-page":"10910","DOI":"10.1021\/jp054714d","article-title":"Ozonolysis of Mixed Oleic-Acid\/Stearic-Acid Particles:\nReaction Kinetics and Chemical Morphology","volume":"109","author":"Katrib","year":"2005","journal-title":"J.\nPhys. Chem. A"},{"issue":"3","key":"2026081810411046100_cit49","doi-asserted-by":"publisher","first-page":"437","DOI":"10.1039\/C7EM00585G","article-title":"Criegee\nintermediates and their impacts on the troposphere","volume":"20","author":"Khan","year":"2018","journal-title":"Environ. Sci.: Processes Impacts"},{"issue":"17","key":"2026081810411046100_cit50","doi-asserted-by":"publisher","first-page":"5597","DOI":"10.1021\/ja00537a032","article-title":"Autoxidation of\npolyunsaturated lipids. Factors controlling the stereochemistry of\nproduct hydroperoxides","volume":"102","author":"Porter","year":"1980","journal-title":"J. Am. Chem. Soc."},{"issue":"2\u20134","key":"2026081810411046100_cit51","doi-asserted-by":"publisher","first-page":"87","DOI":"10.1016\/0009-3084(87)90046-6","article-title":"Cholesterol\nautoxidation 1981\u20131986","volume":"44","author":"Smith","year":"1987","journal-title":"Chem. Phys. Lipids"},{"issue":"13","key":"2026081810411046100_cit52","doi-asserted-by":"publisher","first-page":"2963","DOI":"10.1021\/j100404a035","article-title":"An electron spin\nresonance investigation\nof radical intermediates in cholesterol and related compounds: Relation\nto solid-state autoxidation","volume":"90","author":"Sevilla","year":"1986","journal-title":"J. Phys. Chem."},{"key":"2026081810411046100_cit53","doi-asserted-by":"publisher","first-page":"1377","DOI":"10.1139\/v74-209","article-title":"Product studies of the mutual termination reactions\nof sec-alkylperoxy radicals: Evidence for non-cyclic termination","volume":"52","author":"Bennett","year":"1974","journal-title":"Can. J. Chem."},{"key":"2026081810411046100_cit54","doi-asserted-by":"publisher","first-page":"3871","DOI":"10.1021\/ja01571a068","article-title":"Deuterium-isotope\neffects in the autoxidation of aralkyl hydrocarbons. mechanism of\nthe interaction of peroxy radicals1","volume":"79","author":"Russell","year":"1957","journal-title":"J. Am. Chem. Soc."},{"key":"2026081810411046100_cit55","doi-asserted-by":"publisher","first-page":"833","DOI":"10.1021\/acsearthspacechem.8b00069","article-title":"Criegee Intermediate Reactions with Carboxylic\nAcids: A Potential Source of Secondary Organic Aerosol in the Atmosphere","volume":"2","author":"Chhantyal-Pun","year":"2018","journal-title":"ACS Earth Space Chem."},{"issue":"2","key":"2026081810411046100_cit56","doi-asserted-by":"publisher","first-page":"99","DOI":"10.1002\/(SICI)1097-4601(1997)29:2&lt;99::AID-KIN3&gt;3.0.CO;2-F","article-title":"Atmospheric\nreactions of alkoxy and \u03b2-hydroxyalkoxy radicals","volume":"29","author":"Atkinson","year":"1997","journal-title":"Int. J. Chem. Kinet."},{"issue":"20","key":"2026081810411046100_cit57","doi-asserted-by":"publisher","first-page":"13397","DOI":"10.1039\/D3RA02069J","article-title":"Full-dimensional\nneural network potential energy surface and dynamics of the CH2OO + H2O reaction","volume":"13","author":"Wu","year":"2023","journal-title":"RSC Adv."},{"issue":"1","key":"2026081810411046100_cit58","doi-asserted-by":"publisher","first-page":"13","DOI":"10.1007\/s00214-018-2401-2","article-title":"Formation\nof OH radicals from the simplest Criegee intermediate CH2OO and water","volume":"138","author":"Wei","year":"2019","journal-title":"Theor. Chem. Acc."},{"issue":"27","key":"2026081810411046100_cit59","doi-asserted-by":"publisher","first-page":"11003","DOI":"10.1073\/pnas.1103045108","article-title":"Gas uptake\nand chemical aging of semisolid organic aerosol particles","volume":"108","author":"Shiraiwa","year":"2011","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2026081810411046100_cit60","doi-asserted-by":"publisher","first-page":"12467","DOI":"10.1021\/acs.est.9b04460","article-title":"Kinetics\nand condensed-phase products\nin multiphase ozonolysis of an unsaturated triglyceride","volume":"53","author":"Zhou","year":"2019","journal-title":"Environ. Sci. Technol."}],"container-title":["Environmental Science &amp;\nTechnology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.est.6c08123","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/32\/22813\/66354639\/acs.est.6c08123.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/32\/22813\/66354639\/acs.est.6c08123.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T16:36:05Z","timestamp":1787070965000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/esthag\/article\/60\/32\/22813\/5238333\/Evidence-for-Coupled-Autoxidation-of-Coexisting"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,2]]},"references-count":60,"journal-issue":{"issue":"32","published-online":{"date-parts":[[2026,8,2]]},"published-print":{"date-parts":[[2026,8,18]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.est.6c08123","relation":{},"ISSN":["0013-936X","1520-5851"],"issn-type":[{"value":"0013-936X","type":"print"},{"value":"1520-5851","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,2]]}}}