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Herein, we propose a nonradical high-valent metal-oxo (HVM)-driven oxidation during chlorite activation for decontamination. By constructing a series of transition metal (Fe, Co and Mn) atomic sites into a bipyridine-based covalent organic framework (Bpy-COF), the experiments and theoretical calculations unravel the intensified mechanism that this design confers an enhanced confined effect toward accelerating chlorite diffusion (1.64 \u00d7 10\u201311 m2 s\u20131) and mass transfer into spatial nanopore channels (22\u201336 \u00c5), further inducing a stronger molecular chlorite adsorption (Eads = \u22122.29 eV) upon Fe sites with a higher d-band center to facilitate Fe(IV)\u2550O generation. This atomic-level nanoconfinement simultaneously integrates a size-sieving effect to block large molecular NOMs in nanoreactors, synergistically causing anti-inference against high concentrations of Cl\u2013 and organic matrices. Consequently, Fe-Bpy-COF nanoreactors achieve efficient selective degradation of electron-enriched pollutants, especially kobs of sulfamethoxazole (SMX) degradation at 0.1442 min\u20131, exhibiting a robust resilience to hypersaline and realistic water conditions. This study highlights the pivotal role of the nanoscale COF reactor design and provides novel insights into HVM-mediated decontamination with anti-interference in practical hypersaline wastewater.<\/jats:p>","DOI":"10.1021\/acs.est.6c08762","type":"journal-article","created":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T08:32:21Z","timestamp":1785141141000},"page":"22044-22054","source":"Crossref","is-referenced-by-count":1,"title":["Enhanced Generation\nof Fe(IV)-Oxo Species via Chlorite\nActivation in Nanoconfined Covalent Organic Frameworks for Hypersaline\nWastewater Decontamination"],"prefix":"10.1021","volume":"60","author":[{"given":"Zhenxi","family":"Yuan","sequence":"first","affiliation":[{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Muke","family":"Lin","sequence":"additional","affiliation":[{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhuocheng","family":"Liang","sequence":"additional","affiliation":[{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhipeng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keyu","family":"Chen","sequence":"additional","affiliation":[{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rumeng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yimu","family":"Jiao","sequence":"additional","affiliation":[{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5997-0384","authenticated-orcid":true,"given":"Jingyun","family":"Fang","sequence":"additional","affiliation":[{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]},{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6016-358X","authenticated-orcid":true,"given":"Dehua","family":"Xia","sequence":"additional","affiliation":[{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]},{"name":"Sun Yat-sen University , , ,","place":["Guangzhou, China, 510275"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,27]]},"reference":[{"issue":"6","key":"2026081110081070500_cit1","doi-asserted-by":"publisher","first-page":"3064","DOI":"10.1021\/acs.est.9b07082","article-title":"Persulfate-Based Advanced Oxidation:\nCritical Assessment of Opportunities and Roadblocks","volume":"54","author":"Lee","year":"2020","journal-title":"Environ. 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